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High-Resolution Double-Quantum Deuterium Magic Angle Spinning Solid-State NMR Spectroscopy of Perdeuterated Proteins Vipin Agarwal, Katja Faelber, Peter Schmieder and Bernd Reif pp 2–3 DOI: 10.1021/ja803620r Supporting Info |
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Phenanthroline Decorated by a Crown Ether as a Module for Metallorganic−Polyoxometalate Hybrid Catalysts: The Wacker Type Oxidation of Alkenes with Nitrous Oxide as Terminal Oxidant Jessica Ettedgui and Ronny Neumann pp 4–5 DOI: 10.1021/ja808523n Supporting Info |
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Photoreactivity of As-Fabricated Au Clusters at the Single-Cluster Level Masanori Sakamoto, Takashi Tachikawa, Mamoru Fujitsuka and Tetsuro Majima pp 6–7 DOI: 10.1021/ja8043147 Supporting Info |
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Naphthalenedicarboximide- vs Perylenedicarboximide-Based Copolymers. Synthesis and Semiconducting Properties in Bottom-Gate N-Channel Organic Transistors Zhihua Chen, Yan Zheng, He Yan and Antonio Facchetti pp 8–9 DOI: 10.1021/ja805407g Supporting Info |
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Energy Transfer among Light-Harvesting Macrorings Incorporated into a Bilayer Membrane Naoto Nagata, Yusuke Kuramochi and Yoshiaki Kobuke pp 10–11 DOI: 10.1021/ja8045712 Supporting Info |
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In Situ Temperature-Jump Dynamic Nuclear Polarization: Enhanced Sensitivity in Two Dimensional 13C−13C Correlation Spectroscopy in Solution Chan-Gyu Joo, Andrew Casey, Christopher J. Turner and Robert G. Griffin pp 12–13 DOI: 10.1021/ja805521y |
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AcOLeDMAP and BnOLeDMAP: Conformationally Restricted Nucleophilic Catalysts for Enantioselective Rearrangement of Indolyl Acetates and Carbonates Trisha A. Duffey, Scott A. Shaw and Edwin Vedejs pp 14–15 DOI: 10.1021/ja805541u Supporting Info |
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Bicycle-Pedal Isomerization in a Rhodopsin Chromophore Model Igor Schapiro, Oliver Weingart and Volker Buss pp 16–17 DOI: 10.1021/ja805586z Supporting Info |
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Expanding the Fluorous Arsenal: Tetrafluorinated Phenylalanines for Protein Design Hong Zheng, Kristofer Comeforo and Jianmin Gao pp 18–19 DOI: 10.1021/ja8062309 Supporting Info |
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Anionic Oxidative Polymerization: The Synthesis of Poly(phenylenedicyanovinylene) (PPCN2V) Ryan M. Moslin, Trisha L. Andrew, Steven E. Kooi and Timothy M. Swager pp 20–21 DOI: 10.1021/ja808256n Supporting Info |
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Orthogonal Multi-Readout Identification of Alloy Nanowire Barcodes U. Korcan Demirok, Jared Burdick and Joseph Wang pp 22–23 DOI: 10.1021/ja806396h Supporting Info |
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Structure and Reactivity of Alkynyl Ruthenium Alkylidenes Sang Young Yun, Mansuk Kim, Daesung Lee and Donald J. Wink pp 24–25 DOI: 10.1021/ja806218x Supporting Info |
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Ultrafast Ligand Exchange: Detection of a Pentacoordinate Ru(II) Intermediate and Product Formation Yao Liu, David B. Turner, Tanya N. Singh, Alfredo M. Angeles-Boza, Abdellatif Chouai, Kim R. Dunbar and Claudia Turro pp 26–27 DOI: 10.1021/ja806860w Supporting Info |
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Chlorine Photoelimination from a Diplatinum Core: Circumventing the Back Reaction Timothy R. Cook, Yogesh Surendranath and Daniel G. Nocera pp 28–29 DOI: 10.1021/ja807222p Supporting Info |
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Fluorescence Quenching in a Perylenetetracarboxylic Diimide Trimer Yanfeng Wang, Hailong Chen, Haixia Wu, Xiyou Li and Yuxiang Weng pp 30–31 DOI: 10.1021/ja8072116 Supporting Info |
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Magnetic Observation of Anion Binding in Iron Coordination Complexes: Toward Spin-Switching Chemosensors Zhaoping Ni and Matthew P. Shores pp 32–33 DOI: 10.1021/ja807379a Supporting Info |
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By How Much is Protonated Benzene Stabilized by Coordination of Iron Tricarbonyl? Martin Galvin, J. Peter Guthrie, Claire M. McDonnell, Rory A. More O‘Ferrall and Sandrie Pelet pp 34–35 DOI: 10.1021/ja807259v Supporting Info |
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N−N Bond Cleavage in Diazoalkanes by a Bis(imino)pyridine Iron Complex Sarah K. Russell, Emil Lobkovsky and Paul J. Chirik pp 36–37 DOI: 10.1021/ja8075132 Supporting Info |
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N−CN Bond Cleavage of Cyanamides by a Transition-Metal Complex Kozo Fukumoto, Tsukuru Oya, Masumi Itazaki and Hiroshi Nakazawa pp 38–39 DOI: 10.1021/ja807896b Supporting Info |
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Potential Oxidative Stress of Gold Nanoparticles by Induced-NO Releasing in Serum Hong Ying Jia, Yang Liu, Xue Ji Zhang, Lu Han, Li Bo Du, Qiu Tian and Yuan Chao Xu pp 40–41 DOI: 10.1021/ja808033w Supporting Info |
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Hydrogen-Bonded Ferroelectrics Based on Metal−Organic Coordination Heng-Yun Ye, Da-Wei Fu, Yi Zhang, Wen Zhang, Ren-Gen Xiong and Songping D. Huang pp 42–43 DOI: 10.1021/ja808331g Supporting Info |
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Liquid Crystalline Corannulene Responsive to Electric Field Daigo Miyajima, Kentaro Tashiro, Fumito Araoka, Hideo Takezoe, Jungeun Kim, Kenichi Kato, Masaki Takata and Takuzo Aida pp 44–45 DOI: 10.1021/ja808396b Supporting Info |
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New Epitaxial Phase Transition between DG and HEX in PS-b-PI Hae-Woong Park, Jueun Jung, Taihyun Chang, Kazuyuki Matsunaga and Hiroshi Jinnai pp 46–47 DOI: 10.1021/ja808259m Supporting Info |
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Thinking Outside the Silicon Box: Molecular AND Logic As an Additional Layer of Selectivity in Singlet Oxygen Generation for Photodynamic Therapy Suriye Ozlem and Engin U. Akkaya pp 48–49 DOI: 10.1021/ja808389t Supporting Info |
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Activation of Carbon Nitride Solids by Protonation: Morphology Changes, Enhanced Ionic Conductivity, and Photoconduction Experiments Yuanjian Zhang, Arne Thomas, Markus Antonietti and Xinchen Wang pp 50–51 DOI: 10.1021/ja808329f Supporting Info |
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Reversible, Metal-Free, Heterolytic Activation of H2 at Room Temperature Matthias Ullrich, Alan J. Lough and Douglas W. Stephan pp 52–53 DOI: 10.1021/ja808506t Supporting Info |
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Axially Chiral Binaphthyl Surrogates with an Inner N−H−N Hydrogen Bond Takeo Kawabata, Changsheng Jiang, Kazuhiro Hayashi, Kazunori Tsubaki, Tomoyuki Yoshimura, Swapan Majumdar, Takahiro Sasamori and Norihiro Tokitoh pp 54–55 DOI: 10.1021/ja808213r Supporting Info |
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Development of New Semiconducting Polymers for High Performance Solar Cells Yongye Liang, Yue Wu, Danqin Feng, Szu-Ting Tsai, Hae-Jung Son, Gang Li and Luping Yu pp 56–57 DOI: 10.1021/ja808373p Supporting Info |
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Inversion of Configuration at the Metal in Diastereomeric Imido Alkylidene Monoaryloxide Monopyrrolide Complexes of Molybdenum Smaranda C. Marinescu, Richard R. Schrock, Bo Li and Amir H. Hoveyda pp 58–59 DOI: 10.1021/ja808308e Supporting Info |
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Lewis Acidity Enhancement of Triarylboranes via Peripheral Decoration with Cationic Groups Ching-Wen Chiu, Youngmin Kim and Fran pp 60–61 DOI: 10.1021/ja808572t Supporting Info |
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Chirality-Dependent Transport Properties of Double-Walled Nanotubes Measured in Situ on Their Field-Effect Transistors Kaihui Liu, Wenlong Wang, Zhi Xu, Xuedong Bai, Enge Wang, Yagang Yao, Jin Zhang and Zhongfan Liu pp 62–63 DOI: 10.1021/ja808593v Supporting Info |
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Redox-Regulated Ethylene Binding to a Rhenium-Thiolate Complex Craig A. Grapperhaus, Kagna Ouch and Mark S. Mashuta pp 64–65 DOI: 10.1021/ja8086483 Supporting Info |
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Targeted Paclitaxel by Conjugation to Iron Oxide and Gold Nanoparticles Jih Ru Hwu, Yu Sern Lin, Thainashmuthu Josephrajan, Ming-Hua Hsu, Fong-Yu Cheng, Chen-Sheng Yeh, Wu-Chou Su and Dar-Bin Shieh pp 66–68 DOI: 10.1021/ja804947u Supporting Info |
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Dynamic Intracomplex Heterogeneity of Phytochrome Jana B. Nieder, Marc Brecht and Robert Bittl pp 69–71 DOI: 10.1021/ja8058292 |
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The Binary Silver Nitrogen Anion [Ag(N3)2]− Thomas M. Klapötke, Burkhard Krumm and Matthias Scherr pp 72–74 DOI: 10.1021/ja8077544 Supporting Info |
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Strong Second Harmonic Generation from the Tantalum Thioarsenates A3Ta2AsS11 (A = K and Rb) Tarun K. Bera, Joon I. Jang, John B. Ketterson and Mercouri G. Kanatzidis pp 75–77 DOI: 10.1021/ja807928d Supporting Info |
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Mechanistic Studies on the Copper-Catalyzed N-Arylation of Amides Eric R. Strieter, Brijesh Bhayana and Stephen L. Buchwald pp 78–88 DOI: 10.1021/ja0781893 Supporting Info |
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Electronic Structure of DNA - Unique Properties of 8-Oxoguanosine Tal Z. Markus, Shirley S. Daube, Ron Naaman, Aaron M. Fleming, James G. Muller and Cynthia J. Burrows pp 89–95 DOI: 10.1021/ja804177j Supporting Info |
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Raman Study of Chromophore States in Photochromic Fluorescent Proteins Stefano Luin, Valerio Voliani, Giacomo Lanza, Ranieri Bizzarri, Riccardo Nifosì, Pietro Amat, Valentina Tozzini, Michela Serresi and Fabio Beltram pp 96–103 DOI: 10.1021/ja804504b Supporting Info |
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Multistate Photo-Induced Relaxation and Photoisomerization Ability of Fumaramide Threads: A Computational and Experimental Study Piero Alto pp 104–117 DOI: 10.1021/ja802531j Supporting Info |
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Observation of a Low-Temperature, Dynamically Driven Structural Transition in a Polypeptide by Solid-State NMR Spectroscopy Vikram S. Bajaj, Patrick C.A. van der Wel and Robert G. Griffin pp 118–128 DOI: 10.1021/ja8045926 Supporting Info |
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The Diels−Alder Reaction on Endohedral Y3N@C78: The Importance of the Fullerene Strain Energy S pp 129–139 DOI: 10.1021/ja8048783 Supporting Info |
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Fast Amide Proton Exchange Reveals Close Relation between Native-State Dynamics and Unfolding Kinetics Hagen Hofmann, Ulrich Weininger, Christian L pp 140–146 DOI: 10.1021/ja8048942 Supporting Info |
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Mechanistic Insight into the Role of Transition-State Stabilization in Cyclophilin A Donald Hamelberg and J. Andrew McCammon pp 147–152 DOI: 10.1021/ja806146g |
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Surface Engineering Using Kumada Catalyst-Transfer Polycondensation (KCTP): Preparation and Structuring of Poly(3-hexylthiophene)-Based Graft Copolymer Brushes Natalya Khanduyeva, Volodymyr Senkovskyy, Tetyana Beryozkina, Marta Horecha, Manfred Stamm, Christian Uhrich, Moritz Riede, Karl Leo and Anton Kiriy pp 153–161 DOI: 10.1021/ja8050734 Supporting Info |
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Rapid, Solution-Based Characterization of Optimized SERS Nanoparticle Substrates Ted A. Laurence, Gary Braun, Chad Talley, Adam Schwartzberg, Martin Moskovits, Norbert Reich and Thomas Huser pp 162–169 DOI: 10.1021/ja806236k Supporting Info |
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Structural Rearrangements of Membrane Proteins Probed by Water-Edited Solid-State NMR Spectroscopy Christian Ader, Robert Schneider, Karsten Seidel, Manuel Etzkorn, Stefan Becker and Marc Baldus pp 170–176 DOI: 10.1021/ja806306e Supporting Info |
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Electrochemistry of Oxygen in Concentrated NaOH Solutions: Solubility, Diffusion Coefficients, and Superoxide Formation Cunzhong Zhang, Fu-Ren F. Fan and Allen J. Bard pp 177–181 DOI: 10.1021/ja8064254 |
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Magnetic Permanently Confined Micelle Arrays for Treating Hydrophobic Organic Compound Contamination Peng Wang, Qihui Shi, Yifeng Shi, Kristin K. Clark, Galen D. Stucky and Arturo A. Keller pp 182–188 DOI: 10.1021/ja806556a Supporting Info |
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Measuring Aromaticity with the Dimethyldihydropyrene Ring Current Probe. Experimental and Computational Studies of the Fulvenes and the Strongly Antiaromatic Cyclopentadienone Reveal Large Mills−Nixon-Type Bond Localization Effects. Synthesis of Fulvene-Fused Dihydropyrenes Reginald H. Mitchell, Rui Zhang, David J. Berg, Brendan Twamley and Richard Vaughan Williams pp 189–199 DOI: 10.1021/ja806427n Supporting Info |
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Structure of the Nucleotide Radical Formed during Reaction of CDP/TTP with the E441Q-α2β2 of E. coli Ribonucleotide Reductase Hendrik Zipse, Erin Artin, Stanislaw Wnuk, Gregory J. S. Lohman, Debora Martino, Robert G. Griffin, Sylwia Kacprzak, Martin Kaupp, Brian Hoffman, Marina Bennati, JoAnne Stubbe and Nicholas Lees pp 200–211 DOI: 10.1021/ja806693s Supporting Info |
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Control of Charge Transfer Phase Transition and Ferromagnetism by Photoisomerization of Spiropyran for an Organic−Inorganic Hybrid System, (SP)[FeIIFeIII(dto)3] (SP = spiropyran, dto = C2O2S2) Noriyuki Kida, Masanori Hikita, Izuru Kashima, Masashi Okubo, Miho Itoi, Masaya Enomoto, Kenichi Kato, Masaki Takata and Norimichi Kojima pp 212–220 DOI: 10.1021/ja806879a |
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CaFeO2: A New Type of Layered Structure with Iron in a Distorted Square Planar Coordination C pp 221–229 DOI: 10.1021/ja8072269 |
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First-Principles Prediction of Thermodynamically Reversible Hydrogen Storage Reactions in the Li-Mg-Ca-B-H System V. Ozolins, E. H. Majzoub and C. Wolverton pp 230–237 DOI: 10.1021/ja8066429 Supporting Info |
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A Predicted Organometallic Series Following a 32-Electron Principle: An@C28 (An = Th, Pa+, U2+, Pu4+) Jean-Pierre Dognon, Carine Clavagu pp 238–243 DOI: 10.1021/ja806811p |
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Protein Conformational Transitions: The Closure Mechanism of a Kinase Explored by Atomistic Simulations Anna Berteotti, Andrea Cavalli, Davide Branduardi, Francesco Luigi Gervasio, Maurizio Recanatini and Michele Parrinello pp 244–250 DOI: 10.1021/ja806846q Supporting Info |
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2-Iodoxybenzenesulfonic Acid as an Extremely Active Catalyst for the Selective Oxidation of Alcohols to Aldehydes, Ketones, Carboxylic Acids, and Enones with Oxone Muhammet Uyanik, Matsujiro Akakura and Kazuaki Ishihara pp 251–262 DOI: 10.1021/ja807110n Supporting Info |
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Intramolecular Hydroalkoxylation/Cyclization of Alkynyl Alcohols Mediated by Lanthanide Catalysts. Scope and Reaction Mechanism SungYong Seo, Xianghua Yu and Tobin J. Marks pp 263–276 DOI: 10.1021/ja8072462 Supporting Info |
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Spectroscopic and Computational Studies of Nitrite Reductase: Proton Induced Electron Transfer and Backbonding Contributions to Reactivity Somdatta Ghosh, Abhishek Dey, Yan Sun, Charles P. Scholes and Edward I. Solomon pp 277–288 DOI: 10.1021/ja806873e Supporting Info |
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Phospholipid−Dextran with a Single Coupling Point: A Useful Amphiphile for Functionalization of Nanomaterials Andrew P. Goodwin, Scott M. Tabakman, Kevin Welsher, Sarah P. Sherlock, Giuseppe Prencipe and Hongjie Dai pp 289–296 DOI: 10.1021/ja807307e Supporting Info |
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The Second Step of the Nitric Oxide Synthase Reaction: Evidence for Ferric-Peroxo as the Active Oxidant Joshua J. Woodward, Michelle M. Chang, Nathaniel I. Martin and Michael A. Marletta pp 297–305 DOI: 10.1021/ja807299t Supporting Info |
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Metal Template Controlled Formation of [11]ane-P2CNHC Macrocycles Oliver Kaufhold, Andreas Stasch, Tania Pape, Alexander Hepp, Peter G. Edwards, Paul D. Newman and F. Ekkehardt Hahn pp 306–317 DOI: 10.1021/ja807333f Supporting Info |
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Equilibrium Electrostatics of Responsive Polyelectrolyte Monolayers Kang Wang, Rebecca A. Zangmeister and Rastislav Levicky pp 318–326 DOI: 10.1021/ja807435q Supporting Info |
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Reduction-Controlled Viologen in Bisolvent as an Environmentally Stable n-Type Dopant for Carbon Nanotubes Soo Min Kim, Jin Ho Jang, Ki Kang Kim, Hyeon Ki Park, Jung Jun Bae, Woo Jong Yu, Il Ha Lee, Gunn Kim, Duong Dinh Loc, Un Jeong Kim, Eun-Hong Lee, Hyeon-Jin Shin, Jae-Young Choi and Young Hee Lee pp 327–331 DOI: 10.1021/ja807480g Supporting Info |
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Singlet Oxygen in a Cell: Spatially Dependent Lifetimes and Quenching Rate Constants Marina K. Kuimova, Gokhan Yahioglu and Peter R. Ogilby pp 332–340 DOI: 10.1021/ja807484b |
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NMR Characterization of Fourth-Generation PAMAM Dendrimers in the Presence and Absence of Palladium Dendrimer-Encapsulated Nanoparticles M. Victoria Gomez, Javier Guerra, Aldrik H. Velders and Richard M. Crooks pp 341–350 DOI: 10.1021/ja807488d Supporting Info |
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Photochemical Generation and Reversible Cycloaromatization of a Nine-Membered Ring Cyclic Enediyne Dinesh R. Pandithavidana, Andrei Poloukhtine and Vladimir V. Popik pp 351–356 DOI: 10.1021/ja8077076 Supporting Info |
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Photoswitchable Catalysts: Correlating Structure and Conformational Dynamics with Reactivity by a Combined Experimental and Computational Approach Ragnar S. Stoll, Maike V. Peters, Andreas Kuhn, Sven Heiles, Richard Goddard, Michael B pp 357–367 DOI: 10.1021/ja807694s Supporting Info |
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Dissociative Solvolytic Cleavage of Methyl (ortho-Carboxymethyl)Aryl Phosphate Diesters Mediated by Yb3+ in Methanol Gives a 1012-Fold Rate Acceleration Attributable to Leaving Group Assistance David R. Edwards, Alexei A. Neverov and R. Stan Brown pp 368–377 DOI: 10.1021/ja807984f Supporting Info |
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Identification of a New Endogenous Metabolite and the Characterization of Its Protein Interactions through an Immobilization Approach Jarosław Kalisiak, Sunia A. Trauger, Ewa Kalisiak, Hirotoshi Morita, Valery V. Fokin, Mike W. W. Adams, K. Barry Sharpless and Gary Siuzdak pp 378–386 DOI: 10.1021/ja808172n Supporting Info |
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Factors Relevant for the Regioselective Cyclopolymerization of 1,6-Heptadiynes, N,N-Dipropargylamines, N,N-Dipropargylammonium Salts, and Dipropargyl Ethers by RuIV−Alkylidene-Based Metathesis Initiators P. Santhosh Kumar, K. Wurst and Michael R. Buchmeiser pp 387–395 DOI: 10.1021/ja804563t Supporting Info |
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New Strategy for Quantifying Biological Zinc by a Modified Zinpyr Fluorescence Sensor Xiao-an Zhang, Dugan Hayes, Sarah J. Smith, Simone Friedle and Stephen J. Lippard p 396 DOI: 10.1021/ja809574f |
Issue 02
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Traversing the “Top-Down/Bottom-Up” Divide: Molecular-Scale Lithography of Self-Assembled Ribbons Jonas Jarvholm, Mohan Srinivasarao and Laren M. Tolbert pp 398–399 DOI: 10.1021/ja805319k Supporting Info |
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Charge Recombination in DNA Hairpins Controlled by Counterions Gail S. Blaustein, Brittany Demas, Frederick D. Lewis and Alexander L. Burin pp 400–401 DOI: 10.1021/ja805589r Supporting Info |
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C−H Bond Functionalization via Hydride Transfer: Lewis Acid Catalyzed Alkylation Reactions by Direct Intramolecular Coupling of sp3 C−H Bonds and Reactive Alkenyl Oxocarbenium Intermediates Kevin M. McQuaid and Dalibor Sames pp 402–403 DOI: 10.1021/ja806068h Supporting Info |
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Consequences of a Linear Two-Coordinate Geometry for the Orbital Magnetism and Jahn−Teller Distortion Behavior of the High Spin Iron(II) Complex Fe[N(t-Bu)2]2 William M. Reiff, Charles E. Schulz, Myung-Hwan Whangbo, Jung In Seo, Yoon Sup Lee, Gregory R. Potratz, Charles W. Spicer and Gregory S. Girolami pp 404–405 DOI: 10.1021/ja806660f Supporting Info |
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Well-Defined, Multifunctional Nanostructures of a Paramagnetic Lipid and a Lipopeptide for Macrophage Imaging Esad Vucic, Honorius M. H. F. Sanders, Francesca Arena, Enzo Terreno, Silvio Aime, Klaas Nicolay, Eik Leupold, Margitta Dathe, Nico A. J. M. Sommerdijk, Zahi A. Fayad and Willem J. M. Mulder pp 406–407 DOI: 10.1021/ja808310u Supporting Info |
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Anisotropic Electron Transport Properties in Sumanene Crystal Toru Amaya, Shu Seki, Toshiyuki Moriuchi, Kana Nakamoto, Takuto Nakata, Hiroyuki Sakane, Akinori Saeki, Seiichi Tagawa and Toshikazu Hirao pp 408–409 DOI: 10.1021/ja805997v Supporting Info |
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Prediction of Enantioselectivity in Rhodium Catalyzed Hydrogenations Patrick J. Donoghue, Paul Helquist, Per-Ola Norrby and Olaf Wiest pp 410–411 DOI: 10.1021/ja806246h Supporting Info |
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Catalytic Carbon−Carbon σ Bond Activation: An Intramolecular Carbo-Acylation Reaction with Acylquinolines Ashley M. Dreis and Christopher J. Douglas pp 412–413 DOI: 10.1021/ja8066308 Supporting Info |
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Design of Silica Networks for Development of Highly Permeable Hydrogen Separation Membranes with Hydrothermal Stability Masakoto Kanezashi, Kazuya Yada, Tomohisa Yoshioka and Toshinori Tsuru pp 414–415 DOI: 10.1021/ja806762q Supporting Info |
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Bending a Bond within an Individual Adsorbed Molecule Violeta Simic-Milosevic and Karina Morgenstern pp 416–417 DOI: 10.1021/ja805571b |
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Catalytic Asymmetric Conjugate Addition of Simple Alkyl Thiols to α,β-Unsaturated N-Acylated Oxazolidin-2-ones with Bifunctional Catalysts Yan Liu, Bingfeng Sun, Baomin Wang, Matthew Wakem and Li Deng pp 418–419 DOI: 10.1021/ja8085092 Supporting Info |
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Ruthenium-Catalyzed Cross-Coupling of Tertiary Propargyl Alcohols with ω-Alkynenitriles: A Regio- and Stereoselective Surrogate for an Aldol Condensation Barry M. Trost, Nuno Maulide and Michael T. Rudd pp 420–421 DOI: 10.1021/ja8077686 Supporting Info |
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Insertion Polymerization of Acrylate Damien Guironnet, Philipp Roesle, Thomas R pp 422–423 DOI: 10.1021/ja808017n Supporting Info |
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ZnO-Templated Synthesis of Wurtzite-Type ZnS and ZnSe Nanoparticles Farah Dawood and Raymond E. Schaak pp 424–425 DOI: 10.1021/ja808455u Supporting Info |
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What Makes the Difference between a Cryptochrome and DNA Photolyase? A Spectroelectrochemical Comparison of the Flavin Redox Transitions V pp 426–427 DOI: 10.1021/ja806540j Supporting Info |
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Aerobic Oxidation of Pinacol by Vanadium(V) Dipicolinate Complexes: Evidence for Reduction to Vanadium(III) Susan K. Hanson, R. Tom Baker, John C. Gordon, Brian L. Scott, Andrew D. Sutton and David L. Thorn pp 428–429 DOI: 10.1021/ja807522n Supporting Info |
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Drug Pressure Selected Mutations in HIV-1 Protease Alter Flap Conformations Luis Galiano, Fangyu Ding, Angelo M. Veloro, Mandy E. Blackburn, Carlos Simmerling and Gail E. Fanucci pp 430–431 DOI: 10.1021/ja807531v Supporting Info |
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Cucurbit[n]uril−Polyoxoanion Hybrids Xikui Fang, Paul K pp 432–433 DOI: 10.1021/ja807751b Supporting Info |
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A Highly Selective Luminescent Sensor for the Time-Gated Detection of Potassium Aurore Thibon and Val pp 434–435 DOI: 10.1021/ja8077889 Supporting Info |
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Attomolar Protein Detection Using in-Hole Surface Plasmon Resonance Jacqueline Ferreira, Marcos J. L. Santos, Mohammad M. Rahman, Alexandre G. Brolo, Reuven Gordon, David Sinton and Emerson M. Girotto pp 436–437 DOI: 10.1021/ja807704v Supporting Info |
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Selective Recognition of Protein Tetraserine Motifs with a Cell-Permeable, Pro-fluorescent Bis-boronic Acid Tiffany L. Halo, Jacob Appelbaum, Elissa M. Hobert, Daniel M. Balkin and Alanna Schepartz pp 438–439 DOI: 10.1021/ja807872s Supporting Info |
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Synthesis and Spectroscopic Identification of a μ-1,2-Disulfidodinickel Complex Matthew T. Kieber-Emmons, Katherine M. Van Heuvelen, Thomas C. Brunold and Charles G. Riordan pp 440–441 DOI: 10.1021/ja807735a Supporting Info |
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Mounting Freestanding Molecular Functions onto Surfaces: The Platform Approach Belinda Baisch, Diego Raffa, Ulrich Jung, Olaf M. Magnussen, Cyril Nicolas, Jerome Lacour, Jens Kubitschke and Rainer Herges pp 442–443 DOI: 10.1021/ja807923f Supporting Info |
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Reagent-Controlled Regiodivergent Resolution of Unsymmetrical Oxabicyclic Alkenes Using a Cationic Rhodium Catalyst Robert Webster, Christian B pp 444–445 DOI: 10.1021/ja807942m Supporting Info |
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Two-Electron Reduction of a Vanadium(V) Nitride by CO To Release Cyanate and Open a Coordination Site Jared S. Silvia and Christopher C. Cummins pp 446–447 DOI: 10.1021/ja807767w Supporting Info |
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[(NHC)AuI]-Catalyzed Acid-Free Alkyne Hydration at Part-per-Million Catalyst Loadings Nicolas Marion, Rub pp 448–449 DOI: 10.1021/ja809403e Supporting Info |
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Heme-Copper Assembly Mediated Reductive Coupling of Nitrogen Monoxide (·NO) Jun Wang, Mark P. Schopfer, Amy A. N. Sarjeant and Kenneth D. Karlin pp 450–451 DOI: 10.1021/ja8084324 Supporting Info |
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Total Synthesis of (−)-Penifulvin A, an Insecticide with a Dioxafenestrane Skeleton Tanja Gaich and Johann Mulzer pp 452–453 DOI: 10.1021/ja8083048 Supporting Info |
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Synthesis of Uniform Ferrimagnetic Magnetite Nanocubes Dokyoon Kim, Nohyun Lee, Mihyun Park, Byung Hyo Kim, Kwangjin An and Taeghwan Hyeon pp 454–455 DOI: 10.1021/ja8086906 Supporting Info |
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A Single Antibody Catalyzes Multiple Chemical Transformations upon Replacement of the Functionalized Small Nonprotein Components Fumihiro Ishikawa, Takeshi Tsumuraya and Ikuo Fujii pp 456–457 DOI: 10.1021/ja808792x Supporting Info |
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Supercritical Processing as a Route to High Internal Surface Areas and Permanent Microporosity in Metal−Organic Framework Materials Andrew P. Nelson, Omar K. Farha, Karen L. Mulfort and Joseph T. Hupp pp 458–460 DOI: 10.1021/ja808853q Supporting Info |
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Specific Microsolvation Triggers Dissociation-Mediated Anomalous Red-Shifted Fluorescence in the Gas Phase Maxim Zakharov, Oliver Krauss, Yevgeniy Nosenko, Bernhard Brutschy and Andreas Dreuw pp 461–469 DOI: 10.1021/ja800528p Supporting Info |
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Investigation of the Internal Heterostructure of Highly Luminescent Quantum Dot−Quantum Well Nanocrystals Pralay K. Santra, Ranjani Viswanatha, Steve M. Daniels, Nigel L. Pickett, Jason M. Smith, Paul O’Brien and D. D. Sarma pp 470–477 DOI: 10.1021/ja8033075 Supporting Info |
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Comparative Gas Sensing in Cobalt, Nickel, Copper, Zinc, and Metal-Free Phthalocyanine Chemiresistors Forest I. Bohrer, Corneliu N. Colesniuc, Jeongwon Park, Manuel E. Ruidiaz, Ivan K. Schuller, Andrew C. Kummel and William C. Trogler pp 478–485 DOI: 10.1021/ja803531r Supporting Info |
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Cationic Amphiphiles Increase Activity of Aminoglycoside Antibiotic Tobramycin in the Presence of Airway Polyelectrolytes Kirstin R. Purdy Drew, Lori K. Sanders, Zachary W. Culumber, Olena Zribi and Gerard C. L. Wong pp 486–493 DOI: 10.1021/ja803925n |
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Nanosecond Time-Dependent Stokes Shift at the Tunnel Mouth of Haloalkane Dehalogenases Andrea Jesensk pp 494–501 DOI: 10.1021/ja804020q Supporting Info |
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Time-Resolved X-ray Scattering of an Electronically Excited State in Solution. Structure of the 3A2u State of Tetrakis-μ-pyrophosphitodiplatinate(II) Morten Christensen, Kristoffer Haldrup, Klaus Bechgaard, Robert Feidenhans’l, Qingyu Kong, Marco Cammarata, Manuela Lo Russo, Michael Wulff, Niels Harrit and Martin Meedom Nielsen pp 502–508 DOI: 10.1021/ja804485d Supporting Info |
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Engineering of Supramolecular H-Bonded Nanopolygons via Self-Assembly of Programmed Molecular Modules Anna Llanes-Pallas, Carlos-Andres Palma, Luc Piot, Abdelhalim Belbakra, Andrea Listorti, Maurizio Prato, Paolo Samor pp 509–520 DOI: 10.1021/ja807530m Supporting Info |
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Positioning Multiple Proteins at the Nanoscale with Electron Beam Cross-Linked Functional Polymers Karen L. Christman, Eric Schopf, Rebecca M. Broyer, Ronald C. Li, Yong Chen and Heather D. Maynard pp 521–527 DOI: 10.1021/ja804767j Supporting Info |
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Multiphoton Infrared Initiated Thermal Reactions of Esters: Pseudopericyclic Eight-Centered cis-Elimination Hua Ji, Li Li, Xiaolian Xu, Sihyun Ham, Loubna A. Hammad and David M. Birney* pp 528–537 DOI: 10.1021/ja804812c Supporting Info |
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Control and Manipulation of Gold Nanocatalysis: Effects of Metal Oxide Support Thickness and Composition Chris Harding, Vahideh Habibpour, Sebastian Kunz, Adrian Nam-Su Farnbacher, Ueli Heiz, Bokwon Yoon and Uzi Landman pp 538–548 DOI: 10.1021/ja804893b Supporting Info |
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Iron Nanoparticle Growth in Organic Superstructures Lise-Marie Lacroix, S pp 549–557 DOI: 10.1021/ja805719c Supporting Info |
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Electron Transport and Recombination in Solid-State Dye Solar Cell with Spiro-OMeTAD as Hole Conductor Francisco Fabregat-Santiago, Juan Bisquert, Le Cevey, Peter Chen, Mingkui Wang, Shaik M. Zakeeruddin and Michael Gr pp 558–562 DOI: 10.1021/ja805850q |
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Cryptophane Xenon-129 Nuclear Magnetic Resonance Biosensors Targeting Human Carbonic Anhydrase Jennifer M. Chambers, P. Aru Hill, Julie A. Aaron, Zhaohui Han, David W. Christianson, Nicholas N. Kuzma and Ivan J. Dmochowski pp 563–569 DOI: 10.1021/ja806092w Supporting Info |
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Ag-Catalyzed Diastereo- and Enantioselective Vinylogous Mannich Reactions of α-Ketoimine Esters. Development of a Method and Investigation of its Mechanism Laura C. Wieland, Erika M. Vieira, Marc L. Snapper and Amir H. Hoveyda pp 570–576 DOI: 10.1021/ja8062315 Supporting Info |
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Reorganization Energies of Diprotonated and Saddle-Distorted Porphyrins in Photoinduced Electron-Transfer Reduction Controlled by Conformational Distortion Tatsuaki Nakanishi, Kei Ohkubo, Takahiko Kojima and Shunichi Fukuzumi pp 577–584 DOI: 10.1021/ja806261q Supporting Info |
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The Carbon Dioxide−Water Interface at Conditions of Gas Hydrate Formation Felix Lehmk pp 585–589 DOI: 10.1021/ja806211r |
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Giant Dendritic Molecular Electrochrome Batteries with Ferrocenyl and Pentamethylferrocenyl Termini Catia Ornelas, Jaime Ruiz, Colette Belin and Didier Astruc pp 590–601 DOI: 10.1021/ja8062343 Supporting Info |
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Activating Pd by Morphology Tailoring for Oxygen Reduction Li Xiao, Lin Zhuang, Yi Liu, Juntao Lu and H pp 602–608 DOI: 10.1021/ja8063765 Supporting Info |
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Anion-Controlled Pore Size of Titanium Silicate Molecular Sieves Christopher C. H. Lin, James A. Sawada, Lan Wu, Tony Haastrup and Steven M. Kuznicki pp 609–614 DOI: 10.1021/ja806114z |
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Protein Side-Chain Dynamics and Residual Conformational Entropy Nikola Trbovic, Jae-Hyun Cho, Robert Abel, Richard A. Friesner, Mark Rance and Arthur G. Palmer, III pp 615–622 DOI: 10.1021/ja806475k Supporting Info |
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Synthesis, Photophysical Behavior, and Electronic Structure of Push−Pull Purines Roslyn S. Butler, Pamela Cohn, Phillip Tenzel, Khalil A. Abboud and Ronald K. Castellano pp 623–633 DOI: 10.1021/ja806348z Supporting Info |
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Weak Interactions Dominating the Supramolecular Self-Assembly in a Salt: A Designed Single-Crystal-to-Single-Crystal Topochemical Polymerization of a Terminal Aryldiacetylene Zhong Li, Frank W. Fowler and Joseph W. Lauher pp 634–643 DOI: 10.1021/ja806663h Supporting Info |
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Mesoscopic Donor−Acceptor Multilayer by Ultrahigh-Vacuum Codeposition of Zn-Tetraphenyl-Porphyrin and C70 Paolo Vilmercati, Carla Castellarin-Cudia, Ralph Gebauer, Prasenjit Ghosh, Silvano Lizzit, Luca Petaccia, Cinzia Cepek, Rosanna Larciprete, Alberto Verdini, Luca Floreano, Alberto Morgante and Andrea Goldoni pp 644–652 DOI: 10.1021/ja806914g Supporting Info |
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On the Mechanism of Nitrosoarene−Alkyne Cycloaddition Andrea Penoni, Giovanni Palmisano, Yi-Lei Zhao, Kendall N. Houk, Jerome Volkman and Kenneth M. Nicholas pp 653–661 DOI: 10.1021/ja806715u Supporting Info |
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Activation and Tuning of Green Fluorescent Protein Chromophore Emission by Alkyl Substituent-Mediated Crystal Packing Jian Dong, Kyril M. Solntsev and Laren M. Tolbert pp 662–670 DOI: 10.1021/ja806962e Supporting Info |
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Layer-by-Layer Assembly of All Carbon Nanotube Ultrathin Films for Electrochemical Applications Seung Woo Lee, Byeong-Su Kim, Shuo Chen, Yang Shao-Horn and Paula T. Hammond pp 671–679 DOI: 10.1021/ja807059k Supporting Info |
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Tuning the Electronic and Molecular Structures of Catalytic Active Sites with Titania Nanoligands Elizabeth I. Ross-Medgaarden, Israel E. Wachs, William V. Knowles, Andrew Burrows, Christopher J. Kiely and Michael S. Wong pp 680–687 DOI: 10.1021/ja711456c |
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Transition States and Nonlinear Excitations in Chloroform Observed with a Sub-5 fs Pulse Laser Izumi Iwakura, Atsushi Yabushita and Takayoshi Kobayashi pp 688–696 DOI: 10.1021/ja801829n Supporting Info |
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Selective Synthesis of Single-Crystalline Rhombic Dodecahedral, Octahedral, and Cubic Gold Nanocrystals Wenxin Niu, Shanliang Zheng, Dawei Wang, Xiaoqing Liu, Haijuan Li, Shuang Han, Jiuan Chen, Zhiyong Tang and Guobao Xu pp 697–703 DOI: 10.1021/ja804115r Supporting Info |
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Nucleophilicity Parameters for Phosphoryl-Stabilized Carbanions and Phosphorus Ylides: Implications for Wittig and Related Olefination Reactions Roland Appel, Robert Loos and Herbert Mayr pp 704–714 DOI: 10.1021/ja8056216 Supporting Info |
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Light-Induced Excited Spin State Trapping: Ab Initio Study of the Physics at the Molecular Level Nicolas Suaud, Marie-Laure Bonnet, Corentin Boilleau, Pierre Lab pp 715–722 DOI: 10.1021/ja805626s Supporting Info |
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Nanoengineered Carbon Scaffolds for Hydrogen Storage Ashley D. Leonard, Jared L. Hudson, Hua Fan, Richard Booker, Lin J. Simpson, Kevin J. O’Neill, Philip A. Parilla, Michael J. Heben, Matteo Pasquali, Carter Kittrell and James M. Tour pp 723–728 DOI: 10.1021/ja806633p |
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Rhodium-Catalyzed Direct Oxidative Carbonylation of Aromatic C−H Bond with CO and Alcohols Zheng-Hui Guan, Zhi-Hui Ren, Stephen M. Spinella, Shichao Yu, Yong-Min Liang and Xumu Zhang pp 729–733 DOI: 10.1021/ja807167y Supporting Info |
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Surface Functionalization of Nanomaterials with Dendritic Groups: Toward Enhanced Binding to Biological Targets Amanda L. Martin, Bo Li and Elizabeth R. Gillies pp 734–741 DOI: 10.1021/ja807220u Supporting Info |
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Vertical Alignment of Carbon Nanotubes Using the Magneto-Evaporation Method Sang Cheon Youn, Dae-Hwan Jung, Young Koan Ko, Yong Wan Jin, Jong Min Kim and Hee-Tae Jung pp 742–748 DOI: 10.1021/ja8073209 Supporting Info |
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Anatomy of a Simple Acyl Intermediate in Enzyme Catalysis: Combined Biophysical and Modeling Studies on Ornithine Acetyl Transferase Aman Iqbal, Ian J. Clifton, Maria Bagonis, Nadia J. Kershaw, Carmen Domene, Timothy D. W. Claridge, Christopher W. Wharton and Christopher J. Schofield pp 749–757 DOI: 10.1021/ja807215u Supporting Info |
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Single Nanowire on a Film as an Efficient SERS-Active Platform Ilsun Yoon, Taejoon Kang, Wonjun Choi, Jangbae Kim, Youngdong Yoo, Sang-Woo Joo, Q-Han Park, Hyotcherl Ihee and Bongsoo Kim pp 758–762 DOI: 10.1021/ja807455s Supporting Info |
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Hydroxynaphthyridine-Derived Group III Metal Chelates: Wide Band Gap and Deep Blue Analogues of Green Alq3 (Tris(8-hydroxyquinolate)aluminum) and Their Versatile Applications for Organic Light-Emitting Diodes Szu-Hung Liao, Jin-Ruei Shiu, Shun-Wei Liu, Shi-Jay Yeh, Yu-Hung Chen, Chin-Ti Chen, Tahsin J. Chow and Chih-I Wu pp 763–777 DOI: 10.1021/ja807284e Supporting Info |
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Impaired Acid Catalysis by Mutation of a Protein Loop Hinge Residue in a YopH Mutant Revealed by Crystal Structures Tiago A. S. Brand pp 778–786 DOI: 10.1021/ja807418b Supporting Info |
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Creating Conformational Entropy by Increasing Interdomain Mobility in Ligand Binding Regulation: A Revisit to N-Terminal Tandem PDZ Domains of PSD-95 Wenning Wang, Jingwei Weng, Xu Zhang, Maili Liu and Mingjie Zhang pp 787–796 DOI: 10.1021/ja8076022 Supporting Info |
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Microcontact Printing of Dendrimers, Proteins, and Nanoparticles by Porous Stamps Huaping Xu, Xing Yi Ling, Joost van Bennekom, Xuexin Duan, Manon J. W. Ludden, David N. Reinhoudt, Matthias Wessling, Rob G. H. Lammertink and Jurriaan Huskens pp 797–803 DOI: 10.1021/ja807611n |
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Mechanism of Very Large Scale Assembly of SWNTs in Template Guided Fluidic Assembly Process Laila Jaber-Ansari, Myung Gwan Hahm, Sivasubramanian Somu, Yolanda Echegoyen Sanz, Ahmed Busnaina and Yung Joon Jung pp 804–808 DOI: 10.1021/ja8076523 Supporting Info |
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From Phenylsiloxane Polymer Composition to Size-Controlled Silicon Carbide Nanocrystals Eric J. Henderson and Jonathan G. C. Veinot pp 809–815 DOI: 10.1021/ja807701y Supporting Info |
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Quantum Chemical Modeling of Zeolite-Catalyzed Methylation Reactions: Toward Chemical Accuracy for Barriers Stian Svelle, Christian Tuma, Xavier Rozanska, Torsten Kerber and Joachim Sauer pp 816–825 DOI: 10.1021/ja807695p Supporting Info |
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Biofuel Cell Controlled by Enzyme Logic Systems Liron Amir, Tsz Kin Tam, Marcos Pita, Michael M. Meijler, Lital Alfonta and Evgeny Katz pp 826–832 DOI: 10.1021/ja8076704 Supporting Info |
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White-Light Emitting Hydrogen-Bonded Supramolecular Copolymers Based on π-Conjugated Oligomers Robert Abbel, Christophe Grenier, Maarten J. Pouderoijen, Jan W. Stouwdam, Philippe E. L. G. Lecl pp 833–843 DOI: 10.1021/ja807996y Supporting Info |
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DNA at Aqueous/Solid Interfaces: Chirality-Based Detection via Second Harmonic Generation Activity Faith C. Boman, Julianne M. Gibbs-Davis, Laurel M. Heckman, Brian R. Stepp, SonBinh T. Nguyen and Franz M. Geiger pp 844–848 DOI: 10.1021/ja808007b Supporting Info |
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Surface-Enhanced Raman Excitation Spectroscopy of a Single Rhodamine 6G Molecule Jon A. Dieringer, Kristin L. Wustholz, David J. Masiello, Jon P. Camden, Samuel L. Kleinman, George C. Schatz and Richard P. Van Duyne pp 849–854 DOI: 10.1021/ja8080154 |
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Ammonia Triborane: A New Synthesis, Structural Determinations, and Hydrolytic Hydrogen-Release Properties Chang Won Yoon, Patrick J. Carroll and Larry G. Sneddon pp 855–864 DOI: 10.1021/ja808045p Supporting Info |
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Reversible Phototuning of the Large Anisotropic Magnetization at the Interface between a Self-Assembled Photochromic Monolayer and Gold Masayuki Suda, Naoto Kameyama, Aya Ikegami and Yasuaki Einaga pp 865–870 DOI: 10.1021/ja808231c Supporting Info |
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Probing Transient Copper Chaperone−Wilson Disease Protein Interactions at the Single-Molecule Level with Nanovesicle Trapping Jaime J. Ben p 871 DOI: 10.1021/ja809445z Supporting Info |
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Software Review of Origin 8 R. Alan May and Keith J. Stevenson p 872 DOI: 10.1021/ja809638x |
Issue 03
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The Tandem Cope-Type Hydroamination/[2,3]-Rearrangement Sequence: A Strategy to Favor the Formation of Intermolecular Hydroamination Products and Enable Difficult Cyclizations Joffr pp 874–875 DOI: 10.1021/ja8077895 Supporting Info |
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Organometallic Enantiomeric Scaffolding. Sequential Semipinacol/1,5-“Michael-like” Reactions as a Strategic Approach to Bridgehead-Quaternary Center Aza[3.3.1]Bicyclics: Application to the Total Synthesis of (−)-Adaline Thomas C. Coombs, Yongqiang Zhang, Ethel C. Garnier-Amblard and Lanny S. Liebeskind pp 876–877 DOI: 10.1021/ja808533z Supporting Info |
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Catalytic Homologation of Cycloalkanones with Substituted Diazomethanes. Mild and Efficient Single-Step Access to α-Tertiary and α-Quaternary Carbonyl Compounds David C. Moebius and Jason S. Kingsbury pp 878–879 DOI: 10.1021/ja809220j Supporting Info |
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Chemically Controlled Amplified Ratiometric Fluorescence in Surface-Immobilized End-Capped Oligo(p-phenylene ethynylene)s Jiba Raj Acharya, Huating Zhang, Xian Li and Evgueni E. Nesterov pp 880–881 DOI: 10.1021/ja807621z Supporting Info |
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Pentaceno[2,3-b]thiophene, a Hexacene Analogue for Organic Thin Film Transistors Ming L. Tang, Stefan C. B. Mannsfeld, Ya-Sen Sun, H pp 882–883 DOI: 10.1021/ja808142c Supporting Info |
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Dynamics of “Flap” Structures in Three HIV-1 Protease/Inhibitor Complexes Probed by Total Chemical Synthesis and Pulse-EPR Spectroscopy Vladimir Yu. Torbeev, H. Raghuraman, Kalyaneswar Mandal, Sanjib Senapati, Eduardo Perozo and Stephen B. H. Kent pp 884–885 DOI: 10.1021/ja806526z Supporting Info |
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Efficient Three-Photon Excited Deep Blue Photoluminescence and Lasing of Diphenylamino and 1,2,4-Triazole Endcapped Oligofluorenes Po Lam Wu, Xin Jiang Feng, Hoi Lam Tam, Man Shing Wong and Kok Wai Cheah pp 886–887 DOI: 10.1021/ja806703v Supporting Info |
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Protein-Directed Synthesis of Highly Fluorescent Gold Nanoclusters Jianping Xie, Yuangang Zheng and Jackie Y. Ying pp 888–889 DOI: 10.1021/ja806804u Supporting Info |
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Boron Nitride Nanotubes Are Noncytotoxic and Can Be Functionalized for Interaction with Proteins and Cells Xing Chen, Peng Wu, Michael Rousseas, David Okawa, Zev Gartner, Alex Zettl and Carolyn R. Bertozzi pp 890–891 DOI: 10.1021/ja807334b Supporting Info |
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Photochemical Size Reduction of CdSe and CdSe/ZnS Semiconductor Nanoparticles Assisted by nπ* Aromatic Ketones Raquel E. Galian, Miguel de la Guardia and Julia P pp 892–893 DOI: 10.1021/ja807454u Supporting Info |
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Halide-Stabilized LiBH4, a Room-Temperature Lithium Fast-Ion Conductor Hideki Maekawa, Motoaki Matsuo, Hitoshi Takamura, Mariko Ando, Yasuto Noda, Taiki Karahashi and Shin-ichi Orimo pp 894–895 DOI: 10.1021/ja807392k Supporting Info |
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Site-Specific Immobilization and Micrometer and Nanometer Scale Photopatterning of Yellow Fluorescent Protein on Glass Surfaces Nicholas P. Reynolds, Jaimey D. Tucker, Paul A. Davison, John A. Timney, C. Neil Hunter and Graham J. Leggett pp 896–897 DOI: 10.1021/ja8079252 Supporting Info |
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High Yield Preparation of Macroscopic Graphene Oxide Membranes Zhengtang Luo, Ye Lu, Luke A. Somers and A. T. Charlie Johnson pp 898–899 DOI: 10.1021/ja807934n Supporting Info |
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Dipole-Induced, Thermally Stable Lamellar Structure by Polar Aromatic Silane Jinyue Jiang, Ocelio V. Lima, Yong Pei, Xiao Cheng Zeng, Li Tan and Eric Forsythe pp 900–901 DOI: 10.1021/ja808103h Supporting Info |
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An Approach to Thermodynamically Controlled Supramolecular Assembly Possessing an Integral Locking Mechanism Amy M. Cagulada and Darren G. Hamilton pp 902–903 DOI: 10.1021/ja808162b Supporting Info |
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Hydrophilicity-Controlled Carbon Aerogels with High Mesoporosity Yousheng Tao, Morinobu Endo and Katsumi Kaneko pp 904–905 DOI: 10.1021/ja808132u Supporting Info |
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Chemical Bonding and Electronic and Magnetic Structure in LaOFeAs Jacek C. Wojdeł, Ib pp 906–907 DOI: 10.1021/ja808519y Supporting Info |
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Diversity of Catalysis by an Imido-Hydrido Complex of Molybdenum. Mechanism of Carbonyl Hydrosilylation and Silane Alcoholysis Erik Peterson, Andrey Y. Khalimon, Razvan Simionescu, Lyudmila G. Kuzmina, Judith A. K. Howard and Georgii I. Nikonov pp 908–909 DOI: 10.1021/ja8085388 Supporting Info |
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Preparation of the Binary Technetium Bromides: TcBr3 and TcBr4 Frederic Poineau, Efrain E. Rodriguez, Paul M. Forster, Alfred P. Sattelberger, Anthony K. Cheetham and Kenneth R. Czerwinski pp 910–911 DOI: 10.1021/ja808597r Supporting Info |
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Photochromic Diarylethene-Containing Ionic Liquids and N-Heterocyclic Carbenes Vivian Wing-Wah Yam, Jason Ka-Wai Lee, Chi-Chiu Ko and Nianyong Zhu pp 912–913 DOI: 10.1021/ja808791e Supporting Info |
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Intercalation of Aggregation-Free and Well-Dispersed Gold Nanoparticles into the Walls of Mesoporous Silica as a Robust “Green” Catalyst for n-Alkane Oxidation Lifang Chen, Juncheng Hu and Ryan Richards pp 914–915 DOI: 10.1021/ja808860v Supporting Info |
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Base-Free Molybdenum and Tungsten Bicyclic Silylene Complexes Stabilized by a Homoaromatic Contribution Kazunori Takanashi, Vladimir Ya. Lee, Taka Yokoyama and Akira Sekiguchi pp 916–917 DOI: 10.1021/ja8088313 Supporting Info |
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trans-Difluoro Complexes of Palladium(II) Vladimir V. Grushin and William J. Marshall pp 918–919 DOI: 10.1021/ja808975a Supporting Info |
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A New Doubly Interlocked [2]Catenane Carlos Peinador, V pp 920–921 DOI: 10.1021/ja8088372 Supporting Info |
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Redox-Activating Dip-Pen Nanolithography (RA-DPN) Adam B. Braunschweig, Andrew J. Senesi and Chad A. Mirkin pp 922–923 DOI: 10.1021/ja809107n Supporting Info |
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Regioselective Knitting of Aniline via ortho-C−N Bond Fusion Using OsO4 as a Template Subhas Samanta and Sreebrata Goswami pp 924–925 DOI: 10.1021/ja808901s Supporting Info |
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Photoassisted Overall Water Splitting in a Visible Light-Absorbing Dye-Sensitized Photoelectrochemical Cell W. Justin Youngblood, Seung-Hyun Anna Lee, Yoji Kobayashi, Emil A. Hernandez-Pagan, Paul G. Hoertz, Thomas A. Moore, Ana L. Moore, Devens Gust and Thomas E. Mallouk pp 926–927 DOI: 10.1021/ja809108y Supporting Info |
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Designed α-Helical Tectons for Constructing Multicomponent Synthetic Biological Systems Elizabeth H. C. Bromley, Richard B. Sessions, Andrew R. Thomson and Derek N. Woolfson pp 928–930 DOI: 10.1021/ja804231a Supporting Info |
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Nucleobase Mediated, Photocatalytic Vesicle Formation from an Ester Precursor Michael S. DeClue, Pierre-Alain Monnard, James A. Bailey, Sarah E. Maurer, Gavin E. Collis, Hans-Joachim Ziock, Steen Rasmussen and James M. Boncella pp 931–933 DOI: 10.1021/ja808200n Supporting Info |
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Single-Molecule Observation of Photocatalytic Reaction in TiO2 Nanotube: Importance of Molecular Transport through Porous Structures Kazuya Naito, Takashi Tachikawa, Mamoru Fujitsuka and Tetsuro Majima pp 934–936 DOI: 10.1021/ja808335b Supporting Info |
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Electrogenerated Chemiluminescence of Partially Oxidized Highly Oriented Pyrolytic Graphite Surfaces and of Graphene Oxide Nanoparticles Fu-Ren F. Fan, Sungjin Park, Yanwu Zhu, Rodney S. Ruoff and Allen J. Bard pp 937–939 DOI: 10.1021/ja8086246 Supporting Info |
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Femtosecond Laser-Induced Ionization/Dissociation of Protonated Peptides Christine L. Kalcic, Tissa C. Gunaratne, A. Daniel Jones, Marcos Dantus and Gavin E. Reid pp 940–942 DOI: 10.1021/ja8089119 Supporting Info |
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Design and Stereoselective Preparation of a New Class of Chiral Olefin Metathesis Catalysts and Application to Enantioselective Synthesis of Quebrachamine: Catalyst Development Inspired by Natural Product Synthesis Elizabeth S. Sattely, Simon J. Meek, Steven J. Malcolmson, Richard R. Schrock and Amir H. Hoveyda pp 943–953 DOI: 10.1021/ja8084934 Supporting Info |
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Highly Enantio- and Diastereoselective One-Pot Methods for the Synthesis of Halocyclopropyl Alcohols Hun Young Kim, Luca Salvi, Patrick J. Carroll and Patrick J. Walsh pp 954–962 DOI: 10.1021/ja806989n Supporting Info |
The U C Double Bond: Synthesis and Study of Uranium Nucleophilic Carbene ComplexesThibault Cantat, Th pp 963–972 DOI: 10.1021/ja807282s Supporting Info |
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Thiophene Dendrimers as Entangled Photon Sensor Materials Michael R. Harpham, pp 973–979 DOI: 10.1021/ja803268s |
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Correlation between Bonding Geometry and Band Gap States at Organic−Inorganic Interfaces: Catechol on Rutile TiO2(110) Shao-Chun Li, Jian-guo Wang, Peter Jacobson, X.-Q. Gong, Annabella Selloni and Ulrike Diebold pp 980–984 DOI: 10.1021/ja803595u Supporting Info |
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Protein Structure Refinement Using 13Cα Chemical Shift Tensors Benjamin J. Wylie, Charles D. Schwieters, Eric Oldfield and Chad M. Rienstra pp 985–992 DOI: 10.1021/ja804041p Supporting Info |
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Cyclic Versus Linear Isomers Produced by Reaction of the Methylidyne Radical (CH) with Small Unsaturated Hydrocarbons Fabien Goulay, Adam J. Trevitt, Giovanni Meloni, Talitha M. Selby, David L. Osborn, Craig A. Taatjes, Luc Vereecken and Stephen R. Leone pp 993–1005 DOI: 10.1021/ja804200v Supporting Info |
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Detecting Protein−Ligand Binding on Supported Bilayers by Local pH Modulation Hyunsook Jung, Aaron D. Robison and Paul S. Cremer pp 1006–1014 DOI: 10.1021/ja804542p Supporting Info |
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Initiation of DNA Strand Cleavage by 1,2,4-Benzotriazine 1,4-Dioxide Antitumor Agents: Mechanistic Insight from Studies of 3-Methyl-1,2,4-benzotriazine 1,4-Dioxide Venkatraman Junnotula, Ujjal Sarkar, Sarmistha Sinha and Kent S. Gates pp 1015–1024 DOI: 10.1021/ja8049645 |
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Protein Cold Denaturation as Seen From the Solvent Monika Davidovic, Carlos Mattea, Johan Qvist and Bertil Halle pp 1025–1036 DOI: 10.1021/ja8056419 Supporting Info |
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The Oil−Water Interface: Mapping the Solvation Potential Richard C. Bell, Kai Wu, Martin J. Iedema, Gregory K. Schenter and James P. Cowin pp 1037–1042 DOI: 10.1021/ja805962x |
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Langmuir−Blodgett Assembly of Graphite Oxide Single Layers Laura J. Cote, Franklin Kim and Jiaxing Huang pp 1043–1049 DOI: 10.1021/ja806262m Supporting Info |
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From Monomer to Bulk: Appearance of the Structural Motif of Solid Iodine in Small Clusters Eero Hulkko, Toni Kiljunen, Tiina Kiviniemi and Mika Pettersson pp 1050–1056 DOI: 10.1021/ja806537u Supporting Info |
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CC Bond Cleavage on Neutral VO3(V2O5)n Clusters Feng Dong, Scott Heinbuch, Yan Xie, Elliot R. Bernstein, Jorge J. Rocca, Zhe-Chen Wang, Xun-Lei Ding and Sheng-Gui He pp 1057–1066 DOI: 10.1021/ja8065946 Supporting Info |
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Balance of Beneficial and Deleterious Health Effects of Quinones: A Case Study of the Chemical Properties of Genistein and Estrone Quinones Qiang Zhang, Tingting Tu, D. Andr pp 1067–1076 DOI: 10.1021/ja806478b Supporting Info |
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Mechanistic Insights into the Rhodium-Catalyzed Intramolecular Ketone Hydroacylation Zengming Shen, Peter K. Dornan, Hasan A. Khan, Tom K. Woo and Vy M. Dong pp 1077–1091 DOI: 10.1021/ja806758m Supporting Info |
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Diquaternary Ammonium Compounds in Zeolite Synthesis: Cyclic and Polycyclic N-Heterocycles Connected by Methylene Chains Anna Jackowski, Stacey I. Zones, Son-Jong Hwang and Allen W. Burton pp 1092–1100 DOI: 10.1021/ja806978f |
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Unusually Reactive and Selective Carbonyl Ylides for Three-Component Cycloaddition Reactions Andrew DeAngelis, Michael T. Taylor and Joseph M. Fox pp 1101–1105 DOI: 10.1021/ja807184r Supporting Info |
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New Macrocyclic Terbium(III) Complex for Use in RNA Footprinting Experiments Matthew J. Belousoff, Phuc Ung, Craig M. Forsyth, Yitzhak Tor, Leone Spiccia and Bim Graham pp 1106–1114 DOI: 10.1021/ja807301r Supporting Info |
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Structures of Silicon Cluster Cations in the Gas Phase Jonathan T. Lyon, Philipp Gruene, Andr pp 1115–1121 DOI: 10.1021/ja807518y Supporting Info |
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The CN7− Anion Thomas M. Klap pp 1122–1134 DOI: 10.1021/ja8077522 Supporting Info |
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Probing General Acid Catalysis in the Hammerhead Ribozyme Jason M. Thomas and David M. Perrin pp 1135–1143 DOI: 10.1021/ja807790e Supporting Info |
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Electrolyte Tuning of Surfactant Interfacial Behavior for Enhanced Density-Based Separations of Single-Walled Carbon Nanotubes Sandip Niyogi, Crystal G. Densmore and Stephen K. Doorn pp 1144–1153 DOI: 10.1021/ja807785e Supporting Info |
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Phenolate Hydroxylation in a Bis(μ-oxo)dicopper(III) Complex: Lessons from the Guanidine/Amine Series Sonja Herres-Pawlis, Pratik Verma, Roxana Haase, Peng Kang, Christopher T. Lyons, Erik C. Wasinger, Ulrich Fl pp 1154–1169 DOI: 10.1021/ja807809x Supporting Info |
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Synthesis of an Electromagnetic Wave Absorber for High-Speed Wireless Communication Asuka Namai, Shunsuke Sakurai, Makoto Nakajima, Tohru Suemoto, Kazuyuki Matsumoto, Masahiro Goto, Shinya Sasaki and Shin-ichi Ohkoshi pp 1170–1173 DOI: 10.1021/ja807943v Supporting Info |
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Are Carboxyl Groups the Most Acidic Sites in Amino Acids? Gas-Phase Acidities, Photoelectron Spectra, and Computations on Tyrosine, p-Hydroxybenzoic Acid, and Their Conjugate Bases Zhixin Tian, Xue-Bin Wang, Lai-Sheng Wang and Steven R. Kass pp 1174–1181 DOI: 10.1021/ja807982k Supporting Info |
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Self-Assembly of Colloids with Liquid Protrusions Daniela J. Kraft, Wessel S. Vlug, Carlos M. van Kats, Alfons van Blaaderen, Arnout Imhof and Willem K. Kegel pp 1182–1186 DOI: 10.1021/ja8079803 Supporting Info |
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Total Synthesis and Evaluation of iso-Duocarmycin SA and iso-Yatakemycin Karen S. MacMillan, Trihn Nguyen, Inkyu Hwang and Dale L. Boger pp 1187–1194 DOI: 10.1021/ja808108q Supporting Info |
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Pleomorphic Copper Coordination by Alzheimer’s Disease Amyloid-β Peptide Simon C. Drew, Christopher J. Noble, Colin L. Masters, Graeme R. Hanson and Kevin J. Barnham pp 1195–1207 DOI: 10.1021/ja808073b Supporting Info |
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Tuning the Oxidation Level, the Spin State, and the Degree of Electron Delocalization in Homo- and Heteroleptic Bis(α-diimine)iron Complexes Marat M. Khusniyarov, Thomas Weyherm pp 1208–1221 DOI: 10.1021/ja808149k Supporting Info |
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Insights into Templated Supramolecular Polymerization: Binding of Naphthalene Derivatives to ssDNA Templates of Different Lengths Pim G. A. Janssen, Sara Jabbari-Farouji, Mathieu Surin, Xavier Vila, Jeroen C. Gielen, Tom F. A. de Greef, Matthijn R. J. Vos, Paul H. H. Bomans, Nico A. J. M. Sommerdijk, Peter C. M. Christianen, Philippe Lecl pp 1222–1231 DOI: 10.1021/ja808075h Supporting Info |
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Role of Sequence in Salt-Bridge Formation for Alkali Metal Cationized GlyArg and ArgGly Investigated with IRMPD Spectroscopy and Theory James S. Prell, Maria Demireva, Jos Oomens and Evan R. Williams pp 1232–1242 DOI: 10.1021/ja808177z Supporting Info |
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Probing the Catalytic Mechanism of S-Ribosylhomocysteinase (LuxS) with Catalytic Intermediates and Substrate Analogues Bhaskar Gopishetty, Jinge Zhu, Rakhi Rajan, Adam J. Sobczak, Stanislaw F. Wnuk, Charles E. Bell and Dehua Pei pp 1243–1250 DOI: 10.1021/ja808206w Supporting Info |
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The QTAIM Approach to Chemical Bonding Between Transition Metals and Carbocyclic Rings: A Combined Experimental and Theoretical Study of (η5-C5H5)Mn(CO)3, (η6-C6H6)Cr(CO)3, and (E)-{(η5-C5H4)CFCF(η5-C5H4)}(η5-C5H5)2Fe2 Louis J. Farrugia, Cameron Evans, Dieter Lentz and Max Roemer pp 1251–1268 DOI: 10.1021/ja808303j Supporting Info |
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Borabicyclo[3.3.2]decanes and the Stereoselective Asymmetric Synthesis of 1,3-Diol Stereotriads from 1,3-Diborylpropenes Ana Z. Gonz pp 1269–1273 DOI: 10.1021/ja808360z Supporting Info |
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NMR Structure Determination of a Segmentally Labeled Glycoprotein Using in Vitro Glycosylation Vadim Slynko, Mario Schubert, Shin Numao, Michael Kowarik, Markus Aebi and Fr pp 1274–1281 DOI: 10.1021/ja808682v Supporting Info |
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Peptide Secondary Structures in the Gas Phase: Consensus Motif of N-Linked Glycoproteins Emilio J. Cocinero, E. Cristina Stanca-Kaposta, David P. Gamblin, Benjamin G. Davis and John P. Simons pp 1282–1287 DOI: 10.1021/ja808687j Supporting Info |
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A Germanium(II) Hydride as an Effective Reagent for Hydrogermylation Reactions Anukul Jana, Debajyoti Ghoshal, Herbert W. Roesky, Ina Objartel, Gerald Schwab and Dietmar Stalke pp 1288–1293 DOI: 10.1021/ja808656t Supporting Info |
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Self-Assembly of Dendritic Crowns into Chiral Supramolecular Spheres Virgil Percec, Mohammad R. Imam, Mihai Peterca, Daniela A. Wilson and Paul A. Heiney pp 1294–1304 DOI: 10.1021/ja8087778 Supporting Info |
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Reduction of a Redox-Active Ligand Drives Switching in a Cu(I) Pseudorotaxane by a Bimolecular Mechanism Kristy A. McNitt, Kumar Parimal, Andrew I. Share, Albert C. Fahrenbach, Edward H. Witlicki, Maren Pink, D. Kwabena Bediako, Christina L. Plaisier, Nga Le, Lee P. Heeringa, Douglas A. Vander Griend and Amar H. Flood pp 1305–1313 DOI: 10.1021/ja8085593 Supporting Info |
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Switchable Electrode Controlled by Enzyme Logic Network System: Approaching Physiologically Regulated Bioelectronics Marina Privman, Tsz Kin Tam, Marcos Pita and Evgeny Katz pp 1314–1321 DOI: 10.1021/ja8088108 |
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A Yoctoliter-Scale DNA Reactor for Small-Molecule Evolution Margit Haahr Hansen, Peter Blakskjær, Lars Kolster Petersen, Tara Heitner Hansen, Jonas Westergaard Højfeldt, Kurt Vesterager Gothelf and Nils Jakob Vest Hansen pp 1322–1327 DOI: 10.1021/ja808558a Supporting Info |
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Radiative Recombination of Spatially Extended Excitons in (ZnSe/CdS)/CdS Heterostructured Nanorods Nishshanka N. Hewa-Kasakarage, Maria Kirsanova, Alexander Nemchinov, Nickolas Schmall, Patrick Z. El-Khoury, Alexander N. Tarnovsky and Mikhail Zamkov pp 1328–1334 DOI: 10.1021/ja8082895 Supporting Info |
Issue 04
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Chemical Modification of Epitaxial Graphene: Spontaneous Grafting of Aryl Groups Elena Bekyarova, Mikhail E. Itkis, Palanisamy Ramesh, Claire Berger, Michael Sprinkle, Walt A. de Heer and Robert C. Haddon pp 1336–1337 DOI: 10.1021/ja8057327 Supporting Info |
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Molecular Umbrella Transport: Exceptions to the Classic Size/Lipophilicity Rule Mohamed Mehiri, Wen-Hua Chen, Vaclav Janout and Steven L. Regen pp 1338–1339 DOI: 10.1021/ja806476t Supporting Info |
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Micropatterned Surfaces with Covalently Grafted Unsymmetrical Polyoxometalate-Hybrid Clusters Lead to Selective Cell Adhesion Yu-Fei Song, Nicola McMillan, De-Liang Long, Struan Kane, Jakob Malm, Mathis O Riehle, Chullikkattil P. Pradeep, Nikolaj Gadegaard and Leroy Cronin pp 1340–1341 DOI: 10.1021/ja807091v Supporting Info |
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Structured Mesoporous Tin Oxide with Electrical Conductivity. Application in Electroluminescence Carmela Aprile, Laura Teruel, Mercedes Alvaro and Hermenegildo Garcia pp 1342–1343 DOI: 10.1021/ja807190j Supporting Info |
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Competitive Inhibition of Uracil DNA Glycosylase by a Modified Nucleotide Whose Triphosphate is a Substrate for DNA Polymerase Haidong Huang, James T. Stivers and Marc M. Greenberg pp 1344–1345 DOI: 10.1021/ja807705z Supporting Info |
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Hydrogenolysis of Palladium(II) Hydroxide and Methoxide Pincer Complexes Gregory R. Fulmer, Richard P. Muller, Richard A. Kemp and Karen I. Goldberg pp 1346–1347 DOI: 10.1021/ja807936q Supporting Info |
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Long Distance PELDOR Measurements on the Histone Core Particle Richard Ward, Andrew Bowman, Hassane El-Mkami, Tom Owen-Hughes and David G. Norman pp 1348–1349 DOI: 10.1021/ja807918f Supporting Info |
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Nickel-Catalyzed [4 + 2] Cycloaddition of Enones with Alkynes Ichiro Koyama, Takuya Kurahashi and Seijiro Matsubara pp 1350–1351 DOI: 10.1021/ja807952r Supporting Info |
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A Facile Synthesis of Asymmetric Hybrid Colloidal Particles Akira Ohnuma, Eun Chul Cho, Pedro H. C. Camargo, Leslie Au, Bunsho Ohtani and Younan Xia pp 1352–1353 DOI: 10.1021/ja8079934 Supporting Info |
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Porous Nanoparticle Supported Lipid Bilayers (Protocells) as Delivery Vehicles Juewen Liu, Alison Stace-Naughton, Xingmao Jiang and C. Jeffrey Brinker pp 1354–1355 DOI: 10.1021/ja808018y Supporting Info |
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Helical Nanocomposites from Chiral Block Copolymer Templates Wen-Hsien Tseng, Chun-Ku Chen, Yeo-Wan Chiang, Rong-Ming Ho, Satoshi Akasaka and Hirokazu Hasegawa pp 1356–1357 DOI: 10.1021/ja808092v Supporting Info |
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Identification of the Water Amidogen Radical Complex Courtney P. Ennis, Joseph R. Lane, Henrik G. Kjaergaard and Allan J. McKinley pp 1358–1359 DOI: 10.1021/ja808109m Supporting Info |
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Entrapment of Hydrophobic Drugs in Nanoparticle Monolayers with Efficient Release into Cancer Cells Chae Kyu Kim, Partha Ghosh, Chiara Pagliuca, Zheng-Jiang Zhu, Stefano Menichetti and Vincent M. Rotello pp 1360–1361 DOI: 10.1021/ja808137c Supporting Info |
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X-ray Structure of Native Scorpion Toxin BmBKTx1 by Racemic Protein Crystallography Using Direct Methods Kalyaneswar Mandal, Brad L. Pentelute, Valentina Tereshko, Anthony A. Kossiakoff and Stephen B. H. Kent pp 1362–1363 DOI: 10.1021/ja8077973 Supporting Info |
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4D 1H−13C NMR Spectroscopy for Assignments of Alanine Methyls in Large and Complex Protein Structures Devon Sheppard, Chenyun Guo and Vitali Tugarinov pp 1364–1365 DOI: 10.1021/ja808202q Supporting Info |
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Iridium-Catalyzed Asymmetric Hydrogenation of Cyclic Enamines Guo-Hua Hou, Jian-Hua Xie, Pu-Cha Yan and Qi-Lin Zhou pp 1366–1367 DOI: 10.1021/ja808358r Supporting Info |
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Using NMR to Distinguish Viscosity Effects from Nonspecific Protein Binding under Crowded Conditions Conggang Li and Gary J. Pielak pp 1368–1369 DOI: 10.1021/ja808428d Supporting Info |
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Lactimidomycin, Iso-migrastatin and Related Glutarimide-Containing 12-Membered Macrolides Are Extremely Potent Inhibitors of Cell Migration Jianhua Ju, Scott R. Rajski, Si-Kyu Lim, Jeong-Woo Seo, No pp 1370–1371 DOI: 10.1021/ja808462p Supporting Info |
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Direct Cross-Coupling Reaction of Simple Alkenes with Acrylates Catalyzed by Palladium Catalyst Yun-He Xu, Jun Lu and Teck-Peng Loh pp 1372–1373 DOI: 10.1021/ja8084548 Supporting Info |
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Efficient Excited-State Deactivation of the Gly-Phe-Ala Tripeptide via an Electron-Driven Proton-Transfer Process Dorit Shemesh, Andrzej L. Sobolewski and Wolfgang Domcke pp 1374–1375 DOI: 10.1021/ja808485b Supporting Info |
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Observation of Glassy Ferromagnetism in Al-Doped 4H-SiC Bo Song, Huiqiang Bao, Hui Li, Ming Lei, Tonghua Peng, Jikang Jian, Jun Liu, Wanyan Wang, Wenjun Wang and Xiaolong Chen pp 1376–1377 DOI: 10.1021/ja808507f Supporting Info |
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Growth of Long, Highly Stable, and Densely Packed Worm-Like Nanocolumns of Hexa-peri-Hexabenzocoronenes via Chemisorption on Au(111) Luc Piot, Camille Marie, Xi Dou, Xinliang Feng, Klaus M pp 1378–1379 DOI: 10.1021/ja808752b Supporting Info |
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A Temperature-Sensitive Liposomal 1H CEST and 19F Contrast Agent for MR Image-Guided Drug Delivery Sander Langereis, Jochen Keupp, Juli pp 1380–1381 DOI: 10.1021/ja8087532 Supporting Info |
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Iodomesitylene-Catalyzed Oxidative Cleavage of Carbon−Carbon Double and Triple Bonds Using m-Chloroperbenzoic Acid as a Terminal Oxidant Kazunori Miyamoto, Yoshihisa Sei, Kentaro Yamaguchi and Masahito Ochiai pp 1382–1383 DOI: 10.1021/ja808829t Supporting Info |
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Templated Spherical High Density Lipoprotein Nanoparticles C. Shad Thaxton, Weston L. Daniel, David A. Giljohann, Audrey D. Thomas and Chad A. Mirkin pp 1384–1385 DOI: 10.1021/ja808856z Supporting Info |
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Cooperative DNA Probing Using a β-Cyclodextrin−DNA Conjugate and a Nucleobase-Specific Fluorescent Ligand Toshihiro Ihara, Asuka Uemura, Akika Futamura, Masamichi Shimizu, Noriyuki Baba, Seiichi Nishizawa, Norio Teramae and Akinori Jyo pp 1386–1387 DOI: 10.1021/ja809023n Supporting Info |
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Two-Electron Reduction of a Rh−Mo−Rh Dithiolato Complex To Form a Triplet Ground State Associated with a Change in CO Coordination Mode Satoshi Muratsugu, Keitaro Sodeyama, Fusao Kitamura, Manabu Sugimoto, Shinji Tsuneyuki, Seiji Miyashita, Tatsuhisa Kato and Hiroshi Nishihara pp 1388–1389 DOI: 10.1021/ja8090577 Supporting Info |
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A Hybrid Electrochemical−Colorimetric Sensing Platform for Detection of Explosives Erica S. Forzani, Donglai Lu, Matthew J. Leright, Alvaro Diaz Aguilar, Francis Tsow, Rodrigo A. Iglesias, Qian Zhang, Jin Lu, Jinghong Li and Nongjian Tao pp 1390–1391 DOI: 10.1021/ja809104h Supporting Info |
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Total Synthesis and Structure Elucidation of (+)-Phorbasin C Todd K. Macklin and Glenn C. Micalizio pp 1392–1393 DOI: 10.1021/ja809491b Supporting Info |
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Efficient Asymmetric Transfer Hydrogenation of Ketones Catalyzed by an Iron Complex Containing a P−N−N−P Tetradentate Ligand Formed by Template Synthesis Alexandre Mikhailine, Alan J. Lough and Robert H. Morris pp 1394–1395 DOI: 10.1021/ja809493h Supporting Info |
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Total Synthesis of Piericidin A1. Application of a Modified Negishi Carboalumination-Nickel-Catalyzed Cross-Coupling Bruce H. Lipshutz and Benjamin Amorelli pp 1396–1397 DOI: 10.1021/ja809542r Supporting Info |
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A Role of the Heme-7-Propionate Side Chain in Cytochrome P450cam as a Gate for Regulating the Access of Water Molecules to the Substrate-Binding Site Takashi Hayashi, Katsuyoshi Harada, Keisuke Sakurai, Hideo Shimada and Shun Hirota pp 1398–1400 DOI: 10.1021/ja807420k Supporting Info |
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Label-Free Detection of Drug-Membrane Association Using Ultraviolet−Visible Sum-Frequency Generation Trang T. Nguyen, Kelvin Rembert and John C. Conboy pp 1401–1403 DOI: 10.1021/ja8070607 Supporting Info |
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Nanostructure and Hydrogen Spillover of Bridged Metal-Organic Frameworks Cheng-Si Tsao, Ming-Sheng Yu, Cheng-Yu Wang, Pin-Yen Liao, Hsin-Lung Chen, U-Ser Jeng, Yi-Ren Tzeng, Tsui-Yun Chung and Hsiu-Chu Wu pp 1404–1406 DOI: 10.1021/ja802741b Supporting Info |
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Method to Derive Restoring Forces of Strained Molecules from Kinetic Measurements Zhen Huang, Qing-Zheng Yang, Daria Khvostichenko, Timothy J. Kucharski, Joseph Chen and Roman Boulatov pp 1407–1409 DOI: 10.1021/ja807113m Supporting Info |
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Synthesis and Structure Revision of Nakiterpiosin Shuanhu Gao, Qiaoling Wang and Chuo Chen pp 1410–1412 DOI: 10.1021/ja808110d Supporting Info |
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Symmetry Controls the Face Geometry of DNA Polyhedra Chuan Zhang, Seung Hyeon Ko, Min Su, Yujun Leng, Alexander E. Ribbe, Wen Jiang and Chengde Mao pp 1413–1415 DOI: 10.1021/ja809666h Supporting Info |
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Mechanism for Activation of Molecular Oxygen by cis- and trans-(Pyridine)2Pd(OAc)H: Pd0 versus Direct Insertion Jason M. Keith and William A. Goddard, III pp 1416–1425 DOI: 10.1021/ja8040459 Supporting Info |
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Nonaromatic Core−Shell Structure of Nanodiamond from Solid-State NMR Spectroscopy XiaoWen Fang, JingDong Mao, E. M. Levin and Klaus Schmidt-Rohr pp 1426–1435 DOI: 10.1021/ja8054063 Supporting Info |
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Design, Selection, and Characterization of Thioflavin-Based Intercalation Compounds with Metal Chelating Properties for Application in Alzheimer’s Disease Cristina Rodr pp 1436–1451 DOI: 10.1021/ja806062g Supporting Info |
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Chaperonin Complexes Monitored by Ion Mobility Mass Spectrometry Esther van Duijn, Arjan Barendregt, Silvia Synowsky, Cees Versluis and Albert J. R. Heck pp 1452–1459 DOI: 10.1021/ja8055134 Supporting Info |
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Visible Light Excitable Zn2+ Fluorescent Sensor Derived from an Intramolecular Charge Transfer Fluorophore and Its in Vitro and in Vivo Application Fang Qian, Changli Zhang, Yumin Zhang, Weijiang He, Xiang Gao, Ping Hu and Zijian Guo pp 1460–1468 DOI: 10.1021/ja806489y Supporting Info |
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Na6ZnSn2, Na4.24K1.76(1)ZnSn2, and Na20Zn8Sn11: Three Intermetallic Structures Containing the Linear {Sn−Zn−Sn}6− Unit Sung-Jin Kim, Florian Kraus and Thomas F. F pp 1469–1478 DOI: 10.1021/ja806737k Supporting Info |
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Probing Single-Molecule Interfacial Electron Transfer Dynamics of Porphyrin on TiO2 Nanoparticles Yuanmin Wang, Xuefei Wang, Sujit Kumar Ghosh and H. Peter Lu pp 1479–1487 DOI: 10.1021/ja806988d |
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Fluorescence Dynamics of Directly Meso−Meso Linked Porphyrin Rings Probed by Single Molecule Spectroscopy Hyejin Yoo, Jaesung Yang, Yasuyuki Nakamura, Naoki Aratani, Atsuhiro Osuka and Dongho Kim pp 1488–1494 DOI: 10.1021/ja807105n Supporting Info |
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Polymer Nanoparticles: Shape-Directed Monomer-to-Particle Synthesis Tao He, Dave J. Adams, Michael F. Butler, Andrew I. Cooper and Steve P. Rannard pp 1495–1501 DOI: 10.1021/ja807462e Supporting Info |
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Impact of Perfluorination on the Charge-Transport Parameters of Oligoacene Crystals M. Carmen Ruiz Delgado, Kathryn R. Pigg, Dem pp 1502–1512 DOI: 10.1021/ja807528w Supporting Info |
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Micrometer- and Nanometer-Scale Photopatterning Using 2-Nitrophenylpropyloxycarbonyl-Protected Aminosiloxane Monolayers Shahrul A. Alang Ahmad, Lu Shin Wong, Ehtsham ul-Haq, Jamie K. Hobbs, Graham J. Leggett and Jason Micklefield pp 1513–1522 DOI: 10.1021/ja807612y Supporting Info |
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Hydrogen-Bonding Interactions between Water and the One- and Two-Electron-Reduced Forms of Vitamin K1: Applying Quinone Electrochemistry To Determine the Moisture Content of Non-Aqueous Solvents Yanlan Hui, Elaine Lay Khim Chng, Cheryl Yi Lin Chng, Hwee Ling Poh and Richard D. Webster pp 1523–1534 DOI: 10.1021/ja8080428 |
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Urea’s Action on Hydrophobic Interactions Ronen Zangi, Ruhong Zhou and B. J. Berne pp 1535–1541 DOI: 10.1021/ja807887g Supporting Info |
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New Insights into the Torquoselectivity of the Staudinger Reaction Yong Liang, Lei Jiao, Shiwei Zhang, Zhi-Xiang Yu and Jiaxi Xu pp 1542–1549 DOI: 10.1021/ja808046e Supporting Info |
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Reaction Mechanism of the ε Subunit of E. coli DNA Polymerase III: Insights into Active Site Metal Coordination and Catalytically Significant Residues G. Andr pp 1550–1556 DOI: 10.1021/ja8082818 Supporting Info |
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Influence of the Lipidation Motif on the Partitioning and Association of N-Ras in Model Membrane Subdomains Katrin Weise, Gemma Triola, Luc Brunsveld, Herbert Waldmann and Roland Winter pp 1557–1564 DOI: 10.1021/ja808691r Supporting Info |
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Deactivation Pathways of Neutral Ni(II) Polymerization Catalysts Andreas Berkefeld and Stefan Mecking pp 1565–1574 DOI: 10.1021/ja808855v Supporting Info |
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Kinetic Analysis of β-Phosphoglucomutase and Its Inhibition by Magnesium Fluoride Marko Goli pp 1575–1588 DOI: 10.1021/ja806421f Supporting Info |
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Access to Poly-β-Peptides with Functionalized Side Chains and End Groups via Controlled Ring-Opening Polymerization of β-Lactams Jihua Zhang, Denis A. Kissounko, Sarah E. Lee, Samuel H. Gellman and Shannon S. Stahl pp 1589–1597 DOI: 10.1021/ja8069192 Supporting Info |
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Fluorous Polymeric Membranes for Ionophore-Based Ion-Selective Potentiometry: How Inert Is Teflon AF? Chun-Ze Lai, Secil S. Koseoglu, Elizabeth C. Lugert, Paul G. Boswell, J pp 1598–1606 DOI: 10.1021/ja808047x Supporting Info |
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Total Synthesis of the Potent Anticancer Aglaia Metabolites (−)-Silvestrol and (−)-Episilvestrol and the Active Analogue (−)-4′-Desmethoxyepisilvestrol Tim E. Adams, Mariana El Sous, Bill C. Hawkins, Sebastian Hirner, Georgina Holloway, Mui Ling Khoo, David J. Owen, G. Paul Savage, Peter J. Scammells and Mark A. Rizzacasa pp 1607–1616 DOI: 10.1021/ja808402e Supporting Info |
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ReCore John H. VanDrie p 1617 DOI: 10.1021/ja900089h |
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Book Review of Parallel Computing in Quantum Chemistry Timothy J. Dudley p 1618 DOI: 10.1021/ja809443m |
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Book Review of Ferrocenes: Ligands, Materials, and Biomolecules Jay A. Labinger pp 1618–1619 DOI: 10.1021/ja809247b |
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Book Review of Solution Thermodynamics and Its Application to Aqueous Solutions: A Differential Approach Alex De Visscher pp 1619–1620 DOI: 10.1021/ja809695u |
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Book Review of Molecular Recognition and Polymers: Control of Polymer Structure and Self-Assembly Susanne Striegler p 1620 DOI: 10.1021/ja809837b |
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Book Review of Primary Processes of Photosynthesis: Principles and Apparatus, Parts 1−2 Antony R. Crofts pp 1620–1621 DOI: 10.1021/ja809545u |
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Book Review of Nanostructured Design: Methods and Protocols. Methods in Molecular Biology, 474 Jason Shearer p 1621 DOI: 10.1021/ja809618z |
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Book Review of Probes and Tags to Study Biomolecular Function for Proteins, RNA, and Membranes Sergey N. Krylov pp 1621–1622 DOI: 10.1021/ja809727x |
Issue 05
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Time-Resolved EPR Characterization of a Folded Conformation of Photoinduced Charge-Separated State in Porphyrin−Fullerene Dyad Bridged by Diphenyldisilane Yasuhiro Kobori, Yuki Shibano, Tsubasa Endo, Hayato Tsuji, Hisao Murai and Kohei Tamao pp 1624–1625 DOI: 10.1021/ja8073775 Supporting Info |
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Molecular Glues Carrying Multiple Guanidinium Ion Pendants via an Oligoether Spacer: Stabilization of Microtubules against Depolymerization Kou Okuro, Kazushi Kinbara, Kouhei Tsumoto, Noriyuki Ishii and Takuzo Aida pp 1626–1627 DOI: 10.1021/ja800491v Supporting Info |
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High-Efficiency Preparation of Macrocyclic Diblock Copolymers via Selective Click Reaction in Micellar Media Zhishen Ge, Yueming Zhou, Jian Xu, Hewen Liu, Daoyong Chen and Shiyong Liu pp 1628–1629 DOI: 10.1021/ja808772z Supporting Info |
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Room-Temperature Size Evolution of Thiol-Protected Gold Nanoparticles Assisted by Proton Acids and Halogen Anions Masayuki Kanehara, Jun-ichi Sakurai, Hiroyuki Sugimura and Toshiharu Teranishi pp 1630–1631 DOI: 10.1021/ja8058167 Supporting Info |
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Rate Limiting Step Precedes C−C Bond Formation in the Archetypical Proline-Catalyzed Intramolecular Aldol Reaction Hui Zhu, Fernando R. Clemente, K. N. Houk and Matthew P. Meyer pp 1632–1633 DOI: 10.1021/ja806672y Supporting Info |
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Formation of Self-Assembled Polyelectrolyte Multilayer Nanodots by Scanning Probe Microscopy Geunhee Lee, Young-Han Shin and Jong Yeog Son pp 1634–1635 DOI: 10.1021/ja806795a |
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Synthesis of Rare-metal Absorbing Polymer by Three-component Polyaddition through Combination of Chemo-selective Nucleophilic and Radical Additions Bungo Ochiai, Takayuki Ogihara, Masayuki Mashiko and Takeshi Endo pp 1636–1637 DOI: 10.1021/ja8070978 Supporting Info |
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Back to Back Twin Bowls of D3-Symmetric Tris(spiroborate)s for Supramolecular Chain Structures Hiroshi Danjo, Kadzuya Hirata, Seiki Yoshigai, Isao Azumaya and Kentaro Yamaguchi pp 1638–1639 DOI: 10.1021/ja8071435 Supporting Info |
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Switching the Morphologies of Cylindrical Polycation Brushes by Ionic and Supramolecular Inclusion Complexes Youyong Xu, Sreenath Bolisetty, Matthias Ballauff and Axel H. E. M pp 1640–1641 DOI: 10.1021/ja807302j Supporting Info |
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A Ratiometric pH Reporter For Imaging Protein-dye Conjugates In Living Cells Junyan Han, Aurore Loudet, Rola Barhoumi, Robert C. Burghardt and Kevin Burgess pp 1642–1643 DOI: 10.1021/ja8073374 Supporting Info |
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Selective Recognition of Unnatural Imidazopyridopyrimidine:Naphthyridine Base Pairs Consisting of Four Hydrogen Bonds by the Klenow Fragment Noriaki Minakawa, Shintaro Ogata, Mayumi Takahashi and Akira Matsuda pp 1644–1645 DOI: 10.1021/ja807391g Supporting Info |
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“Twin Copper Source” Growth of Metal−Organic Framework Membrane: Cu3(BTC)2 with High Permeability and Selectivity for Recycling H2 Hailing Guo, Guangshan Zhu, Ian J. Hewitt and Shilun Qiu pp 1646–1647 DOI: 10.1021/ja8074874 Supporting Info |
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Isomer Restriction on a Nanoparticle Surface and Enhanced Blue Emission Xichen Cai, Ravi M. Adhikari, Kelechi C. Anyaogu, Sujeewa S. Palayangoda, Leandro A. Estrada, Puran K. De and Douglas C. Neckers pp 1648–1649 DOI: 10.1021/ja807511f Supporting Info |
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Nanostructure Based on Polymer Brushes for Efficient Heterogeneous Catalysis in Microreactors Francesca Costantini, Wojciech P. Bula, Riccardo Salvio, Jurriaan Huskens, Han J. G. E. Gardeniers, David N. Reinhoudt and Willem Verboom pp 1650–1651 DOI: 10.1021/ja807616z Supporting Info |
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Simultaneous Measurement of Ionic Current and Fluorescence from Single Protein Pores Andrew J. Heron, James R. Thompson, Bríd Cronin, Hagan Bayley and Mark I. Wallace pp 1652–1653 DOI: 10.1021/ja808128s Supporting Info |
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Oxiranyl Anion Methodology Using Microflow Systems Aiichiro Nagaki, Eiji Takizawa and Jun-ichi Yoshida pp 1654–1655 DOI: 10.1021/ja809325a Supporting Info |
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Highly Efficient Incorporation of Functional Groups into Aromatic Main-Chain Polymer Using Iridium-Catalyzed C−H Activation and Suzuki−Miyaura Reaction Tae Soo Jo, Se Hye Kim, Jihoon Shin and Chulsung Bae pp 1656–1657 DOI: 10.1021/ja808374e Supporting Info |
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Mechanism-Based Small Molecule Probes for Labeling CD38 on Live Cells Hong Jiang, Johanna Congleton, Qun Liu, Paolomi Merchant, Fabio Malavasi, Hon Cheung Lee, Quan Hao, Andrew Yen and Hening Lin pp 1658–1659 DOI: 10.1021/ja808387g Supporting Info |
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Photoinduced Abstraction Reactions within NO Dimers on Ag(111) Ki Hyun Kim, Kazuo Watanabe, Dietrich Menzel and Hans-Joachim Freund pp 1660–1661 DOI: 10.1021/ja808615m |
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Silver-Mediated Fluorination of Functionalized Aryl Stannanes Takeru Furuya, Alexandra E. Strom and Tobias Ritter pp 1662–1663 DOI: 10.1021/ja8086664 Supporting Info |
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Use of a Renewable and Degradable Monomer to Study the Temperature-Dependent Olefin Isomerization during ADMET Polymerizations Patrice A. Fokou and Michael A. R. Meier pp 1664–1665 DOI: 10.1021/ja808679w Supporting Info |
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Biomembrane Sensitivity to Structural Changes in Bound Polymers Alexander A. Yaroslavov, Tatiana A. Sitnikova, Anna A. Rakhnyanskaya, Ekaterina G. Yaroslavova, Dmitry A. Davydov, Tatiana V. Burova, Valery Ya. Grinberg, Lei Shi and Fredric M. Menger pp 1666–1667 DOI: 10.1021/ja808461s |
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Metal-Free Oxidative Cross-Coupling of Unfunctionalized Aromatic Compounds Yasuyuki Kita, Koji Morimoto, Motoki Ito, Chieko Ogawa, Akihiro Goto and Toshifumi Dohi pp 1668–1669 DOI: 10.1021/ja808940n Supporting Info |
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Organization of Nanoparticles in Polymer Brushes Ron Oren, Ziqi Liang, Jonathan S. Barnard, Scott C. Warren, Ulrich Wiesner and Wilhelm T. S. Huck pp 1670–1671 DOI: 10.1021/ja8090092 Supporting Info |
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Polyhedral Au Nanocrystals Exclusively Bound by {110} Facets: The Rhombic Dodecahedron Gyoung Hwa Jeong, Minjung Kim, Young Wook Lee, Wonjun Choi, Won Taek Oh, Q-Han Park and Sang Woo Han pp 1672–1673 DOI: 10.1021/ja809112n Supporting Info |
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Magnesium-Catalyzed Asymmetric Direct Aldol Addition of Ethyl Diazoacetate to Aromatic, Aliphatic, and α,β-Unsaturated Aldehydes Barry M. Trost, Sushant Malhotra and Benjamin A. Fried pp 1674–1675 DOI: 10.1021/ja809181m Supporting Info |
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High-Temperature Nanoporous Ceramic Monolith Prepared from a Polymeric Bicontinuous Microemulsion Template Brad H. Jones and Timothy P. Lodge pp 1676–1677 DOI: 10.1021/ja8092554 Supporting Info |
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A 3-D Hexagonal Inverse Micellar Lyotropic Phase Gemma C. Shearman, Arwen I. I. Tyler, Nicholas J. Brooks, Richard H. Templer, Oscar Ces, Robert V. Law and John M. Seddon pp 1678–1679 DOI: 10.1021/ja809280r Supporting Info |
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Polymer Semiconductors for Artificial Photosynthesis: Hydrogen Evolution by Mesoporous Graphitic Carbon Nitride with Visible Light Xinchen Wang, Kazuhiko Maeda, Xiufang Chen, Kazuhiro Takanabe, Kazunari Domen, Yidong Hou, Xianzhi Fu and Markus Antonietti pp 1680–1681 DOI: 10.1021/ja809307s Supporting Info |
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C-BN Single-Walled Nanotubes from Hybrid Connection of BN/C Nanoribbons: Prediction by ab initio Density Functional Calculations Aijun Du, Ying Chen, Zhonghua Zhu, Gaoqing Lu and Sean C. Smith pp 1682–1683 DOI: 10.1021/ja809053x Supporting Info |
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Redox-Responsive Recombination of Carbon−Carbon Bonds on Flexible Tetrairon Cores Masaaki Okazaki, Masato Takano and Fumiyuki Ozawa pp 1684–1685 DOI: 10.1021/ja809540w Supporting Info |
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Light-Operated Mechanized Nanoparticles Daniel P. Ferris, Yan-Li Zhao, Niveen M. Khashab, Hussam A. Khatib, J. Fraser Stoddart and Jeffrey I. Zink pp 1686–1688 DOI: 10.1021/ja807798g Supporting Info |
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Ultrasound-Induced Switching of Sheetlike Coordination Polymer Microparticles to Nanofibers Capable of Gelating Solvents Shiyong Zhang, Shuaijun Yang, Jingbo Lan, Yurong Tang, Ying Xue and Jingsong You pp 1689–1691 DOI: 10.1021/ja808210z Supporting Info |
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Synthesis, Structural Characterization, and Unusual Field-Effect Behavior of Organic Transistor Semiconductor Oligomers: Inferiority of Oxadiazole Compared with Other Electron-Withdrawing Subunits Taegweon Lee, Chad A. Landis, Bal Mukund Dhar, Byung Jun Jung, Jia Sun, Amy Sarjeant, Ho-Jin Lee and Howard E. Katz pp 1692–1705 DOI: 10.1021/ja807219x Supporting Info |
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Free Energy for the Permeation of Na+ and Cl− Ions and Their Ion-Pair through a Zwitterionic Dimyristoyl Phosphatidylcholine Lipid Bilayer by Umbrella Integration with Harmonic Fourier Beads Ilja V. Khavrutskii, Alemayehu A. Gorfe, Benzhuo Lu and J. Andrew McCammon pp 1706–1716 DOI: 10.1021/ja8081704 |
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Intramolecular Electron-Transfer Rates in Mixed-Valence Triarylamines: Measurement by Variable-Temperature ESR Spectroscopy and Comparison with Optical Data Kelly Lancaster, Susan A. Odom, Simon C. Jones, S. Thayumanavan, Seth R. Marder, Jean-Luc Br pp 1717–1723 DOI: 10.1021/ja808465c Supporting Info |
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Dynamics of Water and Ions Near DNA: Comparison of Simulation to Time-Resolved Stokes-Shift Experiments Sobhan Sen, Daniele Andreatta, Sergei Y. Ponomarev, David L. Beveridge and Mark A. Berg pp 1724–1735 DOI: 10.1021/ja805405a Supporting Info |
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Mapping the Interaction between the Hemophore HasA and Its Outer Membrane Receptor HasR Using CRINEPT−TROSY NMR Spectroscopy C pp 1736–1744 DOI: 10.1021/ja804783x Supporting Info |
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Explorations into Neolignan Biosynthesis: Concise Total Syntheses of Helicterin B, Helisorin, and Helisterculin A from a Common Intermediate Scott A. Snyder and Ferenc Kontes pp 1745–1752 DOI: 10.1021/ja806865u Supporting Info |
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Total Synthesis of Diverse Carbogenic Complexity within the Resveratrol Class from a Common Building Block Scott A. Snyder, Steven P. Breazzano, Audrey G. Ross, Yunqing Lin and Alexandros L. Zografos pp 1753–1765 DOI: 10.1021/ja806183r Supporting Info |
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Ruthenium-Catalyzed N-Alkylation of Amines and Sulfonamides Using Borrowing Hydrogen Methodology M. Haniti S. A. Hamid, C. Liana Allen, Gareth W. Lamb, Aoife C. Maxwell, Hannah C. Maytum, Andrew J. A. Watson and Jonathan M. J. Williams pp 1766–1774 DOI: 10.1021/ja807323a Supporting Info |
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Green and Efficient Synthesis of Sulfonamides Catalyzed by Nano-Ru/Fe3O4 Feng Shi, Man Kin Tse, Shaolin Zhou, Marga-Martina Pohl, J pp 1775–1779 DOI: 10.1021/ja807681v Supporting Info |
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Synthesis, Optical, and Electronic Properties of Soluble Poly-p-phenylene Oligomers as Models for Molecular Wires Moloy Banerjee, Ruchi Shukla and Rajendra Rathore pp 1780–1786 DOI: 10.1021/ja805102d Supporting Info |
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Ultrafast Energy Transfer in Oligofluorene−Aluminum Bis(8-hydroxyquinoline)acetylacetone Coordination Polymers Victor A. Montes, Grigory V. Zyryanov, Evgeny Danilov, Neeraj Agarwal, Manuel A. Palacios and Pavel Anzenbacher, Jr. pp 1787–1795 DOI: 10.1021/ja805175w Supporting Info |
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Magnetism of C Adatoms on BN Nanostructures: Implications for Functional Nanodevices Jia Li, Gang Zhou, Ying Chen, Bing-Lin Gu and Wenhui Duan pp 1796–1801 DOI: 10.1021/ja805632p Supporting Info |
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Templated Nanocrystal-Based Porous TiO2 Films for Next-Generation Electrochemical Capacitors Torsten Brezesinski, John Wang, Julien Polleux, Bruce Dunn and Sarah H. Tolbert pp 1802–1809 DOI: 10.1021/ja8057309 Supporting Info |
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Films of Agarose Enable Rapid Formation of Giant Liposomes in Solutions of Physiologic Ionic Strength Kim S. Horger, Daniel J. Estes, Ricardo Capone and Michael Mayer pp 1810–1819 DOI: 10.1021/ja805625u Supporting Info |
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Probing Heteronuclear 15N−17O and 13C−17O Connectivities and Proximities by Solid-State NMR Spectroscopy Ivan Hung, Anne-Christine Uldry, Johanna Becker-Baldus, Amy L. Webber, Alan Wong, Mark E. Smith, Si pp 1820–1834 DOI: 10.1021/ja805898d Supporting Info |
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Platinum(II) Complexes with Dipyridophenazine Ligands as Human Telomerase Inhibitors and Luminescent Probes for G-Quadruplex DNA Dik-Lung Ma, Chi-Ming Che and Siu-Cheong Yan pp 1835–1846 DOI: 10.1021/ja806045x Supporting Info |
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Catalytic Hydrodefluorination of Aromatic Fluorocarbons by Ruthenium N-Heterocyclic Carbene Complexes Steven P. Reade, Mary F. Mahon and Michael K. Whittlesey pp 1847–1861 DOI: 10.1021/ja806545e Supporting Info |
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Size-Dependent Kinetic Enhancement in Hydrogen Absorption and Desorption of the Li−Mg−N−H System Yongfeng Liu, Kai Zhong, Kun Luo, Mingxia Gao, Hongge Pan and Qidong Wang pp 1862–1870 DOI: 10.1021/ja806565t Supporting Info |
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Synthesis of Rod-Shaped Gold Nanorattles with Improved Plasmon Sensitivity and Catalytic Activity Yuriy Khalavka, Jan Becker and Carsten S pp 1871–1875 DOI: 10.1021/ja806766w Supporting Info |
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ILPR G-Quadruplexes Formed in Seconds Demonstrate High Mechanical Stabilities Zhongbo Yu, Joseph D. Schonhoft, Soma Dhakal, Rabindra Bajracharya, Ravi Hegde, Soumitra Basu and Hanbin Mao pp 1876–1882 DOI: 10.1021/ja806782s Supporting Info |
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Highly Stable Crystalline Catalysts Based on a Microporous Metal−Organic Framework and Polyoxometalates Chun-Yan Sun, Shu-Xia Liu, Da-Dong Liang, Kui-Zhan Shao, Yuan-Hang Ren and Zhong-Min Su pp 1883–1888 DOI: 10.1021/ja807357r Supporting Info |
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Orthogonal “Relay” Reactions for Designing Functionalized Soft Nanoparticles Hamilton Kakwere and S pp 1889–1895 DOI: 10.1021/ja8075499 Supporting Info |
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Inefficient Crystal Packing in Chiral [Ru(phen)3](PF6)2 Enables Oxygen Molecule Quenching of the Solid-State MLCT Emission Kari A. McGee and Kent R. Mann pp 1896–1902 DOI: 10.1021/ja8075605 Supporting Info |
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Imperfect Crystal and Unusual Semiconductor: Boron, a Frustrated Element Tadashi Ogitsu, Fran pp 1903–1909 DOI: 10.1021/ja807622w Supporting Info |
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Deprotection, Tethering, and Activation of a Catalytically Active Metalloporphyrin to a Chemically Active Metal Surface: [SAc]4P−Mn(III)Cl on Ag(100) Mark Turner, Owain P. H. Vaughan, Georgios Kyriakou, David J. Watson, Lukas J. Scherer, Greg J. E. Davidson, Jeremy K. M. Sanders and Richard M. Lambert pp 1910–1914 DOI: 10.1021/ja8076389 |
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Accurate Measurement of Alpha Proton Chemical Shifts of Excited Protein States by Relaxation Dispersion NMR Spectroscopy Patrik Lundstr pp 1915–1926 DOI: 10.1021/ja807796a Supporting Info |
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Gas−Surface Chemical Reactions at High Collision Energies? Michael J. Gordon, Xiangdong Qin, Alex Kutana and Konstantinos P. Giapis pp 1927–1930 DOI: 10.1021/ja807672n Supporting Info |
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Conformations of N-Heterocyclic Carbene Ligands in Ruthenium Complexes Relevant to Olefin Metathesis Ian C. Stewart, Diego Benitez, Daniel J. O’Leary, Ekaterina Tkatchouk, Michael W. Day, William A. Goddard, III and Robert H. Grubbs pp 1931–1938 DOI: 10.1021/ja8078913 Supporting Info |
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Electronic Structure of the Ground and Excited States of the CuA Site by NMR Spectroscopy Luciano A. Abriata, Gabriela N. Ledesma, Roberta Pierattelli and Alejandro J. Vila pp 1939–1946 DOI: 10.1021/ja8079669 Supporting Info |
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Diels−Alder Exo Selectivity in Terminal-Substituted Dienes and Dienophiles: Experimental Discoveries and Computational Explanations Yu-hong Lam, Paul Ha-Yeon Cheong, Jos pp 1947–1957 DOI: 10.1021/ja8079548 Supporting Info |
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Catalytic Consequences of Spatial Constraints and Acid Site Location for Monomolecular Alkane Activation on Zeolites Rajamani Gounder and Enrique Iglesia pp 1958–1971 DOI: 10.1021/ja808292c Supporting Info |
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Thermodynamic Analysis of the Effect of Cholesterol on Dipalmitoylphosphatidylcholine Lipid Membranes W. F. Drew Bennett, Justin L. MacCallum and D. Peter Tieleman pp 1972–1978 DOI: 10.1021/ja808541r |
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Simple Chemical Transformation of Lignocellulosic Biomass into Furans for Fuels and Chemicals Joseph B. Binder and Ronald T. Raines pp 1979–1985 DOI: 10.1021/ja808537j Supporting Info |
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Structure of the Biliverdin Radical Intermediate in Phycocyanobilin:Ferredoxin Oxidoreductase Identified by High-Field EPR and DFT Stefan Stoll, Alexander Gunn, Marcin Brynda, Wesley Sughrue, Amanda C. Kohler, Andrew Ozarowski, Andrew J. Fisher, J. Clark Lagarias and R. David Britt pp 1986–1995 DOI: 10.1021/ja808573f Supporting Info |
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Five-Membered Zirconacycloallenoids: Synthesis and Characterization of Members of a Unique Class of Internally Metal-Stabilized Bent Allenoid Compounds Juri Ugolotti, Gerald Kehr, Roland Fr pp 1996–2007 DOI: 10.1021/ja8084302 Supporting Info |
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Coumarin-Derived Cu2+-Selective Fluorescence Sensor: Synthesis, Mechanisms, and Applications in Living Cells Hyo Sung Jung, Pil Seung Kwon, Jeong Won Lee, Jae Il Kim, Chang Seop Hong, Jong Wan Kim, Shihai Yan, Jin Yong Lee, Jung Hwa Lee, Taiha Joo and Jong Seung Kim pp 2008–2012 DOI: 10.1021/ja808611d Supporting Info |
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Identification and Cleavage Site Analysis of DNA Sequences Bound Strongly by Bleomycin Qian Ma, Yoshitsugu Akiyama, Zhidong Xu, Kazuhide Konishi and Sidney M. Hecht pp 2013–2022 DOI: 10.1021/ja808629s |
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Efficient Intramolecular General-Acid Catalysis of the Reactions of α-Effect Nucleophiles and Ammonia Oxide with a Phosphate Triester Anthony J. Kirby, Daniel W. Tondo, Michelle Medeiros, Bruno S. Souza, Jacks P. Priebe, Marcelo F. Lima and Faruk Nome pp 2023–2028 DOI: 10.1021/ja808746f Supporting Info |
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On the Mechanism of B(C6F5)3-Catalyzed Direct Hydrogenation of Imines: Inherent and Thermally Induced Frustration Tibor Andr pp 2029–2036 DOI: 10.1021/ja809125r Supporting Info |
Issue 06
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A Tandem Approach to Photoactivated Olefin Metathesis: Combining a Photoacid Generator with an Acid Activated Catalyst Benjamin K. Keitz and Robert H. Grubbs pp 2038–2039 DOI: 10.1021/ja807187u Supporting Info |
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Selective Fluorogenic and Chromogenic Probe for Detection of Silver Ions and Silver Nanoparticles in Aqueous Media Amrita Chatterjee, Mithun Santra, Nayoun Won, Sungjee Kim, Jae Kyung Kim, Seung Bin Kim and Kyo Han Ahn pp 2040–2041 DOI: 10.1021/ja807230c Supporting Info |
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Couplings between Peptide Linkages across a 310-Helical Hydrogen Bond Revealed by Two-Dimensional Infrared Spectroscopy Hiroaki Maekawa, Matteo De Poli, Claudio Toniolo and Nien-Hui Ge pp 2042–2043 DOI: 10.1021/ja807572f Supporting Info |
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Experimental Evidence for Water Mediated Electron Transfer Through Bis-Amino Acid Donor−Bridge−Acceptor Oligomers Subhasis Chakrabarti, Matthew F. L. Parker, Christopher W. Morgan, Christian E. Schafmeister and David H. Waldeck pp 2044–2045 DOI: 10.1021/ja8079324 Supporting Info |
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Interactions of a Tetraanionic Porphyrin with DNA: from a Z-DNA Sensor to a Versatile Supramolecular Device Alessandro D’Urso, Angela Mammana, Milan Balaz, Andrea E. Holmes, Nina Berova, Rosaria Lauceri and Roberto Purrello pp 2046–2047 DOI: 10.1021/ja808099u Supporting Info |
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A Secondary Kinetic Isotope Effect Study of the 1-Deoxy-d-xylulose-5-phosphate Reductoisomerase-Catalyzed Reaction: Evidence for a Retroaldol-Aldol Rearrangement Jeffrey W. Munos, Xiaotao Pu, Steven O. Mansoorabadi, Hak Joong Kim and Hung-wen Liu pp 2048–2049 DOI: 10.1021/ja807987h Supporting Info |
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Reversible Haptotropic Shift in Zirconocene−Hexapentaene Complexes Noriyuki Suzuki, Daisuke Hashizume, Hajime Yoshida, Meguru Tezuka, Keisuke Ida, Sayoko Nagashima and Teiji Chihara pp 2050–2051 DOI: 10.1021/ja8077472 Supporting Info |
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Synthesis of Epoxides by Palladium-Catalyzed Reactions of Tertiary Allyl Alcohols with Aryl or Alkenyl Halides Sayuri Hayashi, Hideki Yorimitsu and Koichiro Oshima pp 2052–2053 DOI: 10.1021/ja8084065 Supporting Info |
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A Mutagenesis-Free Approach to Assignment of 19F NMR Resonances in Biosynthetically Labeled Proteins Julianne L. Kitevski-LeBlanc, M. Sameer Al-Abdul-Wahid and R. Scott Prosser pp 2054–2055 DOI: 10.1021/ja8085752 Supporting Info |
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Asymmetric Synthesis of Medium-Sized Rings by Intramolecular Au(I)-Catalyzed Cyclopropanation Iain D. G. Watson, Stefanie Ritter and F. Dean Toste pp 2056–2057 DOI: 10.1021/ja8085005 Supporting Info |
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Adsorption−Desorption Induced Structural Changes of Cu-MOF Evidenced by Solid State NMR and EPR Spectroscopy Yijiao Jiang, Jun Huang, Besnik Kasumaj, Gunnar Jeschke, Michael Hunger, Tamas Mallat and Alfons Baiker pp 2058–2059 DOI: 10.1021/ja8088718 Supporting Info |
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Facile Synthesis of Highly Stable Gold Nanoparticles and Their Unexpected Excellent Catalytic Activity for Suzuki−Miyaura Cross-Coupling Reaction in Water Jie Han, Yan Liu and Rong Guo pp 2060–2061 DOI: 10.1021/ja808935n Supporting Info |
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Organoactinide-Mediated Hydrothiolation of Terminal Alkynes with Aliphatic, Aromatic, and Benzylic Thiols Charles J. Weiss, Stephen D. Wobser and Tobin J. Marks pp 2062–2063 DOI: 10.1021/ja808764q Supporting Info |
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Nazarov Type Cyclization on an Osmium−Dienylcarbene Complex Tamara Bola pp 2064–2065 DOI: 10.1021/ja8093058 Supporting Info |
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Direct Vinylation of Alcohols or Aldehydes Employing Alkynes as Vinyl Donors: A Ruthenium Catalyzed C−C Bond-Forming Transfer Hydrogenation Ryan L. Patman, Mani Raj Chaulagain, Vanessa M. Williams and Michael J. Krische pp 2066–2067 DOI: 10.1021/ja809456u Supporting Info |
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Synthesis of Thermally Stable Extra-Large Pore Crystalline Materials: A Uranyl Germanate with 12-Ring Channels Chia-Hui Lin, Ray-Kuang Chiang and Kwang-Hwa Lii pp 2068–2069 DOI: 10.1021/ja8084143 Supporting Info |
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Single Conical Nanopores Displaying pH-Tunable Rectifying Characteristics. Manipulating Ionic Transport With Zwitterionic Polymer Brushes Basit Yameen, Mubarak Ali, Reinhard Neumann, Wolfgang Ensinger, Wolfgang Knoll and Omar Azzaroni pp 2070–2071 DOI: 10.1021/ja8086104 Supporting Info |
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Gene Regulation with Polyvalent siRNA−Nanoparticle Conjugates David A. Giljohann, Dwight S. Seferos, Andrew E. Prigodich, Pinal C. Patel and Chad A. Mirkin pp 2072–2073 DOI: 10.1021/ja808719p Supporting Info |
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Protein Folding Rates and Stability: How Much Is There Beyond Size? David De Sancho, Urmi Doshi and Victor Mu pp 2074–2075 DOI: 10.1021/ja808843h Supporting Info |
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Highly Fluorescent Rigid Supramolecular Polymeric Nanowires Constructed Through Multiple Hydrogen Bonds Jia Luo, Ting Lei, Lei Wang, Yuguo Ma, Yong Cao, Jian Wang and Jian Pei pp 2076–2077 DOI: 10.1021/ja8090774 Supporting Info |
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Alternative Donor−Acceptor Stacks from Crown Ethers and Naphthalene Diimide Derivatives: Rapid, Selective Formation from Solution and Solid State Grinding Gayane Koshkakaryan, Liana M. Klivansky, Dennis Cao, Marian Snauko, Simon J. Teat, Jochem O. Struppe and Yi Liu pp 2078–2079 DOI: 10.1021/ja809088v Supporting Info |
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Tightly Connected Water Wires Facilitate Fast Proton Uptake at The Proton Entrance of Proton Pumping Proteins Wei Gu and Volkhard Helms pp 2080–2081 DOI: 10.1021/ja809301w Supporting Info |
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Metal-Catalyst-Free Growth of Single-Walled Carbon Nanotubes Bilu Liu, Wencai Ren, Libo Gao, Shisheng Li, Songfeng Pei, Chang Liu, Chuanbin Jiang and Hui-Ming Cheng pp 2082–2083 DOI: 10.1021/ja8093907 Supporting Info |
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Nickel-Mediated Three-Component Cycloaddition Reaction of Carboryne, Alkenes, and Alkynes Zaozao Qiu and Zuowei Xie pp 2084–2085 DOI: 10.1021/ja809389k Supporting Info |
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Enantioselective Intramolecular Friedel−Crafts-Type α-Arylation of Aldehydes K. C. Nicolaou, R pp 2086–2087 DOI: 10.1021/ja809405c Supporting Info |
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Intrinsically Disordered p53 Extreme C-Terminus Binds to S100B(ββ) through “Fly-Casting” Jianhan Chen pp 2088–2089 DOI: 10.1021/ja809547p Supporting Info |
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Stereocontrolled Synthesis of Complicated Oxacyclic Compounds via Platinum-Catalyzed [4 + 2]-Cycloadditions and Annulations of Enynals with Allylic Alcohols Yu-Chia Hsu, Chun-Ming Ting and Rai-Shung Liu pp 2090–2091 DOI: 10.1021/ja809560c Supporting Info |
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The Effect of Alkynyl Groups on Torquoselectivity. Highly Stereoselective Olefination of Alkynyl Ketones with Ynolates Takashi Yoshikawa, Seiji Mori and Mitsuru Shindo pp 2092–2093 DOI: 10.1021/ja809592q Supporting Info |
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Metal-Catalyst-Free Growth of Single-Walled Carbon Nanotubes on Substrates Shaoming Huang, Qiran Cai, Jiangying Chen, Yong Qian and Lijie Zhang pp 2094–2095 DOI: 10.1021/ja809635s Supporting Info |
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Asymmetric C2−C3 Cyclopentannulation of the Indole Ring Jos pp 2096–2097 DOI: 10.1021/ja809919t Supporting Info |
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Cation−π Controlled Solid-State Photodimerization of 4-Azachalcones Shinji Yamada and Yoko Tokugawa pp 2098–2099 DOI: 10.1021/ja809906c Supporting Info |
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Organotellurium-Mediated Controlled/Living Radical Polymerization Initiated by Direct C−Te Bond Photolysis Shigeru Yamago, Yuu Ukai, Atsushi Matsumoto and Yasuyuki Nakamura pp 2100–2101 DOI: 10.1021/ja8099689 Supporting Info |
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Monolayer Resist for Patterned Contact Printing of Aligned Nanowire Arrays Toshitake Takahashi, Kuniharu Takei, Johnny C. Ho, Yu-Lun Chueh, Zhiyong Fan and Ali Javey pp 2102–2103 DOI: 10.1021/ja8099954 Supporting Info |
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Synthesis and Theoretical Characterization of an Acetylene-Ammonia Cocrystal Roland Boese, Dieter Bl pp 2104–2106 DOI: 10.1021/ja8059705 Supporting Info |
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Initial Response of the Potassium Channel Voltage Sensor to a Transmembrane Potential Werner Treptow, Mounir Tarek and Michael L. Klein pp 2107–2109 DOI: 10.1021/ja807330g Supporting Info |
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In Vitro Imaging and in Vivo Liver Targeting with Carbohydrate Capped Quantum Dots Raghavendra Kikkeri, Bernd Lepenies, Alexander Adibekian, Paola Laurino and Peter H. Seeberger pp 2110–2112 DOI: 10.1021/ja807711w Supporting Info |
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Cascade Reactions during Coronafacic Acid Biosynthesis: Elongation, Cyclization, and Functionalization during Cfa7-Catalyzed Condensation Eric R. Strieter, Alexander Koglin, Zachary D. Aron and Christopher T. Walsh pp 2113–2115 DOI: 10.1021/ja8077945 Supporting Info |
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Selective C−H Activation α to Primary Amines. Bridging Metallaaziridines for Catalytic, Intramolecular α-Alkylation Jason A. Bexrud, Patrick Eisenberger, David C. Leitch, Philippa R. Payne and Laurel L. Schafer pp 2116–2118 DOI: 10.1021/ja808862w Supporting Info |
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N2′→P3′ Phosphoramidate Glycerol Nucleic Acid as a Potential Alternative Genetic System Jesse J. Chen, Xin Cai and Jack W. Szostak pp 2119–2121 DOI: 10.1021/ja809069b Supporting Info |
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Using Marine Natural Products to Discover a Protease that Catalyzes Peptide Macrocyclization of Diverse Substrates Jaeheon Lee, John McIntosh, Brian J. Hathaway and Eric W. Schmidt pp 2122–2124 DOI: 10.1021/ja8092168 Supporting Info |
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Imaging Single ZnO Vertical Nanowire Laser Cavities Using UV-laser Scanning Confocal Microscopy Daniel J. Gargas, Maria Eugenia Toimil-Molares and Peidong Yang pp 2125–2127 DOI: 10.1021/ja8092339 Supporting Info |
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A New Synthesis of Difluorodiazirine and the Absolute Reactivity of Difluorocarbene Robert A. Moss, Lei Wang and Karsten Krogh-Jespersen pp 2128–2130 DOI: 10.1021/ja809370j Supporting Info |
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Mapping NO Movements in Crystalline [Fe(Porph)(NO)(1-MeIm)] Nathan J. Silvernail, Alexander Barabanschikov, J. Timothy Sage, Bruce C. Noll and W. Robert Scheidt pp 2131–2140 DOI: 10.1021/ja8055613 Supporting Info |
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Redox Site-Mediated Charge Transport in a Hg−SAM//Ru(NH3)63+/2+//SAM−Hg Junction with a Dynamic Interelectrode Separation: Compatibility with Redox Cycling and Electron Hopping Mechanisms Elizabeth Tran, Adam E. Cohen, Royce W. Murray, Maria A. Rampi and George M. Whitesides pp 2141–2150 DOI: 10.1021/ja804075y |
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Nanoparticles of Adaptive Supramolecular Networks Self-Assembled from Nucleotides and Lanthanide Ions Ryuhei Nishiyabu, Nozomi Hashimoto, Ten Cho, Kazuto Watanabe, Takefumi Yasunaga, Ayataka Endo, Kenji Kaneko, Takuro Niidome, Masaharu Murata, Chihaya Adachi, Yoshiki Katayama, Makoto Hashizume and Nobuo Kimizuka pp 2151–2158 DOI: 10.1021/ja8058843 Supporting Info |
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High Capacity Hydrogen Adsorption in Cu(II) Tetracarboxylate Framework Materials: The Role of Pore Size, Ligand Functionalization, and Exposed Metal Sites Xiang Lin, Irvin Telepeni, Alexander J. Blake, Anne Dailly, Craig M. Brown, Jason M. Simmons, Marco Zoppi, Gavin S. Walker, K. Mark Thomas, Timothy J. Mays, Peter Hubberstey, Neil R. Champness and Martin Schr pp 2159–2171 DOI: 10.1021/ja806624j Supporting Info |
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High Population of Individualized SWCNTs through the Adsorption of Water-Soluble Perylenes Claudia Backes, Cordula D. Schmidt, Frank Hauke, Christoph B pp 2172–2184 DOI: 10.1021/ja805660b Supporting Info |
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Zinc Oxide Nanostructures Confined in Porous Silicas Benoit Coasne, Aude Mezy, R. J. M. Pellenq, D. Ravot and J. C. Tedenac pp 2185–2198 DOI: 10.1021/ja806666n Supporting Info |
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Element Lines: Bonding in the Ternary Gold Polyphosphides, Au2MP2 with M = Pb, Tl, or Hg Xiao-Dong Wen, Thomas J. Cahill and Roald Hoffmann pp 2199–2207 DOI: 10.1021/ja806884a Supporting Info |
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Surface-Enhanced Raman Scattering Based Ligase Detection Reaction Yun Suk Huh, Adam J. Lowe, Aaron D. Strickland, Carl A. Batt and David Erickson pp 2208–2213 DOI: 10.1021/ja807526v Supporting Info |
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Glycosynthases Enable a Highly Efficient Chemoenzymatic Synthesis of N-Glycoproteins Carrying Intact Natural N-Glycans Wei Huang, Cishan Li, Bing Li, Midori Umekawa, Kenji Yamamoto, Xinyu Zhang and Lai-Xi Wang pp 2214–2223 DOI: 10.1021/ja8074677 Supporting Info |
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An Approach to the Construction of Tailor-Made Amphiphilic Peptides That Strongly and Selectively Bind to Hairpin RNA Targets Su Jin Lee, Soonsil Hyun, Jeffrey S. Kieft and Jaehoon Yu pp 2224–2230 DOI: 10.1021/ja807609m Supporting Info |
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Structures and Aggregation of the Methylamine−Borane Molecules, MenH3−nN·BH3 (n = 1−3), Studied by X-ray Diffraction, Gas-Phase Electron Diffraction, and Quantum Chemical Calculations Simon Aldridge, Anthony J. Downs, Christina Y. Tang, Simon Parsons, Michael C. Clarke, Russell D. L. Johnstone, Heather E. Robertson, David W. H. Rankin and Derek A. Wann pp 2231–2243 DOI: 10.1021/ja807545p Supporting Info |
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Dendritic Structure Having a Potential Gradient: New Synthesis and Properties of Carbazole Dendrimers Ken Albrecht and Kimihisa Yamamoto pp 2244–2251 DOI: 10.1021/ja807312e Supporting Info |
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Reversible Lability by in Situ Reaction of Self-Assembled Monolayers H pp 2252–2259 DOI: 10.1021/ja807648g |
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Ru(bpy)3 Covalently Doped Silica Nanoparticles as Multicenter Tunable Structures for Electrochemiluminescence Amplification Simone Zanarini, Enrico Rampazzo, Leopoldo Della Ciana, Massimo Marcaccio, Ettore Marzocchi, Marco Montalti, Francesco Paolucci and Luca Prodi pp 2260–2267 DOI: 10.1021/ja8077158 Supporting Info |
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Enhanced Intersystem Crossing in Three-Spin Systems: A Perturbation Theory Treatment Sina Yeganeh, Michael R. Wasielewski and Mark A. Ratner pp 2268–2273 DOI: 10.1021/ja807590q Supporting Info |
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Tetrapod-Shaped Colloidal Nanocrystals of II−VI Semiconductors Prepared by Seeded Growth Angela Fiore, Rosanna Mastria, Maria Grazia Lupo, Guglielmo Lanzani, Cinzia Giannini, Elvio Carlino, Giovanni Morello, Milena De Giorgi, Yanqin Li, Roberto Cingolani and Liberato Manna pp 2274–2282 DOI: 10.1021/ja807874e Supporting Info |
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Structure-Based Approach to the Photocontrol of Protein Folding Fuzhong Zhang, Arash Zarrine-Afsar, M. Sameer Al-Abdul-Wahid, R. Scott Prosser, Alan R. Davidson and G. Andrew Woolley pp 2283–2289 DOI: 10.1021/ja807938v Supporting Info |
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High Lipophilicity of Perfluoroalkyl Carboxylate and Sulfonate: Implications for Their Membrane Permeability Ping Jing, Patrick J. Rodgers and Shigeru Amemiya pp 2290–2296 DOI: 10.1021/ja807961s Supporting Info |
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Cleavage of Four Carbon−Carbon Bonds during Biosynthesis of the Griseorhodin A Spiroketal Pharmacophore Zeynep Yunt, Kathrin Reinhardt, Aiying Li, Marianne Engeser, Hans-Martin Dahse, Michael G pp 2297–2305 DOI: 10.1021/ja807827k Supporting Info |
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Theory for Protein Folding Cooperativity: Helix Bundles Kingshuk Ghosh and K. A. Dill pp 2306–2312 DOI: 10.1021/ja808136x |
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Effect of Mutation of Carboxyl Side-Chain Amino Acids Near the Heme on the Midpoint Potentials and Ligand Binding Constants of Nitrophorin 2 and Its NO, Histamine, and Imidazole Complexes Robert E. Berry, Maxim N. Shokhirev, Arthur Y. W. Ho, Fei Yang, Tatiana K. Shokhireva, Hongjun Zhang, Andrzej Weichsel, William R. Montfort and F. Ann Walker pp 2313–2327 DOI: 10.1021/ja808105d Supporting Info |
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Redox Actuation of a Microcantilever Driven by a Self-Assembled Ferrocenylundecanethiolate Monolayer: An Investigation of the Origin of the Micromechanical Motion and Surface Stress Lana L. Norman and Antonella Badia pp 2328–2337 DOI: 10.1021/ja808400s Supporting Info |
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Different Intermediate Populations Formed by Tazobactam, Sulbactam, and Clavulanate Reacting with SHV-1 β-Lactamases: Raman Crystallographic Evidence Matthew Kalp, Monica A. Totir, John D. Buynak and Paul R. Carey pp 2338–2347 DOI: 10.1021/ja808311s Supporting Info |
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Evolution of the Total Synthesis of (−)-Okilactomycin Exploiting a Tandem Oxy-Cope Rearrangement/Oxidation, a Petasis−Ferrier Union/Rearrangement, and Ring-Closing Metathesis Amos B. Smith III, Todd Bosanac and Kallol Basu pp 2348–2358 DOI: 10.1021/ja8084669 Supporting Info |
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DNA Mismatch Binding and Antiproliferative Activity of Rhodium Metalloinsertors Russell J. Ernst, Hang Song and Jacqueline K. Barton pp 2359–2366 DOI: 10.1021/ja8081044 Supporting Info |
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Gd5Si4−xPx: Targeted Structural Changes through Increase in Valence Electron Count Volodymyr Svitlyk, Gordon J. Miller and Yurij Mozharivskyj pp 2367–2374 DOI: 10.1021/ja8085033 Supporting Info |
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Closer Insight into the Reactivity of TMP−Dialkyl Zincates in Directed ortho-Zincation of Anisole: Experimental Evidence of Amido Basicity and Structural Elucidation of Key Reaction Intermediates William Clegg, Ben Conway, Eva Hevia, Matthew D. McCall, Luca Russo and Robert E. Mulvey pp 2375–2384 DOI: 10.1021/ja8087168 Supporting Info |
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Spectroscopic Studies of the Light-Color Modulation Mechanism of Firefly (Beetle) Bioluminescence Takashi Hirano, Yosuke Hasumi, Kazuhiro Ohtsuka, Shojiro Maki, Haruki Niwa, Minoru Yamaji and Daisuke Hashizume pp 2385–2396 DOI: 10.1021/ja808836b Supporting Info |
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Transition-State Geometry Measurements from 13C Isotope Effects. The Experimental Transition State for the Epoxidation of Alkenes with Oxaziridines Jennifer S. Hirschi, Tetsuya Takeya, Chao Hang and Daniel A. Singleton pp 2397–2403 DOI: 10.1021/ja8088636 Supporting Info |
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Adsorption-Driven Surface Segregation of the Less Reactive Alloy Component Klas J. Andersson, Federico Calle-Vallejo, Jan Rossmeisl and Ib Chorkendorff pp 2404–2407 DOI: 10.1021/ja8089087 |
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Multivalent Recognition of Peptides by Modular Self-Assembled Receptors Joseph J. Reczek, Aimee A. Kennedy, Brian T. Halbert and Adam R. Urbach pp 2408–2415 DOI: 10.1021/ja808936y Supporting Info |
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MOLCAS 7.2 James A. Duncan p 2416 DOI: 10.1021/ja900300h |
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Chemical Oceanography and the Marine Carbon Cycle Rainer Amon p 2417 DOI: 10.1021/ja900090t |
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Radiation Induced Molecular Phenomena in Nucleic Acids: A Comprehensive Theoretical and Experimental Analysis. Challenges and Advances in Computational Chemistry and Physics, 5 Bern Kohler pp 2417–2418 DOI: 10.1021/ja810048v |
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Ion-Radical Organic Chemistry: Principles and Applications Gregory K. Friestad p 2418 DOI: 10.1021/ja900119d |
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Fiesers’ Reagents for Organic Synthesis, Volume 24 p 2418 DOI: 10.1021/ja9003188 |
Issue 07
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Spore Photoproduct Lyase Catalyzes Specific Repair of the 5R but Not the 5S Spore Photoproduct Tilak Chandra, Sunshine C. Silver, Egidijus Zilinskas, Eric M. Shepard, William E. Broderick and Joan B. Broderick pp 2420–2421 DOI: 10.1021/ja807375c Supporting Info |
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Kinetically Controlled Self-Assembly of DNA Oligomers Daniel Lubrich, Simon J. Green and Andrew J. Turberfield pp 2422–2423 DOI: 10.1021/ja807765v Supporting Info |
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Ultrafast Charge Separation in Multiexcited CdSe Quantum Dots Mediated by Adsorbed Electron Acceptors Victor V. Matylitsky, Lars Dworak, Vladimir V. Breus, Thomas Basch pp 2424–2425 DOI: 10.1021/ja808084y Supporting Info |
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Alignment of Lone Pairs in a New Polar Material: Synthesis, Characterization, and Functional Properties of Li2Ti(IO3)6 Hong-Young Chang, Sang-Hwan Kim, P. Shiv Halasyamani and Kang Min Ok pp 2426–2427 DOI: 10.1021/ja808469a Supporting Info |
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Stiff, and Sticky in the Right Places: Binding Interactions in Isolated Mechanically Interlocked Molecules Probed by Mid-Infrared Spectroscopy Anouk M. Rijs, Isabelle Compagnon, Jos Oomens, Jeffrey S. Hannam, David A. Leigh and Wybren J. Buma pp 2428–2429 DOI: 10.1021/ja808788c |
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Gold Nanostructures in Diacetylene Monolayer Templates Noa Markovich, Roman Volinsky and Raz Jelinek pp 2430–2431 DOI: 10.1021/ja808718s Supporting Info |
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Phthalocyanine Dimerization-Based Molecular Beacons Using Near-IR Fluorescence Irina V. Nesterova, S. Sibel Erdem, Serhii Pakhomov, Robert P. Hammer and Steven A. Soper pp 2432–2433 DOI: 10.1021/ja8088247 Supporting Info |
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π-Nucleophile Traps for Metallonitrene/Alkyne Cascade Reactions: A Versatile Process for the Synthesis of α-Aminocyclopropanes and β-Aminostyrenes Aaron R. Thornton, V pp 2434–2435 DOI: 10.1021/ja809078d Supporting Info |
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MgB2 Superconducting Whiskers Synthesized by Using the Hybrid Physical−Chemical Vapor Deposition Yazhou Wang, Chenggang Zhuang, Jingyun Gao, Xudong Shan, Jingmin Zhang, Zhimin Liao, Hongjun Xu, Dapeng Yu and Qingrong Feng pp 2436–2437 DOI: 10.1021/ja8087828 Supporting Info |
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Carbohydrate Dependent Targeting of Cancer Cells by Bleomycin−Microbubble Conjugates Jean-Charles Chapuis, Ryan M. Schmaltz, Krystal S. Tsosie, Marek Belohlavek and Sidney M. Hecht pp 2438–2439 DOI: 10.1021/ja8091104 Supporting Info |
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Pseudo-Capsule Assemblies Characterized by 19F NMR Techniques Agustí Lled pp 2440–2441 DOI: 10.1021/ja809224p Supporting Info |
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Gold Nanoparticles Surface Plasmon Field Effects on the Proton Pump Process of the Bacteriorhodopsin Photosynthesis Arianna Biesso, Wei Qian, Xiaohua Huang and Mostafa A. El-Sayed pp 2442–2443 DOI: 10.1021/ja8088873 |
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Cellular Lipid Metabolism Is Influenced by the Coordination Environment of Copper David C. Kennedy, Rodney K. Lyn and John Paul Pezacki pp 2444–2445 DOI: 10.1021/ja809451w Supporting Info |
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Melting Dramatically Enhances the Reactivity of Aluminum Nanoclusters Baopeng Cao, Anne K. Starace, Oscar H. Judd and Martin F. Jarrold pp 2446–2447 DOI: 10.1021/ja809516h |
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2-Aminopurine-Modified Abasic-Site-Containing Duplex DNA for Highly Selective Detection of Theophylline Minjie Li, Yusuke Sato, Seiichi Nishizawa, Takehiro Seino, Kodai Nakamura and Norio Teramae pp 2448–2449 DOI: 10.1021/ja8095625 Supporting Info |
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In Situ Preparation and Modification of Supported Lipid Layers by Lipid Transfer from Vesicles Studied by QCM-D and TOF-SIMS Angelika Kunze, Peter Sj pp 2450–2451 DOI: 10.1021/ja809608n Supporting Info |
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Highly Selective Monomethylation of Primary Amines Through Host−Guest Product Sequestration Roger M. Yebeutchou and Enrico Dalcanale pp 2452–2453 DOI: 10.1021/ja809614y Supporting Info |
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Optical Characterizations and Electronic Devices of Nearly Pure (10,5) Single-Walled Carbon Nanotubes Li Zhang, Xiaomin Tu, Kevin Welsher, Xinran Wang, Ming Zheng and Hongjie Dai pp 2454–2455 DOI: 10.1021/ja8096674 Supporting Info |
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Necklace-like Chains of Hybrid Nanospheres Consisting of Pd Nanocystals and Peptidic Lipids Yong Zhou, Masaki Kogiso and Toshimi Shimizu pp 2456–2457 DOI: 10.1021/ja809728c Supporting Info |
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Catechols as Membrane Anion Transporters Sofya Kostina Berezin and Jeffery T. Davis pp 2458–2459 DOI: 10.1021/ja809733c Supporting Info |
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A Stable Hyponitrite-Bridged Iron Porphyrin Complex Nan Xu, Adam L. O. Campbell, Douglas R. Powell, Jana Khandogin and George B. Richter-Addo pp 2460–2461 DOI: 10.1021/ja809781r Supporting Info |
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High Electron Mobility in Vacuum and Ambient for PDIF-CN2 Single-Crystal Transistors Anna S. Molinari, Helena Alves, Zhihua Chen, Antonio Facchetti and Alberto F. Morpurgo pp 2462–2463 DOI: 10.1021/ja809848y Supporting Info |
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Highly Uniaxial Orientation in Oligo(p-phenylenevinylene) Films Induced During Wet-Coating Process Takeshi Nishizawa, Hady Kesuma Lim, Keisuke Tajima and Kazuhito Hashimoto pp 2464–2465 DOI: 10.1021/ja810123b Supporting Info |
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Oxy-Functionalization of Nucleophilic Rhenium(I) Metal Carbon Bonds Catalyzed by Selenium(IV) William J. Tenn, III, Brian L. Conley, Claas H. H pp 2466–2468 DOI: 10.1021/ja806814c Supporting Info |
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Expansile Nanoparticles: Synthesis, Characterization, and in Vivo Efficacy of an Acid-Responsive Polymeric Drug Delivery System Aaron P. Griset, Joseph Walpole, Rong Liu, Ann Gaffey, Yolonda L. Colson and Mark W. Grinstaff pp 2469–2471 DOI: 10.1021/ja807416t Supporting Info |
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Observation of β-Sheet Aggregation in a Gas-Phase Tau-Peptide Dimer Timothy D. Vaden, Sally A. N. Gowers and Lavina C. Snoek pp 2472–2474 DOI: 10.1021/ja807760d Supporting Info |
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Disulfide-Linked, Gold Nanoparticle Based Reagent for Detecting Small Molecular Weight Thiols Suzanne Durocher, Asad Rezaee, Caroline Hamm, Chitra Rangan, Silvia Mittler and Bulent Mutus pp 2475–2477 DOI: 10.1021/ja808548x |
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Highly Specific and Sensitive Electrochemical Genotyping via Gap Ligation Reaction and Surface Hybridization Detection Yong Huang, Yan-Li Zhang, Xiangmin Xu, Jian-Hui Jiang, Guo-Li Shen and Ru-Qin Yu pp 2478–2480 DOI: 10.1021/ja808700d Supporting Info |
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Genetic Incorporation of a Metal-Ion Chelating Amino Acid into Proteins as a Biophysical Probe Hyun Soo Lee, Glen Spraggon, Peter G. Schultz and Feng Wang pp 2481–2483 DOI: 10.1021/ja808340b Supporting Info |
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Protein Nanoparticles Engineered to Sense Kinase Activity in MRI Mikhail G. Shapiro, Jerzy O. Szablowski, Robert Langer and Alan Jasanoff pp 2484–2486 DOI: 10.1021/ja8086938 Supporting Info |
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Nanoporous Crystals of Calixarene/Porphyrin Supramolecular Complex Functionalized by Diffusion and Coordination of Metal Ions Rita De Zorzi, Nicol Guidolin, Lucio Randaccio, Roberto Purrello and Silvano Geremia pp 2487–2489 DOI: 10.1021/ja808850d Supporting Info |
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Reversible Switching of Magnetism in Thiolate-Protected Au25 Superatoms Manzhou Zhu, Christine M. Aikens, Michael P. Hendrich, Rupal Gupta, Huifeng Qian, George C. Schatz and Rongchao Jin pp 2490–2492 DOI: 10.1021/ja809157f Supporting Info |
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A Light-Gated STOP−GO Molecular Shuttle Ali Coskun, Douglas C. Friedman, Hao Li, Kaushik Patel, Hussam A. Khatib and J. Fraser Stoddart pp 2493–2495 DOI: 10.1021/ja809225e Supporting Info |
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Development of a Formal [4 + 1] Cycloaddition: Pd(OAc)2-Catalyzed Intramolecular Cyclopropanation of 1,3-Dienyl β-Keto Esters and MgI2-Promoted Vinylcyclopropane−Cyclopentene Rearrangement Rockford W. Coscia and Tristan H. Lambert pp 2496–2498 DOI: 10.1021/ja809226x Supporting Info |
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Cyclopentadienone Iron Alcohol Complexes: Synthesis, Reactivity, and Implications for the Mechanism of Iron-Catalyzed Hydrogenation of Aldehydes Charles P. Casey and Hairong Guan pp 2499–2507 DOI: 10.1021/ja808683z Supporting Info |
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Development of an Arylthiobismuthine Cocatalyst in Organobismuthine-Mediated Living Radical Polymerization: Applications for Synthesis of Ultrahigh Molecular Weight Polystyrenes and Polyacrylates Eiichi Kayahara and Shigeru Yamago pp 2508–2513 DOI: 10.1021/ja8092899 Supporting Info |
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anti-Diastereo- and Enantioselective Carbonyl Crotylation from the Alcohol or Aldehyde Oxidation Level Employing a Cyclometallated Iridium Catalyst: α-Methyl Allyl Acetate as a Surrogate to Preformed Crotylmetal Reagents In Su Kim, Soo Bong Han and Michael J. Krische pp 2514–2520 DOI: 10.1021/ja808857w Supporting Info |
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High-Lamellar Ordering and Amorphous-Like π-Network in Short-Chain Thiazolothiazole−Thiophene Copolymers Lead to High Mobilities Itaru Osaka, Rui Zhang, Genevi pp 2521–2529 DOI: 10.1021/ja801475h Supporting Info |
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Multidimensional Exploration of Valley−Ridge Inflection Points on Potential-Energy Surfaces April N. Sheppard and Orlando Acevedo pp 2530–2540 DOI: 10.1021/ja803879k Supporting Info |
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Native-like RNA Tertiary Structures Using a Sequence-Encoded Cleavage Agent and Refinement by Discrete Molecular Dynamics Costin M. Gherghe, Christopher W. Leonard, Feng Ding, Nikolay V. Dokholyan and Kevin M. Weeks pp 2541–2546 DOI: 10.1021/ja805460e Supporting Info |
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A Hierarchy of Homodesmotic Reactions for Thermochemistry Steven E. Wheeler, Kendall N. Houk, Paul v. R. Schleyer and Wesley D. Allen pp 2547–2560 DOI: 10.1021/ja805843n Supporting Info |
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Photocurrent Enhancement of n-Type Cu2O Electrodes Achieved by Controlling Dendritic Branching Growth Colleen M. McShane and Kyoung-Shin Choi pp 2561–2569 DOI: 10.1021/ja806370s Supporting Info |
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Structure of Propeller-Type Parallel-Stranded RNA G-Quadruplexes, Formed by Human Telomeric RNA Sequences in K+ Solution Herry Martadinata and Anh Tu pp 2570–2578 DOI: 10.1021/ja806592z Supporting Info |
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Free-Standing Nanocomposite Multilayers with Various Length Scales, Adjustable Internal Structures, and Functionalities Seryun Lee, Bokyoung Lee, Bumjoon J. Kim, Junwoo Park, Misang Yoo, Wan Ki Bae, Kookheon Char, Craig J. Hawker, Joona Bang and Jinhan Cho pp 2579–2587 DOI: 10.1021/ja8064478 Supporting Info |
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Manipulating Crystal Orientation in Nanoscale Cylindrical Pores by Stereochemical Inhibition Benjamin D. Hamilton, Isabelle Weissbuch, Meir Lahav, Marc A. Hillmyer and Michael D. Ward pp 2588–2596 DOI: 10.1021/ja807193s |
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Multifrequency Electron Spin Resonance Spectra of a Spin-Labeled Protein Calculated from Molecular Dynamics Simulations Deniz Sezer, Jack H. Freed and Benoît Roux pp 2597–2605 DOI: 10.1021/ja8073819 Supporting Info |
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Invariant Polymorphism in Virus Capsid Assembly Hung D. Nguyen, Vijay S. Reddy and Charles L. Brooks III pp 2606–2614 DOI: 10.1021/ja807730x Supporting Info |
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Electrolyte-Dependent Electrosynthesis and Activity of Cobalt-Based Water Oxidation Catalysts Yogesh Surendranath, Mircea Dinc pp 2615–2620 DOI: 10.1021/ja807769r Supporting Info |
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Highly Reactive Porphyrin−Iron−Oxo Derivatives Produced by Photolyses of Metastable Porphyrin−Iron(IV) Diperchlorates Zhengzheng Pan, Qin Wang, Xin Sheng, John H. Horner and Martin Newcomb pp 2621–2628 DOI: 10.1021/ja807847q |
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Efficient Kinetic Macrocyclization Wen Feng, Kazuhiro Yamato, Liuqing Yang, Joseph S. Ferguson, Lijian Zhong, Shuliang Zou, Lihua Yuan, Xiao Cheng Zeng and Bing Gong pp 2629–2637 DOI: 10.1021/ja807935y Supporting Info |
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A Spectroscopic Study of Nicotine Analogue 2-Phenylpyrrolidine (PPD) Using Resonant Two-Photon Ionization (R2PI), Microwave, and 2D NMR Techniques Danielle E. Martin, Evan G. Robertson, Jonathan G. MacLellan, Peter D. Godfrey, Christopher D. Thompson and Richard J. S. Morrison pp 2638–2646 DOI: 10.1021/ja807995n Supporting Info |
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Flexible Polar Nanowires of Cs5BiP4Se12 from Weak Interactions between Coordination Complexes: Strong Nonlinear Optical Second Harmonic Generation In Chung, Jung-Hwan Song, Joon I. Jang, Arthur J. Freeman, John B. Ketterson and Mercouri G. Kanatzidis pp 2647–2656 DOI: 10.1021/ja808242g Supporting Info |
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Origin of High Fidelity in Target-Sequence Recognition by PNA−Ce(IV)/EDTA Combinations as Site-Selective DNA Cutters Yoshitaka Miyajima, Takumi Ishizuka, Yoji Yamamoto, Jun Sumaoka and Makoto Komiyama pp 2657–2662 DOI: 10.1021/ja808290e Supporting Info |
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Valence Anions of 9-Methylguanine−1-Methylcytosine Complexes. Computational and Photoelectron Spectroscopy Studies Anna Szyperska, Janusz Rak, Jerzy Leszczynski, Xiang Li, Yeon Jae Ko, Haopeng Wang and Kit H. Bowen pp 2663–2669 DOI: 10.1021/ja808313e Supporting Info |
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Ring-Expansion Metathesis Polymerization: Catalyst-Dependent Polymerization Profiles Yan Xia, Andrew J. Boydston, Yefeng Yao, Julia A. Kornfield, Irina A. Gorodetskaya, Hans W. Spiess and Robert H. Grubbs pp 2670–2677 DOI: 10.1021/ja808296a Supporting Info |
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Reactivity of (C5Me5)3LaLx Complexes: Synthesis of a Tris(pentamethylcyclopentadienyl) Complex with Two Additional Ligands, (C5Me5)3La(NCCMe3)2 William J. Evans, Thomas J. Mueller and Joseph W. Ziller pp 2678–2686 DOI: 10.1021/ja808763y Supporting Info |
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Critical Role of Substrate Conformational Change in the Proton Transfer Process Catalyzed by 4-Oxalocrotonate Tautomerase J. Javier Ruiz-Pern pp 2687–2698 DOI: 10.1021/ja8087423 Supporting Info |
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Design of SERS-Encoded, Submicron, Hollow Particles Through Confined Growth of Encapsulated Metal Nanoparticles Marcos Sanles-Sobrido, Wibke Exner, Laura Rodr pp 2699–2705 DOI: 10.1021/ja8088444 Supporting Info |
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Self-assembly of Collagen Peptides into Microflorettes via Metal Coordination Marcos M. Pires and Jean Chmielewski pp 2706–2712 DOI: 10.1021/ja8088845 Supporting Info |
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Evidence of Natural Isotopic Distribution from Single-Molecule SERS Pablo G. Etchegoin, Eric C. Le Ru and Matthias Meyer pp 2713–2716 DOI: 10.1021/ja808934d Supporting Info |
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Biologically Formed Mesoporous Amorphous Silica Martin Jensen, Ralf Keding, Thomas H pp 2717–2721 DOI: 10.1021/ja808847y Supporting Info |
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Synthesis and Magnetic and Charge-Transport Properties of the Correlated 4d Post-Perovskite CaRhO3 Kazunari Yamaura, Yuichi Shirako, Hiroshi Kojitani, Masao Arai, David P. Young, Masaki Akaogi, Mamoru Nakashima, Tetsuhiro Katsumata, Yoshiyuki Inaguma and Eiji Takayama-Muromachi pp 2722–2726 DOI: 10.1021/ja8091906 |
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Dendritic and Linear Macromolecular Architectures for Photovoltaics: A Photoinduced Charge Transfer Investigation Arpornrat Nantalaksakul, Astrid Mueller, Akamol Klaikherd, Christopher J. Bardeen and S. Thayumanavan pp 2727–2738 DOI: 10.1021/ja809194u Supporting Info |
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Noncooperative Formation of the Off-Pathway Molten Globule during Folding of the α−β Parallel Protein Apoflavodoxin Sanne M. Nabuurs, Adrie H. Westphal and Carlo P. M. van Mierlo pp 2739–2746 DOI: 10.1021/ja8089476 Supporting Info |
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Measuring and Relating the Electronic Structures of Nonmodel Supported Catalytic Materials to Their Performance Eranda Nikolla, Johannes Schwank and Suljo Linic pp 2747–2754 DOI: 10.1021/ja809291e Supporting Info |
Issue 08
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Controllable Fabrication of Supramolecular Nanocoils and Nanoribbons and Their Morphology-Dependent Photoswitching Yiqun Zhang, Penglei Chen, Lang Jiang, Wenping Hu and Minghua Liu pp 2756–2757 DOI: 10.1021/ja805891k Supporting Info |
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Amphiphilic Porphyrins for Second Harmonic Generation Imaging James E. Reeve, Hazel A. Collins, Kurt De Mey, Michael M. Kohl, Karl J. Thorley, Ole Paulsen, Koen Clays and Harry L. Anderson pp 2758–2759 DOI: 10.1021/ja8061369 Supporting Info |
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Many-Body Polarization Effects and the Membrane Dipole Potential Edward Harder, Alexander D. MacKerell, Jr. and Benoît Roux pp 2760–2761 DOI: 10.1021/ja806825g Supporting Info |
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C−H Bond Cleavage with Reductants: Re-Investigating the Reactivity of Monomeric MnIII/IV−Oxo Complexes and the Role of Oxo Ligand Basicity Trenton H. Parsell, Meng-Yin Yang and A. S. Borovik pp 2762–2763 DOI: 10.1021/ja8100825 Supporting Info |
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Synthesis of Stishovite Nanocrystals from Periodic Mesoporous Silica Paritosh Mohanty, Dong Li, Tianbo Liu, Yingwei Fei and Kai Landskron pp 2764–2765 DOI: 10.1021/ja8075007 Supporting Info |
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Hydrophilic Fluorescent Nanogel Thermometer for Intracellular Thermometry Chie Gota, Kohki Okabe, Takashi Funatsu, Yoshie Harada and Seiichi Uchiyama pp 2766–2767 DOI: 10.1021/ja807714j Supporting Info |
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Oxygen−Oxygen Bond Formation by the Ru-Hbpp Water Oxidation Catalyst Occurs Solely via an Intramolecular Reaction Pathway Sophie Romain, Fernando Bozoglian, Xavier Sala and Antoni Llobet pp 2768–2769 DOI: 10.1021/ja808166d Supporting Info |
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In Search of a Chemiluminescence 1,4-Dioxy Biradical Richard Bos, Sarah A. Tonkin, Graeme R. Hanson, Christopher M. Hindson, Kieran F. Lim and Neil W. Barnett pp 2770–2771 DOI: 10.1021/ja808401p |
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TiO2/TiSi2 Heterostructures for High-Efficiency Photoelectrochemical H2O Splitting Yongjing Lin, Sa Zhou, Xiaohua Liu, Stafford Sheehan and Dunwei Wang pp 2772–2773 DOI: 10.1021/ja808426h Supporting Info |
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Formation of Yolk/SiO2 Shell Structures Using Surfactant Mixtures as Template Xue-Jun Wu and Dongsheng Xu pp 2774–2775 DOI: 10.1021/ja808452r Supporting Info |
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MOFs as Adsorbents for Low Temperature Heating and Cooling Applications Stefan K. Henninger, Hesham A. Habib and Christoph Janiak pp 2776–2777 DOI: 10.1021/ja808444z Supporting Info |
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Magnetically Recyclable Fe@Pt Core−Shell Nanoparticles and Their Use as Electrocatalysts for Ammonia Borane Oxidation: The Role of Crystallinity of the Core Xin-Bo Zhang, Jun-Min Yan, Song Han, Hiroshi Shioyama and Qiang Xu pp 2778–2779 DOI: 10.1021/ja808830a Supporting Info |
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Pederin-Type Pathways of Uncultivated Bacterial Symbionts: Analysis of O-Methyltransferases and Generation of a Biosynthetic Hybrid Katrin Zimmermann, Marianne Engeser, John W. Blunt, Murray H. G. Munro and J pp 2780–2781 DOI: 10.1021/ja808889k Supporting Info |
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Spin Crossover by Encapsulation Kosuke Ono, Michito Yoshizawa, Munetaka Akita, Tatsuhisa Kato, Yoshihide Tsunobuchi, Shin-ichi Ohkoshi and Makoto Fujita pp 2782–2783 DOI: 10.1021/ja8089894 Supporting Info |
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Fe(OTf)3-Catalyzed Addition of sp C−H Bonds to Olefins Kazufumi Kohno, Kou Nakagawa, Takeshi Yahagi, Jun-Chul Choi, Hiroyuki Yasuda and Toshiyasu Sakakura pp 2784–2785 DOI: 10.1021/ja8090593 Supporting Info |
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Enantioselective Intramolecular Openings of Oxetanes Catalyzed by (salen)Co(III) Complexes: Access to Enantioenriched Tetrahydrofurans Rebecca N. Loy and Eric N. Jacobsen pp 2786–2787 DOI: 10.1021/ja809176m Supporting Info |
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Mononuclear Copper(II)−Superoxo Complexes that Mimic the Structure and Reactivity of the Active Centers of PHM and DβM Atsushi Kunishita, Minoru Kubo, Hideki Sugimoto, Takashi Ogura, Kazunobu Sato, Takeji Takui and Shinobu Itoh pp 2788–2789 DOI: 10.1021/ja809464e Supporting Info |
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Isotopic Dilution Study of the Water/Vapor Interface by Phase-Sensitive Sum-Frequency Vibrational Spectroscopy Chuan-Shan Tian and Y. Ron Shen pp 2790–2791 DOI: 10.1021/ja809497y |
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Ruthenium-Catalyzed Amino- and Alkoxycarbonylations with Carbamoyl Chlorides and Alkyl Chloroformates via Aromatic C−H Bond Cleavage Takuya Kochi, Seiya Urano, Hajime Seki, Eiichiro Mizushima, Mitsuo Sato and Fumitoshi Kakiuchi pp 2792–2793 DOI: 10.1021/ja8097492 Supporting Info |
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Hydricities of d6 Metal Hydride Complexes in Water Carol Creutz and Mei H. Chou pp 2794–2795 DOI: 10.1021/ja809724s Supporting Info |
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Versatile Synthesis of Pentalene Derivatives via the Pd-Catalyzed Homocoupling of Haloenynes Zerubba U. Levi and T. Don Tilley pp 2796–2797 DOI: 10.1021/ja809930f Supporting Info |
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PAMAM Dendrimers Undergo pH Responsive Conformational Changes without Swelling Yi Liu, Vyacheslav S. Bryantsev, Mamadou S. Diallo and William A. Goddard III pp 2798–2799 DOI: 10.1021/ja8100227 Supporting Info |
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Expanding the Repertoire of Chalcogenide Nanocrystal Networks: Ag2Se Gels and Aerogels by Cation Exchange Reactions Qinghong Yao, Indika U. Arachchige and Stephanie L. Brock pp 2800–2801 DOI: 10.1021/ja900042y Supporting Info |
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Synthesis and Isolation of [Fe@Ge10]3−: A Pentagonal Prismatic Zintl Ion Cage Encapsulating an Interstitial Iron Atom Binbin Zhou, Mark S. Denning, Deborah L. Kays and Jose M. Goicoechea pp 2802–2803 DOI: 10.1021/ja900055j Supporting Info |
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Five-Bond Cleavage in Copper-Catalyzed Skeletal Rearrangement of O-Propargyl Arylaldoximes to β-Lactams Itaru Nakamura, Toshiharu Araki and Masahiro Terada pp 2804–2805 DOI: 10.1021/ja900133m Supporting Info |
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Structure of Isolated Biomolecules by Electron Diffraction−Laser Desorption: Uracil and Guanine Andreas Gahlmann, Sang Tae Park and Ahmed H. Zewail pp 2806–2808 DOI: 10.1021/ja808720j |
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Au(I)-Catalyzed Cycloisomerizations Terminated by sp3 C−H Bond Insertion Yoshikazu Horino, Takuya Yamamoto, Kohki Ueda, Shigeyasu Kuroda and F. Dean Toste pp 2809–2811 DOI: 10.1021/ja808780r Supporting Info |
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Reduction of Nitrous Oxide to Dinitrogen by a Mixed Valent Tricopper-Disulfido Cluster Itsik Bar-Nahum, Aalo K. Gupta, Stefan M. Huber, Mehmed Z. Ertem, Christopher J. Cramer and William B. Tolman pp 2812–2814 DOI: 10.1021/ja808917k Supporting Info |
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Synthesis and Structure of a Cyanoaurate-Based Organotin Polymer Exhibiting Unusual Ion-Exchange Properties Andrea De pp 2815–2817 DOI: 10.1021/ja809067t Supporting Info |
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Reliable Prediction of Charge Transfer Excitations in Molecular Complexes Using Time-Dependent Density Functional Theory Tamar Stein, Leeor Kronik and Roi Baer pp 2818–2820 DOI: 10.1021/ja8087482 Supporting Info |
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NMR Second Site Screening for Structure Determination of Ligands Bound in the Hydrophobic Pocket of HIV-1 gp41 Edina Balogh, Dong Wu, Guangyan Zhou and Miriam Gochin pp 2821–2823 DOI: 10.1021/ja8094558 Supporting Info |
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A Spray-Processable, Low Bandgap, and Ambipolar Donor−Acceptor Conjugated Polymer Timothy T. Steckler, Xuan Zhang, Jungseek Hwang, Ryan Honeyager, Shino Ohira, Xiao-Hong Zhang, Adrian Grant, Stefan Ellinger, Susan A. Odom, Daniel Sweat, David B. Tanner, Andrew G. Rinzler, Stephen Barlow, Jean-Luc Br pp 2824–2826 DOI: 10.1021/ja809372u Supporting Info |
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Halogen-Induced Corrosion of Platinum Enrico Don pp 2827–2829 DOI: 10.1021/ja809674n Supporting Info |
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Animal Pigment Bilirubin Discovered in Plants Cary Pirone, J. Martin E. Quirke, Horacio A. Priestap and David W. Lee p 2830 DOI: 10.1021/ja809065g Supporting Info |
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Membrane-Anchored DNA Assembly for Energy and Electron Transfer Karl B pp 2831–2839 DOI: 10.1021/ja8038294 Supporting Info |
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Manipulating Biomolecules with Aqueous Liquids Confined within Single-Walled Nanotubes Peng Xiu, Bo Zhou, Wenpeng Qi, Hangjun Lu, Yusong Tu and Haiping Fang pp 2840–2845 DOI: 10.1021/ja804586w Supporting Info |
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Ultrafast Proteinquake Dynamics in Cytochrome c Chen Zang, Jeffrey A. Stevens, Justin J. Link, Lijun Guo, Lijuan Wang and Dongping Zhong pp 2846–2852 DOI: 10.1021/ja8057293 Supporting Info |
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Matrix Isolation Study of the Early Intermediates in the Ozonolysis of Cyclopentene and Cyclopentadiene: Observation of Two Criegee Intermediates Michael D. Hoops and Bruce S. Ault pp 2853–2863 DOI: 10.1021/ja8065286 Supporting Info |
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Zeolite-like Metal−Organic Frameworks (ZMOFs) as Hydrogen Storage Platform: Lithium and Magnesium Ion-Exchange and H2-(rho-ZMOF) Interaction Studies Farid Nouar, Juergen Eckert, Jarrod F. Eubank, Paul Forster and Mohamed Eddaoudi pp 2864–2870 DOI: 10.1021/ja807229a Supporting Info |
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Human Telomeric DNA Sequence-Specific Cleaving by G-Quadruplex Formation Yan Xu, Yuta Suzuki, Tuomas L pp 2871–2874 DOI: 10.1021/ja807313x Supporting Info |
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Simulation of Self-Assembly of Cationic Lipids and DNA into Structured Complexes Oded Farago and Niels Grønbech-Jensen pp 2875–2881 DOI: 10.1021/ja807278p |
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Hybrid Materials and Periodic Mesoporous Organosilicas Containing Covalently Bonded Organic Anion and Cation Featuring MCM-41 and SBA-15 Structure Abdelkrim El Kadib, Peter Hesemann, Karine Molvinger, J pp 2882–2892 DOI: 10.1021/ja807630j Supporting Info |
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Dynamics of Localized Charges in Dopamine-Modified TiO2 and their Effect on the Formation of Reactive Oxygen Species Nada M. Dimitrijevic, Elena Rozhkova and Tijana Rajh pp 2893–2899 DOI: 10.1021/ja807654k Supporting Info |
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Synthesis and Conformation−Activity Relationships of the Peptide Isosteres of FK228 and Largazole Albert A. Bowers, Thomas J. Greshock, Nathan West, Guillermina Estiu, Stuart L. Schreiber, Olaf Wiest, Robert M. Williams and James E. Bradner pp 2900–2905 DOI: 10.1021/ja807772w Supporting Info |
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Synthesis, Radiolabeling, and Bio-imaging of High-Generation Polyester Dendrimers Matthew C. Parrott, S. Rahima Benhabbour, Chantal Saab, Jennifer A. Lemon, Shannon Parker, John F. Valliant and Alex Adronov pp 2906–2916 DOI: 10.1021/ja8078175 Supporting Info |
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Crystallographic Characterization of Helical Secondary Structures in 2:1 and 1:2 α/β-Peptides Soo Hyuk Choi, Ilia A. Guzei, Lara C. Spencer and Samuel H. Gellman pp 2917–2924 DOI: 10.1021/ja808168y Supporting Info |
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Evanescent-Field Spectroscopy using Structured Optical Fibers: Detection of Charge-Transfer at the Porphyrin-Silica Interface Cicero Martelli, John Canning, Jeffrey R. Reimers, Maxine Sintic, Danial Stocks, Tony Khoury and Maxwell J. Crossley pp 2925–2933 DOI: 10.1021/ja8081473 Supporting Info |
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Liquid Crystalline Phase Transition Induces Spin Crossover in a Polyelectrolyte Amphiphile Complex Yves Bodenthin, Guntram Schwarz, Zbigniew Tomkowicz, Thomas Geue, Wolfgang Haase, Ullrich Pietsch and Dirk G. Kurth pp 2934–2941 DOI: 10.1021/ja808278s |
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Protein Folding, Protein Collapse, and Tanford’s Transfer Model: Lessons from Single-Molecule FRET Guy Ziv and Gilad Haran pp 2942–2947 DOI: 10.1021/ja808305u Supporting Info |
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CdSe/CdS/ZnS Double Shell Nanorods with High Photoluminescence Efficiency and Their Exploitation As Biolabeling Probes Sasanka Deka, Alessandra Quarta, Maria Grazia Lupo, Andrea Falqui, Simona Boninelli, Cinzia Giannini, Giovanni Morello, Milena De Giorgi, Guglielmo Lanzani, Corrado Spinella, Roberto Cingolani, Teresa Pellegrino and Liberato Manna pp 2948–2958 DOI: 10.1021/ja808369e Supporting Info |
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Hydrazine-Linked Convergent Self-Assembly of Sophisticated Concave Polyhedrons of β-Ni(OH)2 and NiO from Nanoplate Building Blocks Wei Zhou, Meng Yao, Lin Guo, Yueming Li, Jinghong Li and Shihe Yang pp 2959–2964 DOI: 10.1021/ja808784s Supporting Info |
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A Gene Cluster Containing Two Fungal Polyketide Synthases Encodes the Biosynthetic Pathway for a Polyketide, Asperfuranone, in Aspergillus nidulans Yi-Ming Chiang, Edyta Szewczyk, Ashley D. Davidson, Nancy Keller, Berl R. Oakley and Clay C. C. Wang pp 2965–2970 DOI: 10.1021/ja8088185 Supporting Info |
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Kinetics of Oxidation of Benzphetamine by Compounds I of Cytochrome P450 2B4 and Its Mutants Xin Sheng, Haoming Zhang, Sang-Choul Im, John H. Horner, Lucy Waskell, Paul F. Hollenberg and Martin Newcomb pp 2971–2976 DOI: 10.1021/ja808982g Supporting Info |
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Stable “Inverse” Sandwich Complex with Unprecedented Organocalcium(I): Crystal Structures of [(thf)2Mg(Br)-C6H2-2,4,6-Ph3] and [(thf)3Ca{μ-C6H3-1,3,5-Ph3}Ca(thf)3] Sven Krieck, Helmar G pp 2977–2985 DOI: 10.1021/ja808524y Supporting Info |
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Response of Superconductivity and Crystal Structure of LiFeAs to Hydrostatic Pressure Masaki Mito, Michael J. Pitcher, Wilson Crichton, Gaston Garbarino, Peter J. Baker, Stephen J. Blundell, Paul Adamson, Dinah R. Parker and Simon J. Clarke pp 2986–2992 DOI: 10.1021/ja808914a Supporting Info |
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Generation and Trapping of Cyclopentenylidene Gold Species: Four Pathways to Polycyclic Compounds Gilles Lemi pp 2993–3006 DOI: 10.1021/ja808872u Supporting Info |
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Silicon−Hydrogen Bond Activation and Hydrosilylation of Alkenes Mediated by CpCo Complexes: A Theoretical Study Vincent Gandon, Nicolas Agenet, K. Peter C. Vollhardt, Max Malacria and Corinne Aubert pp 3007–3015 DOI: 10.1021/ja809100t Supporting Info |
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A Near-Infrared Neutral pH Fluorescent Probe for Monitoring Minor pH Changes: Imaging in Living HepG2 and HL-7702 Cells Bo Tang, Fabiao Yu, Ping Li, Lili Tong, Xia Duan, Ting Xie and Xu Wang pp 3016–3023 DOI: 10.1021/ja809149g Supporting Info |
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In Situ Observation of Rapid Ligand Exchange in Colloidal Nanocrystal Suspensions Using Transfer NOE Nuclear Magnetic Resonance Spectroscopy Bernd Fritzinger, Iwan Moreels, Petra Lommens, Rolf Koole, Zeger Hens and Jos pp 3024–3032 DOI: 10.1021/ja809436y |
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Design, Synthesis, Biological Evaluation, and Structural Characterization of Potent Histone Deacetylase Inhibitors Based on Cyclic α/β-Tetrapeptide Architectures Ana Montero, John M. Beierle, Christian A. Olsen and M. Reza Ghadiri pp 3033–3041 DOI: 10.1021/ja809508f Supporting Info |
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C−H Bonds as Ubiquitous Functionality: A General Approach to Complex Arylated Pyrazoles via Sequential Regioselective C-Arylation and N-Alkylation Enabled by SEM-Group Transposition Roman Goikhman, Teresa L. Jacques and Dalibor Sames pp 3042–3048 DOI: 10.1021/ja8096114 Supporting Info |
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Characterization of Fluorescence in Heat-Treated Silver-Exchanged Zeolites Gert De Cremer, Eduardo Couti pp 3049–3056 DOI: 10.1021/ja810071s Supporting Info |
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Non-Zinc Mediated Inhibition of Carbonic Anhydrases: Coumarins Are a New Class of Suicide Inhibitors Alfonso Maresca, Claudia Temperini, Hoan Vu, Ngoc B. Pham, Sally-Ann Poulsen, Andrea Scozzafava, Ronald J. Quinn and Claudiu T. Supuran pp 3057–3062 DOI: 10.1021/ja809683v |
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Direct Observation of the Dynamic Process Underlying Allosteric Signal Transmission Sven Br pp 3063–3068 DOI: 10.1021/ja809947w Supporting Info |
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Substituent Effects on Xenon Binding Affinity and Solution Behavior of Water-Soluble Cryptophanes P. Aru Hill, Qian Wei, Thomas Troxler and Ivan J. Dmochowski pp 3069–3077 DOI: 10.1021/ja8100566 Supporting Info |
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Anatomy of Phobanes. Diastereoselective Synthesis of the Three Isomers of n-Butylphobane and a Comparison of their Donor Properties Monica Carreira, Manutsavin Charernsuk, Michael Eberhard, Natalie Fey, Roel van Ginkel, Alex Hamilton, Wilhelmus P. Mul, A. Guy Orpen, Hirihataya Phetmung and Paul G. Pringle pp 3078–3092 DOI: 10.1021/ja808807s Supporting Info |
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Temperature Sensitive Copolymer Microgels with Nanophase Separated Structure Martina Keerl, Jan Skov Pedersen and Walter Richtering pp 3093–3097 DOI: 10.1021/ja807367p |
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Defect Sites and Their Distributions on MgO(100) by Li and Ca Adsorption Calorimetry Jason A. Farmer, Charles T. Campbell, Lijun Xu and Graeme Henkelman pp 3098–3103 DOI: 10.1021/ja808986b |
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Cross-Coupling Reactions of Aromatic and Heteroaromatic Silanolates with Aromatic and Heteroaromatic Halides Scott E. Denmark, Russell C. Smith, Wen-Tau T. Chang and Joseck M. Muhuhi pp 3104–3118 DOI: 10.1021/ja8091449 Supporting Info |
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Polyfluorenes William C. Trogler p 3119 DOI: 10.1021/ja900637w |
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Handbook of Asymmetric Heterogeneous Catalysis David E. Bergbreiter pp 3119–3120 DOI: 10.1021/ja9006854 |
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Advanced Excel for Scientific Data Analysis, 2nd ed. p 3120 DOI: 10.1021/ja900759t |
Issue 09
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Catalytic Enantioselective Synthesis of Tetrahydrofurans: A Dynamic Kinetic Asymmetric [3 + 2] Cycloaddition of Racemic Cyclopropanes and Aldehydes Andrew T. Parsons and Jeffrey S. Johnson pp 3122–3123 DOI: 10.1021/ja809873u Supporting Info |
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Multicatalytic Synthesis of α-Pyrrolidinyl Ketones via a Tandem Palladium(II)/Indium(III)-Catalyzed Aminochlorocarbonylation/Friedel−Crafts Acylation Reaction Tim A. Cernak and Tristan H. Lambert pp 3124–3125 DOI: 10.1021/ja809897f Supporting Info |
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Substituent Effects in Cation/π Interactions and Electrostatic Potentials above the Centers of Substituted Benzenes Are Due Primarily to Through-Space Effects of the Substituents Steven E. Wheeler and K. N. Houk pp 3126–3127 DOI: 10.1021/ja809097r Supporting Info |
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Connecting Single Molecule Electrical Measurements to Ensemble Spectroscopic Properties for Quantification of Single-Walled Carbon Nanotube Separation Woo-Jae Kim, Chang Young Lee, Kevin P. O’brien, John J. Plombon, James M. Blackwell and Michael S. Strano pp 3128–3129 DOI: 10.1021/ja807989d Supporting Info |
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Dynamics and the Failure of Transition State Theory in Alkene Hydroboration Yatsandra Oyola and Daniel A. Singleton pp 3130–3131 DOI: 10.1021/ja807666d Supporting Info |
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LiCB11(CH3)12-Catalyzed Radical Polymerization of Isobutylene: Highly Branched Polyisobutylene and an Isobutylene−Ethyl Acrylate Copolymer Victoria Volkis, Hua Mei, Richard K. Shoemaker and Josef Michl pp 3132–3133 DOI: 10.1021/ja807297g Supporting Info |
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Synthesis of CuInSe2 Nanocrystals with Trigonal Pyramidal Shape Bonil Koo, Reken N. Patel and Brian A. Korgel pp 3134–3135 DOI: 10.1021/ja8080605 Supporting Info |
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Motions of the Substrate Recognition Duplex in a Group I Intron Assessed by Site-Directed Spin Labeling Gian Paola G. Grant, Nathan Boyd, Daniel Herschlag and Peter Z. Qin pp 3136–3137 DOI: 10.1021/ja808217s Supporting Info |
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Synthesis of S-Linked α(2→9) Octasialic Acid via Exclusive α S-Glycosidic Bond Formation Chien-Fu Liang, Ming-Chung Yan, Tsung-Che Chang and Chun-Cheng Lin pp 3138–3139 DOI: 10.1021/ja808353m Supporting Info |
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Oxygen Vacancy Clusters Promoting Reducibility and Activity of Ceria Nanorods Xiangwen Liu, Kebin Zhou, Lei Wang, Baoyi Wang and Yadong Li pp 3140–3141 DOI: 10.1021/ja808433d Supporting Info |
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Selective Vinyl C−H Lithiation of cis-Stilbenes Thomas Tricotet, Patricia Fleming, Juliet Cotter, Anne-Marie L. Hogan, Carsten Strohmann, Viktoria H. Gessner and Donal F. O’Shea pp 3142–3143 DOI: 10.1021/ja809941n Supporting Info |
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High Proton Conductivity of One-Dimensional Ferrous Oxalate Dihydrate Teppei Yamada, Masaaki Sadakiyo and Hiroshi Kitagawa pp 3144–3145 DOI: 10.1021/ja808681m Supporting Info |
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Direct Conversion of Alcohols to Acetals and H2 Catalyzed by an Acridine-Based Ruthenium Pincer Complex Chidambaram Gunanathan, Linda J. W. Shimon and David Milstein pp 3146–3147 DOI: 10.1021/ja808893g Supporting Info |
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A PLP-Dependent Polyketide Chain Releasing Mechanism in the Biosynthesis of Mycotoxin Fumonisins in Fusarium verticillioides Ryan Gerber, Lili Lou and Liangcheng Du pp 3148–3149 DOI: 10.1021/ja8091054 Supporting Info |
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Remarkable Bromination and Blue Emission of 9-Anthracenyl Pt(II) Complexes Bao-Yu Wang, Alice Raphael Karikachery, Yunjing Li, Anupam Singh, Han Baek Lee, Wenfang Sun and Paul R. Sharp pp 3150–3151 DOI: 10.1021/ja809046p Supporting Info |
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Synthesis of Titania Nanosheets with a High Percentage of Exposed (001) Facets and Related Photocatalytic Properties Xiguang Han, Qin Kuang, Mingshang Jin, Zhaoxiong Xie and Lansun Zheng pp 3152–3153 DOI: 10.1021/ja8092373 Supporting Info |
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Synthesis of Molecular Nanostructures by Multicomponent Condensation Reactions in a Ball Mill Bur pp 3154–3155 DOI: 10.1021/ja809279s Supporting Info |
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Anthryl-Substituted Trialkyldisilene Showing Distinct Intramolecular Charge-Transfer Transition Takeaki Iwamoto, Maiko Kobayashi, Kei Uchiyama, Shin Sasaki, Selvarajan Nagendran, Hiroyuki Isobe and Mitsuo Kira pp 3156–3157 DOI: 10.1021/ja8093313 Supporting Info |
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Vertical Organic Nanowire Arrays: Controlled Synthesis and Chemical Sensors Yong Sheng Zhao, Jinsong Wu and Jiaxing Huang pp 3158–3159 DOI: 10.1021/ja809360v Supporting Info |
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Efficient Boron−Copper Additions to Aryl-Substituted Alkenes Promoted by NHC−Based Catalysts. Enantioselective Cu-Catalyzed Hydroboration Reactions Yunmi Lee and Amir H. Hoveyda pp 3160–3161 DOI: 10.1021/ja809382c Supporting Info |
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Atomically Efficient Synthesis of Self-assembled Monodisperse and Ultrathin Lanthanide Oxychloride Nanoplates Ya-Ping Du, Ya-Wen Zhang, Ling-Dong Sun and Chun-Hua Yan pp 3162–3163 DOI: 10.1021/ja8095416 Supporting Info |
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Hyperpolarized 1H NMR Employing Low γ Nucleus for Spin Polarization Storage Eduard Y. Chekmenev, Valerie A. Norton, Daniel P. Weitekamp and Pratip Bhattacharya pp 3164–3165 DOI: 10.1021/ja809634u |
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Rh-Catalyzed Isomerization and Intramolecular Redox Reaction of Alkynyl Ethers Affording Dihydropyrans and Ketoolefins Daisuke Shikanai, Hirohiko Murase, Takeshi Hata and Hirokazu Urabe pp 3166–3167 DOI: 10.1021/ja809826a Supporting Info |
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A Neutral Ga6 Octahedron: Synthesis, Structure, and Aromaticity Brandon Quillian, Pingrong Wei, Chaitanya S. Wannere, Paul v. R. Schleyer and Gregory H. Robinson pp 3168–3169 DOI: 10.1021/ja809945v Supporting Info |
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Ion Pairing in Cationic Olefin−Gold(I) Complexes Daniele Zuccaccia, Leonardo Belpassi, Francesco Tarantelli and Alceo Macchioni pp 3170–3171 DOI: 10.1021/ja809998y Supporting Info |
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Perfluoroaryltetrahedranes: Tetrahedranes with Extended σ−π Conjugation Masaaki Nakamoto, Yusuke Inagaki, Motoaki Nishina and Akira Sekiguchi pp 3172–3173 DOI: 10.1021/ja810055w Supporting Info |
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Rhodium-Catalyzed Reductive Cleavage of Carbon−Cyano Bonds with Hydrosilane: A Catalytic Protocol for Removal of Cyano Groups Mamoru Tobisu, Ryo Nakamura, Yusuke Kita and Naoto Chatani pp 3174–3175 DOI: 10.1021/ja810142v Supporting Info |
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Nickel-Catalyzed Highly Regio- and Stereoselective Cross-Trimerization between Triisopropylsilylacetylene and Internal Alkynes Leading to 1,3-Diene-5-ynes Kenichi Ogata, Hiroyuki Murayama, Jun Sugasawa, Noriyuki Suzuki and Shin-ichi Fukuzawa pp 3176–3177 DOI: 10.1021/ja900146u Supporting Info |
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Molecular Recognition of Pyridine N-Oxides in Water Using Calix[4]pyrrole Receptors Bego pp 3178–3179 DOI: 10.1021/ja900151u Supporting Info |
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Helical Structure of Disodium 5′-Guanosine Monophosphate Self-Assembly in Neutral Solution Gang Wu and Irene C. M. Kwan pp 3180–3182 DOI: 10.1021/ja809258y Supporting Info |
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Metal−Bis(helicene) Assemblies Incorporating π-Conjugated Phosphole-Azahelicene Ligands: Impacting Chiroptical Properties by Metal Variation S pp 3183–3185 DOI: 10.1021/ja809396f Supporting Info |
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Solvent-Induced High Fidelity Switching Between Two Discrete Supramolecules Jos pp 3186–3188 DOI: 10.1021/ja809612d Supporting Info |
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Nonsurfactant Supramolecular Synthesis of Ordered Mesoporous Silica Rambabu Atluri, Niklas Hedin and Alfonso E. Garcia-Bennett pp 3189–3191 DOI: 10.1021/ja8096477 Supporting Info |
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Stereoselective Synthesis and Osteogenic Activity of Subglutinols A and B Hyoungsu Kim, Joseph B. Baker, Su-Ui Lee, Yongho Park, Kyle L. Bolduc, Hyung-Bae Park, Marina G. Dickens, Dong-Sup Lee, Yongchul Kim, Seong Hwan Kim and Jiyong Hong pp 3192–3194 DOI: 10.1021/ja8101192 Supporting Info |
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Direct Catalytic Asymmetric Addition of Allyl Cyanide to Ketones Ryo Yazaki, Naoya Kumagai and Masakatsu Shibasaki pp 3195–3197 DOI: 10.1021/ja900001u Supporting Info |
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Supramolecular Donor−Acceptor Heterojunctions by Vectorial Stepwise Assembly of Porphyrins and Coordination-Bonded Fullerene Arrays for Photocurrent Generation Aiko Kira, Tomokazu Umeyama, Yoshihiro Matano, Kaname Yoshida, Seiji Isoda, Jong Kang Park, Dongho Kim and Hiroshi Imahori pp 3198–3200 DOI: 10.1021/ja8096465 Supporting Info |
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N-Heterocyclic Carbene-Induced Zwitterionic Ring-Opening Polymerization of Ethylene Oxide and Direct Synthesis of α,ω-Difunctionalized Poly(ethylene oxide)s and Poly(ethylene oxide)-b-poly(ε-caprolactone) Block Copolymers Jean Raynaud, Christelle Absalon, Yves Gnanou and Daniel Taton pp 3201–3209 DOI: 10.1021/ja809246f |
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SiC(0001) 3 × 3 Heterochirality Revealed by Single-Molecule STM Imaging Guillaume Baffou, Andrew J. Mayne, Genevi pp 3210–3215 DOI: 10.1021/ja806002k |
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Photoelectrochemical Study of the Band Structure of Zn2SnO4 Prepared by the Hydrothermal Method Mario A. Alpuche-Aviles and Yiying Wu pp 3216–3224 DOI: 10.1021/ja806719x |
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Biosynthesis of the Thiamin Thiazole in Bacillus subtilis: Identification of the Product of the Thiazole Synthase-Catalyzed Reaction Amrita Hazra, Abhishek Chatterjee and Tadhg P. Begley pp 3225–3229 DOI: 10.1021/ja806752h Supporting Info |
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Toluene and Ethylbenzene Aliphatic C−H Bond Oxidations Initiated by a Dicopper(II)-μ-1,2-Peroxo Complex Heather R. Lucas, Lei Li, Amy A. Narducci Sarjeant, Michael A. Vance, Edward I. Solomon and Kenneth D. Karlin pp 3230–3245 DOI: 10.1021/ja807081d Supporting Info |
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Optimization of an Unnatural Base Pair toward Natural-Like Replication Young Jun Seo, Gil Tae Hwang, Phillip Ordoukhanian and Floyd E. Romesberg pp 3246–3252 DOI: 10.1021/ja807853m Supporting Info |
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Effects of Lattice Expansion on the Reactivity of a One-Dimensional Oxide Cristina Africh, Lukas K pp 3253–3259 DOI: 10.1021/ja808100f |
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Substrate−Protein Interaction in Human Tryptophan Dioxygenase: The Critical Role of H76 Dipanwita Batabyal and Syun-Ru Yeh pp 3260–3270 DOI: 10.1021/ja807969a Supporting Info |
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Site-Saturation Mutagenesis of Tryptophan 116 of Saccharomyces pastorianus Old Yellow Enzyme Uncovers Stereocomplementary Variants Santosh Kumar Padhi, Despina J. Bougioukou and Jon D. Stewart pp 3271–3280 DOI: 10.1021/ja8081389 Supporting Info |
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Self-Assembled Simple Hexagonal AB2 Binary Nanocrystal Superlattices: SEM, GISAXS, and Defects Danielle K. Smith, Brian Goodfellow, Detlef-M. Smilgies and Brian A. Korgel pp 3281–3290 DOI: 10.1021/ja8085438 Supporting Info |
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Palladium-Catalyzed Direct Arylation of Azine and Azole N-Oxides: Reaction Development, Scope and Applications in Synthesis Louis-Charles Campeau, David R. Stuart, Jean-Philippe Leclerc, M pp 3291–3306 DOI: 10.1021/ja808332k Supporting Info |
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One- and Two-Electron Reactivity of a Tantalum(V) Complex with a Redox-Active Tris(amido) Ligand Andy I. Nguyen, Karen J. Blackmore, Shawn M. Carter, Ryan A. Zarkesh and Alan F. Heyduk pp 3307–3316 DOI: 10.1021/ja808542j Supporting Info |
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Solid-State Chlorine NMR of Group IV Transition Metal Organometallic Complexes Aaron J. Rossini, Ryan W. Mills, Graham A. Briscoe, Erin L. Norton, Stephen J. Geier, Ivan Hung, Shaohui Zheng, Jochen Autschbach and Robert W. Schurko pp 3317–3330 DOI: 10.1021/ja808390a Supporting Info |
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Macrocyclic Receptor Exhibiting Unprecedented Selectivity for Light Lanthanides Adri pp 3331–3341 DOI: 10.1021/ja808534w Supporting Info |
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Discovery of Inhibitors of Aberrant Gene Transcription from Libraries of DNA Binding Molecules: Inhibition of LEF-1-Mediated Gene Transcription and Oncogenic Transformation James S. Stover, Jin Shi, Wei Jin, Peter K. Vogt and Dale L. Boger pp 3342–3348 DOI: 10.1021/ja809083d Supporting Info |
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Spin Glass Behavior of Isolated, Geometrically Frustrated Tetrahedra of Iron Atoms in the Intermetallic La21Fe8Sn7C12 Evan M. Benbow, Naresh S. Dalal and Susan E. Latturner pp 3349–3354 DOI: 10.1021/ja809084n Supporting Info |
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Pulsed-Addition Ring-Opening Metathesis Polymerization: Catalyst-Economical Syntheses of Homopolymers and Block Copolymers John B. Matson, Scott C. Virgil and Robert H. Grubbs pp 3355–3362 DOI: 10.1021/ja809081h Supporting Info |
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Cationic Boranes for the Complexation of Fluoride Ions in Water below the 4 ppm Maximum Contaminant Level Youngmin Kim and Fran pp 3363–3369 DOI: 10.1021/ja8091467 Supporting Info |
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Identification of Protonated Oxygenic Ligands of Ribonucleotide Reductase Intermediate X Muralidharan Shanmugam, Peter E. Doan, Nicholas S. Lees, JoAnne Stubbe and Brian M. Hoffman pp 3370–3376 DOI: 10.1021/ja809223s Supporting Info |
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Metal-Binding Dependent Disruption of Membranes by Designed Helices Rachel S. Signarvic and William F. DeGrado pp 3377–3384 DOI: 10.1021/ja809580b |
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Amide I′−II′ 2D IR Spectroscopy Provides Enhanced Protein Secondary Structural Sensitivity Lauren P. DeFlores, Ziad Ganim, Rebecca A. Nicodemus and Andrei Tokmakoff pp 3385–3391 DOI: 10.1021/ja8094922 Supporting Info |
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Putting Atoms and Molecules into Chemically Opened Fullerenes Christopher M. Stanisky, R. James Cross and Martin Saunders pp 3392–3395 DOI: 10.1021/ja809831a Supporting Info |
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Structural Evolution of Doped Gold Clusters: MAux− (M = Si, Ge, Sn; x = 5−8) Rhitankar Pal, Lei-Ming Wang, Wei Huang, Lai-Sheng Wang and Xiao Cheng Zeng pp 3396–3404 DOI: 10.1021/ja810093t Supporting Info |
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Heterocyclic Supramolecules I Gabor Borzsonyi and Hicham Fenniri p 3405 DOI: 10.1021/ja900567x |
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Nanostructured and Photoelectrochemical Systems for Solar Photon Conversion Stacey F. Bent pp 3405–3406 DOI: 10.1021/ja900723m |
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Dictionary of Nanotechnology, Colloid and Interface Science p 3406 DOI: 10.1021/ja9007613 |
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Multivariate Methods in Chromatography: A Practical Guide James Harynuk pp 3406–3407 DOI: 10.1021/ja9008503 |
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Photoresponsive Polymers I Xichen Cai and D. C. Neckers p 3407 DOI: 10.1021/ja900878r |
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Cheminformatics Approaches to Virtual Screening Pavel A. Petukhov pp 3407–3408 DOI: 10.1021/ja9007326 |
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Polymer Microscopy, 3rd ed. Karen I. Winey p 3408 DOI: 10.1021/ja900764t |
Issue 10
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N to C Aryl Migration in Lithiated Carbamates: α-Arylation of Benzylic Alcohols Jonathan Clayden, William Farnaby, Damian M. Grainger, Ulrich Hennecke, Michele Mancinelli, Daniel J. Tetlow, Ian H. Hillier and Mark A. Vincent pp 3410–3411 DOI: 10.1021/ja808959e Supporting Info |
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Photoswitching in Azafullerene Encapsulated Single-Walled Carbon Nanotube FET Devices Yongfeng Li, Toshiro Kaneko, Jing Kong and Rikizo Hatakeyama pp 3412–3413 DOI: 10.1021/ja810086g Supporting Info |
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Formation of S-[1-(N2-Deoxyguanosinyl)methyl]glutathione between Glutathione and DNA Induced by Formaldehyde Kun Lu, Wenjie Ye, Avram Gold, Louise M. Ball and James A. Swenberg pp 3414–3415 DOI: 10.1021/ja808048c Supporting Info |
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Binding Optimization through Coordination Chemistry: CXCR4 Chemokine Receptor Antagonists from Ultrarigid Metal Complexes Abid Khan, Gary Nicholson, John Greenman, Leigh Madden, Graeme McRobbie, Christophe Pannecouque, Erik De Clercq, Robert Ullom, Danny L. Maples, Randall D. Maples, Jon D. Silversides, Timothy J. Hubin and Stephen J. Archibald pp 3416–3417 DOI: 10.1021/ja807921k Supporting Info |
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Pentacoordinate Organoantimony Compounds That Isomerize by Turnstile Rotation Shiro Matsukawa, Hideaki Yamamichi, Yohsuke Yamamoto and Kaori Ando pp 3418–3419 DOI: 10.1021/ja808113q Supporting Info |
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Phosphatidylcholine “Wobble” in Vesicles Assessed by High-Resolution 13C Field Cycling NMR Spectroscopy V. N. Sivanandam, Jingfei Cai, Alfred G. Redfield and Mary F. Roberts pp 3420–3421 DOI: 10.1021/ja808431h |
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High-Nuclearity Silver Clusters Templated by Carbonates Generated from Atmospheric Carbon Dioxide Fixation Shu-Dan Bian, Jian-Hua Jia and Quan-Ming Wang pp 3422–3423 DOI: 10.1021/ja8087696 Supporting Info |
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Exploiting Substituent Effects for the Synthesis of a Photooxidatively Resistant Heptacene Derivative Irvinder Kaur, Nathan N. Stein, Ryan P. Kopreski and Glen P. Miller pp 3424–3425 DOI: 10.1021/ja808881x Supporting Info |
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Dinitrosyl Iron Complexes (DNICs) Bearing O-Bound Nitrito Ligand: Reversible Transformation between the Six-Coordinate {Fe(NO)2}9 [(1-MeIm)2(η2-ONO)Fe(NO)2] (g = 2.013) and Four-Coordinate {Fe(NO)2}9 [(1-MeIm)(ONO)Fe(NO)2] (g = 2.03) Fu-Te Tsai, Ting-Shen Kuo and Wen-Feng Liaw pp 3426–3427 DOI: 10.1021/ja808743g Supporting Info |
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Unusual Electronic Features and Reactivity of the Dipyridylazaallyl Ligand: Characterizations of (smif)2M [M = Fe, Co, Co+, Ni; smif = {(2-py)CH}2N] and [(TMS)2NFe]2(smif)2 Brenda A. Frazier, Peter T. Wolczanski, Emil B. Lobkovsky and Thomas R. Cundari pp 3428–3429 DOI: 10.1021/ja8089747 Supporting Info |
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Enantioselective Direct Aldol-Type Reaction of Azlactone via Protonation of Vinyl Ethers by a Chiral Brønsted Acid Catalyst Masahiro Terada, Hiroyasu Tanaka and Keiichi Sorimachi pp 3430–3431 DOI: 10.1021/ja8090643 Supporting Info |
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Label-Free, Real-Time Multiplexed DNA Detection Using Fluorescent Conjugated Polymers Weiming Zheng and Lin He pp 3432–3433 DOI: 10.1021/ja809175q Supporting Info |
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Nonvolatile Bipolar Resistive Memory Switching in Single Crystalline NiO Heterostructured Nanowires Keisuke Oka, Takeshi Yanagida, Kazuki Nagashima, Hidekazu Tanaka and Tomoji Kawai pp 3434–3435 DOI: 10.1021/ja8089922 Supporting Info |
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Colloidal Synthesis of Infrared-Emitting Germanium Nanocrystals Doh C. Lee, Jeffrey M. Pietryga, Istvan Robel, Donald J. Werder, Richard D. Schaller and Victor I. Klimov pp 3436–3437 DOI: 10.1021/ja809218s Supporting Info |
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Transmembrane Structures of Amyloid Precursor Protein Dimer Predicted by Replica-Exchange Molecular Dynamics Simulations Naoyuki Miyashita, John E. Straub, D. Thirumalai and Yuji Sugita pp 3438–3439 DOI: 10.1021/ja809227c Supporting Info |
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Reversible Structural Switching of a DNA−DDAB Film Thorsten Neumann, Surekha Gajria, Matthew Tirrell and Luc Jaeger pp 3440–3441 DOI: 10.1021/ja809349m Supporting Info |
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Double Structural Transition in Hybrid Material MIL-53 upon Hydrocarbon Adsorption: The Thermodynamics Behind the Scenes Fran pp 3442–3443 DOI: 10.1021/ja8094153 Supporting Info |
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Synthesis of Copolymers by Alternating ROMP (AROMP) Airong Song, Kathlyn A. Parker and Nicole S. Sampson pp 3444–3445 DOI: 10.1021/ja809661k Supporting Info |
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Versatile Formation of CdSe Nanoparticle-Single Walled Carbon Nanotube Hybrid Structures Chenguang Lu, Austin Akey, Wei Wang and Irving P. Herman pp 3446–3447 DOI: 10.1021/ja809713w Supporting Info |
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Fast Two-Dimensional NMR Spectroscopy of High Molecular Weight Protein Assemblies Carlos Amero, Paul Schanda, M. Asunci pp 3448–3449 DOI: 10.1021/ja809880p Supporting Info |
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Direct Asymmetric Benzoyloxylation of Aldehydes Catalyzed by 2-Tritylpyrrolidine Taichi Kano, Haruka Mii and Keiji Maruoka pp 3450–3451 DOI: 10.1021/ja809963s Supporting Info |
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PdII/PdIV Catalytic Enantioselective Synthesis of Bicyclo[3.1.0]hexanes via Oxidative Cyclization of Enynes Tetsuya Tsujihara, Kazuhiro Takenaka, Kiyotaka Onitsuka, Minoru Hatanaka and Hiroaki Sasai pp 3452–3453 DOI: 10.1021/ja809965e Supporting Info |
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Catalytic Hydrogenation of Sensitive Organometallic Compounds by Antagonistic N/B Lewis Pair Catalyst Systems Kirill V. Axenov, Gerald Kehr, Roland Fr pp 3454–3455 DOI: 10.1021/ja8100006 Supporting Info |
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A Nanoscale Adhesion Layer to Promote Cell Attachment on PEEK T. Joseph Dennes and Jeffrey Schwartz pp 3456–3457 DOI: 10.1021/ja810075c Supporting Info |
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Template Trapping and Crystal Structure of the Magic Number (H2O)21 Cluster in the Tetrahedral Hole of a Nanoscale Global Ion Packed in a Face-Centered Cubic Pattern Man-Li Cao, Jin-Ji Wu, Hao-Jun Mo and Bao-Hui Ye pp 3458–3459 DOI: 10.1021/ja810107a Supporting Info |
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Building 2D Crystals from 5-Fold-Symmetric Molecules Tobias Bauert, Leo Merz, Davide Bandera, Manfred Parschau, Jay S. Siegel and Karl-Heinz Ernst pp 3460–3461 DOI: 10.1021/ja8101083 Supporting Info |
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Photoinduced Intracellular Controlled Release Drug Delivery in Human Cells by Gold-Capped Mesoporous Silica Nanosphere Juan L. Vivero-Escoto, Igor I. Slowing, Chian-Wen Wu and Victor S.-Y. Lin pp 3462–3463 DOI: 10.1021/ja900025f Supporting Info |
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Gold(I)-Catalyzed Enantioselective Synthesis of Benzopyrans via Rearrangement of Allylic Oxonium Intermediates Minoru Uemura, Iain D. G. Watson, Mikimoto Katsukawa and F. Dean Toste pp 3464–3465 DOI: 10.1021/ja900155x Supporting Info |
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Palladium-Catalyzed C−H Bond Functionalization with Arylsulfonyl Chlorides Xiaodan Zhao, Elena Dimitrijevi pp 3466–3467 DOI: 10.1021/ja900200g Supporting Info |
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Electrochromic Behavior of a Self-Propagating Molecular-Based Assembly Leila Motiei, Michal Lahav, Dalia Freeman and Milko E. van der Boom pp 3468–3469 DOI: 10.1021/ja900507c Supporting Info |
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Total Synthesis of the Lycopodium Alkaloid (+)-Serratezomine A Aroop Chandra, Julie A. Pigza, Jeong-Seok Han, Daniel Mutnick and Jeffrey N. Johnston pp 3470–3471 DOI: 10.1021/ja900536d Supporting Info |
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Efficient Access to the Core of the Strychnos, Aspidosperma and Iboga Alkaloids. A Short Synthesis of Norfluorocurarine David B. C. Martin and Christopher D. Vanderwal pp 3472–3473 DOI: 10.1021/ja900640v Supporting Info |
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Reductive Coupling of Six Carbon Monoxides by a Ditantalum Hydride Complex Takahito Watanabe, Yutaka Ishida, Tsukasa Matsuo and Hiroyuki Kawaguchi pp 3474–3475 DOI: 10.1021/ja9007276 Supporting Info |
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Lutidine/B(C6F5)3: At the Boundary of Classical and Frustrated Lewis Pair Reactivity Stephen J. Geier and Douglas W. Stephan pp 3476–3477 DOI: 10.1021/ja900572x Supporting Info |
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Atomic Layer Deposition of Metal Tellurides and Selenides Using Alkylsilyl Compounds of Tellurium and Selenium Viljami Pore, Timo Hatanp pp 3478–3480 DOI: 10.1021/ja8090388 Supporting Info |
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2-Amino-2-deoxyisochorismate Is a Key Intermediate in Bacillus subtilis p-Aminobenzoic Acid Biosynthesis Heiko S. Schadt, Simone Schadt, Florian Oldach and Roderich D. S pp 3481–3483 DOI: 10.1021/ja809283u Supporting Info |
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Assembly of Magnetically Tunable Photonic Crystals in Nonpolar Solvents Jianping Ge, Le He, James Goebl and Yadong Yin pp 3484–3486 DOI: 10.1021/ja809772v Supporting Info |
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Direct and Quantitative Characterization of Dynamic Ligand Exchange between Coordination-Driven Self-Assembled Supramolecular Polygons Yao-Rong Zheng and Peter J. Stang pp 3487–3489 DOI: 10.1021/ja809788x Supporting Info |
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Observation of Direct Sulfenium and Selenenium Group Transfer from Thiiranium and Seleniranium Ions to Alkenes Scott E. Denmark, William R. Collins and Matthew D. Cullen pp 3490–3492 DOI: 10.1021/ja900187y Supporting Info |
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2-Indenylidene Pincer Complexes of Zirconium and Palladium Pascal Ouli pp 3493–3498 DOI: 10.1021/ja809892a Supporting Info |
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A Pseudocatenane Structure Formed between DNA and A Cyclic Bisintercalator Yongjun Chu, David W. Hoffman and Brent L. Iverson pp 3499–3508 DOI: 10.1021/ja805676w Supporting Info |
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How the Substrate d-Glutamate Drives the Catalytic Action of Bacillus subtilis Glutamate Racemase Eduard Puig, Edgar Mixcoha, Mireia Garcia-Viloca, pp 3509–3521 DOI: 10.1021/ja806012h Supporting Info |
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Hydration of Watson−Crick Base Pairs and Dehydration of Hoogsteen Base Pairs Inducing Structural Polymorphism under Molecular Crowding Conditions Daisuke Miyoshi, Kaori Nakamura, Hisae Tateishi-Karimata, Tatsuo Ohmichi and Naoki Sugimoto pp 3522–3531 DOI: 10.1021/ja805972a Supporting Info |
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Structure-Guided Engineering of the Regioselectivity of RNA Ligase Ribozymes Jason N. Pitt and Adrian R. Ferr pp 3532–3540 DOI: 10.1021/ja8067325 Supporting Info |
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Structure/Function Relationships in Dyes for Solar Energy Conversion: A Two-Atom Change in Dye Structure and the Mechanism for Its Effect on Cell Voltage Brian C. O’Regan, Kate Walley, Mindaugas Juozapavicius, Assaf Anderson, Farah Matar, Tarek Ghaddar, Shaik M. Zakeeruddin, C pp 3541–3548 DOI: 10.1021/ja806869x Supporting Info |
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Unprecedented Binding Cooperativity between CuI and CuII in the Copper Resistance Protein CopK from Cupriavidus metallidurans CH34: Implications from Structural Studies by NMR Spectroscopy and X-Ray Crystallography Lee Xin Chong, Miriam-Rose Ash, Megan J. Maher, Mark G. Hinds, Zhiguang Xiao and Anthony G. Wedd pp 3549–3564 DOI: 10.1021/ja807354z Supporting Info |
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High-Affinity Recognition of Lanthanide(III) Chelate Complexes by a Reprogrammed Human Lipocalin 2 Hyun Jin Kim, Andreas Eichinger and Arne Skerra pp 3565–3576 DOI: 10.1021/ja806857r Supporting Info |
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Redox Photochemistry of Methionine by Sulfur K-edge X-ray Absorption Spectroscopy: Potential Implications for Cataract Formation Anusha Karunakaran-Datt and Pierre Kennepohl pp 3577–3582 DOI: 10.1021/ja806946r Supporting Info |
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A Combined Theoretical and Experimental Study on the Role of Spin States in the Chemistry of Fe(CO)5 Photoproducts Maria Besora, Jos pp 3583–3592 DOI: 10.1021/ja807149t Supporting Info |
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Proton-Assisted Activation of Dihydrogen: Mechanistic Aspects of Proton-Catalyzed Addition of H2 to Ru and Ir Amido Complexes Zachariah M. Heiden and Thomas B. Rauchfuss pp 3593–3600 DOI: 10.1021/ja807277s Supporting Info |
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Selectivity as a Function of Nanoparticle Size in the Catalytic Hydrogenation of Unsaturated Alcohols Somnath Bhattacharjee, David M. Dotzauer and Merlin L. Bruening pp 3601–3610 DOI: 10.1021/ja807415k Supporting Info |
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Liquid Phase Production of Graphene by Exfoliation of Graphite in Surfactant/Water Solutions Mustafa Lotya, Yenny Hernandez, Paul J. King, Ronan J. Smith, Valeria Nicolosi, Lisa S. Karlsson, Fiona M. Blighe, Sukanta De, Zhiming Wang, I. T. McGovern, Georg S. Duesberg and Jonathan N. Coleman pp 3611–3620 DOI: 10.1021/ja807449u Supporting Info |
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Synthesis and Helicate Formation of a New Family of BINOL-Based Bis(bipyridine) Ligands Jens Bunzen, Torsten Bruhn, Gerhard Bringmann and Arne L pp 3621–3630 DOI: 10.1021/ja807780j Supporting Info |
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Early Stages of Oxidative Stress-Induced Membrane Permeabilization: A Neutron Reflectometry Study Hillary L. Smith, Michael C. Howland, Alan W. Szmodis, Qijuan Li, Luke L. Daemen, Atul N. Parikh and Jaroslaw Majewski pp 3631–3638 DOI: 10.1021/ja807680m Supporting Info |
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Pushing and Pulling a Sn Ion through an Adsorbed Phthalocyanine Molecule Yongfeng Wang, J pp 3639–3643 DOI: 10.1021/ja807876c Supporting Info |
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Interfacial Nanostructuring on the Performance of Polymer/TiO2 Nanorod Bulk Heterojunction Solar Cells Yun-Yue Lin, Tsung-Hung Chu, Shao-Sian Li, Chia-Hao Chuang, Chia-Hao Chang, Wei-Fang Su, Ching-Pin Chang, Ming-Wen Chu and Chun-Wei Chen pp 3644–3649 DOI: 10.1021/ja8079143 Supporting Info |
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C−C Reductive Elimination in Palladium Complexes, and the Role of Coupling Additives. A DFT Study Supported by Experiment Mart pp 3650–3657 DOI: 10.1021/ja808036j Supporting Info |
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Probing the Mechanism of the PCl5−Initiated Living Cationic Polymerization of the Phosphoranimine Cl3PNSiMe3 using Model Compound Chemistry Vivienne Blackstone, Alan J. Lough, Martin Murray and Ian Manners pp 3658–3667 DOI: 10.1021/ja808517d Supporting Info |
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Correlated Dynamics between Protein HN and HC Bonds Observed by NMR Cross Relaxation Beat V pp 3668–3678 DOI: 10.1021/ja808616v Supporting Info |
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Shape- and Dimension-Controlled Single-Crystalline Silicon and SiGe Nanotubes: Toward Nanofluidic FET Devices Moshit Ben Ishai and Fernando Patolsky pp 3679–3689 DOI: 10.1021/ja808483t Supporting Info |
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New Synthetic Technologies for the Construction of Heterocycles and Tryptamines K. C. Nicolaou, Arkady Krasovskiy, Utpal Majumder, Vincent pp 3690–3699 DOI: 10.1021/ja808692j Supporting Info |
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Ultrafast Intersystem Crossing and Spin Dynamics of Photoexcited Perylene-3,4:9,10-bis(dicarboximide) Covalently Linked to a Nitroxide Radical at Fixed Distances Emilie M. Giacobbe, Qixi Mi, Michael T. Colvin, Boiko Cohen, Charusheela Ramanan, Amy M. Scott, Sina Yeganeh, Tobin J. Marks, Mark A. Ratner and Michael R. Wasielewski pp 3700–3712 DOI: 10.1021/ja808924f Supporting Info |
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Enhanced Thermoelectric Performance in Barium and Indium Double-Filled Skutterudite Bulk Materials via Orbital Hybridization Induced by Indium Filler Wenyu Zhao, Ping Wei, Qingjie Zhang, Chunlei Dong, Lisheng Liu and Xinfeng Tang pp 3713–3720 DOI: 10.1021/ja8089334 |
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Architectural Chemistry: Synthesis of Topologically Diverse Macromulticycles by Sequential Multiple Multicomponent Macrocyclizations Daniel G. Rivera and Ludger A. Wessjohann pp 3721–3732 DOI: 10.1021/ja809005k Supporting Info |
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Chlorination: A General Route toward Electron Transport in Organic Semiconductors Ming Lee Tang, Joon Hak Oh, Anna Devi Reichardt and Zhenan Bao pp 3733–3740 DOI: 10.1021/ja809045s Supporting Info |
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Configurationally Rigid Pentaorganosilicates Erik P. A. Couzijn, Dani pp 3741–3751 DOI: 10.1021/ja809154g Supporting Info |
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Solvation Dynamics of Model Peptides Probed by Terahertz Spectroscopy. Observation of the Onset of Collective Network Motions Benjamin Born, Hermann Weing pp 3752–3755 DOI: 10.1021/ja808997y |
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Nanowire-Based All-Oxide Solar Cells Benjamin D. Yuhas and Peidong Yang pp 3756–3761 DOI: 10.1021/ja8095575 |
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Getting Harder: Cobalt(III)-Template Synthesis of Catenanes and Rotaxanes David A. Leigh, Paul J. Lusby, Roy T. McBurney, Alessandra Morelli, Alexandra M. Z. Slawin, Andrew R. Thomson and D. Barney Walker pp 3762–3771 DOI: 10.1021/ja809627j Supporting Info |
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Specific Nucleotide Binding and Rebinding to Individual DNA Polymerase Complexes Captured on a Nanopore Nicholas Hurt, Hongyun Wang, Mark Akeson and Kate R. Lieberman pp 3772–3778 DOI: 10.1021/ja809663f Supporting Info |
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Linking Structural Dynamics and Functional Diversity in Asymmetric Catalysis Akihiro Nojiri, Naoya Kumagai and Masakatsu Shibasaki pp 3779–3784 DOI: 10.1021/ja900084k Supporting Info |
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Dry Thienylation of the Silicon (111)-(7 × 7) Surface Yong Cao, Kian Soon Yong, Zheng Qiang Wang, Wee Shong Chin, Yee Hing Lai, Jing Fa Deng and Guo Qin Xu p 3785 DOI: 10.1021/ja900434g |
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Evidence for Partially Bound States in Cooperative Molecular Recognition Interfaces [J. Am. Chem. Soc., 2008, 130, 17718−17725] Elena Chekmeneva, Christopher A. Hunter, Martin J. Packer and Simon M. Turega p 3786 DOI: 10.1021/ja900730z |
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Oxiranyl Anion Methodology Using Microflow Systems Aiichiro Nagaki, Eiji Takizawa and Jun-ichi Yoshida p 3787 DOI: 10.1021/ja9008979 |
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Book Review of Carotenoids, Volume 4: Natural Functions Glenn E. Bartley p 3788 DOI: 10.1021/ja900693y |
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Iron Catalysis in Organic Chemistry: Reactions and Applications Paul J. Chirik pp 3788–3789 DOI: 10.1021/ja900791z |
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Standardization and Quality Assurance in Fluorescence Measurements I: Techniques Jonathan E. Kenny pp 3789–3790 DOI: 10.1021/ja901039q |
Issue 11
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Nucleic Acids: Expanding the Structural and Functional Horizons Sidney M. Hecht pp 3791–3793 DOI: 10.1021/ja9012485 |
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High-Throughput Thermal Scanning: A General, Rapid Dye-Binding Thermal Shift Screen for Protein Engineering Jason J. Lavinder, Sanjay B. Hari, Brandon J. Sullivan and Thomas J. Magliery pp 3794–3795 DOI: 10.1021/ja8049063 Supporting Info |
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Synthesis and Reactivity of a Mono-σ-Aryl Palladium(IV) Fluoride Complex Nicholas D. Ball and Melanie S. Sanford pp 3796–3797 DOI: 10.1021/ja8054595 Supporting Info |
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Intermolecular Electron-Transfer Catalyzed on Nanoparticle Surfaces Adrienne M. Carver, Mrinmoy De, Halil Bayraktar, Subinoy Rana, Vincent M. Rotello and Michael J. Knapp pp 3798–3799 DOI: 10.1021/ja806064t Supporting Info |
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A Thermoresponsive Fluorogenic Conjugated Polymer for a Temperature Sensor in Microfluidic Devices Sungmin Ryu, Imsung Yoo, Simon Song, Bora Yoon and Jong-Man Kim pp 3800–3801 DOI: 10.1021/ja808077d Supporting Info |
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Stereoselective Synthesis of Multisubstituted Enamides via Rhodium-Catalyzed Carbozincation of Ynamides Benoit Gourdet and Hon Wai Lam pp 3802–3803 DOI: 10.1021/ja900946h Supporting Info |
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Monodispersed Polymeric Nanocapsules: Spontaneous Evolution and Morphology Transition from Reducible Hetero-PEG PICmicelles by Controlled Degradation Wen-Fei Dong, Akihiro Kishimura, Yasutaka Anraku, Sayan Chuanoi and Kazunori Kataoka pp 3804–3805 DOI: 10.1021/ja808419b Supporting Info |
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Stabilization of RNA Oligomers through Reverse Micelle Encapsulation Hillary Workman and Peter F. Flynn pp 3806–3807 DOI: 10.1021/ja8084753 Supporting Info |
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Surface-Enhanced Raman Scattering inside Metal Nanoshells Peng Zhang and Yanyan Guo pp 3808–3809 DOI: 10.1021/ja8086642 Supporting Info |
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Toward an Accurate Determination of Free Energy Landscapes in Solution States of Proteins Alfonso De Simone, Barbara Richter, Xavier Salvatella and Michele Vendruscolo pp 3810–3811 DOI: 10.1021/ja8087295 Supporting Info |
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Timing of the Δ10,12-Δ11,13 Double Bond Migration During Ansamitocin Biosynthesis in Actinosynnema pretiosum Florian Taft, Marco Br pp 3812–3813 DOI: 10.1021/ja8088923 Supporting Info |
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Metathesis in Single Crystal: Complete and Reversible Exchange of Metal Ions Constituting the Frameworks of Metal−Organic Frameworks Sunirban Das, Hyunuk Kim and Kimoon Kim pp 3814–3815 DOI: 10.1021/ja808995d Supporting Info |
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Using Two Fluorescent Probes to Dissect the Binding, Insertion, and Dimerization Kinetics of a Model Membrane Peptide Jia Tang, Hang Yin, Jade Qiu, Matthew J. Tucker, William F. DeGrado and Feng Gai pp 3816–3817 DOI: 10.1021/ja809007f Supporting Info |
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Extending the Range of Microsecond-to-Millisecond Chemical Exchange Detected in Labeled and Unlabeled Nucleic Acids by Selective Carbon R1ρ NMR Spectroscopy Alexandar L. Hansen, Evgenia N. Nikolova, Anette Casiano-Negroni and Hashim M. Al-Hashimi pp 3818–3819 DOI: 10.1021/ja8091399 Supporting Info |
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Total Helical-Sense Bias of an Achiral Peptide Main Chain Induced by a Chiral Side-Chain Bridge Naoki Ousaka, Tomohiro Sato and Reiko Kuroda pp 3820–3821 DOI: 10.1021/ja8091714 Supporting Info |
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Light-Regulated Activation of Cellular Signaling by Gold Nanoparticles That Capture and Release Amines Jun Nakanishi, Hidekazu Nakayama, Takahiro Shimizu, Haruhisa Ishida, Yukiko Kikuchi, Kazuo Yamaguchi and Yasuhiro Horiike pp 3822–3823 DOI: 10.1021/ja809236a Supporting Info |
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Golden Metallopolymers with an Active T1 State via Coordination of Poly(4-vinyl)pyridine to Pentahalophenyl-Gold(I) Precursors Manal A. Rawashdeh-Omary, Jos pp 3824–3825 DOI: 10.1021/ja809585n Supporting Info |
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Silver Ion Unusually Stabilizes the Structure of a Parallel-Motif DNA Triplex Toshihiro Ihara, Tatsuaki Ishii, Norie Araki, Anthony W. Wilson and Akinori Jyo pp 3826–3827 DOI: 10.1021/ja809702n Supporting Info |
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Sensing Caspase 3 Activity with Quantum Dot−Fluorescent Protein Assemblies Kelly Boeneman, Bing C. Mei, Allison M. Dennis, Gang Bao, Jeffrey R. Deschamps, Hedi Mattoussi and Igor L. Medintz pp 3828–3829 DOI: 10.1021/ja809721j Supporting Info |
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A Single Molecular System Gating Electron Transfer by Ring Inversion of a Methylpyridylpyrimidine Ligand on Copper Kuniharu Nomoto, Shoko Kume and Hiroshi Nishihara pp 3830–3831 DOI: 10.1021/ja8097564 Supporting Info |
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DABCO-Catalyzed 1,4-Bromolactonization of Conjugated Enynes: Highly Stereoselective Formation of a Stereogenic Center and an Axially Chiral Allene Wen Zhang, Huadong Xu, Hui Xu and Weiping Tang pp 3832–3833 DOI: 10.1021/ja8099008 Supporting Info |
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Isolation of Notoamide E, a Key Precursor in the Biosynthesis of Prenylated Indole Alkaloids in a Marine-Derived Fungus, Aspergillus sp. Sachiko Tsukamoto, Hikaru Kato, Thomas J. Greshock, Hiroshi Hirota, Tomihisa Ohta and Robert M. Williams pp 3834–3835 DOI: 10.1021/ja810029b Supporting Info |
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Generation of Chiral Phosphonium Dialkyl Phosphite as a Highly Reactive P-Nucleophile: Application to Asymmetric Hydrophosphonylation of Aldehydes Daisuke Uraguchi, Takaki Ito and Takashi Ooi pp 3836–3837 DOI: 10.1021/ja810043d Supporting Info |
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A Self-Healing Oxygen-Evolving Catalyst Daniel A. Lutterman, Yogesh Surendranath and Daniel G. Nocera pp 3838–3839 DOI: 10.1021/ja900023k Supporting Info |
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An Aldol-Based Synthesis of (+)-Peloruside A, A Potent Microtubule Stabilizing Agent David A. Evans, Dennie S. Welch, Alexander W. H. Speed, George A. Moniz, Andreas Reichelt and Stephen Ho pp 3840–3841 DOI: 10.1021/ja900020a Supporting Info |
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Dependence of Pharmacokinetics and Biodistribution on Polymer Architecture: Effect of Cyclic versus Linear Polymers Norased Nasongkla, Bo Chen, Nichole Macaraeg, Megan E. Fox, Jean M. J. Fr pp 3842–3843 DOI: 10.1021/ja900062u Supporting Info |
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Highly Z- and Enantioselective Ring-Opening/Cross-Metathesis Reactions Catalyzed by Stereogenic-at-Mo Adamantylimido Complexes Ismail Ibrahem, Miao Yu, Richard R. Schrock and Amir H. Hoveyda pp 3844–3845 DOI: 10.1021/ja900097n Supporting Info |
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Palladium-Catalyzed Diacetoxylation of Alkenes with Molecular Oxygen as Sole Oxidant Azhong Wang, Huanfeng Jiang and Huoji Chen pp 3846–3847 DOI: 10.1021/ja900213d Supporting Info |
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Binding and Enantiomeric Selectivity of Threonyl-tRNA Synthetase Alpeshkumar K. Malde and Alan E. Mark pp 3848–3849 DOI: 10.1021/ja9002124 Supporting Info |
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Asymmetric Synthesis of α-Branched Allylic Amines by the Rh(I)-Catalyzed Addition of Alkenyltrifluoroborates to N-tert-Butanesulfinyl Aldimines Katrien Brak and Jonathan A. Ellman pp 3850–3851 DOI: 10.1021/ja9002603 Supporting Info |
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Theoretical Study of CO Escaping Pathway in Myoglobin with the 3D-RISM Theory Yasuomi Kiyota, Ryusuke Hiraoka, Norio Yoshida, Yutaka Maruyama, Takashi Imai and Fumio Hirata pp 3852–3853 DOI: 10.1021/ja900332e Supporting Info |
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An Unexpected Bis-ligation of S-Nitrosothiols Jiming Zhang, Hua Wang and Ming Xian pp 3854–3855 DOI: 10.1021/ja900370y Supporting Info |
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Photocatalytic Activity of NaNbO3 Thin Films Ken-ichi Katsumata, Christopher E. J. Cordonier, Tetsuya Shichi and Akira Fujishima pp 3856–3857 DOI: 10.1021/ja900394x Supporting Info |
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Two Methods for Catalytic Generation of Reactive Enolates Promoted by a Chiral Poly Gd Complex: Application to Catalytic Enantioselective Protonation Reactions Masataka Morita, Ludovic Drouin, Rie Motoki, Yasuaki Kimura, Ikuo Fujimori, Motomu Kanai and Masakatsu Shibasaki pp 3858–3859 DOI: 10.1021/ja9005018 Supporting Info |
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Formation of a Thermally Stable, Porous Coordination Network via a Crystalline-to-Amorphous-to-Crystalline Phase Transition Kazuaki Ohara, Javier Martí-Rujas, Tsuyoshi Haneda, Masaki Kawano, Daisuke Hashizume, Fujio Izumi and Makoto Fujita pp 3860–3861 DOI: 10.1021/ja9005145 Supporting Info |
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Synthesis, Structure, and Reactivity of Zirconacyclopentene Incorporating a Carboranyl Unit Shikuo Ren, Hoi-Shan Chan and Zuowei Xie pp 3862–3863 DOI: 10.1021/ja900563u Supporting Info |
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A Reagent for the Convenient, Solid-Phase Synthesis of N-Terminal Peptide Hydroxylamines for Chemoselective Ligations Takeo Fukuzumi and Jeffrey W. Bode pp 3864–3865 DOI: 10.1021/ja900601c Supporting Info |
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Post-Synthesis Alkoxide Formation Within Metal−Organic Framework Materials: A Strategy for Incorporating Highly Coordinatively Unsaturated Metal Ions Karen L. Mulfort, Omar K. Farha, Charlotte L. Stern, Amy A. Sarjeant and Joseph T. Hupp pp 3866–3868 DOI: 10.1021/ja809954r Supporting Info |
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A Dianionic Phosphorane Intermediate and Transition States in an Associative AN+DN Mechanism for the RibonucleaseA Hydrolysis Reaction Brigitta Els pp 3869–3871 DOI: 10.1021/ja807940y Supporting Info |
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Photoinitiated Destruction of Composite Porphyrin−Protein Polymersomes Gregory P. Robbins, Masaya Jimbo, Joe Swift, Michael J. Therien, Daniel A. Hammer and Ivan J. Dmochowski pp 3872–3874 DOI: 10.1021/ja808586q Supporting Info |
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Control of Pore Size and Functionality in Isoreticular Zeolitic Imidazolate Frameworks and their Carbon Dioxide Selective Capture Properties Rahul Banerjee, Hiroyasu Furukawa, David Britt, Carolyn Knobler, Michael O’Keeffe and Omar M. Yaghi pp 3875–3877 DOI: 10.1021/ja809459e Supporting Info |
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Three-Coordinate Copper(I) Amido and Aminyl Radical Complexes Neal P. Mankad, William E. Antholine, Robert K. Szilagyi and Jonas C. Peters pp 3878–3880 DOI: 10.1021/ja809834k Supporting Info |
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High-Quality 2D Metal−Organic Coordination Network Providing Giant Cavities within Mesoscale Domains Dirk K pp 3881–3883 DOI: 10.1021/ja809946z Supporting Info |
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Temperature- and Pressure-Induced Proton Transfer in the 1:1 Adduct Formed between Squaric Acid and 4,4′-Bipyridine David M. S. Martins, Derek S. Middlemiss, Colin R. Pulham, Chick C. Wilson, Mark T. Weller, Paul F. Henry, Norman Shankland, Kenneth Shankland, William G. Marshall, Richard M. Ibberson, Kevin Knight, Stephen Moggach, Michela Brunelli and Carole A. Morrison pp 3884–3893 DOI: 10.1021/ja8082973 Supporting Info |
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Efficient Approach to Androstene-Fused Arylpyrazolines as Potent Antiproliferative Agents. Experimental and Theoretical Studies of Substituent Effects on BF3-Catalyzed Intramolecular [3 + 2] Cycloadditions of Olefinic Phenylhydrazones pp 3894–3904 DOI: 10.1021/ja808636e Supporting Info |
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Changes in Binding Motif of Protonated Heterodimers Containing Valine and Amines Investigated Using IRMPD Spectroscopy between 800 and 3700 cm−1 and Theory Jeremy T. O’Brien, James S. Prell, Jeffrey D. Steill, Jos Oomens and Evan R. Williams pp 3905–3912 DOI: 10.1021/ja809928h Supporting Info |
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Both Intra- and Interstrand Charge-Transfer Excited States in Aqueous B-DNA Are Present at Energies Comparable To, or Just Above, the 1ππ* Excitonic Bright States Adrian W. Lange and John M. Herbert pp 3913–3922 DOI: 10.1021/ja808998q Supporting Info |
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Polyfluorophores on a DNA Backbone: A Multicolor Set of Labels Excited at One Wavelength Yin Nah Teo, James N. Wilson and Eric T. Kool pp 3923–3933 DOI: 10.1021/ja805502k Supporting Info |
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Antioxidant Single-Walled Carbon Nanotubes Rebecca M. Lucente-Schultz, Valerie C. Moore, Ashley D. Leonard, B. Katherine Price, Dmitry V. Kosynkin, Meng Lu, Ranga Partha, Jodie L. Conyers and James M. Tour pp 3934–3941 DOI: 10.1021/ja805721p Supporting Info |
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Donor Acceptor Complexes of Noble Gases Leonie Anna M pp 3942–3949 DOI: 10.1021/ja805990h Supporting Info |
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Color-Tuned Highly Fluorescent Organic Nanowires/Nanofabrics: Easy Massive Fabrication and Molecular Structural Origin Byeong-Kwan An, Se Hoon Gihm, Jong Won Chung, Chong Rae Park, Soon-Ki Kwon and Soo Young Park pp 3950–3957 DOI: 10.1021/ja806162h Supporting Info |
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Synthesis and Polymerase Chain Reaction Amplification of DNA Strands Containing an Unnatural Triazole Linkage Afaf H. El-Sagheer and Tom Brown pp 3958–3964 DOI: 10.1021/ja8065896 Supporting Info |
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Quantitative DFT Modeling of the Enantiomeric Excess for Dioxirane-Catalyzed Epoxidations Severin T. Schneebeli, Michelle Lynn Hall, Ronald Breslow and Richard Friesner pp 3965–3973 DOI: 10.1021/ja806951r Supporting Info |
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Proximity and Cooperativity Effects in Binuclear d0 Olefin Polymerization Catalysis. Theoretical Analysis of Structure and Reaction Mechanism Alessandro Motta, Ignazio L. Fragal pp 3974–3984 DOI: 10.1021/ja8077208 Supporting Info |
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Growth of Oriented Single-Crystalline Rutile TiO2 Nanorods on Transparent Conducting Substrates for Dye-Sensitized Solar Cells Bin Liu and Eray S. Aydil pp 3985–3990 DOI: 10.1021/ja8078972 Supporting Info |
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Synthesis of (−)-PNU-286607 by Asymmetric Cyclization of Alkylidene Barbiturates J. Craig Ruble, Alexander R. Hurd, Timothy A. Johnson, Debra A. Sherry, Michael R. Barbachyn, Peter L. Toogood, Gordon L. Bundy, David R. Graber and Gregg M. Kamilar pp 3991–3997 DOI: 10.1021/ja808014h Supporting Info |
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Anion-Exchange Induced Phase Transformation of Mesostructured Silica Ming-Chang Liu, Hwo-Shuenn Sheu and Soofin Cheng pp 3998–4005 DOI: 10.1021/ja808025m |
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Photo-Induced and Resist-Free Imprint Patterning of Fullerene Materials for Use in Functional Electronics Andrzej Dzwilewski, Thomas Wågberg and Ludvig Edman pp 4006–4011 DOI: 10.1021/ja807964x |
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Host−Guest Complexes with Protein−Ligand-like Affinities: Computational Analysis and Design Sarvin Moghaddam, Yoshihisa Inoue and Michael K. Gilson pp 4012–4021 DOI: 10.1021/ja808175m Supporting Info |
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Pressure-Induced Cooperative Bond Rearrangement in a Zinc Imidazolate Framework: A High-Pressure Single-Crystal X-Ray Diffraction Study Elinor C. Spencer, Ross J. Angel, Nancy L. Ross, Brian E. Hanson and Judith A. K. Howard pp 4022–4026 DOI: 10.1021/ja808531m Supporting Info |
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Caged Progesterone: A New Tool for Studying Rapid Nongenomic Actions of Progesterone Funda Kilic, Nachiket D. Kashikar, Reinhard Schmidt, Luis Alvarez, Luru Dai, Ingo Weyand, Burkhard Wiesner, Normann Goodwin, Volker Hagen and U. Benjamin Kaupp pp 4027–4030 DOI: 10.1021/ja808334f Supporting Info |
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Modular Synthesis of Indoles from Imines and o-Dihaloarenes or o-Chlorosulfonates by a Pd-Catalyzed Cascade Process Jos pp 4031–4041 DOI: 10.1021/ja808652a Supporting Info |
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On the Nature of DNA Self-Assembled Monolayers on Au: Measuring Surface Heterogeneity with Electrochemical in Situ Fluorescence Microscopy Jeffrey N. Murphy, Alan K. H. Cheng, Hua-Zhong Yu and Dan Bizzotto pp 4042–4050 DOI: 10.1021/ja808696p Supporting Info |
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Combined Experimental and Theoretical Study of Long-Range Interactions Modulating Dimerization and Activity of Yeast Geranylgeranyl Diphosphate Synthase Chia-Hsiang Lo, Ying-Hsuan Chang, Jon D. Wright, Shih-Hsun Chen, Daphne Kan, Carmay Lim and Po-Huang Liang pp 4051–4062 DOI: 10.1021/ja808699c Supporting Info |
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Acyl Radical Reactions in Fullerene Chemistry: Direct Acylation of [60]Fullerene through an Efficient Decatungstate-Photomediated Approach Manolis D. Tzirakis and Michael Orfanopoulos pp 4063–4069 DOI: 10.1021/ja808658b Supporting Info |
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Mechanism of BINOL−Phosphoric Acid-Catalyzed Strecker Reaction of Benzyl Imines Luis Sim pp 4070–4077 DOI: 10.1021/ja808715j Supporting Info |
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Solvothermal Synthesis and Photoreactivity of Anatase TiO2 Nanosheets with Dominant {001} Facets Hua Gui Yang, Gang Liu, Shi Zhang Qiao, Cheng Hua Sun, Yong Gang Jin, Sean Campbell Smith, Jin Zou, Hui Ming Cheng and Gao Qing (Max) Lu pp 4078–4083 DOI: 10.1021/ja808790p Supporting Info |
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Transition State Distortion Energies Correlate with Activation Energies of 1,4-Dihydrogenations and Diels−Alder Cycloadditions of Aromatic Molecules Amy E. Hayden and K. N. Houk pp 4084–4089 DOI: 10.1021/ja809142x Supporting Info |
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Understanding the Molecule−Surface Chemical Coupling in SERS Seth M. Morton and Lasse Jensen pp 4090–4098 DOI: 10.1021/ja809143c Supporting Info |
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Mechanistic Study of the Manganese-Catalyzed [2 + 2 + 2] Annulation of 1,3-Dicarbonyl Compounds and Terminal Alkynes Naohiko Yoshikai, Song-Lin Zhang, Ken-ichi Yamagata, Hayato Tsuji and Eiichi Nakamura pp 4099–4109 DOI: 10.1021/ja809202y Supporting Info |
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Structures of Thermal, Mass-Selected Water Clusters Probed with Hydrophobic Ion Tags and Infrared Photodissociation Spectroscopy James S. Prell and Evan R. Williams pp 4110–4119 DOI: 10.1021/ja809414a Supporting Info |
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Mechanistic Insights on the Hydrodesulfurization of Biphenyl-2-thiol with Nickel Compounds Jorge Torres-Nieto, William W. Brennessel, William D. Jones and Juventino J. Garc pp 4120–4126 DOI: 10.1021/ja809457s Supporting Info |
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Photolabile Protecting Groups Based on the Singlet State Photodecarboxylation of Xanthone Acetic Acid Jessie A. Blake, Matthew Lukeman and Juan C. Scaiano pp 4127–4135 DOI: 10.1021/ja8094872 Supporting Info |
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Helical Triskelion Monophosphites as Ligands in Asymmetric Catalysis Manfred T. Reetz, Hongchao Guo, Jun-An Ma, Richard Goddard and Richard J. Mynott pp 4136–4142 DOI: 10.1021/ja809297a Supporting Info |
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Ab Initio Study of Hydrogen Adsorption in MOF-5 Kaido Sillar, Alexander Hofmann and Joachim Sauer pp 4143–4150 DOI: 10.1021/ja8099079 Supporting Info |
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Biologics through Chemistry: Total Synthesis of a Proposed Dual-Acting Vaccine Targeting Ovarian Cancer by Orchestration of Oligosaccharide and Polypeptide Domains Jianglong Zhu, Qian Wan, Govind Ragupathi, Constantine M. George, Philip O. Livingston and Samuel J. Danishefsky pp 4151–4158 DOI: 10.1021/ja810147j Supporting Info |
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Dinuclear Zn(II) Complex Promotes Cleavage and Isomerization of 2-Hydroxypropyl Alkyl Phosphates by a Common Cyclic Phosphate Intermediate Wing Yin Tsang, David R. Edwards, Stephanie A. Melnychuk, C. Tony Liu, Chaomin Liu, Alexei A. Neverov, Nicholas H. Williams and R. Stan Brown pp 4159–4166 DOI: 10.1021/ja900525t Supporting Info |
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Advances in Chemical Physics, Volume 140 R. V. Krems pp 4167–4168 DOI: 10.1021/ja9008002 |
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Raman and SERS Investigations of Pharmaceuticals Robert A. Lodder p 4168 DOI: 10.1021/ja900639r |
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Spectroelectrochemistry Karen J. Brewer pp 4168–4169 DOI: 10.1021/ja9009887 |
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Targets in Heterocyclic Systems: Chemistry and Properties, Volume 11 (2007) p 4169 DOI: 10.1021/ja901277y |
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M p 4169 DOI: 10.1021/ja901245x |
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Reaction Mechanisms in Organic Synthesis p 4169 DOI: 10.1021/ja9013979 |
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Modified Nucleosides in Biochemistry, Biotechnology and Medicine Christine S. Chow pp 4169–4170 DOI: 10.1021/ja901280d |
Issue 12
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Jacobsen’s Catalyst for Hydrolytic Kinetic Resolution: Structure Elucidation of Paramagnetic Co(III) Salen Complexes in Solution via Combined NMR and Quantum Chemical Studies Sebastian Kemper, Peter Hrob pp 4172–4173 DOI: 10.1021/ja806151g Supporting Info |
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Oxidative Palladium Catalysis in SNAr Reactions Leading to Heteroaryl Ethers from Pyridotriazol-1-yloxy Heterocycles with Aryl Boronic Acids Sumrit Wacharasindhu, Sujata Bardhan, Zhao-Kui Wan, Keiko Tabei and Tarek S. Mansour pp 4174–4175 DOI: 10.1021/ja808622z Supporting Info |
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Structure and Mechanism of the Photoactivatable Green Fluorescent Protein J. Nathan Henderson, Rinat Gepshtein, Josef R. Heenan, Karen Kallio, Dan Huppert and S. James Remington pp 4176–4177 DOI: 10.1021/ja808851n Supporting Info |
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Self-Assembly of Nanostructured Diatom Microshells into Patterned Arrays Assisted by Polyelectrolyte Multilayer Deposition and Inkjet Printing Wei Wang, Timothy Gutu, Debra K. Gale, Jun Jiao, Gregory L. Rorrer and Chih-hung Chang pp 4178–4179 DOI: 10.1021/ja809079n Supporting Info |
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Heteroatom-Controlled Kinetics of Switchable Polyoxometalate Frameworks Johannes Thiel, Chris Ritchie, Carsten Streb, De-Liang Long and Leroy Cronin pp 4180–4181 DOI: 10.1021/ja809422k Supporting Info |
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Nucleobase-Templated Polymerization: Copying the Chain Length and Polydispersity of Living Polymers into Conjugated Polymers Pik Kwan Lo and Hanadi F. Sleiman pp 4182–4183 DOI: 10.1021/ja809613n Supporting Info |
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A Porous Coordination Copolymer with over 5000 m2/g BET Surface Area Kyoungmoo Koh, Antek G. Wong-Foy and Adam J. Matzger pp 4184–4185 DOI: 10.1021/ja809985t Supporting Info |
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Reassessment of the Reaction Mechanism in the Heme Dioxygenases Nishma Chauhan, Sarah J. Thackray, Sara A. Rafice, Graham Eaton, Michael Lee, Igor Efimov, Jaswir Basran, Paul R. Jenkins, Christopher G Mowat, Stephen K. Chapman and Emma Lloyd Raven pp 4186–4187 DOI: 10.1021/ja808326g Supporting Info |
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A Genetically Encoded Bioluminescent Indicator for the Sodium Channel Activity in Living Cells Asami Kaihara, Akihiko Sunami, Junko Kurokawa and Tetsushi Furukawa pp 4188–4189 DOI: 10.1021/ja808669y Supporting Info |
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Asymmetric Synthesis of Diamine Derivatives via Sequential Palladium and Rhodium Catalysis Barry M. Trost, Sushant Malhotra, David E. Olson, Autumn Maruniak and J. Du Bois pp 4190–4191 DOI: 10.1021/ja809697p Supporting Info |
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Reaction of Allylic Phosphoranes with Iron Porphyrin Carbenoids: Efficient, Selective, and Catalytic Intermolecular Formal Carbenoid Insertion into Olefinic C−H Bonds Sunewang R. Wang, Chun-Yin Zhu, Xiu-Li Sun and Yong Tang pp 4192–4193 DOI: 10.1021/ja8097959 Supporting Info |
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Palladium-Catalyzed Intramolecular Direct Arylation of Benzoic Acids by Tandem Decarboxylation/C−H Activation Congyang Wang, Isabel Piel and Frank Glorius pp 4194–4195 DOI: 10.1021/ja8100598 Supporting Info |
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Anion-Catalyzed Addition of γ-Silylallenyl Esters to Aldehydes: A New Entry into [3.2.1] Bicyclic Natural Products Pradip Maity and Salvatore D. Lepore pp 4196–4197 DOI: 10.1021/ja810136m Supporting Info |
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Platinum-Catalyzed Dehydroalkoxylation−Cyclization Cascade via N−O Bond Cleavage Itaru Nakamura, Yusuke Sato and Masahiro Terada pp 4198–4199 DOI: 10.1021/ja900174t Supporting Info |
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Palladium-Catalyzed Allylic Amination Using Aqueous Ammonia for the Synthesis of Primary Amines Takashi Nagano and Sh pp 4200–4201 DOI: 10.1021/ja900328x Supporting Info |
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EuKNaTaO5: Crystal Growth, Structure and Photoluminescence Property Irina P. Roof, Mark D. Smith, Sangmoon Park and Hans-Conrad zur Loye pp 4202–4203 DOI: 10.1021/ja8100769 Supporting Info |
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A Catalytically Active, Permanently Microporous MOF with Metalloporphyrin Struts Abraham M. Shultz, Omar K. Farha, Joseph T. Hupp and SonBinh T. Nguyen pp 4204–4205 DOI: 10.1021/ja900203f Supporting Info |
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A PARACEST Agent Responsive to Inner- And Outer-Sphere Phosphate Ester Interactions for MRI Applications Ching-Hui Huang and Janet R. Morrow pp 4206–4207 DOI: 10.1021/ja900290z Supporting Info |
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Experimental Electron Density Study of the Mg−Mg Bonding Character in a Magnesium(I) Dimer Jacob Overgaard, Cameron Jones, Andreas Stasch and Bo B. Iversen pp 4208–4209 DOI: 10.1021/ja900385u Supporting Info |
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Magnesium−Magnesium Bond Stabilized by a Doubly Reduced α-Diimine: Synthesis and Structure of [K(THF)3]2[LMg−MgL] (L = [(2,6-iPr2C6H3)NC(Me)]22−) Yanyan Liu, Shaoguang Li, Xiao-Juan Yang, Peiju Yang and Biao Wu pp 4210–4211 DOI: 10.1021/ja900568c Supporting Info |
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Direct Observation of Acyl Azide Excited States and Their Decay Processes by Ultrafast Time Resolved Infrared Spectroscopy Jacek Kubicki, Yunlong Zhang, Jin Wang, Hoi Ling Luk, Huo-Lei Peng, Shubham Vyas and Matthew S. Platz pp 4212–4213 DOI: 10.1021/ja9002102 Supporting Info |
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Concise Enantioselective Synthesis of ent-Malbrancheamide B Frederic Frebault, Nigel S. Simpkins and Ashley Fenwick pp 4214–4215 DOI: 10.1021/ja900688y Supporting Info |
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Dumbbell-like Au−Fe3O4 Nanoparticles for Target-Specific Platin Delivery Chenjie Xu, Baodui Wang and Shouheng Sun pp 4216–4217 DOI: 10.1021/ja900790v Supporting Info |
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High-Purity Separation of Gold Nanoparticle Dimers and Trimers Gang Chen, Yong Wang, Li Huey Tan, Miaoxin Yang, Lee Siew Tan, Yuan Chen and Hongyu Chen pp 4218–4219 DOI: 10.1021/ja900809z Supporting Info |
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Layer-by-Layer Films of Dual-Pore Carbon Capsules with Designable Selectivity of Gas Adsorption Qingmin Ji, Suk Bon Yoon, Jonathan P. Hill, Ajayan Vinu, Jong-Sung Yu and Katsuhiko Ariga pp 4220–4221 DOI: 10.1021/ja9010354 Supporting Info |
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Highly Enantioselective and Diastereoselective Synthesis of Chiral Amino Alcohols by Ruthenium-Catalyzed Asymmetric Hydrogenation of α-Amino Aliphatic Ketones Jian-Hua Xie, Sheng Liu, Wei-Ling Kong, Wen-Ju Bai, Xiao-Chen Wang, Li-Xin Wang and Qi-Lin Zhou pp 4222–4223 DOI: 10.1021/ja901058u Supporting Info |
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Catalyzed Hydrogen Spillover for Hydrogen Storage Ralph T. Yang and Yuhe Wang pp 4224–4226 DOI: 10.1021/ja808864r Supporting Info |
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A Fast Photochromic Molecule That Colors Only under UV Light Yuta Kishimoto and Jiro Abe pp 4227–4229 DOI: 10.1021/ja810032t Supporting Info |
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Amphiphilic TiO2 Nanotube Arrays: An Actively Controllable Drug Delivery System Yan-Yan Song, Felix Schmidt-Stein, Sebastian Bauer and Patrik Schmuki pp 4230–4232 DOI: 10.1021/ja810130h Supporting Info |
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Metal Nanoparticles Functionalized with Molecular and Supramolecular Switches Rafal Klajn, Lei Fang, Ali Coskun, Mark A. Olson, Paul J. Wesson, J. Fraser Stoddart and Bartosz A. Grzybowski pp 4233–4235 DOI: 10.1021/ja9001585 Supporting Info |
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Fluxionality of [(Ph3P)3Rh(X)]: The Extreme Case of X = CF3 Jenni Goodman, Vladimir V. Grushin, Roman B. Larichev, Stuart A. Macgregor, William J. Marshall and D. Christopher Roe pp 4236–4238 DOI: 10.1021/ja9005699 Supporting Info |
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Evidence for Solution-State Nonlinearity of sp-Carbon Chains Based on IR and Raman Spectroscopy: Violation of Mutual Exclusion Andrea Lucotti, Matteo Tommasini, Daniele Fazzi, Mirella Del Zoppo, Wesley A. Chalifoux, Michael J. Ferguson, Giuseppe Zerbi and Rik R. Tykwinski pp 4239–4244 DOI: 10.1021/ja078198b Supporting Info |
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Single-Chromophore-Based Photoswitchable Nanoparticles Enable Dual-Alternating-Color Fluorescence for Unambiguous Live Cell Imaging Zhiyuan Tian, Wuwei Wu, Wei Wan and Alexander D. Q. Li pp 4245–4252 DOI: 10.1021/ja805150g |
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Plasmonic Cu2−xS Nanocrystals: Optical and Structural Properties of Copper-Deficient Copper(I) Sulfides Yixin Zhao, Hongcheng Pan, Yongbing Lou, Xiaofeng Qiu, JunJie Zhu and Clemens Burda pp 4253–4261 DOI: 10.1021/ja805655b |
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Continuous, Real-Time Monitoring of Cocaine in Undiluted Blood Serum via a Microfluidic, Electrochemical Aptamer-Based Sensor James S. Swensen, Yi Xiao, Brian S. Ferguson, Arica A. Lubin, Rebecca Y. Lai, Alan J. Heeger, Kevin W. Plaxco and H. Tom. Soh pp 4262–4266 DOI: 10.1021/ja806531z Supporting Info |
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Analysis of the UV/Vis and CD Spectral Line Shapes of Carotenoid Assemblies: Spectral Signatures of Chiral H-Aggregates Frank C. Spano pp 4267–4278 DOI: 10.1021/ja806853v Supporting Info |
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Photoinduced Oxidation of Water to Oxygen in the Ionic Liquid BMIMBF4 as the Counter Reaction in the Fabrication of Exceptionally Long Semiconducting Silver-Tetracyanoquinodimethane Nanowires Chuan Zhao and Alan M. Bond pp 4279–4287 DOI: 10.1021/ja806893t Supporting Info |
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Nucleic Acid Base Analog FRET-Pair Facilitating Detailed Structural Measurements in Nucleic Acid Containing Systems Karl B pp 4288–4293 DOI: 10.1021/ja806944w Supporting Info |
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Active-Site Motions and Polarity Enhance Catalytic Turnover of Hydrated Subtilisin Dissolved in Organic Solvents Elton P. Hudson, Ross K. Eppler, Julianne M. Beaudoin, Jonathan S. Dordick, Jeffrey A. Reimer and Douglas S. Clark pp 4294–4300 DOI: 10.1021/ja806996q Supporting Info |
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Structure of the Human Telomere in K+ Solution: A Stable Basket-Type G-Quadruplex with Only Two G-Tetrad Layers Kah Wai Lim, Samir Amrane, Serge Bouaziz, Weixin Xu, Yuguang Mu, Dinshaw J. Patel, Kim Ngoc Luu and Anh Tu pp 4301–4309 DOI: 10.1021/ja807503g Supporting Info |
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Gas-Phase IR Spectroscopy of Deprotonated Amino Acids Jos Oomens, Jeffrey D. Steill and Britta Redlich pp 4310–4319 DOI: 10.1021/ja807615v Supporting Info |
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Conformational Behavior of Norephedrine, Ephedrine, and Pseudoephedrine Jos pp 4320–4326 DOI: 10.1021/ja807674q Supporting Info |
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Thiostrepton Biosynthesis: Prototype for a New Family of Bacteriocins Wendy L. Kelly, Lisa Pan and Chaoxuan Li pp 4327–4334 DOI: 10.1021/ja807890a Supporting Info |
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Trends in Ground-State Entropies for Transition Metal Based Hydrogen Atom Transfer Reactions Elizabeth A. Mader, Virginia W. Manner, Todd F. Markle, Adam Wu, James A. Franz and James M. Mayer pp 4335–4345 DOI: 10.1021/ja8081846 Supporting Info |
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Synthesis of a Cross-Linked Branched Polymer Network in the Interior of a Protein Cage Md Joynal Abedin, Lars Liepold, Peter Suci, Mark Young and Trevor Douglas pp 4346–4354 DOI: 10.1021/ja8079862 Supporting Info |
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Binding Mechanism of an SH3 Domain Studied by NMR and ITC Jean-Philippe Demers and Anthony Mittermaier pp 4355–4367 DOI: 10.1021/ja808255d |
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The Role of Adenine Excimers in the Photophysics of Oligonucleotides Gloria Olaso-Gonz pp 4368–4377 DOI: 10.1021/ja808280j Supporting Info |
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Low-Resolution Structures of Transient Protein−Protein Complexes Using Small-Angle X-ray Scattering Jascha Blobel, Pau Bernad pp 4378–4386 DOI: 10.1021/ja808490b Supporting Info |
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Spin Dynamics in the Negatively Charged Terbium (III) Bis-phthalocyaninato Complex Francesca Branzoli, Pietro Carretta, Marta Filibian, Giorgio Zoppellaro, Michael J. Graf, Jose R. Galan-Mascaros, Olaf Fuhr, Susan Brink and Mario Ruben pp 4387–4396 DOI: 10.1021/ja808649g Supporting Info |
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Cationic and Anionic Surface Binding Sites on Nanocrystalline Zinc Oxide: Surface Influence on Photoluminescence and Photocatalysis D. Scott Bohle and Carla J. Spina pp 4397–4404 DOI: 10.1021/ja808663b Supporting Info |
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cis-β-Bis(carbonyl) Ruthenium−Salen Complexes: X-ray Crystal Structures and Remarkable Catalytic Properties toward Asymmetric Intramolecular Alkene Cyclopropanation Zhen-Jiang Xu, Ran Fang, Cunyuan Zhao, Jie-Sheng Huang, Gong-Yong Li, Nianyong Zhu and Chi-Ming Che pp 4405–4417 DOI: 10.1021/ja8086399 Supporting Info |
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Bottom-up Design of Hybrid Polymer Nanoassemblies Elucidates Plasmon-Enhanced Second Harmonic Generation from Nonlinear Optical Dyes Miki Ishifuji, Masaya Mitsuishi and Tokuji Miyashita pp 4418–4424 DOI: 10.1021/ja808749h Supporting Info |
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Probing the Coupling between Proton and Electron Transfer in Photosystem II Core Complexes Containing a 3-Fluorotyrosine Fabrice Rappaport, Alain Boussac, Dee Ann Force, Jeffrey Peloquin, Marcin Brynda, Miwa Sugiura, Sun Un, R. David Britt and Bruce A. Diner pp 4425–4433 DOI: 10.1021/ja808604h Supporting Info |
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Photo and pH Stable, Highly-Luminescent Silicon Nanospheres and Their Bioconjugates for Immunofluorescent Cell Imaging Yao He, Yuanyuan Su, Xiaobao Yang, Zhenhui Kang, Tingting Xu, Ruiqin Zhang, Chunhai Fan and Shuit-Tong Lee pp 4434–4438 DOI: 10.1021/ja808827g Supporting Info |
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Controlled Self-Assembly of C3-Symmetric Hexa-peri-hexabenzocoronenes with Alternating Hydrophilic and Hydrophobic Substituents in Solution, in the Bulk, and on a Surface Xinliang Feng, Wojciech Pisula, Tibor Kudernac, Dongqing Wu, Linjie Zhi, Steven De Feyter and Klaus M pp 4439–4448 DOI: 10.1021/ja808979t Supporting Info |
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Experimental and Theoretical Analysis of Asymmetric Induction in Heterogeneous Catalysis: Diastereoselective Hydrogenation of Chiral α-Hydroxyketones over Pt Catalyst Igor Busygin, Antti Taskinen, Ville Nieminen, Esa Toukoniitty, Thomas Stillger, Reko Leino and Dmitry Yu. Murzin pp 4449–4462 DOI: 10.1021/ja809070g Supporting Info |
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Combination of Spectroscopic Methods: In Situ NMR and UV/Vis Measurements To Understand the Formation of Group 4 Metallacyclopentanes from the Corresponding Metallacyclopropenes Torsten Beweries, Christian Fischer, Stephan Peitz, Vladimir V. Burlakov, Perdita Arndt, Wolfgang Baumann, Anke Spannenberg, Detlef Heller and Uwe Rosenthal pp 4463–4469 DOI: 10.1021/ja809368s Supporting Info |
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Induction of Negative Curvature as a Mechanism of Cell Toxicity by Amyloidogenic Peptides: The Case of Islet Amyloid Polypeptide Pieter E. S. Smith, Jeffrey R. Brender and Ayyalusamy Ramamoorthy pp 4470–4478 DOI: 10.1021/ja809002a Supporting Info |
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Insights into the Kinetics of Semiconductor Nanocrystal Nucleation and Growth Jane Y. Rempel, Moungi G. Bawendi and Klavs F. Jensen pp 4479–4489 DOI: 10.1021/ja809156t Supporting Info |
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Determining the Effects of Lipophilic Drugs on Membrane Structure by Solid-State NMR Spectroscopy: The Case of the Antioxidant Curcumin Jeffrey Barry, Michelle Fritz, Jeffrey R. Brender, Pieter E. S. Smith, Dong-Kuk Lee and Ayyalusamy Ramamoorthy pp 4490–4498 DOI: 10.1021/ja809217u Supporting Info |
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Stop-Flow Lithography for the Production of Shape-Evolving Degradable Microgel Particles Dae Kun Hwang, John Oakey, Mehmet Toner, Jeffrey A. Arthur, Kristi S. Anseth, Sunyoung Lee, Adam Zeiger, Krystyn J. Van Vliet and Patrick S. Doyle pp 4499–4504 DOI: 10.1021/ja809256d Supporting Info |
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Metal Clips That Induce Unstructured Pentapeptides To Be α-Helical In Water Michelle T. Ma, Huy N. Hoang, Conor C. G. Scully, Trevor G. Appleton and David P. Fairlie pp 4505–4512 DOI: 10.1021/ja900047w Supporting Info |
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Mechanistic Studies on Au(I)-Catalyzed [3,3]-Sigmatropic Rearrangements using Cyclopropane Probes Pablo Maule pp 4513–4520 DOI: 10.1021/ja900456m Supporting Info |
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Path-Integral Method for Predicting Relative Binding Affinities of Protein−Ligand Complexes Chandrika Mulakala and Yiannis N. Kaznessis pp 4521–4528 DOI: 10.1021/ja807460s Supporting Info |
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Selective Etching of Thin Single-Walled Carbon Nanotubes Martin Kalb pp 4529–4534 DOI: 10.1021/ja807578n |
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Intra- and Intermolecular Interaction Inducing Pyramidalization on Both Sides of a Proline Dipeptide during Isomerization: An Ab Initio QM/MM Molecular Dynamics Simulation Study in Explicit Water Yasushige Yonezawa, Kazuto Nakata, Kota Sakakura, Toshikazu Takada and Haruki Nakamura pp 4535–4540 DOI: 10.1021/ja807814x Supporting Info |
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Ordered Mesoporous Pd/Silica−Carbon as a Highly Active Heterogeneous Catalyst for Coupling Reaction of Chlorobenzene in Aqueous Media Ying Wan, Haiyan Wang, Qingfei Zhao, Miia Klingstedt, Osamu Terasaki and Dongyuan Zhao pp 4541–4550 DOI: 10.1021/ja808481g Supporting Info |
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Guanidinium Groups Act as General-Acid Catalysts in Phosphoryl Transfer Reactions: A Two-Proton Inventory on a Model System Anna M. Pi p 4551 DOI: 10.1021/ja901152u |
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Nature of Cl Bonding on the Au(111) Surface: Evidence of a Mainly Covalent Interaction Thomas A. Baker, Cynthia M. Friend and Efthimios Kaxiras p 4551 DOI: 10.1021/ja901085k |
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Organic Reactions, Volume 72 p 4552 DOI: 10.1021/ja901476s |
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Nuclear Receptors as Drug Targets. Methods and Principles in Medicinal Chemistry, Volume 39 Matthew R. Redinbo, Ph.D.* and Yuan Cheng p 4552 DOI: 10.1021/ja9015233 |
Issue 13
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Polymer-Induced Heteronucleation of Tolfenamic Acid: Structural Investigation of a Pentamorph Vilmalí L pp 4554–4555 DOI: 10.1021/ja806289a Supporting Info |
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Inter- and Intramolecular [4 + 3] Cycloadditions Using Epoxy Enol Silanes As Functionalized Oxyallyl Cation Precursors Wing Ki Chung, Sze Kui Lam, Brian Lo, Lok Lok Liu, Wing-Tak Wong and Pauline Chiu pp 4556–4557 DOI: 10.1021/ja807566t Supporting Info |
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VTVH-MCD Study of the ΔnifBΔnifZ MoFe Protein from Azotobacter vinelandii Marcia S. Cotton, Kresimir Rupnik, Robyn B. Broach, Yilin Hu, Aaron W. Fay, Markus W. Ribbe and Brian J. Hales pp 4558–4559 DOI: 10.1021/ja807525m |
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Bistability of Magnetization without Spin-Transition in a High-Spin Cobalt(II) Complex due to Angular Momentum Quenching Gergely Juh pp 4560–4561 DOI: 10.1021/ja808448j Supporting Info |
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Chiral Brønsted Acid-Catalyzed Enantioselective α-Hydroxylation of β-Dicarbonyl Compounds Min Lu, Di Zhu, Yunpeng Lu, Xiaofei Zeng, Bin Tan, Zhenjiang Xu and Guofu Zhong pp 4562–4563 DOI: 10.1021/ja8088907 Supporting Info |
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Electrochemiluminescence of Water-Soluble Carbon Nanocrystals Released Electrochemically from Graphite Liyan Zheng, Yuwu Chi, Yongqing Dong, Jianpeng Lin and Binbin Wang pp 4564–4565 DOI: 10.1021/ja809073f Supporting Info |
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Alkyne-Linked 2,2-Disubstituted-indolin-3-one Oligomers as Extended β-Strand Mimetics Pauline N. Wyrembak and Andrew D. Hamilton pp 4566–4567 DOI: 10.1021/ja809245t Supporting Info |
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Quasi-Planar Homopolymetallic and Heteropolymetallic Coordination Arrays. Surface-Like Molecular Clusters of Magnesium and Aluminum Megumi Fujita, Owen C. Lightbody, Michael J. Ferguson, Robert McDonald and Jeffrey M. Stryker pp 4568–4569 DOI: 10.1021/ja8093229 Supporting Info |
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A Crystalline Imine-Linked 3-D Porous Covalent Organic Framework Fernando J. Uribe-Romo, Joseph R. Hunt, Hiroyasu Furukawa, Cornelius Kl pp 4570–4571 DOI: 10.1021/ja8096256 Supporting Info |
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Direct Asymmetric Michael Addition to Nitroalkenes: Vinylogous Nucleophilicity under Dinuclear Zinc Catalysis Barry M. Trost and Julien Hitce pp 4572–4573 DOI: 10.1021/ja809723u Supporting Info |
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Substituent Effects in Sandwich Configurations of Multiply Substituted Benzene Dimers Are Not Solely Governed By Electrostatic Control Ashley L. Ringer and C. David Sherrill pp 4574–4575 DOI: 10.1021/ja809720r Supporting Info |
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One-Pot Synthesis of Interpenetrating Inorganic/Organic Networks of CuO/Resorcinol-Formaldehyde Aerogels: Nanostructured Energetic Materials Nicholas Leventis, Naveen Chandrasekaran, Anand G. Sadekar, Chariklia Sotiriou-Leventis and Hongbing Lu pp 4576–4577 DOI: 10.1021/ja809746t Supporting Info |
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Zinc Incorporation via the Vapor−Liquid−Solid Mechanism into InP Nanowires Maarten H. M. van Weert, Ana Helman, Wim van den Einden, Rienk E. Algra, Marcel A. Verheijen, Magnus T. Borgstr pp 4578–4579 DOI: 10.1021/ja809871j |
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Time-Resolved Sum Frequency Generation Reveals Adsorbate Migration between Different Surface Active Sites on Titanium Oxide/Pt(111) Jun Chen, Jun Kubota, Akihide Wada, Junko Nomura Kondo and Kazunari Domen pp 4580–4581 DOI: 10.1021/ja900052w Supporting Info |
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Demonstration of a Peroxide Shunt in the Tetrahydropterin-Dependent Aromatic Amino Acid Monooxygenases Jorge Alex Pavon and Paul F. Fitzpatrick pp 4582–4583 DOI: 10.1021/ja900128m |
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On the Pd-Catalyzed Vinylation of Aryl Halides with Tris(alkoxy)vinylsilanes in Water pp 4584–4585 DOI: 10.1021/ja900333x Supporting Info |
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Constructing Robust Channel Structures by Packing Metallacalixarenes: Reversible Single-Crystal-to-Single-Crystal Dehydration Cristian D. Ene, Augustin M. Madalan, Catalin Maxim, Bogdan Jurca, Narcis Avarvari and Marius Andruh pp 4586–4587 DOI: 10.1021/ja900416e Supporting Info |
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Oleylamine-Mediated Synthesis of Pd Nanoparticles for Catalytic Formic Acid Oxidation Vismadeb Mazumder and Shouheng Sun pp 4588–4589 DOI: 10.1021/ja9004915 Supporting Info |
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Characterization of the Antiferromagnetism in Ag(pyz)2(S2O8) (pyz = Pyrazine) with a Two-Dimensional Square Lattice of Ag2+ Ions Jamie L. Manson, Kevin H. Stone, Heather I. Southerland, Tom Lancaster, Andrew J. Steele, Stephen J. Blundell, Francis L. Pratt, Peter J. Baker, Ross D. McDonald, Pinaki Sengupta, John Singleton, Paul A. Goddard, Changhoon Lee, Myung-Hwan Whangbo, Michelle M. Warter, Charles H. Mielke and Peter W. Stephens pp 4590–4591 DOI: 10.1021/ja9005223 Supporting Info |
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Alternate Arrangements of Two Different Metals at Chemically-Equivalent Binding Sites on a Circle Shuichi Hiraoka, Mitsuyoshi Goda and Mitsuhiko Shionoya pp 4592–4593 DOI: 10.1021/ja9006113 Supporting Info |
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Wet Chemistry Route to Hydrophobic Blue Fluorescent Nanodiamond Vadym N. Mochalin and Yury Gogotsi pp 4594–4595 DOI: 10.1021/ja9004514 Supporting Info |
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Facile Ionothermal Synthesis of Microporous and Mesoporous Carbons from Task Specific Ionic Liquids Je Seung Lee, Xiqing Wang, Huimin Luo, Gary A. Baker and Sheng Dai pp 4596–4597 DOI: 10.1021/ja900686d Supporting Info |
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Chiral Brønsted Acid-Catalyzed Enantioselective Three-Component Povarov Reaction Hua Liu, Guillaume Dagousset, G pp 4598–4599 DOI: 10.1021/ja900806q Supporting Info |
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Oxidative Addition of Ammonia at a Silicon(II) Center and an Unprecedented Hydrogenation Reaction of Compounds with Low-Valent Group 14 Elements Using Ammonia Borane Anukul Jana, Carola Schulzke and Herbert W. Roesky pp 4600–4601 DOI: 10.1021/ja900880z Supporting Info |
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One-Pot, High-Yield Synthesis of 5-Fold Twinned Pd Nanowires and Nanorods Xiaoqing Huang and Nanfeng Zheng pp 4602–4603 DOI: 10.1021/ja9009343 Supporting Info |
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Activation of an Alkyl C−H Bond Geminal to an Agostic Interaction: An Unusual Mode of Base-Induced C−H Activation L. Jonas L. H pp 4604–4605 DOI: 10.1021/ja900953d Supporting Info |
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A Hydrogen-Substituted Osmium Stannylene Complex: Isomerization to a Metallostannylene Complex via an Unusual α-Hydrogen Migration from Tin to Osmium Paul G. Hayes, Christopher W. Gribble, Rory Waterman and T. Don Tilley pp 4606–4607 DOI: 10.1021/ja901050m Supporting Info |
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Capturing In+ Monomers in a Neutral Weakly Coordinating Environment Titel Jurca, Justin Lummiss, Tara J. Burchell, Serge I. Gorelsky and Darrin S. Richeson pp 4608–4609 DOI: 10.1021/ja901128q Supporting Info |
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Highly Porous and Robust 4,8-Connected Metal−Organic Frameworks for Hydrogen Storage Liqing Ma, David J. Mihalcik and Wenbin Lin pp 4610–4612 DOI: 10.1021/ja809590n Supporting Info |
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Hairpin Structure of a Biarsenical−Tetracysteine Motif Determined by NMR Spectroscopy Fatemeh Madani, Jesper Lind, Peter Damberg, Stephen R. Adams, Roger Y. Tsien and Astrid O. Gr pp 4613–4615 DOI: 10.1021/ja809315x Supporting Info |
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Zeptomol Detection Through Controlled Ultrasensitive Surface-Enhanced Raman Scattering Laura Rodr pp 4616–4618 DOI: 10.1021/ja809418t Supporting Info |
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Optically Modulated Fluorophores for Selective Fluorescence Signal Recovery Chris I. Richards, Jung-Cheng Hsiang, Dulal Senapati, Sandeep Patel, Junhua Yu, Tom Vosch and Robert M. Dickson pp 4619–4621 DOI: 10.1021/ja809785s Supporting Info |
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All-Atom Model for Stabilization of α-Helical Structure in Peptides by Hydrocarbon Staples Peter S. Kutchukian, Jae Shick Yang, Gregory L. Verdine and Eugene I. Shakhnovich pp 4622–4627 DOI: 10.1021/ja805037p Supporting Info |
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Reductive Half-Reaction of Aldehyde Oxidoreductase toward Acetaldehyde: A Combined QM/MM Study Sebastian Metz, Dongqi Wang and Walter Thiel pp 4628–4640 DOI: 10.1021/ja805938w Supporting Info |
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Overhauser Dynamic Nuclear Polarization To Study Local Water Dynamics Brandon D. Armstrong and Songi Han pp 4641–4647 DOI: 10.1021/ja809259q |
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Spectroscopy by Integration of Frequency and Time Domain Information for Fast Acquisition of High-Resolution Dark Spectra Yoh Matsuki, Matthew T. Eddy and Judith Herzfeld pp 4648–4656 DOI: 10.1021/ja807893k |
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Galactose Oxidase as a Model for Reactivity at a Copper Superoxide Center Kristi J. Humphreys, Liviu M. Mirica, Yi Wang and Judith P. Klinman pp 4657–4663 DOI: 10.1021/ja807963e |
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Collective Dynamics of Protein Hydration Water by Brillouin Neutron Spectroscopy Andrea Orecchini, Alessandro Paciaroni, Alessio De Francesco, Caterina Petrillo and Francesco Sacchetti pp 4664–4669 DOI: 10.1021/ja807957p Supporting Info |
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A New Ferrimagnet Based on a Radical-Substituted Radical Cation Salt Yuki Masuda, Masato Kuratsu, Shuichi Suzuki, Masatoshi Kozaki, Daisuke Shiomi, Kazunobu Sato, Takeji Takui, Yuko Hosokoshi, Xiao-Zheng Lan, Yuji Miyazaki, Akira Inaba and Keiji Okada pp 4670–4673 DOI: 10.1021/ja808093z Supporting Info |
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Characterization of Salt Bridges to Lysines in the Protein G B1 Domain Jennifer H. Tomlinson, Saif Ullah, Poul Erik Hansen and Mike P. Williamson pp 4674–4684 DOI: 10.1021/ja808223p Supporting Info |
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Transition States of Plasmodium falciparum and Human Orotate Phosphoribosyltransferases Yong Zhang, Minkui Luo and Vern L. Schramm pp 4685–4694 DOI: 10.1021/ja808346y Supporting Info |
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Hydration of Protonated Aromatic Amino Acids: Phenylalanine, Tryptophan, and Tyrosine Bing Gao, Thomas Wyttenbach and Michael T. Bowers pp 4695–4701 DOI: 10.1021/ja8085017 Supporting Info |
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Characterizing Loop Dynamics and Ligand Recognition in Human- and Avian-Type Influenza Neuraminidases via Generalized Born Molecular Dynamics and End-Point Free Energy Calculations Rommie E. Amaro, Xiaolin Cheng, Ivaylo Ivanov, Dong Xu and J. Andrew McCammon pp 4702–4709 DOI: 10.1021/ja8085643 Supporting Info |
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Double Helix Formation of Oligoresorcinols in Water: Thermodynamic and Kinetic Aspects Hidetoshi Goto, Yoshio Furusho, Kazuhiro Miwa and Eiji Yashima pp 4710–4719 DOI: 10.1021/ja808585y Supporting Info |
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Self-Assembly of Janus Cylinders into Hierarchical Superstructures Andreas Walther, Markus Drechsler, Sabine Rosenfeldt, Ludger Harnau, Matthias Ballauff, Volker Abetz and Axel H. E. M pp 4720–4728 DOI: 10.1021/ja808614q Supporting Info |
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Slow Hydrogen Atom Transfer Reactions of Oxo- and Hydroxo-Vanadium Compounds: The Importance of Intrinsic Barriers Christopher R. Waidmann, Xin Zhou, Erin A. Tsai, Werner Kaminsky, David A. Hrovat, Weston Thatcher Borden and James M. Mayer pp 4729–4743 DOI: 10.1021/ja808698x Supporting Info |
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Ring-Opening Polymerization-Mediated Controlled Formulation of Polylactide−Drug Nanoparticles Rong Tong and Jianjun Cheng pp 4744–4754 DOI: 10.1021/ja8084675 Supporting Info |
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How is the Reactivity of Cytochrome P450cam Affected by Thr252X Mutation? A QM/MM Study for X = Serine, Valine, Alanine, Glycine Muhannad Altarsha, Tobias Benighaus, Devesh Kumar and Walter Thiel pp 4755–4763 DOI: 10.1021/ja808744k Supporting Info |
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In Situ Spectroscopic, Electrochemical, and Theoretical Studies of the Photoinduced Host−Guest Electron Transfer that Precedes Unusual Host-Mediated Alkane Photooxidation Yuji Furutani, Hideki Kandori, Masaki Kawano, Koji Nakabayashi, Michito Yoshizawa and Makoto Fujita pp 4764–4768 DOI: 10.1021/ja8089075 Supporting Info |
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Quantitative Three-Dimensional Modeling of Zeotile Through Discrete Electron Tomography Sara Bals, K. Joost Batenburg, Duoduo Liang, Oleg Lebedev, Gustaaf Van Tendeloo, Alexander Aerts, Johan A. Martens and Christine E. A. Kirschhock pp 4769–4773 DOI: 10.1021/ja8089125 |
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Wrenchnolol Derivative Optimized for Gene Activation in Cells Dongju Jung, Hiroki Shimogawa, Youngjoo Kwon, Qian Mao, Shin-ichi Sato, Shinji Kamisuki, Hideo Kigoshi and Motonari Uesugi pp 4774–4782 DOI: 10.1021/ja900669k Supporting Info |
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PEG Branched Polymer for Functionalization of Nanomaterials with Ultralong Blood Circulation Giuseppe Prencipe, Scott M. Tabakman, Kevin Welsher, Zhuang Liu, Andrew P. Goodwin, Li Zhang, Joy Henry and Hongjie Dai pp 4783–4787 DOI: 10.1021/ja809086q Supporting Info |
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Direct Detection of Molecular Biorecognition by Dipole Sensing Mechanism Ilya Goykhman, Nina Korbakov, Carmen Bartic, Gustaaf Borghs, Micha E. Spira, Joseph Shappir and Shlomo Yitzchaik pp 4788–4794 DOI: 10.1021/ja809051p Supporting Info |
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Charge Redistribution in Oxidized and Semiquinone E. coli DNA Photolyase upon Photoexcitation: Stark Spectroscopy Reveals a Rationale for the Position of Trp382 Goutham Kodali, Salim U. Siddiqui and Robert J. Stanley pp 4795–4807 DOI: 10.1021/ja809214r Supporting Info |
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Parameters Influencing the Efficiency of Electron Injection in Dye-Sensitized Solar Cells Sara E. Koops, Brian C. O’Regan, Piers R. F. Barnes and James R. Durrant pp 4808–4818 DOI: 10.1021/ja8091278 |
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Helical Aromatic Oligoamide Foldamers as Organizational Scaffolds for Photoinduced Charge Transfer Martin Wolffs, Nicolas Delsuc, Dirk Veldman, Nguy pp 4819–4829 DOI: 10.1021/ja809367u Supporting Info |
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Multi-Stimuli Sensitive Amphiphilic Block Copolymer Assemblies Akamol Klaikherd, Chikkannagari Nagamani and S. Thayumanavan pp 4830–4838 DOI: 10.1021/ja809475a Supporting Info |
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The Nature of Radiative Transitions in O-Doped Boron Nitride Nanotubes Gaoyang Gou, Bicai Pan and Lei Shi pp 4839–4845 DOI: 10.1021/ja809550u Supporting Info |
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Activation Parameters for Heme−NO Binding in Alcaligenes xylosoxidans Cytochrome c′: The Putative Dinitrosyl Intermediate Forms via a Dissociative Mechanism David A. Pixton, Christine A. Petersen, Alicja Franke, Rudi van Eldik, Elizabeth M. Garton and Colin R. Andrew pp 4846–4853 DOI: 10.1021/ja809587q |
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Perturbations of Membrane Structure by Cholesterol and Cholesterol Derivatives Are Determined by Sterol Orientation Brett N. Olsen, Paul H. Schlesinger and Nathan A. Baker pp 4854–4865 DOI: 10.1021/ja8095224 Supporting Info |
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Impact of Metallophilicity on “Colossal” Positive and Negative Thermal Expansion in a Series of Isostructural Dicyanometallate Coordination Polymers Jasmine L. Kor pp 4866–4871 DOI: 10.1021/ja809631r Supporting Info |
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Structural Analysis of an Open Active Site Conformation of Nonheme Iron Halogenase CytC3 Cintyu Wong, Danica Galoni pp 4872–4879 DOI: 10.1021/ja8097355 |
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Oxygen Ordering and Mobility in YBaCo4O7+δ Yan Jia, Hua Jiang, Markus Valkeap pp 4880–4883 DOI: 10.1021/ja809745k Supporting Info |
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Zwitterionic Polymerization: A Kinetic Strategy for the Controlled Synthesis of Cyclic Polylactide Wonhee Jeong, Eun Ji Shin, Darcy A. Culkin, James L. Hedrick and Robert M. Waymouth pp 4884–4891 DOI: 10.1021/ja809617v Supporting Info |
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Electron Transfer Across Multiple Hydrogen Bonds: The Case of Ureapyrimidinedione-Substituted Vinyl Ruthenium and Osmium Complexes Markus Pichlmaier, Rainer F. Winter, Manfred Zabel and Stanislav Z pp 4892–4903 DOI: 10.1021/ja809566g Supporting Info |
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Total Synthesis of Vinblastine, Vincristine, Related Natural Products, and Key Structural Analogues Hayato Ishikawa, David A. Colby, Shigeki Seto, Porino Va, Annie Tam, Hiroyuki Kakei, Thomas J. Rayl, Inkyu Hwang and Dale L. Boger pp 4904–4916 DOI: 10.1021/ja809842b Supporting Info |
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Mesityl Alkyne Substituents for Control of Regiochemistry and Reversibility in Zirconocene Couplings: New Synthetic Strategies for Unsymmetrical Zirconacyclopentadienes and Conjugated Polymers Adam D. Miller, John F. Tannaci, Samuel A. Johnson, Hyuk Lee, Jennifer L. McBee and T. Don Tilley pp 4917–4927 DOI: 10.1021/ja809896t Supporting Info |
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Using a Hydrazone-Protected Benzenediazonium Salt to Introduce a Near-Monolayer of Benzaldehyde on Glassy Carbon Surfaces Kristoffer Malmos, Mingdong Dong, Saju Pillai, Peter Kingshott, Flemming Besenbacher, Steen U. Pedersen and Kim Daasbjerg pp 4928–4936 DOI: 10.1021/ja809816x Supporting Info |
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Interlocked Host Anion Recognition by an Indolocarbazole-Containing [2]Rotaxane Asha Brown, Kathleen M. Mullen, Jay Ryu, Michał J. Chmielewski, S pp 4937–4952 DOI: 10.1021/ja809905x Supporting Info |
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Morpholino Monolayers: Preparation and Label-free DNA Analysis by Surface Hybridization Napoleon Tercero, Kang Wang, Ping Gong and Rastislav Levicky pp 4953–4961 DOI: 10.1021/ja810051q Supporting Info |
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Phase Transformation of Biphasic Cu2S−CuInS2 to Monophasic CuInS2 Nanorods Stephen T. Connor, Ching-Mei Hsu, Benjamin D. Weil, Shaul Aloni and Yi Cui pp 4962–4966 DOI: 10.1021/ja809901u Supporting Info |
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Robust Fluorescent Detection of Protein Fatty-Acylation with Chemical Reporters Guillaume Charron, Mingzi M. Zhang, Jacob S. Yount, John Wilson, Anuradha S. Raghavan, Eliah Shamir and Howard C. Hang pp 4967–4975 DOI: 10.1021/ja810122f Supporting Info |
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Controllable Epitaxial Crystallization and Reversible Oriented Patterning of Two-Dimensional Colloidal Crystals Rongguo Xie and Xiang-Yang Liu pp 4976–4982 DOI: 10.1021/ja900049r Supporting Info |
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Spectroscopic Identification of Tri-n-octylphosphine Oxide (TOPO) Impurities and Elucidation of Their Roles in Cadmium Selenide Quantum-Wire Growth Fudong Wang, Rui Tang, Jeff L.-F. Kao, Sean D. Dingman and William E. Buhro pp 4983–4994 DOI: 10.1021/ja900191n Supporting Info |
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High-Capacity Methane Storage in Metal−Organic Frameworks M2(dhtp): The Important Role of Open Metal Sites Hui Wu, Wei Zhou and Taner Yildirim pp 4995–5000 DOI: 10.1021/ja900258t Supporting Info |
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Hydrogen- and Oxygen-Driven Interconversion between Imido-Bridged Dirhodium(III) and Amido-Bridged Dirhodium(II) Complexes Koji Ishiwata, Shigeki Kuwata and Takao Ikariya pp 5001–5009 DOI: 10.1021/ja900650j Supporting Info |
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Reduction-Controlled Viologen in Bisolvent as an Environmentally Stable n-Type Dopant for Carbon Nanotubes Soo Min Kim, Jin Ho Jang, Ki Kang Kim, Hyeon Ki Park, Jung Jun Bae, Woo Jong Yu, Il Ha Lee, Gunn Kim, Duong Dinh Loc, Un Jeong Kim, Eun-Hong Lee, Hyeon-Jin Shin, Jae-Young Choi and Young Hee Lee p 5010 DOI: 10.1021/ja900682b |
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Synthesis and Magnetic and Charge-Transport Properties of the Correlated 4d Post-Perovskite CaRhO3 Kazunari Yamaura, Yuichi Shirako, Hiroshi Kojitani, Masao Arai, David P. Young, Masaki Akaogi, Mamoru Nakashima, Tetsuhiro Katsumata, Yoshiyuki Inaguma and Eiji Takayama-Muromachi p 5010 DOI: 10.1021/ja901621f |
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Linking Structural Dynamics and Functional Diversity in Asymmetric Catalysis Akihiro Nojiri, Naoya Kumagai and Masakatsu Shibasaki p 5010 DOI: 10.1021/ja901533b |
Issue 14
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Self-Propelled Oil Droplets Consuming “Fuel” Surfactant Taro Toyota, Naoto Maru, Martin M. Hanczyc, Takashi Ikegami and Tadashi Sugawara pp 5012–5013 DOI: 10.1021/ja806689p Supporting Info |
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A Microfluidic High-Resolution NMR Flow Probe Jacob Bart, Ard J. Kolkman, Anna Jo Oosthoek-de Vries, Kaspar Koch, Pieter J. Nieuwland, Hans (J. W. G.) Janssen, Jan (P. J. M.) van Bentum, Kirsten A. M. Ampt, Floris P. J. T. Rutjes, Sybren S. Wijmenga, Han (J. G. E.) Gardeniers and Arno P. M. Kentgens pp 5014–5015 DOI: 10.1021/ja900389x Supporting Info |
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Covalent Protein Labeling Based on Noncatalytic β-Lactamase and a Designed FRET Substrate Shin Mizukami, Shuji Watanabe, Yuichiro Hori and Kazuya Kikuchi pp 5016–5017 DOI: 10.1021/ja8082285 Supporting Info |
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On the Mechanism of Trolox as Antiblinking and Antibleaching Reagent Thorben Cordes, Jan Vogelsang and Philip Tinnefeld pp 5018–5019 DOI: 10.1021/ja809117z Supporting Info |
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Multivalent Protein Binding and Precipitation by Self-Assembling Molecules on a DNA Pentaplex Scaffold Brooke A. Rosenzweig, Nathan T. Ross, Debarati M. Tagore, Janarthanan Jayawickramarajah, Ishu Saraogi and Andrew D. Hamilton pp 5020–5021 DOI: 10.1021/ja809219p Supporting Info |
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Shuttling Germanium Atoms into Branched Polysilanes Harald Wagner, Judith Baumgartner, Thomas M pp 5022–5023 DOI: 10.1021/ja809270m Supporting Info |
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Cross Coupling Reactions of Chiral Secondary Organoboronic Esters With Retention of Configuration Daisuke Imao, Ben W. Glasspoole, V pp 5024–5025 DOI: 10.1021/ja8094075 Supporting Info |
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Highly Stable Performance of Supercapacitors from Phosphorus-Enriched Carbons Denisa Hulicova-Jurcakova, Alexander M. Puziy, Olga I. Poddubnaya, Fabian Su pp 5026–5027 DOI: 10.1021/ja809265m Supporting Info |
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Supramolecular Cocaine−Aptamer Complexes Activate Biocatalytic Cascades Ronit Freeman, Etery Sharon, Ran Tel-Vered and Itamar Willner pp 5028–5029 DOI: 10.1021/ja809496n Supporting Info |
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Identification of an Overabundant Cholesterol Precursor in Hepatitis B Virus Replicating Cells by Untargeted Lipid Metabolite Profiling Mary A. Rodgers, Alan Saghatelian and Priscilla L. Yang pp 5030–5031 DOI: 10.1021/ja809949r Supporting Info |
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Facile Cycling of Ti-Doped LiAlH4 for High Performance Hydrogen Storage Xiangfeng Liu, G. Sean McGrady, Henrietta W. Langmi and Craig M. Jensen pp 5032–5033 DOI: 10.1021/ja809917g Supporting Info |
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Catalytic Reduction of O2 by Cytochrome c Using a Synthetic Model of Cytochrome c Oxidase James P. Collman, Somdatta Ghosh, Abhishek Dey, Richard A. Decr pp 5034–5035 DOI: 10.1021/ja9001579 Supporting Info |
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Light-Induced Transfer of Molecular Chirality in Solution: Enantiospecific Photocyclization of Molecularly Chiral Acrylanilides Anoklase Jean-Luc Ayitou and J. Sivaguru pp 5036–5037 DOI: 10.1021/ja9003552 Supporting Info |
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Thymine Dimerization in DNA Model Systems: Cyclobutane Photolesion Is Predominantly Formed via the Singlet Channel Wolfgang J. Schreier, Julia Kubon, Nadja Regner, Karin Haiser, Tobias E. Schrader, Wolfgang Zinth, Pascale Clivio and Peter Gilch pp 5038–5039 DOI: 10.1021/ja900436t Supporting Info |
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Translation Initiation with Initiator tRNA Charged with Exotic Peptides Yuki Goto and Hiroaki Suga pp 5040–5041 DOI: 10.1021/ja900597d Supporting Info |
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Palladium Catalyzed Tandem Ring Opening−Ring Closing Reaction of Diazabicyclic Alkenes: A Facile One Pot Strategy for Cyclopentannulation of Heterocycles Jubi John, Indu U., Eringathodi Suresh and K. V. Radhakrishnan pp 5042–5043 DOI: 10.1021/ja900477e Supporting Info |
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Mechanistic Study of Copper-Catalyzed Aerobic Oxidative Coupling of Arylboronic Esters and Methanol: Insights into an Organometallic Oxidase Reaction Amanda E. King, Thomas C. Brunold and Shannon S. Stahl pp 5044–5045 DOI: 10.1021/ja9006657 Supporting Info |
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Transcription of an Expanded Genetic Alphabet Young Jun Seo, Shigeo Matsuda and Floyd E. Romesberg pp 5046–5047 DOI: 10.1021/ja9006996 Supporting Info |
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Facile Preparation of Highly-Scattering Metal Nanoparticle-Coated Polymer Microbeads and Their Surface Plasmon Resonance Jung-Hyun Lee, Mahmoud A. Mahmoud, Valerie Sitterle, Jeffrey Sitterle and J. Carson Meredith pp 5048–5049 DOI: 10.1021/ja900698w Supporting Info |
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Complete EPR Spectrum of the S3-State of the Oxygen-Evolving Photosystem II Alain Boussac, Miwa Sugiura, A. William Rutherford and Pierre Dorlet pp 5050–5051 DOI: 10.1021/ja900680t Supporting Info |
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NMR Chemical Exchange as a Probe for Ligand-Binding Kinetics in a Theophylline-Binding RNA Aptamer Michael P. Latham, Grant R. Zimmermann and Arthur Pardi pp 5052–5053 DOI: 10.1021/ja900695m Supporting Info |
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anti-Aminoallylation of Aldehydes via Ruthenium-Catalyzed Transfer Hydrogenative Coupling of Sulfonamido Allenes: 1,2-Aminoalcohols Eduardas Skucas, Jason R. Zbieg and Michael J. Krische pp 5054–5055 DOI: 10.1021/ja900827p Supporting Info |
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Three Siderophores from One Bacterial Enzymatic Assembly Line William M. Wuest, Elizabeth S. Sattely and Christopher T. Walsh pp 5056–5057 DOI: 10.1021/ja900815w Supporting Info |
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Directed Ortho Borylation of Functionalized Arenes Catalyzed by a Silica-Supported Compact Phosphine−Iridium System Soichiro Kawamorita, Hirohisa Ohmiya, Kenji Hara, Atsushi Fukuoka and Masaya Sawamura pp 5058–5059 DOI: 10.1021/ja9008419 Supporting Info |
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Nickel-Catalyzed, Regio- and Stereoselective Hydroalkynylation of Methylenecyclopropanes with Retention of the Cyclopropane Ring, Leading to the Synthesis of 1-Methyl-1-Alkynylcyclopropanes Masamichi Shirakura and Michinori Suginome pp 5060–5061 DOI: 10.1021/ja900876w Supporting Info |
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Gold-Catalyzed Homogeneous Oxidative C−O Bond Formation: Efficient Synthesis of 1-Benzoxyvinyl Ketones Yu Peng, Li Cui, Guozhu Zhang and Liming Zhang pp 5062–5063 DOI: 10.1021/ja901048w Supporting Info |
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Hydrogen Elimination in Bulky Calcium Amidoborane Complexes: Isolation of a Calcium Borylamide Complex Jan Spielmann and Sjoerd Harder pp 5064–5065 DOI: 10.1021/ja901073c Supporting Info |
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Coordination of Arsine Ligands as a General Synthetic Approach to Rare Examples of Arsenic−Antimony and Arsenic−Bismuth Bonds Eamonn Conrad, Neil Burford, Robert McDonald and Michael J. Ferguson pp 5066–5067 DOI: 10.1021/ja900968j Supporting Info |
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Loosening and Reorganization of Fluid Phospholipid Bilayers by Chloroform Serhan Turkyilmaz, Wen-Hua Chen, Hideyuki Mitomo and Steven L. Regen pp 5068–5069 DOI: 10.1021/ja9011468 Supporting Info |
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Hydrocarbamoylation of Unsaturated Bonds by Nickel/Lewis-Acid Catalysis Yoshiaki Nakao, Hiroaki Idei, Kyalo Stephen Kanyiva and Tamejiro Hiyama pp 5070–5071 DOI: 10.1021/ja901153s Supporting Info |
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Pd(II)-Catalyzed Olefination of Electron-Deficient Arenes Using 2,6-Dialkylpyridine Ligands Yang-Hui Zhang, Bing-Feng Shi and Jin-Quan Yu pp 5072–5074 DOI: 10.1021/ja900327e Supporting Info |
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Using Biological Performance Similarity To Inform Disaccharide Library Design Tetsuya Tanikawa, Micha Fridman, Wenjiang Zhu, Brian Faulk, Isaac C. Joseph, Daniel Kahne, Bridget K. Wagner and Paul A. Clemons pp 5075–5083 DOI: 10.1021/ja806583y Supporting Info |
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Modulated Conjugation as a Means of Improving the Intrinsic Hyperpolarizability Javier P pp 5084–5093 DOI: 10.1021/ja807394f Supporting Info |
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Process of Accumulation of Metal Ions on the Interior Surface of apo-Ferritin: Crystal Structures of a Series of apo-Ferritins Containing Variable Quantities of Pd(II) Ions Takafumi Ueno, Mizue Abe, Kunio Hirata, Satoshi Abe, Masako Suzuki, Nobutaka Shimizu, Masaki Yamamoto, Masaki Takata and Yoshihito Watanabe pp 5094–5100 DOI: 10.1021/ja806688s Supporting Info |
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A Mixed-Valence VIV/VV Alkoxo-polyoxovanadium Cluster Series [V6O8(OCH3)11]n+/−: Exploring the Influence of a μ-Oxo Ligand in a Spin Frustrated Structure Charles Daniel and Hans Hartl pp 5101–5114 DOI: 10.1021/ja8073648 Supporting Info |
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DFT and ONIOM(DFT:MM) Studies on Co−C Bond Cleavage and Hydrogen Transfer in B12-Dependent Methylmalonyl-CoA Mutase. Stepwise or Concerted Mechanism? Xin Li, Lung Wa Chung, Piotr Paneth and Keiji Morokuma pp 5115–5125 DOI: 10.1021/ja807677z Supporting Info |
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Substrate Induced Population Shifts and Stochastic Gating in the PBCV-1 mRNA Capping Enzyme Robert V. Swift and J. Andrew McCammon pp 5126–5133 DOI: 10.1021/ja808064g |
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Accurate Solution Structures of Proteins from X-ray Data and a Minimal Set of NMR Data: Calmodulin−Peptide Complexes As Examples Ivano Bertini, Petri Kursula, Claudio Luchinat, Giacomo Parigi, Juha Vahokoski, Matthias Wilmanns and Jing Yuan pp 5134–5144 DOI: 10.1021/ja8080764 Supporting Info |
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A Solid-State NMR Study of Lead and Vanadium Substitution into Hydroxyapatite H pp 5145–5152 DOI: 10.1021/ja808270v Supporting Info |
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Lipophilic Bisphosphonates as Dual Farnesyl/Geranylgeranyl Diphosphate Synthase Inhibitors: An X-ray and NMR Investigation Yonghui Zhang, Rong Cao, Fenglin Yin, Michael P. Hudock, Rey-Ting Guo, Kilannin Krysiak, Sujoy Mukherjee, Yi-Gui Gao, Howard Robinson, Yongcheng Song, Joo Hwan No, Kyle Bergan, Annette Leon, Lauren Cass, Amanda Goddard, Ting-Kai Chang, Fu-Yang Lin, Ermond Van Beek, Socrates Papapoulos, Andrew H.-J. Wang, Tadahiko Kubo, Mitsuo Ochi, Dushyant Mukkamala and Eric Oldfield pp 5153–5162 DOI: 10.1021/ja808285e Supporting Info |
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Enhancement of a Catalysis-Based Fluorometric Detection Method for Palladium through Rational Fine-Tuning of the Palladium Species Amanda L. Garner, Fengling Song and Kazunori Koide pp 5163–5171 DOI: 10.1021/ja808385a |
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Electrostatic Control of the Photoisomerization Efficiency and Optical Properties in Visual Pigments: On the Role of Counterion Quenching Gaia Tomasello, Gloria Olaso-Gonz pp 5172–5186 DOI: 10.1021/ja808424b Supporting Info |
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Total Synthesis of N-Acetylglucosamine-1,6-anhydro-N-acetylmuramylpentapeptide and Evaluation of Its Turnover by AmpD from Escherichia coli Dusan Hesek, Mijoon Lee, Weilie Zhang, Bruce C. Noll and Shahriar Mobashery pp 5187–5193 DOI: 10.1021/ja808498m Supporting Info |
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Tuning Transport Properties of Nanofluidic Devices with Local Charge Inversion Yan He, Dirk Gillespie, Dezs pp 5194–5202 DOI: 10.1021/ja808717u Supporting Info |
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One-Electron Reduction Potential of the Neutral Guanyl Radical in the GC Base Pair of Duplex DNA Sujata S. Shinde, Andrej Maroz, Michael P. Hay and Robert F. Anderson pp 5203–5207 DOI: 10.1021/ja8087339 Supporting Info |
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A Sulfur-Terminal Zn(II) Complex and Its Two-Photon Microscopy Biological Imaging Application Yuanhao Gao, Jieying Wu, Yiming Li, Pingping Sun, Hongping Zhou, Jiaxiang Yang, Shengyi Zhang, Baokang Jin and Yupeng Tian pp 5208–5213 DOI: 10.1021/ja808606d Supporting Info |
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Atomistic Details of the Disordered States of KID and pKID. Implications in Coupled Binding and Folding Debabani Ganguly and Jianhan Chen pp 5214–5223 DOI: 10.1021/ja808999m Supporting Info |
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Free Energy Landscapes for S−H Bonds in Cp*2Mo2S4 Complexes Aaron M. Appel, Suh-Jane Lee, James A. Franz, Daniel L. DuBois and M. Rakowski DuBois pp 5224–5232 DOI: 10.1021/ja8093179 Supporting Info |
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Ring Strain Energy in the Cyclooctyl System. The Effect of Strain Energy on [3 + 2] Cycloaddition Reactions with Azides Robert D. Bach pp 5233–5243 DOI: 10.1021/ja8094137 Supporting Info |
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Kinetics of Silica Nucleation on Carboxyl- and Amine-Terminated Surfaces: Insights for Biomineralization Adam F. Wallace, James J. DeYoreo and Patricia M. Dove pp 5244–5250 DOI: 10.1021/ja809486b Supporting Info |
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Columnar Packing Motifs of Functionalized Perylene Derivatives: Local Molecular Order Despite Long-Range Disorder Michael Ryan Hansen, Robert Graf, Sivakumar Sekharan and Daniel Sebastiani pp 5251–5256 DOI: 10.1021/ja8095703 Supporting Info |
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Rapid and Simple Ribozymic Aminoacylation Using Three Conserved Nucleotides N. V. Chumachenko, Y. Novikov and M. Yarus pp 5257–5263 DOI: 10.1021/ja809419f Supporting Info |
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Correlating Carrier Type with Frontier Molecular Orbital Energy Levels in Organic Thin Film Transistors of Functionalized Acene Derivatives Ming L. Tang, Anna D. Reichardt, Peng Wei and Zhenan Bao pp 5264–5273 DOI: 10.1021/ja809659b Supporting Info |
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Determinants of Catalytic Power and Ligand Binding in Glutamate Racemase M. Ashley Spies, Joseph G. Reese, Dylan Dodd, Katherine L. Pankow, Steven R. Blanke and Jerome Baudry pp 5274–5284 DOI: 10.1021/ja809660g Supporting Info |
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Selective Facet Reactivity during Cation Exchange in Cadmium Sulfide Nanorods Bryce Sadtler, Denis O. Demchenko, Haimei Zheng, Steven M. Hughes, Maxwell G. Merkle, Ulrich Dahmen, Lin-Wang Wang and A. Paul Alivisatos pp 5285–5293 DOI: 10.1021/ja809854q Supporting Info |
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Shear-Driven Motion of Supported Lipid Bilayers in Microfluidic Channels Peter J pp 5294–5297 DOI: 10.1021/ja809987b Supporting Info |
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Versatile Coordination of Cyclopentadienyl-Arene Ligands and Its Role in Titanium-Catalyzed Ethylene Trimerization Edwin Otten, Aurora A. Batinas, Auke Meetsma and Bart Hessen pp 5298–5312 DOI: 10.1021/ja810089f Supporting Info |
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Effects of NHC-Backbone Substitution on Efficiency in Ruthenium-Based Olefin Metathesis Kevin M. Kuhn, Jean-Baptiste Bourg, Cheol K. Chung, Scott C. Virgil and Robert H. Grubbs pp 5313–5320 DOI: 10.1021/ja900067c Supporting Info |
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MCM−Enzyme−Supramolecular Hydrogel Hybrid as a Fluorescence Sensing Material for Polyanions of Biological Significance Atsuhiko Wada, Shun-ichi Tamaru, Masato Ikeda and Itaru Hamachi pp 5321–5330 DOI: 10.1021/ja900500j Supporting Info |
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Controlling Axial Conformation in 2-Arylpyridines and 1-Arylisoquinolines: Application to the Asymmetric Synthesis of QUINAP by Dynamic Thermodynamic Resolution Jonathan Clayden, Stephen P. Fletcher, Joseph J. W. McDouall and Stephen J. M. Rowbottom pp 5331–5343 DOI: 10.1021/ja900722q Supporting Info |
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NMR Resonance Assignments of Sparsely Labeled Proteins: Amide Proton Exchange Correlations in Native and Denatured States Wendy K. Nkari and James H. Prestegard pp 5344–5349 DOI: 10.1021/ja8100775 |
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Formation of Monodisperse FePt Alloy Nanocrystals Using Air-Stable Precursors: Fatty Acids as Alloying Mediator and Reductant for Fe3+ Precursors Fei Zhao, Michael Rutherford, Susan Y. Grisham and Xiaogang Peng pp 5350–5358 DOI: 10.1021/ja900202t Supporting Info |
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Li+-Catalyzed Radical Polymerization of Simple Terminal Alkenes Kamesh Vyakaranam, Josiah B. Barbour and Josef Michl p 5359 DOI: 10.1021/ja9016045 |
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STR3DI32.EXE v3.000.3.A George Kaminski p 5360 DOI: 10.1021/ja9010892 |
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Advances in Polymer Chemistry and Methods Reported in Recent US Patents p 5361 DOI: 10.1021/ja901682f |
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Photosynthetic Protein Complexes: A Structural Approach Terry M. Bricker p 5361 DOI: 10.1021/ja901979e |
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Tin Chemistry: Fundamentals, Frontiers, and Applications Kieran C. Molloy pp 5361–5362 DOI: 10.1021/ja901973r |
Issue 15
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Selective Band Structure Modulation of Single-Walled Carbon Nanotubes in Ionic Liquids Jinyong Wang and Yan Li pp 5364–5365 DOI: 10.1021/ja807202m Supporting Info |
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Shape Discrimination with Hexapole−Dipole Interactions in Magic Angle Spinning Colloidal Magnetic Resonance Pietro Tierno, Steffen Schreiber, Walter Zimmermann and Thomas M. Fischer pp 5366–5367 DOI: 10.1021/ja808888g Supporting Info |
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Oxidative Enzymatic Alkene Cleavage: Indications for a Nonclassical Enzyme Mechanism Miguel Lara, Francesco G. Mutti, Silvia M. Glueck and Wolfgang Kroutil pp 5368–5369 DOI: 10.1021/ja8097096 Supporting Info |
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New Tantalum Ligand-Free Catalyst System for Highly Selective Trimerization of Ethylene Affording 1-Hexene: New Evidence of a Metallacycle Mechanism Rocío Arteaga-M pp 5370–5371 DOI: 10.1021/ja8100837 Supporting Info |
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Intermolecular Hydroamination of Ethylene and 1-Alkenes with Cyclic Ureas Catalyzed by Achiral and Chiral Gold(I) Complexes Zhibin Zhang, Seong Du Lee and Ross A. Widenhoefer pp 5372–5373 DOI: 10.1021/ja9001162 Supporting Info |
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Molecular-Scale Force Measurement in a Coiled-Coil Peptide Dimer by Electron Spin Resonance Stefano V. Gull pp 5374–5375 DOI: 10.1021/ja900230w Supporting Info |
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Porphyrin-Based Two-Dimensional Coordination Kagome Lattice Self-Assembled on a Au(111) Surface Ziliang Shi and Nian Lin pp 5376–5377 DOI: 10.1021/ja900499b Supporting Info |
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Synthesis and Characterization of Organometallic Coordination Polymer Nanoshells of Prussian Blue Using Miniemulsion Periphery Polymerization (MEPP) Guodong Liang, Junting Xu and Xiaosong Wang pp 5378–5379 DOI: 10.1021/ja900516a Supporting Info |
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Facilitated Assignment of Adenine H2 Resonances in Oligonucleotides Using Homonuclear Long-Range Couplings Jin Zhang, Alexander Spring and Markus W. Germann pp 5380–5381 DOI: 10.1021/ja900771b Supporting Info |
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Directed Carbozincation Reactions of Cyclopropene Derivatives Vinod Tarwade, Xiaozhong Liu, Ni Yan and Joseph M. Fox pp 5382–5383 DOI: 10.1021/ja900949n Supporting Info |
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Dual Reactivity of Step-Bound Carbon Monoxide during Oxidation on a Stepped Platinum Electrode in Alkaline Media Gonzalo García and Marc T. M. Koper pp 5384–5385 DOI: 10.1021/ja9009869 |
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Stimulus-Responsive Liquid Marbles Damien Dupin, Steven P. Armes and Syuji Fujii pp 5386–5387 DOI: 10.1021/ja901641v Supporting Info |
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A Direct Route to Cyclic Organic Nanostructures via Ring-Expansion Metathesis Polymerization of a Dendronized Macromonomer Andrew J. Boydston, Thomas W. Holcombe, David A. Unruh, Jean M. J. Fr pp 5388–5389 DOI: 10.1021/ja901658c Supporting Info |
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Molecular Basis for Inhibition of GH84 Glycoside Hydrolases by Substituted Azepanes: Conformational Flexibility Enables Probing of Substrate Distortion Filipa Marcelo, Yuan He, Scott A. Yuzwa, Lidia Nieto, Jes pp 5390–5392 DOI: 10.1021/ja809776r Supporting Info |
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Metal Complexes of Cinchonine as Chiral Building Blocks: A Strategy for the Construction of Nanotubular Architectures and Helical Coordination Polymers Tomasz Kaczorowski, Iwona Justyniak, Teodozja Lipi pp 5393–5395 DOI: 10.1021/ja8098867 Supporting Info |
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Surface Tension Mediated Conversion of Light to Work David Okawa, Stefan J. Pastine, Alex Zettl and Jean M. J. Fr pp 5396–5398 DOI: 10.1021/ja900130n Supporting Info |
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Toward a Mechanism for Biliprotein Lyases: Revisiting Nucleophilic Addition to Phycocyanobilin Jun-Ming Tu, Ming Zhou, Rainer Haessner, Matthias Pl pp 5399–5401 DOI: 10.1021/ja9002348 Supporting Info |
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Probing Cucurbituril Assemblies in Water with TEMPO-like Nitroxides: A Trinitroxide Supraradical with Spin−Spin Interactions David Bardelang, Karol Banaszak, Hakim Karoui, Antal Rockenbauer, M pp 5402–5404 DOI: 10.1021/ja900306m Supporting Info |
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CaFe4As3: A Metallic Iron Arsenide with Anisotropic Magnetic and Charge-Transport Properties Iliya Todorov, Duck Young Chung, Christos D. Malliakas, Quing’an Li, Thomas Bakas, Alexios Douvalis, Giancarlo Trimarchi, Kenneth Gray, John F. Mitchell, Arthur J. Freeman and Mercouri G. Kanatzidis pp 5405–5407 DOI: 10.1021/ja900534h Supporting Info |
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Reversible Transformation between Rings and Coils in a Dynamic Hydrogen-Bonded Self-Assembly Shiki Yagai, Shun Kubota, Hikaru Saito, Kanako Unoike, Takashi Karatsu, Akihide Kitamura, Ayyappanpillai Ajayaghosh, Masatoshi Kanesato and Yoshihiro Kikkawa pp 5408–5410 DOI: 10.1021/ja9005892 Supporting Info |
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A “Shortcut” Mosher Ester Method To Assign Configurations of Stereocenters in Nearly Symmetric Environments. Fluorous Mixture Synthesis and Structure Assignment of Petrocortyne A Dennis P. Curran and Bin Sui pp 5411–5413 DOI: 10.1021/ja900849f Supporting Info |
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Surface-Isomerization Dynamics of trans-Stilbene Molecules Adsorbed on Si(100)-2×1 Damien Riedel, Marion Cranney, Marta Martin, Romain Guillory, G pp 5414–5423 DOI: 10.1021/ja807498v |
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Toward Homogeneous Erythropoietin: Non-NCL-Based Chemical Synthesis of the Gln78−Arg166 Glycopeptide Domain Zhongping Tan, Shiying Shang, Tamara Halkina, Yu Yuan and Samuel J. Danishefsky pp 5424–5431 DOI: 10.1021/ja808704m Supporting Info |
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Toward Homogeneous Erythropoietin: Fine Tuning of the C-Terminal Acyl Donor in the Chemical Synthesis of the Cys29−Gly77 Glycopeptide Domain Yu Yuan, Jin Chen, Qian Wan, Zhongping Tan, Gong Chen, Cindy Kan and Samuel J. Danishefsky pp 5432–5437 DOI: 10.1021/ja808705v Supporting Info |
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Toward Homogeneous Erythropoietin: Chemical Synthesis of the Ala1−Gly28 Glycopeptide Domain by “Alanine” Ligation Cindy Kan, John D. Trzupek, Bin Wu, Qian Wan, Gong Chen, Zhongping Tan, Yu Yuan and Samuel J. Danishefsky pp 5438–5443 DOI: 10.1021/ja808707w Supporting Info |
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Probing the Mechanism of Electron Capture and Electron Transfer Dissociation Using Tags with Variable Electron Affinity Chang Ho Sohn, Cheol K. Chung, Sheng Yin, Prasanna Ramachandran, Joseph A. Loo and J. L. Beauchamp pp 5444–5459 DOI: 10.1021/ja806534r Supporting Info |
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Influence of Charge State on Catalytic Oxidation Reactions at Metal Oxide Clusters Containing Radical Oxygen Centers Grant E. Johnson, Roland Mitri pp 5460–5470 DOI: 10.1021/ja807499z Supporting Info |
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Carbohydrate Modified Catanionic Vesicles: Probing Multivalent Binding at the Bilayer Interface Glen B. Thomas, Lenea H. Rader, Juhee Park, Ludmila Abezgauz, Dganit Danino, Philip DeShong and Douglas S. English pp 5471–5477 DOI: 10.1021/ja8076439 Supporting Info |
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Conformation of Receptor Adopted upon Interaction with Virus Revealed by Site-Specific Fluorescence Quenchers and FRET Analysis J pp 5478–5482 DOI: 10.1021/ja807917t Supporting Info |
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Nitrogen-Rich Heterocycles as Reactivity Retardants in Shocked Insensitive Explosives M. Riad Manaa, Evan J. Reed, Laurence E. Fried and Nir Goldman pp 5483–5487 DOI: 10.1021/ja808196e |
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Nonpolar Nucleoside Mimics as Active Substrates for Human Thymidine Kinases Sarah K. Jarchow-Choy, Elena Sjuvarsson, Herman O. Sintim, Staffan Eriksson and Eric T. Kool pp 5488–5494 DOI: 10.1021/ja808244t Supporting Info |
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Synthesis and Structural Characterization of Sialic Acid−Glutamic Acid Hybrid Foldamers as Conformational Surrogates of α-2,8-Linked Polysialic Acid Jonel P. Saludes, James B. Ames and Jacquelyn Gervay-Hague pp 5495–5505 DOI: 10.1021/ja808286x Supporting Info |
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Activity, Folding and Z-DNA Formation of the 8-17 DNAzyme in the Presence of Monovalent Ions Debapriya Mazumdar, Nandini Nagraj, Hee-Kyung Kim, Xiangli Meng, Andrea K. Brown, Qian Sun, Wei Li and Yi Lu pp 5506–5515 DOI: 10.1021/ja8082939 Supporting Info |
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Optimized Acetylene/Carbon Dioxide Sorption in a Dynamic Porous Crystal Jie-Peng Zhang and Xiao-Ming Chen pp 5516–5521 DOI: 10.1021/ja8089872 Supporting Info |
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Mechanism of Charge Transport along Zinc Porphyrin-Based Molecular Wires Aleksey A. Kocherzhenko, Sameer Patwardhan, Ferdinand C. Grozema, Harry L. Anderson and Laurens D. A. Siebbeles pp 5522–5529 DOI: 10.1021/ja809174y Supporting Info |
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Water Dynamics and Interactions in Water−Polyether Binary Mixtures Emily E. Fenn, David E. Moilanen, Nancy E. Levinger and Michael D. Fayer pp 5530–5539 DOI: 10.1021/ja809261d |
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H-Atom Position as Pattern-Determining Factor in Arenethiol Films Ki-Young Kwon, Greg Pawin, Kin L. Wong, Eric Peters, Daeho Kim, Sampyo Hong, Talat S. Rahman, Michael Marsella and Ludwig Bartels pp 5540–5545 DOI: 10.1021/ja809417k Supporting Info |
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Adaptation to Shape Switching by Component Selection in a Constitutional Dynamic System S pp 5546–5559 DOI: 10.1021/ja809828g Supporting Info |
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Anomalous Dual-Element Filling in Partially Filled Skutterudites Lili Xi, Jiong Yang, Wenqing Zhang, Lidong Chen and Jihui Yang pp 5560–5563 DOI: 10.1021/ja8093845 |
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Design, Synthesis, and Evaluation of an α-Helix Mimetic Library Targeting Protein−Protein Interactions Alex Shaginian, Landon R. Whitby, Sukwon Hong, Inkyu Hwang, Bilal Farooqi, Mark Searcey, Jiandong Chen, Peter K. Vogt and Dale L. Boger pp 5564–5572 DOI: 10.1021/ja810025g Supporting Info |
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Magnetic Anisotropy of Dysprosium(III) in a Low-Symmetry Environment: A Theoretical and Experimental Investigation Kevin Bernot, Javier Luzon, Lapo Bogani, Mael Etienne, Claudio Sangregorio, Muralidharan Shanmugam, Andrea Caneschi, Roberta Sessoli and Dante Gatteschi pp 5573–5579 DOI: 10.1021/ja8100038 Supporting Info |
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Supramolecular Hydrogel Exhibiting Four Basic Logic Gate Functions To Fine-Tune Substance Release Harunobu Komatsu, Shinji Matsumoto, Shun-ichi Tamaru, Kenji Kaneko, Masato Ikeda and Itaru Hamachi pp 5580–5585 DOI: 10.1021/ja8098239 Supporting Info |
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Design, Synthesis, and Characterization of Ladder-Type Molecules and Polymers. Air-Stable, Solution-Processable n-Channel and Ambipolar Semiconductors for Thin-Film Transistors via Experiment and Theory Hakan Usta, Chad Risko, Zhiming Wang, Hui Huang, Murat K. Deliomeroglu, Aleksandr Zhukhovitskiy, Antonio Facchetti and Tobin J. Marks pp 5586–5608 DOI: 10.1021/ja809555c Supporting Info |
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Adjustable Receptor Based on a [3]Rotaxane Whose Two Threaded Rings Are Rigidly Attached to Two Porphyrinic Plates: Synthesis and Complexation Studies Jean-Paul Collin, Julien Frey, Val pp 5609–5620 DOI: 10.1021/ja900565p Supporting Info |
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Structure Proof and Synthesis of Kotalanol and De-O-sulfonated Kotalanol, Glycosidase Inhibitors Isolated from an Herbal Remedy for the Treatment of Type-2 Diabetes Kumarasamy Jayakanthan, Sankar Mohan and B. Mario Pinto pp 5621–5626 DOI: 10.1021/ja900867q Supporting Info |
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Formula Weight Prediction by Internal Reference Diffusion-Ordered NMR Spectroscopy (DOSY) Deyu Li, Gerald Kagan, Russell Hopson and Paul G. Williard pp 5627–5634 DOI: 10.1021/ja810154u Supporting Info |
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Substituent Effects on Regioselectivity in the Autoxidation of Nonconjugated Dienes Keri A. Tallman, Christopher L. Rector and Ned A. Porter pp 5635–5641 DOI: 10.1021/ja900040d Supporting Info |
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Functionally Important Conformations of the Met20 Loop in Dihydrofolate Reductase are Populated by Rapid Thermal Fluctuations Karunesh Arora and Charles L. Brooks III pp 5642–5647 DOI: 10.1021/ja9000135 Supporting Info |
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Investigation of the Catalytic Mechanism of a Synthetic DNAzyme with Protein-like Functionality: An RNaseA Mimic? Jason M. Thomas, Jung-Ki Yoon and David M. Perrin pp 5648–5658 DOI: 10.1021/ja900125n Supporting Info |
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Synthesis of J-Aggregating Dibenz[a,j]anthracene-Based Macrocycles Julian M. W. Chan, Jonathan R. Tischler, Steve E. Kooi, Vladimir Bulovi pp 5659–5666 DOI: 10.1021/ja900382r Supporting Info |
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Gold(I)-Catalyzed Coupling Reactions for the Synthesis of Diverse Small Molecules Using the Build/Couple/Pair Strategy Tuoping Luo and Stuart L. Schreiber pp 5667–5674 DOI: 10.1021/ja900414s Supporting Info |
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Interaction of Organoplatinum(II) Complexes with Monovalent Coinage Metal Triflates Marc-Etienne Moret and Peter Chen pp 5675–5690 DOI: 10.1021/ja900449y Supporting Info |
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Formation of High-Quality I−III−VI Semiconductor Nanocrystals by Tuning Relative Reactivity of Cationic Precursors Renguo Xie, Michael Rutherford and Xiaogang Peng pp 5691–5697 DOI: 10.1021/ja9005767 Supporting Info |
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Al4(PtBu2)6 − a Derivative of Al4H6 − and Other Al4 Species: A Challenge for Bonding Interpretation between Zintl Ions and Metalloid Clusters Patrick Henke, Michael Huber, Jochen Steiner, Kit Bowen, Bryan Eichhorn and Hansgeorg Schn pp 5698–5704 DOI: 10.1021/ja9007563 Supporting Info |
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Coupled Growth and Division of Model Protocell Membranes Ting F. Zhu and Jack W. Szostak pp 5705–5713 DOI: 10.1021/ja900919c Supporting Info |
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PCMODEL 9.2 Austin L. Gille, Brendan C. Dutmer and Thomas M. Gilbert p 5714 DOI: 10.1021/ja9022144 |
Issue 16
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Uranium−Nitrogen Multiple Bonding: The Case of a Four-Coordinate Uranium(VI) Nitridoborate Complex Alexander R. Fox and Christopher C. Cummins pp 5716–5717 DOI: 10.1021/ja8095812 Supporting Info |
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Core Functionalization of Hollow Polymer Nanocapsules Xiang Liu and Amit Basu pp 5718–5719 DOI: 10.1021/ja809619w Supporting Info |
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Synthesis of CuPt Nanorod Catalysts with Tunable Lengths Qingsheng Liu, Zhen Yan, Nathaniel L. Henderson, J. Chris Bauer, D. Wayne Goodman, James D. Batteas and Raymond E. Schaak pp 5720–5721 DOI: 10.1021/ja810151r Supporting Info |
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Molecular Propulsion: Chemical Sensing and Chemotaxis of DNA Driven by RNA Polymerase Hua Yu, Kyubong Jo, Kristy L. Kounovsky, Juan J. de Pablo and David C. Schwartz pp 5722–5723 DOI: 10.1021/ja900372m Supporting Info |
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Insight into Environmental Effects on Bonding and Redox Properties of [4Fe-4S] Clusters in Proteins Shuqiang Niu and Toshiko Ichiye pp 5724–5725 DOI: 10.1021/ja900406j Supporting Info |
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Direct Observation of Structural Heterogeneity in a β-Sheet Matthew E. Cremeens, J pp 5726–5727 DOI: 10.1021/ja900505e Supporting Info |
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Photoregulated Release of Caged Anticancer Drugs from Gold Nanoparticles Sarit S. Agasti, Apiwat Chompoosor, Chang-Cheng You, Partha Ghosh, Chae Kyu Kim and Vincent M. Rotello pp 5728–5729 DOI: 10.1021/ja900591t Supporting Info |
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Structure and Ultrafast Dynamics of White-Light-Emitting CdSe Nanocrystals Michael J. Bowers II, James R. McBride, Maria D. Garrett, Jessica A. Sammons, Albert D. Dukes III, Michael A. Schreuder, Tony L. Watt, Andrew R. Lupini, Stephen J. Pennycook and Sandra J. Rosenthal pp 5730–5731 DOI: 10.1021/ja900529h Supporting Info |
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Shape-Dependent Activity of Platinum Array Catalyst Vladimir Komanicky, Hakim Iddir, Kee-Chul Chang, Andreas Menzel, Goran Karapetrov, Daniel Hennessy, Peter Zapol and Hoydoo You pp 5732–5733 DOI: 10.1021/ja900459w Supporting Info |
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CO Oxidation over AuPd(100) from Ultrahigh Vacuum to Near-Atmospheric Pressures: The Critical Role of Contiguous Pd Atoms Feng Gao, Yilin Wang and D. Wayne Goodman pp 5734–5735 DOI: 10.1021/ja9008437 Supporting Info |
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Magnetic Transition and Long-Time Relaxation Behavior Induced by Selective Injection of Guest Molecules into Clathrate Hydrates Youngjune Park, Joonghoe Dho, Jiwoong Seol, Sun-Hwa Yeon, Minjun Cha, Y. H. Jeong, Yongwon Seo and Huen Lee pp 5736–5737 DOI: 10.1021/ja9009088 Supporting Info |
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Synthesis of Aromatic Esters via Pd-Catalyzed Decarboxylative Coupling of Potassium Oxalate Monoesters with Aryl Bromides and Chlorides Rui Shang, Yao Fu, Jia-Bin Li, Song-Lin Zhang, Qing-Xiang Guo and Lei Liu pp 5738–5739 DOI: 10.1021/ja900984x Supporting Info |
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[{(η5-C5Me5)2Sm}4P8]: A Molecular Polyphosphide of the Rare-Earth Elements Sergey N. Konchenko, Nikolay A. Pushkarevsky, Michael T. Gamer, Ralf K pp 5740–5741 DOI: 10.1021/ja901045m Supporting Info |
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Excited State Localization and Delocalization of Internal Charge Transfer in Branched Push−Pull Chromophores Studied by Single-Molecule Spectroscopy Damir Aumiler, Sufan Wang, Xudong Chen and Andong Xia pp 5742–5743 DOI: 10.1021/ja901268h Supporting Info |
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Enantioselective Total Synthesis of (−)-Napyradiomycin A1 via Asymmetric Chlorination of an Isolated Olefin Scott A. Snyder, Zhen-Yu Tang and Ritu Gupta pp 5744–5745 DOI: 10.1021/ja9014716 Supporting Info |
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A Short and Efficient Synthesis of (−)-7-Methylomuralide, a Potent Proteasome Inhibitor Ryan A. Shenvi and E. J. Corey pp 5746–5747 DOI: 10.1021/ja901400q Supporting Info |
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Surpassing the Use of Copper in the Click Functionalization of Polymeric Nanostructures: A Strain-Promoted Approach Enrique Lallana, Eduardo Fernandez-Megia and Ricardo Riguera pp 5748–5750 DOI: 10.1021/ja8100243 Supporting Info |
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Sequential Phosphine-Catalyzed, Nucleophilic Thiol−Ene/Radical-Mediated Thiol−Yne Reactions and the Facile Orthogonal Synthesis of Polyfunctional Materials Justin W. Chan, Charles E. Hoyle and Andrew B. Lowe pp 5751–5753 DOI: 10.1021/ja8099135 Supporting Info |
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Sensitivity Enhancement in Static Solid-State NMR Experiments via Single- and Multiple-Quantum Dipolar Coherences T. Gopinath and Gianluigi Veglia pp 5754–5756 DOI: 10.1021/ja900096d |
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Surface-Mediated Self-Coupling of Ethanol on Gold Xiaoying Liu, Bingjun Xu, Jan Haubrich, Robert J. Madix and Cynthia M. Friend pp 5757–5759 DOI: 10.1021/ja900822r Supporting Info |
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Selective Toxin Sequestrants for the Treatment of Bacterial Infections Levi S. Simpson, Lyle Burdine, Amal K. Dutta, Andrew P. Feranchak and Thomas Kodadek pp 5760–5762 DOI: 10.1021/ja900852k Supporting Info |
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A Method for the Preparation of Differentiated trans-1,2-Diol Derivatives with Enantio- and Diastereocontrol Sang Min Lim, Nicholas Hill and Andrew G. Myers pp 5763–5765 DOI: 10.1021/ja901283q Supporting Info |
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An Efficient Process for Pd-Catalyzed C−N Cross-Coupling Reactions of Aryl Iodides: Insight Into Controlling Factors Brett P. Fors, Nicole R. Davis and Stephen L. Buchwald pp 5766–5768 DOI: 10.1021/ja901414u Supporting Info |
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15N−15N Proton Assisted Recoupling in Magic Angle Spinning NMR J pp 5769–5776 DOI: 10.1021/ja806578y Supporting Info |
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“Molecular Basket” Sorbents for Separation of CO2 and H2S from Various Gas Streams Xiaoliang Ma, Xiaoxing Wang and Chunshan Song pp 5777–5783 DOI: 10.1021/ja8074105 |
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H2 Ejection from Polycyclic Aromatic Hydrocarbons: Infrared Multiphoton Dissociation Study of Protonated 1,2-Dihydronaphthalene Martin Vala, Jan Szczepanski, Jos Oomens and Jeffrey D. Steill pp 5784–5791 DOI: 10.1021/ja808965x Supporting Info |
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Toward Fully Synthetic Homogeneous β-Human Follicle-Stimulating Hormone (β-hFSH) with a Biantennary N-Linked Dodecasaccharide. Synthesis of β-hFSH with Chitobiose Units at the Natural Linkage Sites Pavel Nagorny, Bernhard Fasching, Xuechen Li, Gong Chen, Baptiste Aussedat and Samuel J. Danishefsky pp 5792–5799 DOI: 10.1021/ja809554x Supporting Info |
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Cleavage of Carbon Dioxide by an Iridium-Supported Fischer Carbene. A DFT Investigation Nigel J. Brookes, Alireza Ariafard, Robert Stranger and Brian F. Yates pp 5800–5808 DOI: 10.1021/ja809320x Supporting Info |
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Modeling Ethanol Decomposition on Transition Metals: A Combined Application of Scaling and Brønsted−Evans−Polanyi Relations P. Ferrin, D. Simonetti, S. Kandoi, E. Kunkes, J. A. Dumesic, J. K. Nørskov and M. Mavrikakis pp 5809–5815 DOI: 10.1021/ja8099322 |
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Sub-10 nm Platinum Nanocrystals with Size and Shape Control: Catalytic Study for Ethylene and Pyrrole Hydrogenation Chia-Kuang Tsung, John N. Kuhn, Wenyu Huang, Cesar Aliaga, Ling-I Hung, Gabor A. Somorjai and Peidong Yang pp 5816–5822 DOI: 10.1021/ja809936n |
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M Marl pp 5823–5830 DOI: 10.1021/ja8098917 Supporting Info |
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Solution Structure and Thermodynamics of 2′,5′ RNA Intercalation Eric D. Horowitz, Seth Lilavivat, Benjamin W. Holladay, Markus W. Germann and Nicholas V. Hud pp 5831–5838 DOI: 10.1021/ja810068e Supporting Info |
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Photoinduced Dynamics of Guanosine Monophosphate in Water from Broad-Band Transient Absorption Spectroscopy and Quantum-Chemical Calculations Venugopal Karunakaran, K. Kleinermanns, R. Improta and S. A. Kovalenko pp 5839–5850 DOI: 10.1021/ja810092k Supporting Info |
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Coassembly of Graphene Oxide and Nanowires for Large-Area Nanowire Alignment Yanguang Li and Yiying Wu pp 5851–5857 DOI: 10.1021/ja9000882 Supporting Info |
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Isolation of Free Phenylide-like Carbanions with N-Heterocyclic Carbene Frameworks Kelly E. Krahulic, Heikki M. Tuononen, Masood Parvez and Roland Roesler pp 5858–5865 DOI: 10.1021/ja9001234 Supporting Info |
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Nanowire Structured Hybrid Cell for Concurrently Scavenging Solar and Mechanical Energies Chen Xu, Xudong Wang and Zhong Lin Wang pp 5866–5872 DOI: 10.1021/ja810158x Supporting Info |
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Semisynthetic Fluorescent Sensor Proteins Based on Self-Labeling Protein Tags Matthias A. Brun, Kui-Thong Tan, Eiji Nakata, Marlon J. Hinner and Kai Johnsson pp 5873–5884 DOI: 10.1021/ja900149e Supporting Info |
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Spontaneous Chiral Resolution in Supramolecular Assembly of 2,4,6-Tris(2-pyridyl)-1,3,5-triazine on Au(111) Jing Zhang, Bin Li, Xuefeng Cui, Bing Wang, Jinlong Yang and J. G. Hou pp 5885–5890 DOI: 10.1021/ja9001986 Supporting Info |
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Spectroscopic and Kinetic Evidence on How Bacteriorhodopsin Accomplishes Vectorial Proton Transport under Functional Conditions V pp 5891–5901 DOI: 10.1021/ja900334c Supporting Info |
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Bimetallic Effects for Enhanced Polar Comonomer Enchainment Selectivity in Catalytic Ethylene Polymerization Brandon A. Rodriguez, Massimiliano Delferro and Tobin J. Marks pp 5902–5919 DOI: 10.1021/ja900257k Supporting Info |
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Hydrophobic Dimerization and Thermal Dissociation of Perylenediimide-Linked DNA Hairpins Mahesh Hariharan, Yan Zheng, Hai Long, Tarek A. Zeidan, George C. Schatz, Josh Vura-Weis, Michael R. Wasielewski, Xiaobing Zuo, David M. Tiede and Frederick D. Lewis pp 5920–5929 DOI: 10.1021/ja900347t Supporting Info |
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New Paradigm in Molecular Engineering of Sensitizers for Solar Cell Applications Takeru Bessho, Eiji Yoneda, Jun-Ho Yum, Matteo Guglielmi, Ivano Tavernelli, Hachiro Imai, Ursula Rothlisberger, Mohammad K. Nazeeruddin and Michael Gr pp 5930–5934 DOI: 10.1021/ja9002684 Supporting Info |
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Mechanistic Insights into Catalytic H2 Oxidation by Ni Complexes Containing a Diphosphine Ligand with a Positioned Amine Base Jenny Y. Yang, R. Morris Bullock, Wendy J. Shaw, Brendan Twamley, Kendra Fraze, M. Rakowski DuBois and Daniel L. DuBois pp 5935–5945 DOI: 10.1021/ja900483x Supporting Info |
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Ribosomally Synthesized Thiopeptide Antibiotics Targeting Elongation Factor Tu Rowan P. Morris, Jennifer A. Leeds, Hans Ulrich Naegeli, Lukas Oberer, Klaus Memmert, Eric Weber, Matthew J. LaMarche, Christian N. Parker, Nathalie Burrer, Stacey Esterow, Andreas E. Hein, Esther K. Schmitt and Philipp Krastel pp 5946–5955 DOI: 10.1021/ja900488a Supporting Info |
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Expanding the Peptide β-Turn in αγ Hybrid Sequences: 12 Atom Hydrogen Bonded Helical and Hairpin Turns Sunanda Chatterjee, Prema G. Vasudev, Srinivasarao Raghothama, Chandrasekharan Ramakrishnan, Narayanaswamy Shamala and Padmanabhan Balaram pp 5956–5965 DOI: 10.1021/ja900618h Supporting Info |
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Biomimetic Synthesis and Structural Reassignment of the Tridachiahydropyrones Pallavi Sharma, Barry Lygo, William Lewis and John E. Moses pp 5966–5972 DOI: 10.1021/ja900369z Supporting Info |
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Probing Hydrophobic Interactions Using Trajectories of Amphiphilic Molecules at a Hydrophobic/Water Interface Andrei Honciuc and Daniel K. Schwartz pp 5973–5979 DOI: 10.1021/ja900607g Supporting Info |
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Enhancement of Field Emission Transport by Molecular Tilt Configuration in Metal−Molecule−Metal Junctions Gunuk Wang, Tae-Wook Kim, Gunho Jo and Takhee Lee pp 5980–5985 DOI: 10.1021/ja900773h Supporting Info |
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Helical Transfer through Nonlocal Interactions Xiaojian Wu, Sunjun Ji, Yi Li, Baozong Li, Xiulin Zhu, Kenji Hanabusa and Yonggang Yang pp 5986–5993 DOI: 10.1021/ja9001376 Supporting Info |
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An N-Aroyltransferase of the BAHD Superfamily Has Broad Aroyl CoA Specificity in Vitro with Analogues of N-Dearoylpaclitaxel Danielle M. Nevarez, Yemane A. Mengistu, Irosha N. Nawarathne and Kevin D. Walker pp 5994–6002 DOI: 10.1021/ja900545m Supporting Info |
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Formation of Carbocycles by Intramolecular Conjugate Displacement: Scope and Mechanistic Insights Lihong Wang, Bodhuri Prabhudas and Derrick L. J. Clive pp 6003–6012 DOI: 10.1021/ja900857h Supporting Info |
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Total Synthesis of the Akuammiline Alkaloid (±)-Vincorine Min Zhang, Xiaoping Huang, Liqun Shen and Yong Qin pp 6013–6020 DOI: 10.1021/ja901219v Supporting Info |
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Development of Ruthenium Catalysts for the Enantioselective Synthesis of P-Stereogenic Phosphines via Nucleophilic Phosphido Intermediates Vincent S. Chan, Melanie Chiu, Robert G. Bergman and F. Dean Toste pp 6021–6032 DOI: 10.1021/ja9014887 Supporting Info |
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Mathematica 7.0 Thorsteinn Adalsteinsson pp 6033–6034 DOI: 10.1021/ja901938t |
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Fundamentals of Asymmetric Catalysis Michael A. Calter p 6035 DOI: 10.1021/ja9017607 |
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Corrosion Handbook: Corrosive Agents and Their Interactions with Materials. Second, Completely Revised and Extended Edition. Volume 11: Sulfuric Acid p 6035 DOI: 10.1021/ja9018995 |
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Highlights in Colloid Science John C. Berg pp 6035–6036 DOI: 10.1021/ja902438t |
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Fragment-Based Drug Discovery: A Practical Approach Andrew Petros and Philip J. Hajduk p 6036 DOI: 10.1021/ja902461y |
Issue 17
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Autocorrelation Analysis of NOESY Data Provides Residue Compactness for Folded and Unfolded Proteins Andreas Schedlbauer, Nicolas Coudevylle, Renate Auer, Karin Kloiber, Martin Tollinger and Robert Konrat pp 6038–6039 DOI: 10.1021/ja8074067 Supporting Info |
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SERS of Semiconducting Nanoparticles (TiO2 Hybrid Composites) Anthony Musumeci, David Gosztola, Tara Schiller, Nada M. Dimitrijevic, Vladimiro Mujica, Darren Martin and Tijana Rajh pp 6040–6041 DOI: 10.1021/ja808277u Supporting Info |
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Laterally Mobile, Functionalized Self-Assembled Monolayers at the Fluorous−Aqueous Interface in a Plug-Based Microfluidic System: Characterization and Testing with Membrane Protein Crystallization Jason E. Kreutz, Liang Li, L. Spencer Roach, Takuji Hatakeyama and Rustem F. Ismagilov pp 6042–6043 DOI: 10.1021/ja808697e Supporting Info |
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Proof of Intercrystallite Ionic Transport in LiMPO4 Electrodes (M = Fe, Mn) Kyu Tae Lee, Wang H. Kan and Linda F. Nazar pp 6044–6045 DOI: 10.1021/ja8090559 Supporting Info |
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The Electron Attachment Energy of the Aqueous Hydroxyl Radical Predicted from the Detachment Energy of the Aqueous Hydroxide Anion Christopher Adriaanse, Marialore Sulpizi, Joost VandeVondele and Michiel Sprik pp 6046–6047 DOI: 10.1021/ja809155k Supporting Info |
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Accurate Sampling of High-Frequency Motions in Proteins by Steady-State 15N−{1H} Nuclear Overhauser Effect Measurements in the Presence of Cross-Correlated Relaxation Fabien Ferrage, David Cowburn and Ranajeet Ghose pp 6048–6049 DOI: 10.1021/ja809526q Supporting Info |
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Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic Cells Akihiro Kojima, Kenjiro Teshima, Yasuo Shirai and Tsutomu Miyasaka pp 6050–6051 DOI: 10.1021/ja809598r Supporting Info |
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A Collagen-Mimic Dendrimer Capable of Controlled Release Chie Kojima, Sayako Tsumura, Atsushi Harada and Kenji Kono pp 6052–6053 DOI: 10.1021/ja809639c Supporting Info |
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Direct Observation of Ligand Dynamics in Cytochrome c Megan C. Thielges, J pp 6054–6055 DOI: 10.1021/ja810155s Supporting Info |
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Dramatic Effect of Aggregation on Rates and Thermodynamics of Stereoisomerization of Magnesium Enolates Erin R. Hurley, Xuyang He, Seth N. Brown and Kenneth W. Henderson pp 6056–6057 DOI: 10.1021/ja809716j Supporting Info |
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Design and Development of Enzymatically Activatable Photosensitizer Based on Unique Characteristics of Thiazole Orange Yuichiro Koide, Yasuteru Urano, Akira Yatsushige, Kenjiro Hanaoka, Takuya Terai and Tetsuo Nagano pp 6058–6059 DOI: 10.1021/ja900443b Supporting Info |
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Spatial Separation of Cavitating Bubble Populations: The Nanodroplet Injection Model Hangxun Xu, Nathan C. Eddingsaas and Kenneth S. Suslick pp 6060–6061 DOI: 10.1021/ja900457v Supporting Info |
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Total Synthesis of the α-Glucosidase Inhibitors Schulzeine A, B, and C and a Structural Revision of Schulzeine A Edward G. Bowen and Duncan J. Wardrop pp 6062–6063 DOI: 10.1021/ja9005755 Supporting Info |
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Remarkable Stabilization of M12L24 Spherical Frameworks through the Cooperation of 48 Pd(II)−Pyridine Interactions Sota Sato, Yoshitaka Ishido and Makoto Fujita pp 6064–6065 DOI: 10.1021/ja900676f Supporting Info |
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Total Synthesis of the Sphingolipid Biosynthesis Inhibitor Fumonisin B1 Claney L. Pereira, Yi-Hung Chen and Frank E. McDonald pp 6066–6067 DOI: 10.1021/ja9009265 Supporting Info |
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High-Yield Uniform Synthesis and Microstructure-Determination of Rice-Shaped Silver Nanocrystals Hongyan Liang, Huaixin Yang, Wenzhong Wang, Jianqi Li and Hongxing Xu pp 6068–6069 DOI: 10.1021/ja9010207 |
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Synthesis of 1-Borylisoindoles via Palladium-Catalyzed Dehydrogenation/C−H Borylation of Isoindolines Toshimichi Ohmura, Akihito Kijima and Michinori Suginome pp 6070–6071 DOI: 10.1021/ja901095h Supporting Info |
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Facile Deposition of Nanodimensional Ceria Particles and Their Assembly into Conformal Films at Liquid−Liquid Interface with a Phase Transfer Catalyst Sibusiso N. Mlondo, P. John Thomas and Paul O’Brien pp 6072–6073 DOI: 10.1021/ja901126n Supporting Info |
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Characterization of a Peroxodiiron(III) Intermediate in the T201S Variant of Toluene/o-Xylene Monooxygenase Hydroxylase from Pseudomonas sp. OX1 Woon Ju Song, Rachel K. Behan, Sunil G. Naik, Boi Hanh Huynh and Stephen J. Lippard pp 6074–6075 DOI: 10.1021/ja9011782 Supporting Info |
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A General and Efficient Catalyst System for a Wacker-Type Oxidation Using TBHP as the Terminal Oxidant: Application to Classically Challenging Substrates Brian W. Michel, Andrew M. Camelio, Candace N. Cornell and Matthew S. Sigman pp 6076–6077 DOI: 10.1021/ja901212h Supporting Info |
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Effect of TMEDA on Iron-Catalyzed Coupling Reactions of ArMgX with Alkyl Halides Daisuke Noda, Yusuke Sunada, Takuji Hatakeyama, Masaharu Nakamura and Hideo Nagashima pp 6078–6079 DOI: 10.1021/ja901262g Supporting Info |
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PKU-9: An Aluminogermanate with a New Three-Dimensional Zeolite Framework Constructed from CGS Layers and Spiro-5 Units Jie Su, Yingxia Wang, Zheming Wang and Jianhua Lin pp 6080–6081 DOI: 10.1021/ja901330u Supporting Info |
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Iron-Catalyzed Asymmetric Aerobic Oxidation: Oxidative Coupling of 2-Naphthols Hiromichi Egami and Tsutomu Katsuki pp 6082–6083 DOI: 10.1021/ja901391u Supporting Info |
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Cylindrical Superparticles from Semiconductor Nanorods Jiaqi Zhuang, Andrew D. Shaller, Jared Lynch, Huimeng Wu, Ou Chen, Alexander D. Q. Li and Y. Charles Cao pp 6084–6085 DOI: 10.1021/ja9015183 Supporting Info |
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Solar Water Oxidation by Composite Catalyst/α-Fe2O3 Photoanodes Diane K. Zhong, Jianwei Sun, Hiroki Inumaru and Daniel R. Gamelin pp 6086–6087 DOI: 10.1021/ja9016478 Supporting Info |
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Multiplexed Sandwich Immunoassays Using Electrochemiluminescence Imaging Resolved at the Single Bead Level Fr pp 6088–6089 DOI: 10.1021/ja901876z Supporting Info |
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High-Field Dynamic Nuclear Polarization in Aqueous Solutions M. J. Prandolini, V. P. Denysenkov, M. Gafurov, B. Endeward and T. F. Prisner pp 6090–6092 DOI: 10.1021/ja901496g |
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Identification of an Imino Group Indispensable for Cleavage by a Small Ribozyme Robert C. Spitale, Rosaria Volpini, Moriah G. Heller, Jolanta Krucinska, Gloria Cristalli and Joseph E. Wedekind pp 6093–6095 DOI: 10.1021/ja900450h Supporting Info |
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Controlled Formation of an Axially Bonded Co-Phthalocyanine Dimer Xin Ge, Carlos Manzano, Richard Berndt, Lennart T. Anger, Felix K pp 6096–6098 DOI: 10.1021/ja900484c Supporting Info |
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A New Class of Cyanine-like Dyes with Large Bond-Length Alternation Shino Ohira, Joel M. Hales, Karl J. Thorley, Harry L. Anderson, Joseph W. Perry and Jean-Luc Br pp 6099–6101 DOI: 10.1021/ja9007003 Supporting Info |
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A Direct and Nondestructive Approach To Determine the Folding Structure of the I-Motif DNA Secondary Structure by NMR Jixun Dai, Attila Ambrus, Laurence H. Hurley and Danzhou Yang pp 6102–6104 DOI: 10.1021/ja900967r Supporting Info |
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Pyridylalanine (Pal)-Peptide Catalyzed Enantioselective Allenoate Additions to N-Acyl Imines Bryan J. Cowen, Lindsey B. Saunders and Scott J. Miller pp 6105–6107 DOI: 10.1021/ja901279m Supporting Info |
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Star-Shaped Multichromophoric Arrays from Bodipy Dyes Grafted on Truxene Core St pp 6108–6110 DOI: 10.1021/ja9015364 Supporting Info |
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Zeolite RHO-Type Net with the Lightest Elements Tao Wu, Jian Zhang, Cong Zhou, Le Wang, Xianhui Bu and Pingyun Feng pp 6111–6113 DOI: 10.1021/ja901725v Supporting Info |
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Iminohydantoin Lesion Induced in DNA by Peracids and Other Epoxidizing Oxidants Wenjie Ye, R. Sangaiah, Diana E. Degen, Avram Gold, K. Jayaraj, Karl M. Koshlap, Gunnar Boysen, Jason Williams, Kenneth B. Tomer, Viorel Mocanu, Nedyalka Dicheva, Carol E. Parker, Roel M. Schaaper and Louise M. Ball pp 6114–6123 DOI: 10.1021/ja8090752 Supporting Info |
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Liquid-Crystalline Semiconducting Copolymers with Intramolecular Donor−Acceptor Building Blocks for High-Stability Polymer Transistors Do Hwan Kim, Bang-Lin Lee, Hyunsik Moon, Hee Min Kang, Eun Jeong Jeong, Jeong-Il Park, Kuk-Min Han, Sangyoon Lee, Byung Wook Yoo, Bon Won Koo, Joo Young Kim, Wi Hyoung Lee, Kilwon Cho, Hector Alejandro Becerril and Zhenan Bao pp 6124–6132 DOI: 10.1021/ja8095569 Supporting Info |
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Light Penetration and Photoisomerization in Rhodopsin studied by Numerical Simulations and Double-Quantum Solid-State NMR Spectroscopy Maria Concistrè, Axel Gansm pp 6133–6140 DOI: 10.1021/ja809878c Supporting Info |
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How Mitogen-Activated Protein Kinases Recognize and Phosphorylate Their Targets: A QM/MM Study Adrian Gustavo Turjanski, Gerhard Hummer and J. Silvio Gutkind pp 6141–6148 DOI: 10.1021/ja8071995 Supporting Info |
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Native Escherichia coli SufA, Coexpressed with SufBCDSE, Purifies as a [2Fe−2S] Protein and Acts as an Fe−S Transporter to Fe−S Target Enzymes Vibha Gupta, Ma pp 6149–6153 DOI: 10.1021/ja807551e Supporting Info |
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Charge Density Analysis of the (C−C)→Ti Agostic Interactions in a Titanacyclobutane Complex Stephan Scheins, Marc Messerschmidt, Milan Gembicky, Mateusz Pitak, Anatoliy Volkov, Philip Coppens, Benjamin G. Harvey, Gregory C. Turpin, Atta M. Arif and Richard D. Ernst pp 6154–6160 DOI: 10.1021/ja807649k Supporting Info |
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Predicting the Electrochemical Properties of MnO2 Nanomaterials Used in Rechargeable Li Batteries: Simulating Nanostructure at the Atomistic Level Thi X. T. Sayle, R. Rapela Maphanga, Phuti E. Ngoepe and Dean C. Sayle pp 6161–6173 DOI: 10.1021/ja8082335 Supporting Info |
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Submolecular Observation of Photosensitive Macrocycles and Their Isomerization Effects on Host−Guest Network Yong-Tao Shen, Li Guan, Xiao-Yang Zhu, Qing-Dao Zeng and Chen Wang pp 6174–6180 DOI: 10.1021/ja808434n Supporting Info |
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Theoretical Study of the Chemiluminescent Decomposition of Dioxetanone Fengyi Liu, Yajun Liu, Luca De Vico and Roland Lindh pp 6181–6188 DOI: 10.1021/ja808511t Supporting Info |
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Spin Crossover-Coupled Electron Transfer of [M(tacn)2]3+/2+ Complexes (tacn = 1,4,7-Triazacyclononane; M = Cr, Mn, Fe, Co, Ni) Richard L. Lord, Franklin A. Schultz and Mu-Hyun Baik pp 6189–6197 DOI: 10.1021/ja809552p Supporting Info |
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Stability and Photoelectronic Properties of Layered Titanate Nanostructures Alexander Riss, Michael J. Elser, Johannes Bernardi and Oliver Diwald pp 6198–6206 DOI: 10.1021/ja810109g Supporting Info |
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Differentiating Solvation Mechanisms at Polar Solid/Liquid Interfaces Michael R. Brindza and Robert A. Walker pp 6207–6214 DOI: 10.1021/ja810117f Supporting Info |
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High-Performance Air-Stable n-Channel Organic Thin Film Transistors Based on Halogenated Perylene Bisimide Semiconductors R pp 6215–6228 DOI: 10.1021/ja901077a Supporting Info |
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Observation of Redox-Induced Electron Transfer and Spin Crossover for Dinuclear Cobalt and Iron Complexes with the 2,5-Di-tert-butyl-3,6-dihydroxy-1,4-benzoquinonate Bridging Ligand Kil Sik Min, Antonio G. DiPasquale, Arnold L. Rheingold, Henry S. White and Joel S. Miller pp 6229–6236 DOI: 10.1021/ja900909u Supporting Info |
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Chemoenzymatic Synthesis of Glycosylated Glucagon-like Peptide 1: Effect of Glycosylation on Proteolytic Resistance and in Vivo Blood Glucose-Lowering Activity Taichi Ueda, Kazuyoshi Tomita, Yoshihide Notsu, Takaomi Ito, Masataka Fumoto, Tomoaki Takakura, Hirofumi Nagatome, Akio Takimoto, Shin-Ichi Mihara, Hiroko Togame, Keiko Kawamoto, Takanori Iwasaki, Kenji Asakura, Takeo Oshima, Kohji Hanasaki, Shin-Ichiro Nishimura and Hirosato Kondo pp 6237–6245 DOI: 10.1021/ja900261g Supporting Info |
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Two-Leg Molecular Ladders Formed by Hierarchical Self-Assembly of an Organic Radical N pp 6246–6252 DOI: 10.1021/ja900453n Supporting Info |
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Unusual Luminescence Enhancement of Metallogels of Alkynylplatinum(II) 2,6-Bis(N-alkylbenzimidazol-2′-yl)pyridine Complexes upon a Gel-to-Sol Phase Transition at Elevated Temperatures Anthony Yiu-Yan Tam, Keith Man-Chung Wong and Vivian Wing-Wah Yam pp 6253–6260 DOI: 10.1021/ja900895x Supporting Info |
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Metal-Induced Folding of Diels−Alderase Ribozymes Studied by Static and Time-Resolved NMR Spectroscopy Vijayalaxmi Manoharan, Boris F pp 6261–6270 DOI: 10.1021/ja900244x Supporting Info |
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β-Lactam Probes As Selective Chemical-Proteomic Tools for the Identification and Functional Characterization of Resistance Associated Enzymes in MRSA Isabell Staub and Stephan A. Sieber pp 6271–6276 DOI: 10.1021/ja901304n Supporting Info |
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Mechanistic Aspects of Horseradish Peroxidase Elucidated through Single-Molecule Studies Hans H. Gorris and David R. Walt pp 6277–6282 DOI: 10.1021/ja9008858 Supporting Info |
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Multiple H-Bonds Directed Self-Assembly of an Amphiphilic and Plate-Like Codendrimer with Janus Faces at Water−Air Interface Miao Yang, Wei Wang, Ingo Lieberwirth and Gerhard Wegner pp 6283–6292 DOI: 10.1021/ja900739e Supporting Info |
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In Situ and Real-Time Monitoring of Oxide Growth in a Few Monolayers at Surfaces of Platinum Nanoparticles in Aqueous Media Hideto Imai, Koichi Izumi, Masashi Matsumoto, Yoshimi Kubo, Kazuo Kato and Yasuhiko Imai pp 6293–6300 DOI: 10.1021/ja810036h Supporting Info |
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Chemoselective Tryptophan Labeling with Rhodium Carbenoids at Mild pH John M. Antos, Jesse M. McFarland, Anthony T. Iavarone and Matthew B. Francis pp 6301–6308 DOI: 10.1021/ja900094h Supporting Info |
Issue 18
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Study of SERS Chemical Enhancement Factors Using Buffer Layer Assisted Growth of Metal Nanoparticles on Self-Assembled Monolayers Masato M. Maitani, Douglas A. A. Ohlberg, Zhiyong Li, David L. Allara, Duncan R. Stewart and R. Stanley Williams pp 6310–6311 DOI: 10.1021/ja809347y Supporting Info |
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Protection and Deprotection Approach for the Introduction of Functional Groups into Metal−Organic Frameworks Teppei Yamada and Hiroshi Kitagawa pp 6312–6313 DOI: 10.1021/ja809352y Supporting Info |
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Charge and Temperature Dependence of Biomolecule Conformations: K+Tryptamine(H2O)n=0−1Arm=0−1 Cluster Ions Amy L. Nicely, Dorothy J. Miller and James M. Lisy pp 6314–6315 DOI: 10.1021/ja8094526 Supporting Info |
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Amyloid β Protein: Aβ40 Inhibits Aβ42 Oligomerization Megan M. Murray, Summer L. Bernstein, Vy Nyugen, Margaret M. Condron, David B. Teplow and Michael T. Bowers pp 6316–6317 DOI: 10.1021/ja8092604 Supporting Info |
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Phosphine-Promoted [3 + 3] Annulations of Aziridines With Allenoates: Facile Entry Into Highly Functionalized Tetrahydropyridines Hongchao Guo, Qihai Xu and Ohyun Kwon pp 6318–6319 DOI: 10.1021/ja8097349 Supporting Info |
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How Graphene Is Cut upon Oxidation? Zhenyu Li, Wenhua Zhang, Yi Luo, Jinlong Yang and Jian Guo Hou pp 6320–6321 DOI: 10.1021/ja8094729 Supporting Info |
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Conservation of Side-Chain Dynamics Within a Protein Family Anthony B. Law, Ernesto J. Fuentes and Andrew L. Lee pp 6322–6323 DOI: 10.1021/ja809915a |
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Real-Time Monitoring of Peptide Cleavage Using a Nanopore Probe Qitao Zhao, Ranulu Samanthi S. de Zoysa, Deqiang Wang, Dilani A. Jayawardhana and Xiyun Guan pp 6324–6325 DOI: 10.1021/ja9004893 Supporting Info |
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An Amine-Functionalized MIL-53 Metal−Organic Framework with Large Separation Power for CO2 and CH4 Sarah Couck, Joeri F. M. Denayer, Gino V. Baron, Tom R pp 6326–6327 DOI: 10.1021/ja900555r Supporting Info |
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Effective Transition Probability for the Faraday Effect of Lanthanide(III) Ion Solutions Kayoko Miyamoto, Kento Isai, Masayori Suwa and Hitoshi Watarai pp 6328–6329 DOI: 10.1021/ja9006468 Supporting Info |
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Evolution of a Histone H4-K16 Acetyl-Specific DNA Aptamer Berea A. R. Williams, Liyun Lin, Stuart M. Lindsay and John C. Chaput pp 6330–6331 DOI: 10.1021/ja900916p Supporting Info |
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Biosynthesis of the Sesquiterpene Antibiotic Albaflavenone in Streptomyces coelicolor. Mechanism and Stereochemistry of the Enzymatic Formation of Epi-isozizaene Xin Lin and David E. Cane pp 6332–6333 DOI: 10.1021/ja901313v Supporting Info |
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Thermal Expansion Matching via Framework Flexibility in Zinc Dicyanometallates Andrew L. Goodwin, Brendan J. Kennedy and Cameron J. Kepert pp 6334–6335 DOI: 10.1021/ja901355b Supporting Info |
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Lanthanide(III)-Doped Magnetite Nanoparticles Channa R. De Silva, Steve Smith, Inbo Shim, Jeffrey Pyun, Timothy Gutu, Jun Jiao and Zhiping Zheng pp 6336–6337 DOI: 10.1021/ja9014277 Supporting Info |
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Methane in an Open-Cage [60]Fullerene Keith E. Whitener, Jr., R. James Cross, Martin Saunders, Sho-ichi Iwamatsu, Shizuaki Murata, Naomi Mizorogi and Shigeru Nagase pp 6338–6339 DOI: 10.1021/ja901383r Supporting Info |
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Side Chain Resonances in Static Oriented Proton-Decoupled 15N Solid-State NMR Spectra of Membrane Proteins Christopher Aisenbrey, Lydia Prongidi-Fix, Alexandre Chenal, Daniel Gillet and Burkhard Bechinger pp 6340–6341 DOI: 10.1021/ja900677b Supporting Info |
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Dynamic Measurements of Aqueous Lanthanide Triflate-Catalyzed Reactions Using Luminescence Decay Prabani Dissanayake and Matthew J. Allen pp 6342–6343 DOI: 10.1021/ja900630d Supporting Info |
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Classical versus Bridged Allyl Ligands in Magnesium Complexes: The Role of Solvent Stephen C. Chmely, Christin N. Carlson, Timothy P. Hanusa and Arnold L. Rheingold pp 6344–6345 DOI: 10.1021/ja900998t Supporting Info |
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NMR Analysis of the Architecture and Functional Remodeling of a Modular Multidomain Protein, RPA Chris A. Brosey, Marie-Eve Chagot, Mark Ehrhardt, Dalyir I. Pretto, Brian E. Weiner and Walter J. Chazin pp 6346–6347 DOI: 10.1021/ja9013634 Supporting Info |
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Ligand-Controlled Access to [4 + 2] and [4 + 3] Cycloadditions in Gold-Catalyzed Reactions of Allene-Dienes Pablo Maule pp 6348–6349 DOI: 10.1021/ja901649s Supporting Info |
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Syntheses, X-ray Crystal Structures, and Solution Behavior of Monomeric, Cationic, Two-Coordinate Gold(I) π-Alkene Complexes Timothy J. Brown, Marina G. Dickens and Ross A. Widenhoefer pp 6350–6351 DOI: 10.1021/ja9015827 Supporting Info |
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Si3C2-Rings: From a Nonconjugated Trisilacyclopentadiene to an Aromatic Trisilacyclopentadienide and Cyclic Disilenide Hiroyuki Yasuda, Vladimir Ya. Lee and Akira Sekiguchi pp 6352–6353 DOI: 10.1021/ja901881z Supporting Info |
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Double Bond Isomerization/Enantioselective Aza-Petasis−Ferrier Rearrangement Sequence as an Efficient Entry to Anti- and Enantioenriched β-Amino Aldehydes Masahiro Terada and Yasunori Toda pp 6354–6355 DOI: 10.1021/ja902202g Supporting Info |
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In Silico Improvement of β3-Peptide Inhibitors of p53•hDM2 and p53•hDMX Julien Michel, Elizabeth A. Harker, Julian Tirado-Rives, William L. Jorgensen and Alanna Schepartz pp 6356–6357 DOI: 10.1021/ja901478e Supporting Info |
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Metallization of the Single Component Molecular Semiconductor [Ni(ptdt)2] under Very High Pressure Hengbo Cui, James S. Brooks, Akiko Kobayashi and Hayao Kobayashi pp 6358–6359 DOI: 10.1021/ja901553z |
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Enantiospecific Total Syntheses of Kapakahines B and F Timothy Newhouse, Chad A. Lewis and Phil S. Baran pp 6360–6361 DOI: 10.1021/ja901573x Supporting Info |
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Colorimetric Nitrite and Nitrate Detection with Gold Nanoparticle Probes and Kinetic End Points Weston L. Daniel, Min Su Han, Jae-Seung Lee and Chad A. Mirkin pp 6362–6363 DOI: 10.1021/ja901609k Supporting Info |
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Locked Nucleic Acid (LNA)-Modified Dinucleotide mRNA Cap Analogue: Synthesis, Enzymatic Incorporation, and Utilization Anilkumar R. Kore, Muthian Shanmugasundaram, Irudaya Charles, Alexander V. Vlassov and Timothy J. Barta pp 6364–6365 DOI: 10.1021/ja901655p Supporting Info |
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Genesis of Anisotropic Colloidal Particles via Protrusion of Polystyrene from Polyelectrolyte Multilayer Encapsulation Hyung Kyun Yu, Zhengwei Mao and Dayang Wang pp 6366–6367 DOI: 10.1021/ja901705f Supporting Info |
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Interconversion between Molecular Polyhedra and Metal−Organic Frameworks Jian-Rong Li, Daren J. Timmons and Hong-Cai Zhou pp 6368–6369 DOI: 10.1021/ja901731z Supporting Info |
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Long-Lived Charge-Separated Configuration of a Push−Pull Archetype of Disperse Red 1 End-Capped Poly[9,9-Bis(4-diphenylaminophenyl)fluorene] Mohamed E. El-Khouly, Yu Chen, Xiaodong Zhuang and Shunichi Fukuzumi pp 6370–6371 DOI: 10.1021/ja901588f Supporting Info |
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Solvent Engineering for Shape-Shifter Pure Fullerene (C60) Marappan Sathish, Kun’ichi Miyazawa, Jonathan P. Hill and Katsuhiko Ariga pp 6372–6373 DOI: 10.1021/ja902061r Supporting Info |
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Hydroelectric Voltage Generation Based on Water-Filled Single-Walled Carbon Nanotubes Quanzi Yuan and Ya-Pu Zhao pp 6374–6376 DOI: 10.1021/ja8093372 Supporting Info |
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First Principles Dynamics and Minimum Energy Pathways for Mechanochemical Ring Opening of Cyclobutene Mitchell T. Ong, Jeff Leiding, Hongli Tao, Aaron M. Virshup and Todd J. Mart pp 6377–6379 DOI: 10.1021/ja8095834 Supporting Info |
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Flexible Pores of a Metal Oxide-Based Capsule Permit Entry of Comparatively Larger Organic Guests Ayala Ziv, Alina Grego, Sivil Kopilevich, Leila Zeiri, Pere Miro, Carles Bo, Achim M pp 6380–6382 DOI: 10.1021/ja900452d Supporting Info |
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On the Synergism Between H2O and a Tetrahydropyran Template in the Regioselective Cyclization of an Epoxy Alcohol Jeffery A. Byers and Timothy F. Jamison pp 6383–6385 DOI: 10.1021/ja9004909 Supporting Info |
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M Yan Ling and Yong Zhang pp 6386–6388 DOI: 10.1021/ja9006723 Supporting Info |
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Monitoring Supported-Nanocluster Heterogeneous Catalyst Formation: Product and Kinetic Evidence for a 2-Step, Nucleation and Autocatalytic Growth Mechanism of Pt(0)n Formation from H2PtCl6 on Al2O3 or TiO2 Joseph E. Mondloch, Xinhuan Yan and Richard G. Finke pp 6389–6396 DOI: 10.1021/ja808980a Supporting Info |
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Chemical Redox Reactions Induced by Cryptoelectrons on a PMMA Surface Chong-yang Liu and Allen J. Bard pp 6397–6401 DOI: 10.1021/ja806785x |
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Biosynthesis of Steroidal Antibiotic Fusidanes: Functional Analysis of Oxidosqualene Cyclase and Subsequent Tailoring Enzymes from Aspergillus fumigatus Hisashi Mitsuguchi, Yasuyo Seshime, Isao Fujii, Masaaki Shibuya, Yutaka Ebizuka and Tetsuo Kushiro pp 6402–6411 DOI: 10.1021/ja8095976 Supporting Info |
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Unusual Interchromophoric Interactions in β,β′ Directly and Doubly Linked Corrole Dimers: Prohibited Electronic Communication and Abnormal Singlet Ground States Sung Cho, Jong Min Lim, Satoru Hiroto, Pyosang Kim, Hiroshi Shinokubo, Atsuhiro Osuka and Dongho Kim pp 6412–6420 DOI: 10.1021/ja900220y Supporting Info |
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Reaction Coordinate of a Functional Model of Tyrosinase: Spectroscopic and Computational Characterization Bryan T. Op’t Holt, Michael A. Vance, Liviu M. Mirica, David E. Heppner, T. Daniel P. Stack and Edward I. Solomon pp 6421–6438 DOI: 10.1021/ja807898h Supporting Info |
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Molecular Resolution Imaging of an Antibiotic Peptide in a Lipid Matrix Slawomir Sek, Thamara Laredo, John R. Dutcher and Jacek Lipkowski pp 6439–6444 DOI: 10.1021/ja808180m |
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Preparation and Gas Adsorption Studies of Three Mesh-Adjustable Molecular Sieves with a Common Structure Shengqian Ma, Daofeng Sun, Daqiang Yuan, Xi-Sen Wang and Hong-Cai Zhou pp 6445–6451 DOI: 10.1021/ja808896f Supporting Info |
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A Solution NMR Approach to the Measurement of Amphiphile Immersion Depth and Orientation in Membrane Model Systems M. Sameer Al-Abdul-Wahid, Chris Neale, R pp 6452–6459 DOI: 10.1021/ja808964e Supporting Info |
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Ionization Energies of Aqueous Nucleic Acids: Photoelectron Spectroscopy of Pyrimidine Nucleosides and ab Initio Calculations Petr Slav pp 6460–6467 DOI: 10.1021/ja8091246 |
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Conformations of Polyaniline Molecules Adsorbed on Au(111) Probed by in Situ STM and ex Situ XPS and NEXAFS YiHui Lee, ChinZen Chang, ShuehLin Yau, LiangJen Fan, YawWen Yang, LiangYueh Ou Yang and Kingo Itaya pp 6468–6474 DOI: 10.1021/ja809263y Supporting Info |
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One-Carbon Extrusion from a Tetraazafulvalene. Isolation of Aldehydes and a Study of Their Origin John A. Murphy, Franziska Schoenebeck, Neil J. Findlay, Douglas W. Thomson, Sheng-ze Zhou and Jean Garnier pp 6475–6479 DOI: 10.1021/ja8092746 Supporting Info |
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Decamethylytterbocene Complexes of Bipyridines and Diazabutadienes: Multiconfigurational Ground States and Open-Shell Singlet Formation Corwin H. Booth, Marc D. Walter, Daniel Kazhdan, Yung-Jin Hu, Wayne W. Lukens, Eric D. Bauer, Laurent Maron, Odile Eisenstein and Richard A. Andersen pp 6480–6491 DOI: 10.1021/ja809624w Supporting Info |
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Imaging of mRNA in Live Cells Using Nucleic Acid-Templated Reduction of Azidorhodamine Probes Zbigniew Pianowski, Katarzyna Gorska, Laurence Oswald, Christoph A. Merten and Nicolas Winssinger pp 6492–6497 DOI: 10.1021/ja809656k Supporting Info |
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Role of Nucleobase Energetics and Nucleobase Interactions in Single-Stranded Peptide Nucleic Acid Charge Transfer Amit Paul, Silvia Bezer, Ravindra Venkatramani, Laura Kocsis, Emil Wierzbinski, Alexander Balaeff, Shahar Keinan, David N. Beratan, Catalina Achim and David H. Waldeck pp 6498–6507 DOI: 10.1021/ja9000163 Supporting Info |
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Synthesis of Methyl Halides from Biomass Using Engineered Microbes Travis S. Bayer, Daniel M. Widmaier, Karsten Temme, Ethan A. Mirsky, Daniel V. Santi and Christopher A. Voigt pp 6508–6515 DOI: 10.1021/ja809461u Supporting Info |
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Applications of 1-Alkenyl-1,1-Heterobimetallics in the Stereoselective Synthesis of Cyclopropylboronate Esters, Trisubstituted Cyclopropanols and 2,3-Disubstituted Cyclobutanones Mahmud M. Hussain, Hongmei Li, Nusrah Hussain, Mercedes Ure pp 6516–6524 DOI: 10.1021/ja900147s Supporting Info |
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Magnetic Resonance Imaging Studies on Catalyst Impregnation Processes: Discriminating Metal Ion Complexes within Millimeter-Sized γ-Al2O3 Catalyst Bodies Leticia Espinosa-Alonso, Anna A. Lysova, Peter de Peinder, Krijn P. de Jong, Igor V. Koptyug and Bert M. Weckhuysen pp 6525–6534 DOI: 10.1021/ja900346k Supporting Info |
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Probing the Structure and Charge State of Glutathione-Capped Au25(SG)18 Clusters by NMR and Mass Spectrometry Zhikun Wu, Chakicherla Gayathri, Roberto R. Gil and Rongchao Jin pp 6535–6542 DOI: 10.1021/ja900386s Supporting Info |
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Fluorescent BODIPY-Based Zn(II) Complex as a Molecular Probe for Selective Detection of Neurofibrillary Tangles in the Brains of Alzheimer’s Disease Patients Akio Ojida, Takashi Sakamoto, Masa-aki Inoue, Sho-hei Fujishima, Guy Lippens and Itaru Hamachi pp 6543–6548 DOI: 10.1021/ja9008369 Supporting Info |
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Regulation of Lysozyme Activity Based on Thermotolerant Protein/Smart Polymer Complex Formation Sumon Ganguli, Keitaro Yoshimoto, Shunsuke Tomita, Hiroshi Sakuma, Tsuneyoshi Matsuoka, Kentaro Shiraki and Yukio Nagasaki pp 6549–6553 DOI: 10.1021/ja900786z Supporting Info |
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Consequences of Acid Strength for Isomerization and Elimination Catalysis on Solid Acids Josef Macht, Robert T. Carr and Enrique Iglesia pp 6554–6565 DOI: 10.1021/ja900829x Supporting Info |
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Capturing and Analyzing the Excited-State Structure of a Cu(I) Phenanthroline Complex by Time-Resolved Diffraction and Theoretical Calculations Ivan I. Vorontsov, Tim Graber, Andrey Yu. Kovalevsky, Irina V. Novozhilova, Milan Gembicky, Yu-Sheng Chen and Philip Coppens pp 6566–6573 DOI: 10.1021/ja900921p Supporting Info |
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Single-Conformation and Diastereomer Specific Ultraviolet and Infrared Spectroscopy of Model Synthetic Foldamers: α/β-Peptides William H. James, III, Esteban E. Baquero, V. Alvin Shubert, Soo Hyuk Choi, Samuel H. Gellman and Timothy S. Zwier pp 6574–6590 DOI: 10.1021/ja901051v Supporting Info |
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Resistive Molecular Memories: Influence of Molecular Parameters on the Electrical Bistability Simone Di Motta, Eugenio Di Donato, Fabrizia Negri, Giorgio Orlandi, Daniele Fazzi and Chiara Castiglioni pp 6591–6598 DOI: 10.1021/ja901101c Supporting Info |
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Highly Efficient and Rapid Cs+ Uptake by the Layered Metal Sulfide K2xMnxSn3−xS6 (KMS-1) Manolis J. Manos and Mercouri G. Kanatzidis pp 6599–6607 DOI: 10.1021/ja900977p Supporting Info |
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Free Energies and Entropies of Water Molecules at the Inhibitor−Protein Interface of DNA Gyrase Hongtao Yu and Steven W. Rick pp 6608–6613 DOI: 10.1021/ja809696s Supporting Info |
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Stereoselective Construction of Seven-Membered Rings with an All-Carbon Quaternary Center by Direct Tiffeneau−Demjanov-type Ring Expansion Takuya Hashimoto, Yuki Naganawa and Keiji Maruoka pp 6614–6617 DOI: 10.1021/ja900941k Supporting Info |
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Hydrophobically Self-Assembled Nanoparticles as Molecular Receptors in Water Salvador Tomas and Lilia Milanesi pp 6618–6623 DOI: 10.1021/ja900561j Supporting Info |
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Cyanoesterification of 1,2-Dienes Catalyzed by Nickel Yasuhiro Hirata, Tomohiko Inui, Yoshiaki Nakao and Tamejiro Hiyama pp 6624–6631 DOI: 10.1021/ja9010282 Supporting Info |
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Theoretical Bond Dissociation Energies of Halo-Heterocycles: Trends and Relationships to Regioselectivity in Palladium-Catalyzed Cross-Coupling Reactions Yeimy Garcia, Franziska Schoenebeck, Claude Y. Legault, Craig A. Merlic and K. N. Houk pp 6632–6639 DOI: 10.1021/ja9004927 Supporting Info |
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Residue-Specific pKa Determination of Lysine and Arginine Side Chains by Indirect 15N and 13C NMR Spectroscopy: Application to apo Calmodulin Ingemar Andr p 6640 DOI: 10.1021/ja902385j |
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Ligand Controlled Highly Regio- and Enantioselective Synthesis of α-Acyloxyketones by Palladium-Catalyzed Allylic Alkylation of 1,2-Enediol Carbonates Barry M. Trost, Jiayi Xu and Thomas Schmidt p 6640 DOI: 10.1021/ja902816z |
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Enantioselective Intramolecular Friedel−Crafts-Type α-Arylation of Aldehydes K. C. Nicolaou, R p 6640 DOI: 10.1021/ja902682t Supporting Info |
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Valence Anions of 9-Methylguanine−1-Methylcytosine Complexes. Computational and Photoelectron Spectroscopy Studies Anna Szyperska, Janusz Rak, Jerzy Leszczynski, Xiang Li, Yeon Jae Ko, Haopeng Wang and Kit H. Bowen p 6641 DOI: 10.1021/ja9020638 |
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Jacobsen’s Catalyst for Hydrolytic Kinetic Resolution: Structure Elucidation of Paramagnetic Co(III) Salen Complexes in Solution via Combined NMR and Quantum Chemical Studies Sebastian Kemper, Peter Hrob p 6641 DOI: 10.1021/ja902706f |
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Oxidative Folding of Peptides and Proteins p 6642 DOI: 10.1021/ja902638z |
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Atomic Charges, Bond Properties, and Molecular Energies p 6642 DOI: 10.1021/ja902554z |
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Metallic Nanomaterials Clemens Burda, Ph.D. p 6642 DOI: 10.1021/ja902592k |
Issue 19
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N Doping of Oxide Nanosheets Yasumichi Matsumoto, Michio Koinuma, Yoshifumi Iwanaga, Tetsuya Sato and Shintaro Ida pp 6644–6645 DOI: 10.1021/ja807388t Supporting Info |
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Electrochemically Driven Drug Metabolism by Membranes Containing Human Cytochrome P450 Yasuhiro Mie, Masaaki Suzuki and Yasuo Komatsu pp 6646–6647 DOI: 10.1021/ja809364r Supporting Info |
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In Situ Controllable Loading of Ultrafine Noble Metal Particles on Titania Yun Xie, Kunlun Ding, Zhimin Liu, Ranting Tao, Zhenyu Sun, Hongye Zhang and Guimin An pp 6648–6649 DOI: 10.1021/ja900447d Supporting Info |
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Microstructured Materials Based on Multicompartmental Fibers Srijanani Bhaskar and Joerg Lahann pp 6650–6651 DOI: 10.1021/ja900354b Supporting Info |
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Electronic Communication between Immobilized Ferrocenyl-Terminated Dendrimers Aifang Wang, C pp 6652–6653 DOI: 10.1021/ja900645j Supporting Info |
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Mechanism and Transition-State Structures for Nickel-Catalyzed Reductive Alkyne−Aldehyde Coupling Reactions P. R. McCarren, Peng Liu, Paul Ha-Yeon Cheong, Timothy F. Jamison and K. N. Houk pp 6654–6655 DOI: 10.1021/ja900701g Supporting Info |
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“Signal-On” Detection of DNA Hole Transfer at the Single Molecule Level Tadao Takada, Yuichiro Takeda, Mamoru Fujitsuka and Tetsuro Majima pp 6656–6657 DOI: 10.1021/ja9009919 Supporting Info |
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Fast and Simple Acquisition of Solid-State 14N NMR Spectra with Signal Enhancement via Population Transfer Luke A. O’Dell and Robert W. Schurko pp 6658–6659 DOI: 10.1021/ja901278q |
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NTA Directed Protein Nanopatterning on DNA Origami Nanoconstructs Wanqiu Shen, Hong Zhong, David Neff and Michael L. Norton pp 6660–6661 DOI: 10.1021/ja901407j Supporting Info |
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Enhanced Long-Term Stability for Single Ion Channel Recordings Using Suspended Poly(lipid) Bilayers Benjamin A. Heitz, Juhua Xu, Henry K. Hall, Jr., Craig A. Aspinwall and S. Scott Saavedra pp 6662–6663 DOI: 10.1021/ja901442t Supporting Info |
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Thermodynamic Control of the Electrocyclic Ring Opening of Cyclobutenes: CX Substituents at C-3 Mask the Kinetic Torquoselectivity Joann M. Um, Huadong Xu, K. N. Houk and Weiping Tang pp 6664–6665 DOI: 10.1021/ja9016446 Supporting Info |
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N-Heterocyclic Carbene-Functionalized Ruthenium Phosphinidenes: What a Difference a Twist Makes Halil Aktas, J. Chris Slootweg, Marius Schakel, Andreas W. Ehlers, Martin Lutz, Anthony L. Spek and Koop Lammertsma pp 6666–6667 DOI: 10.1021/ja901540h Supporting Info |
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Iridium-Catalyzed Addition of Acid Chlorides to Terminal Alkynes Tomohiro Iwai, Tetsuaki Fujihara, Jun Terao and Yasushi Tsuji pp 6668–6669 DOI: 10.1021/ja901778y Supporting Info |
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Patterned Growth of Horizontal ZnO Nanowire Arrays Sheng Xu, Yong Ding, Yaguang Wei, Hao Fang, Yue Shen, Ashok K. Sood, Dennis L. Polla and Zhong Lin Wang pp 6670–6671 DOI: 10.1021/ja902119h Supporting Info |
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Electrostatic Binding among Equilibrating 2-D and 3-D Self-Assemblies Fredric M. Menger and Lei Shi pp 6672–6673 DOI: 10.1021/ja902174g Supporting Info |
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Total Synthesis of (−)-Acutumine Fang Li, Samuel S. Tartakoff and Steven L. Castle pp 6674–6675 DOI: 10.1021/ja9024403 Supporting Info |
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Palladium-Catalyzed Asymmetric Dearomatization of Naphthalene Derivatives Jorge Garc pp 6676–6677 DOI: 10.1021/ja9025193 Supporting Info |
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Water Overcomes Methyl Group Directing Effects in Epoxide-Opening Cascades Christopher J. Morten and Timothy F. Jamison pp 6678–6679 DOI: 10.1021/ja9025243 Supporting Info |
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A General Screening Strategy for Peptide-Based Fluorogenic Ligands: Probes for Dynamic Studies of PDZ Domain-Mediated Interactions Matthieu Sainlos, Wendy S. Iskenderian and Barbara Imperiali pp 6680–6682 DOI: 10.1021/ja900371q Supporting Info |
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Sulfonamido−Phosphoramidite Ligands in Cooperative Dinuclear Hydrogenation Catalysis Frederic W. Patureau, Sandra de Boer, Mark Kuil, Jurjen Meeuwissen, Pierre-Alain R. Breuil, Maxime A. Siegler, Anthony L. Spek, Albertus J. Sandee, Bas de Bruin and Joost N. H. Reek pp 6683–6685 DOI: 10.1021/ja9024879 Supporting Info |
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A Chemical Genetic Method for Generating Bivalent Inhibitors of Protein Kinases Zachary B. Hill, B. Gayani K. Perera and Dustin J. Maly pp 6686–6688 DOI: 10.1021/ja900871y Supporting Info |
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Characterization of β-B-Agostic Isomers in Zirconocene Amidoborane Complexes Taryn D. Forster, Heikki M. Tuononen, Masood Parvez and Roland Roesler pp 6689–6691 DOI: 10.1021/ja901460y Supporting Info |
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Heterogeneous Catalysis of a Copper-Coated Atomic Force Microscopy Tip for Direct-Write Click Chemistry Walter F. Paxton, Jason M. Spruell and J. Fraser Stoddart pp 6692–6694 DOI: 10.1021/ja9015974 Supporting Info |
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Construction of Multifunctional Cuboctahedra via Coordination-Driven Self-Assembly Koushik Ghosh, Jiming Hu, Henry S. White and Peter J. Stang pp 6695–6697 DOI: 10.1021/ja902045q Supporting Info |
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Emission Mechanism of Doubly ortho-Linked Quinoxaline/Diphenylfluorene or cis-Stilbene/Fluorene Hybrid Compounds Based on the Transient Absorption and Emission Measurements during Pulse Radiolysis Yi Wei, Shingo Samori, Sachiko Tojo, Mamoru Fujitsuka, Jin-Sheng Lin, Chien-Tien Chen and Tetsuro Majima pp 6698–6707 DOI: 10.1021/ja8090005 Supporting Info |
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Enantiomer-Selective and Helix-Sense-Selective Living Block Copolymerization of Isocyanide Enantiomers Initiated by Single-Handed Helical Poly(phenyl isocyanide)s Zong-Quan Wu, Kanji Nagai, Motonori Banno, Kento Okoshi, Kiyotaka Onitsuka and Eiji Yashima pp 6708–6718 DOI: 10.1021/ja900036n Supporting Info |
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Fluorescent J-Aggregates of Core-Substituted Perylene Bisimides: Studies on Structure−Property Relationship, Nucleation−Elongation Mechanism, and Sergeants-and-Soldiers Principle Theo E. Kaiser, Vladimir Stepanenko and Frank W pp 6719–6732 DOI: 10.1021/ja900684h Supporting Info |
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Strong H···F Hydrogen Bonds as Synthons in Polymeric Quantum Magnets: Structural, Magnetic, and Theoretical Characterization of [Cu(HF2)(pyrazine)2]SbF6, [Cu2F(HF)(HF2)(pyrazine)4](SbF6)2, and [CuAg(H3F4)(pyrazine)5](SbF6)2 Jamie L. Manson, John A. Schlueter, Kylee A. Funk, Heather I. Southerland, Brendan Twamley, Tom Lancaster, Stephen J. Blundell, Peter J. Baker, Francis L. Pratt, John Singleton, Ross D. McDonald, Paul A. Goddard, Pinaki Sengupta, Cristian D. Batista, Letian Ding, Changhoon Lee, Myung-Hwan Whangbo, Isabel Franke, Susan Cox, Chris Baines and Derek Trial pp 6733–6747 DOI: 10.1021/ja808761d Supporting Info |
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Theoretical and Experimental Studies of the Conversion of Chromopyrrolic Acid to an Antitumor Derivative by Cytochrome P450 StaP: The Catalytic Role of Water Molecules Yong Wang, Hui Chen, Masatomo Makino, Yoshitsugu Shiro, Shingo Nagano, Shumpei Asamizu, Hiroyasu Onaka and Sason Shaik pp 6748–6762 DOI: 10.1021/ja9003365 Supporting Info |
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Electric Field-Assisted Alignment of Self-Assembled Fibers Composed of Hydrogen-Bonded Molecules Having Laterally Fluorinated Mesogens Masafumi Yoshio, Yoshiko Shoji, Yusuke Tochigi, Yohei Nishikawa and Takashi Kato pp 6763–6767 DOI: 10.1021/ja8093718 Supporting Info |
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Frontier Orbital Description of the Si(100) Surface: A Route to Symmetry-Allowed and Concerted [2 + 2] Cycloadditions Peter M. Ryan, Lucile C. Teague and John J. Boland pp 6768–6774 DOI: 10.1021/ja808450w Supporting Info |
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Enrichment Mechanism of Semiconducting Single-Walled Carbon Nanotubes by Surfactant Amines Sang-Yong Ju, Marcel Utz and Fotios Papadimitrakopoulos pp 6775–6784 DOI: 10.1021/ja809054c Supporting Info |
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Characterizing the Role of Ensemble Modulation in Mutation-Induced Changes in Binding Affinity Anthony Manson, Steven T. Whitten, Josephine C. Ferreon, Robert O. Fox and Vincent J. Hilser pp 6785–6793 DOI: 10.1021/ja809133u Supporting Info |
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Passing Two Strings through the Same Ring Using an Octahedral Metal Center as Template: A New Synthesis of [3]Rotaxanes Alexander I. Prikhod′ko and Jean-Pierre Sauvage pp 6794–6807 DOI: 10.1021/ja809267z Supporting Info |
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Structural Basis for Iron Mineralization by Bacterioferritin Allister Crow, Tamara L. Lawson, Allison Lewin, Geoffrey R. Moore and Nick E. Le Brun pp 6808–6813 DOI: 10.1021/ja8093444 Supporting Info |
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Prediction of the Rotational Tumbling Time for Proteins with Disordered Segments Sung-Hun Bae, H. Jane Dyson and Peter E. Wright pp 6814–6821 DOI: 10.1021/ja809687r Supporting Info |
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Ligand-Promoted Carbene Insertion into the Aryl Substituent of an N-Heterocyclic Carbene Ligand in Ruthenium-Based Metathesis Catalysts Brandon R. Galan, Mateusz Pitak, Milan Gembicky, Jerome B. Keister and Steven T. Diver pp 6822–6832 DOI: 10.1021/ja809984k Supporting Info |
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pH- and Photo-Switched Release of Guest Molecules from Mesoporous Silica Supports Elena Aznar, Ma Dolores Marcos, Ram pp 6833–6843 DOI: 10.1021/ja810011p |
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Dioxygen and Water Activation Processes on Multi-Ru-Substituted Polyoxometalates: Comparison with the “Blue-Dimer” Water Oxidation Catalyst Aleksey E. Kuznetsov, Yurii V. Geletii, Craig L. Hill, Keiji Morokuma and Djamaladdin G. Musaev pp 6844–6854 DOI: 10.1021/ja900017g Supporting Info |
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Octahedral HSiCl3 and HSiCl2Me Adducts with Pyridines Gerrit W. Fester, J pp 6855–6864 DOI: 10.1021/ja901053w Supporting Info |
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Polar or Nonpolar? A+ Cation Polarity Control in A2Ti(IO3)6(A = Li, Na, K, Rb, Cs, Tl) Hong-Young Chang, Sang-Hwan Kim, Kang Min Ok and P. Shiv Halasyamani pp 6865–6873 DOI: 10.1021/ja9015099 Supporting Info |
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Tunable Ferromagnetic Spin Ordering in Boron Nitride Nanotubes with Topological Fluorine Adsorption Zhuhua Zhang and Wanlin Guo pp 6874–6879 DOI: 10.1021/ja901586k Supporting Info |
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Well-Defined Organic Nanotubes from Multicomponent Bottlebrush Copolymers Kun Huang and Javid Rzayev pp 6880–6885 DOI: 10.1021/ja901936g Supporting Info |
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Supramolecular Cocaine−Aptamer Complexes Activate Biocatalytic Cascades Ronit Freeman, Etery Sharon, Ran Tel-Vered and Itamar Willner p 6886 DOI: 10.1021/ja902775h |
Issue 20
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Evidence for Ligand-Induced Paramagnetism in CdSe Quantum Dots Robert W. Meulenberg, Jonathan R. I. Lee, Scott K. McCall, Khalid M. Hanif, Daniel Haskel, Jonathan C. Lang, Louis J. Terminello and Tony van Buuren pp 6888–6889 DOI: 10.1021/ja8098454 Supporting Info |
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Mechanical Motion of Azobenzene Crystals upon Photoirradiation Hideko Koshima, Naoko Ojima and Hidetaka Uchimoto pp 6890–6891 DOI: 10.1021/ja8098596 Supporting Info |
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Destruction of the Hydration Shell around Tetraalkylammonium Ions at the Electrochemical Interface Akira Yamakata and Masatoshi Osawa pp 6892–6893 DOI: 10.1021/ja8100374 Supporting Info |
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A Multifunctional 3D Ferroelectric and NLO-Active Porous Metal−Organic Framework Zhengang Guo, Rong Cao, Xin Wang, Hongfang Li, Wenbing Yuan, Guojian Wang, Haohan Wu and Jing Li pp 6894–6895 DOI: 10.1021/ja9000129 Supporting Info |
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A Double Charge Density Wave in the Single Tellurium Square Net in Cu0.63EuTe2? Christos D. Malliakas and Mercouri G. Kanatzidis pp 6896–6897 DOI: 10.1021/ja900091f Supporting Info |
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Ruthenium-Catalyzed Carbonylation at Ortho C−H Bonds in Aromatic Amides Leading to Phthalimides: C−H Bond Activation Utilizing a Bidentate System Satoshi Inoue, Hirotaka Shiota, Yoshiya Fukumoto and Naoto Chatani pp 6898–6899 DOI: 10.1021/ja900046z Supporting Info |
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Bifunctional Acyltransferase/Decarboxylase LnmK as the Missing Link for β-Alkylation in Polyketide Biosynthesis Tao Liu, Yong Huang and Ben Shen pp 6900–6901 DOI: 10.1021/ja9012134 Supporting Info |
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On Catalysis by Ionic Liquids Asit K. Chakraborti and Sudipta Raha Roy pp 6902–6903 DOI: 10.1021/ja900076a Supporting Info |
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Amino-Indanol Catalyzed Enantioselective Reactions of 3-Hydroxy-2-Pyridones Julian Ying-Teck Soh and Choon-Hong Tan pp 6904–6905 DOI: 10.1021/ja900582a Supporting Info |
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Highly Diastereoselective Formal Nucleophilic Substitution of Bromocyclopropanes Bassam K. Alnasleh, William M. Sherrill, Marina Rubina, Joseph Banning and Michael Rubin pp 6906–6907 DOI: 10.1021/ja900634m Supporting Info |
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Enantiomerization Dynamics and a Catalytic Dynamic Resolution of N-Trimethylallyl-2-lithiopyrrolidine Timothy K. Beng, Taher I. Yousaf, Iain Coldham and Robert E. Gawley pp 6908–6909 DOI: 10.1021/ja900755a Supporting Info |
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High Performance Zeolite LTA Pervaporation Membranes on Ceramic Hollow Fibers by Dipcoating−Wiping Seed Deposition Zhengbao Wang, Qinqin Ge, Jia Shao and Yushan Yan pp 6910–6911 DOI: 10.1021/ja901626d Supporting Info |
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Room-Temperature Reaction of Carbon Monoxide with a Stable Diarylgermylene Xinping Wang, Zhongliang Zhu, Yang Peng, Hao Lei, James C. Fettinger and Philip P. Power pp 6912–6913 DOI: 10.1021/ja9017286 Supporting Info |
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Universal (Switchable) RAFT Agents Massimo Benaglia, John Chiefari, Yen K. Chong, Graeme Moad, Ezio Rizzardo and San H. Thang pp 6914–6915 DOI: 10.1021/ja901955n Supporting Info |
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Enantioselective Carbonyl Reverse Prenylation from the Alcohol or Aldehyde Oxidation Level Employing 1,1-Dimethylallene as the Prenyl Donor Soo Bong Han, In Su Kim, Hoon Han and Michael J. Krische pp 6916–6917 DOI: 10.1021/ja902437k Supporting Info |
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A Chiral 60-Metal Sodalite Cage Featuring 24 Vertex-Sharing [Er4(μ3-OH)4] Cubanes Xiang-Jian Kong, Yinglan Wu, La-Sheng Long, Lan-Sun Zheng and Zhiping Zheng pp 6918–6919 DOI: 10.1021/ja901214d Supporting Info |
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Self-Organizing Functional Materials via Ionic Self Assembly: Porphyrins H- and J-Aggregates on Synthetic Chrysotile Nanotubes Giovanna De Luca, Andrea Romeo, Valentina Villari, Norberto Micali, Ismaela Foltran, Elisabetta Foresti, Isidoro G. Lesci, Norberto Roveri, Tommaso Zuccheri and Luigi Mons pp 6920–6921 DOI: 10.1021/ja901273h Supporting Info |
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Carbon Nanotube Growth from Diamond Daisuke Takagi, Yoshihiro Kobayashi and Yoshikazu Homma pp 6922–6923 DOI: 10.1021/ja901295j Supporting Info |
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PtMo Alloy and MoOx@Pt Core−Shell Nanoparticles as Highly CO-Tolerant Electrocatalysts Zhufang Liu, Jenny E. Hu, Qi Wang, Karen Gaskell, Anatoly I. Frenkel, Gregory S. Jackson and Bryan Eichhorn pp 6924–6925 DOI: 10.1021/ja901303d Supporting Info |
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Different Reaction Mechanisms for Mesophilic and Thermophilic Dihydrofolate Reductases E. Joel Loveridge, Enas M. Behiry, Richard S. Swanwick and Rudolf K. Allemann pp 6926–6927 DOI: 10.1021/ja901441k Supporting Info |
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A Cysteine-Based Tripodal Chelator with a High Affinity and Selectivity for Copper(I) Ana pp 6928–6929 DOI: 10.1021/ja901700a Supporting Info |
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Facile Synthesis of Pd−Cd Nanostructures with High Capacity for Hydrogen Storage Brian D. Adams, Guosheng Wu, Samantha Nigro and Aicheng Chen pp 6930–6931 DOI: 10.1021/ja901798u Supporting Info |
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Rh-Catalyzed Intramolecular Olefin Hydroacylation: Enantioselective Synthesis of Seven- and Eight-Membered Heterocycles Matthew M. Coulter, Peter K. Dornan and Vy M. Dong pp 6932–6933 DOI: 10.1021/ja901915u Supporting Info |
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Crystal-to-Crystal Transformation from Antiferromagnetic Chains into a Ferromagnetic Diamondoid Framework Zhiming Duan, Yan Zhang, Bin Zhang and Daoben Zhu pp 6934–6935 DOI: 10.1021/ja902101x Supporting Info |
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Cobalt−Oxo Core of a Water-Oxidizing Catalyst Film M. Risch, V. Khare, I. Zaharieva, L. Gerencser, P. Chernev and H. Dau pp 6936–6937 DOI: 10.1021/ja902121f Supporting Info |
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Electrostatic Redesign of the [Myoglobin, Cytochrome b5] Interface To Create a Well-Defined Docked Complex with Rapid Interprotein Electron Transfer Peng Xiong, Judith M. Nocek, Amanda K. K. Griffin, Jingyun Wang and Brian M. Hoffman pp 6938–6939 DOI: 10.1021/ja902131d |
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Mutations in the FMN Domain Modulate MCD Spectra of the Heme Site in the Oxygenase Domain of Inducible Nitric Oxide Synthase Joseph Sempombe, Bradley O. Elmore, Xi Sun, Andrea Dupont, Dipak K. Ghosh, J. Guy Guillemette, Martin L. Kirk and Changjian Feng pp 6940–6941 DOI: 10.1021/ja902141v Supporting Info |
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Nickel−Iron Dithiolato Hydrides Relevant to the [NiFe]-Hydrogenase Active Site Bryan E. Barton, C. Matthew Whaley, Thomas B. Rauchfuss and Danielle L. Gray pp 6942–6943 DOI: 10.1021/ja902570u Supporting Info |
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High Specificity, Electrochemical Sandwich Assays Based on Single Aptamer Sequences and Suitable for the Direct Detection of Small-Molecule Targets in Blood and Other Complex Matrices Xiaolei Zuo, Yi Xiao and Kevin W. Plaxco pp 6944–6945 DOI: 10.1021/ja901315w Supporting Info |
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Enantioselective Synthesis of SM-130686 Based on the Development of Asymmetric Cu(I)F Catalysis To Access 2-Oxindoles Containing a Tetrasubstituted Carbon Daisuke Tomita, Kenzo Yamatsugu, Motomu Kanai and Masakatsu Shibasaki pp 6946–6948 DOI: 10.1021/ja901995a Supporting Info |
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Sandwich Complexes of the Metalloaromatic η3-Al3R3 Ligand Jose M. Mercero, Mario Piris, Jon M. Matxain, Xabier Lopez and Jesus M. Ugalde pp 6949–6951 DOI: 10.1021/ja8095043 Supporting Info |
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Atomic-Level Mapping of Antibody Epitopes on a GPCR Cheryl Paes, Jada Ingalls, Karan Kampani, Chidananda Sulli, Esha Kakkar, Meredith Murray, Valery Kotelnikov, Tiffani A. Greene, Joseph B. Rucker and Benjamin J. Doranz pp 6952–6954 DOI: 10.1021/ja900186n Supporting Info |
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An Electrochemical Sensor for the Detection of Protein−Small Molecule Interactions Directly in Serum and Other Complex Matrices Kevin J. Cash, Francesco Ricci and Kevin W. Plaxco pp 6955–6957 DOI: 10.1021/ja9011595 Supporting Info |
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Polymerization of Phenylacetylene by Rhodium Complexes within a Discrete Space of apo-Ferritin Satoshi Abe, Kunio Hirata, Takafumi Ueno, Kazuhide Morino, Nobutaka Shimizu, Masaki Yamamoto, Masaki Takata, Eiji Yashima and Yoshihito Watanabe pp 6958–6960 DOI: 10.1021/ja901234j Supporting Info |
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A General Solution for Unstable Boronic Acids: Slow-Release Cross-Coupling from Air-Stable MIDA Boronates David M. Knapp, Eric P. Gillis and Martin D. Burke pp 6961–6963 DOI: 10.1021/ja901416p Supporting Info |
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Metastable Supramolecular Polymer Nanoparticles via Intramolecular Collapse of Single Polymer Chains E. Johan Foster, Erik B. Berda and E. W. Meijer pp 6964–6966 DOI: 10.1021/ja901687d Supporting Info |
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Metal−Brønsted Acid Cooperative Catalysis for Asymmetric Reductive Amination Chaoqun Li, Barbara Villa-Marcos and Jianliang Xiao pp 6967–6969 DOI: 10.1021/ja9021683 Supporting Info |
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TfNH2 as Achiral Hydrogen-Bond Donor Additive to Enhance the Selectivity of a Transition Metal Catalyzed Reaction. Highly Enantio- and Diastereoselective Rhodium-Catalyzed Cyclopropanation of Alkenes Using α-Cyano Diazoacetamide David Marcoux, Soula Azzi and Andr pp 6970–6972 DOI: 10.1021/ja902205f Supporting Info |
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Increased Dispersion of Supported Gold during Methanol Carbonylation Conditions Alexandre Goguet, Christopher Hardacre, Ian Harvey, Katabathini Narasimharao, Youssef Saih and Jacinto Sa pp 6973–6975 DOI: 10.1021/ja9021705 Supporting Info |
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Polymorphs and Colors of Polydiacetylenes: A First Principles Study Jean-S pp 6976–6988 DOI: 10.1021/ja803768u Supporting Info |
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Inhibition of Human Sirtuins by in Situ Generation of an Acetylated Lysine−ADP−Ribose Conjugate Tomomi Asaba, Takayoshi Suzuki, Rie Ueda, Hiroki Tsumoto, Hidehiko Nakagawa and Naoki Miyata pp 6989–6996 DOI: 10.1021/ja807083y Supporting Info |
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Hydrogen-Bond-Assisted Epoxidation of Homoallylic and Allylic Alcohols with Hydrogen Peroxide Catalyzed by Selenium-Containing Dinuclear Peroxotungstate Keigo Kamata, Tomohisa Hirano, Shinjiro Kuzuya and Noritaka Mizuno pp 6997–7004 DOI: 10.1021/ja901289r Supporting Info |
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Sulfur versus Oxygen Reactivity of Organic Molecules at the Ge(100)-2×1 Surface Jessica S. Kachian and Stacey F. Bent pp 7005–7015 DOI: 10.1021/ja808066t Supporting Info |
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High Hydrogen Storage Capacity of Porous Carbons Prepared by Using Activated Carbon Huanlei Wang, Qiuming Gao and Juan Hu pp 7016–7022 DOI: 10.1021/ja8083225 Supporting Info |
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Staphylococcus aureus Peptidoglycan Tertiary Structure from Carbon-13 Spin Diffusion Shasad Sharif, Manmilan Singh, Sung Joon Kim and Jacob Schaefer pp 7023–7030 DOI: 10.1021/ja808971c |
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Local Membrane Mechanics of Pore-Spanning Bilayers Ingo Mey, Milena Stephan, Eva K. Schmitt, Martin Michael M pp 7031–7039 DOI: 10.1021/ja809165h Supporting Info |
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The Emergence of Nonbulk Properties in Supported Metal Clusters: Negative Thermal Expansion and Atomic Disorder in Pt Nanoclusters Supported on γ-Al2O3 Sergio I. Sanchez, Laurent D. Menard, Ariella Bram, Joo H. Kang, Matthew W. Small, Ralph G. Nuzzo and Anatoly I. Frenkel pp 7040–7054 DOI: 10.1021/ja809182v Supporting Info |
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The Relationship between Nanoscale Architecture and Charge Transport in Conjugated Nanocrystals Bridged by Multichromophoric Polymers Reza Dabirian, Vincenzo Palermo, Andrea Liscio, Erik Schwartz, Matthijs B. J. Otten, Chris E. Finlayson, Emanuele Treossi, Richard H. Friend, Gianluca Calestani, Klaus M pp 7055–7063 DOI: 10.1021/ja809731e Supporting Info |
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Long-Distance Proton Transfer with a Break in the Bacteriorhodopsin Active Site Prasad Phatak, Jan S. Fr pp 7064–7078 DOI: 10.1021/ja809767v Supporting Info |
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Association of Highly Compact Type II Diabetes Related Islet Amyloid Polypeptide Intermediate Species at Physiological Temperature Revealed by Diffusion NMR Spectroscopy Ronald Soong, Jeffrey R. Brender, Peter M. Macdonald and Ayyalusamy Ramamoorthy pp 7079–7085 DOI: 10.1021/ja900285z |
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Effect of Electronic Structures of Au Clusters Stabilized by Poly(N-vinyl-2-pyrrolidone) on Aerobic Oxidation Catalysis Hironori Tsunoyama, Nobuyuki Ichikuni, Hidehiro Sakurai and Tatsuya Tsukuda pp 7086–7093 DOI: 10.1021/ja810045y Supporting Info |
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Theoretical Analysis of the Unusual Temperature Dependence of the Kinetic Isotope Effect in Quinol Oxidation Michelle K. Ludlow, Alexander V. Soudackov and Sharon Hammes-Schiffer pp 7094–7102 DOI: 10.1021/ja9001184 Supporting Info |
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Role of Covalent Defects on Phonon Softening in Metallic Carbon Nanotubes Khoi T. Nguyen and Moonsub Shim pp 7103–7106 DOI: 10.1021/ja900461m Supporting Info |
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Enhancing Protein Stability by Adsorption onto Raftlike Lipid Domains Jeffrey Litt, Chakradhar Padala, Prashanth Asuri, Srinavya Vutukuru, Krishna Athmakuri, Sanat Kumar, Jonathan Dordick and Ravi S. Kane pp 7107–7111 DOI: 10.1021/ja9005282 |
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Structure and Property Correlations in Heavy Atom Radical Conductors Alicea A. Leitch, Xueyang Yu, Stephen M. Winter, Richard A. Secco, Paul A. Dube and Richard T. Oakley pp 7112–7125 DOI: 10.1021/ja900853t Supporting Info |
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Acid−Base Actuation of [c2]Daisy Chains Lei Fang, Mohamad Hmadeh, Jishan Wu, Mark A. Olson, Jason M. Spruell, Ali Trabolsi, Ying-Wei Yang, Mourad Elhabiri, Anne-Marie Albrecht-Gary and J. Fraser Stoddart pp 7126–7134 DOI: 10.1021/ja900859d Supporting Info |
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Photogelling Colloidal Dispersions Based on Light-Activated Assembly of Nanoparticles Kunshan Sun, Rakesh Kumar, Daniel E. Falvey and Srinivasa R. Raghavan pp 7135–7141 DOI: 10.1021/ja9008584 Supporting Info |
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Solution and Fluorescence Properties of Symmetric Dipicolylamine-Containing Dichlorofluorescein-Based Zn2+ Sensors Brian A. Wong, Simone Friedle and Stephen J. Lippard pp 7142–7152 DOI: 10.1021/ja900980u Supporting Info |
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Target-Directed Organocatalysis: A Direct Asymmetric Catalytic Approach to Chiral Propargylic and Allylic Fluorides Hao Jiang, Aurelia Falcicchio, Kim L. Jensen, M pp 7153–7157 DOI: 10.1021/ja901459z Supporting Info |
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Charge Conduction and Breakdown Mechanisms in Self-Assembled Nanodielectrics Sara A. DiBenedetto, Antonio Facchetti, Mark A. Ratner and Tobin J. Marks pp 7158–7168 DOI: 10.1021/ja9013166 Supporting Info |
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High-Pressure (up to 10.7 GPa) Crystal Structure of Single-Component Molecular Metal [Au(tmdt)2] Yoshinori Okano, Biao Zhou, Hishashi Tanaka, Takafumi Adachi, Yasuo Ohishi, Masaki Takata, Shinobu Aoyagi, Eiji Nishibori, Makoto Sakata, Akiko Kobayashi and Hayao Kobayashi pp 7169–7174 DOI: 10.1021/ja9010018 Supporting Info |
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Solution-Phase Synthesis of Pyrrole−Imidazole Polyamides David M. Chenoweth, Daniel A. Harki and Peter B. Dervan pp 7175–7181 DOI: 10.1021/ja901307m Supporting Info |
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Cyclic Pyrrole−Imidazole Polyamides Targeted to the Androgen Response Element David M. Chenoweth, Daniel A. Harki, John W. Phillips, Christian Dose and Peter B. Dervan pp 7182–7188 DOI: 10.1021/ja901309z Supporting Info |
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Spin Trapping of Au−H Intermediate in the Alcohol Oxidation by Supported and Unsupported Gold Catalysts Marco Conte, Hiroyuki Miyamura, Sh pp 7189–7196 DOI: 10.1021/ja809883c Supporting Info |
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On the Origin of the Cobalt Particle Size Effects in Fischer−Tropsch Catalysis J. P. den Breejen, P. B. Radstake, G. L. Bezemer, J. H. Bitter, V. Frøseth, A. Holmen and K. P. de Jong pp 7197–7203 DOI: 10.1021/ja901006x Supporting Info |
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Organic Reactions, Volume 73 p 7204 DOI: 10.1021/ja902746e |
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Practical Microwave Synthesis for Organic Chemists: Strategies, Instruments, and Protocols p 7204 DOI: 10.1021/ja902635q |
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Polymer Grafting and Crosslinking p 7204 DOI: 10.1021/ja902814m |
Issue 21
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Phthalimide-Based Polymers for High Performance Organic Thin-Film Transistors Xugang Guo, Felix Sunjoo Kim, Samson A. Jenekhe and Mark D. Watson pp 7206–7207 DOI: 10.1021/ja810050y Supporting Info |
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Resolution/Deracemization of Chiral α-Amino Acids Using Resolving Reagents with Flexible Stereogenic Centers Vadim A. Soloshonok, Trevor K. Ellis, Hisanori Ueki and Taizo Ono pp 7208–7209 DOI: 10.1021/ja9026055 Supporting Info |
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Coordination-Assisted Assembly of 1-D Nanostructured Light-Harvesting Antenna Xuanjun Zhang, Zhi-Kuan Chen and Kian Ping Loh pp 7210–7211 DOI: 10.1021/ja901041d Supporting Info |
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Enantioselective Synthesis of Chiral Allenoates by Guanidine-Catalyzed Isomerization of 3-Alkynoates Hongjun Liu, Dasheng Leow, Kuo-Wei Huang and Choon-Hong Tan pp 7212–7213 DOI: 10.1021/ja901528b Supporting Info |
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Selective Reductions of Cyclic 1,3-Diesters Using SmI2 and H2O Giuditta Guazzelli, Sara De Grazia, Karl D. Collins, Hiroshi Matsubara, Malcolm Spain and David J. Procter pp 7214–7215 DOI: 10.1021/ja901715d Supporting Info |
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Catalyst-free Preparation of Melamine-Based Microporous Polymer Networks through Schiff Base Chemistry Matthias Georg Schwab, Birgit Fassbender, Hans Wolfgang Spiess, Arne Thomas, Xinliang Feng and Klaus M pp 7216–7217 DOI: 10.1021/ja902116f Supporting Info |
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Synthetic Haggite V4O6(OH)4 Nanobelts: Oxyhydroxide as a New Catalog of Smart Electrical Switch Materials Changzheng Wu, Jun Dai, Xiaodong Zhang, Jinlong Yang and Yi Xie pp 7218–7219 DOI: 10.1021/ja9020217 Supporting Info |
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Thiolate-Protected Au20 Clusters with a Large Energy Gap of 2.1 eV Manzhou Zhu, Huifeng Qian and Rongchao Jin pp 7220–7221 DOI: 10.1021/ja902208h Supporting Info |
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Use of Protonless NMR Spectroscopy To Alleviate the Loss of Information Resulting from Exchange-Broadening Shang-Te Danny Hsu, Carlos W. Bertoncini and Christopher M. Dobson pp 7222–7223 DOI: 10.1021/ja902307q Supporting Info |
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Organocopper(II) Complex of 21-Diphenylphosphoryl-Carbaporpholactone Hybrid: A Side-On Coordination Mode of Copper(II) Norbert Grzegorzek, Miłosz Pawlicki, Ludmiła Szterenberg and Lechosław Latos-Gra pp 7224–7225 DOI: 10.1021/ja902310n Supporting Info |
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A Dictionary for Protein Side-Chain Entropies from NMR Order Parameters Da-Wei Li and Rafael Br pp 7226–7227 DOI: 10.1021/ja902477s Supporting Info |
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The Allyl Intermediate in Regioselective and Enantioselective Iridium-Catalyzed Asymmetric Allylic Substitution Reactions Sherzod T. Madrahimov, Dean Markovic and John F. Hartwig pp 7228–7229 DOI: 10.1021/ja902609g Supporting Info |
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Chiral Crown Conformation of Rh2(S-PTTL)4: Enantioselective Cyclopropanation with α-Alkyl-α-diazoesters Andrew DeAngelis, Olga Dmitrenko, Glenn P. A. Yap and Joseph M. Fox pp 7230–7231 DOI: 10.1021/ja9026852 Supporting Info |
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Diketiminate Silicon(II) and Related NHSi Ligands Generated in the Coordination Sphere of Nickel(0) Antje Meltzer, Carsten Pr pp 7232–7233 DOI: 10.1021/ja9026727 Supporting Info |
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The Millisecond Intermediate in the Reaction of Nitric Oxide with Oxymyoglobin is an Iron(III)−Nitrato Complex, Not a Peroxynitrite Erik T. Yukl, Simon de Vries and Pierre Mo pp 7234–7235 DOI: 10.1021/ja9026924 Supporting Info |
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Binuclear Intermediates in Oxidation Reactions: [(Me3SiC≡C)Me2(bipy)Pt−PtMe2(bipy)]+ in the Oxidation of PtIIMe2(bipy) (bipy = 2,2′-Bipyridine) by IPh(C≡CSiMe3)(OTf) (OTf = Triflate) Allan J. Canty, Michael G. Gardiner, Roderick C. Jones, Thomas Rodemann and Manab Sharma pp 7236–7237 DOI: 10.1021/ja902799u Supporting Info |
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Cleavage of C−N Bonds in Aniline Derivatives on a Ruthenium Center and Its Relevance to Catalytic C−C Bond Formation Tetsuro Koreeda, Takuya Kochi and Fumitoshi Kakiuchi pp 7238–7239 DOI: 10.1021/ja902829p Supporting Info |
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Facile Formation of a Benzopyrane-Fused [28]Hexaphyrin That Exhibits Distinct M Sumito Tokuji, Jae-Yoon Shin, Kil Suk Kim, Jong Min Lim, Katsuyuki Youfu, Shohei Saito, Dongho Kim and Atsuhiro Osuka pp 7240–7241 DOI: 10.1021/ja902836x Supporting Info |
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Chiral Arylaminophosphonium Barfates as a New Class of Charged Brønsted Acid for the Enantioselective Activation of Nonionic Lewis Bases Daisuke Uraguchi, Daisuke Nakashima and Takashi Ooi pp 7242–7243 DOI: 10.1021/ja903271t Supporting Info |
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Nature of Amide Carbonyl−Carbonyl Interactions in Proteins Amit Choudhary, Deepa Gandla, Grant R. Krow and Ronald T. Raines pp 7244–7246 DOI: 10.1021/ja901188y Supporting Info |
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Topochemical Limits for Solid-State Photoreactivity by Fine Tuning of the π−π Interactions Shi-Yao Yang, Pan pp 7247–7249 DOI: 10.1021/ja902094b Supporting Info |
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Tuning the Rate of Molecular Translocation Bao-Yu Wang, Stephen Rieth and Jovica D Badji pp 7250–7252 DOI: 10.1021/ja9023868 Supporting Info |
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Efficient C−B Bond Formation Promoted by N-Heterocyclic Carbenes: Synthesis of Tertiary and Quaternary B-Substituted Carbons through Metal-Free Catalytic Boron Conjugate Additions to Cyclic and Acyclic α,β-Unsaturated Carbonyls Kang-sang Lee, Adil R. Zhugralin and Amir H. Hoveyda pp 7253–7255 DOI: 10.1021/ja902889s Supporting Info |
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Ultrafast Photodissociation Dynamics of a Hexaarylbiimidazole Derivative with Pyrenyl Groups: Dispersive Reaction from Femtosecond to 10 ns Time Regions Hiroshi Miyasaka, Yusuke Satoh, Yukihide Ishibashi, Syoji Ito, Yutaka Nagasawa, Seiji Taniguchi, Haik Chosrowjan, Noboru Mataga, Daisuke Kato, Azusa Kikuchi and Jiro Abe pp 7256–7263 DOI: 10.1021/ja809195s Supporting Info |
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Auger Electron Spectroscopy as a Probe of the Solution of Aqueous Ions Wandared Pokapanich, Henrik Bergersen, Ioana L. Bradeanu, Ricardo R. T. Marinho, Andreas Lindblad, Sebastien Legendre, Aldana Rosso, Svante Svensson, Olle Bj pp 7264–7271 DOI: 10.1021/ja8096866 Supporting Info |
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Solid-State and Solution Rearrangements of F3S≡NXeF+ Leading to the F4S═NXe+ Cation; Syntheses, HF Solvolyses, and Structural Characterizations of [F4S═NXe][AsF6] and [F4S═NH2][AsF6] Gregory L. Smith, H pp 7272–7286 DOI: 10.1021/ja901187n Supporting Info |
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Noncovalently Netted, Photoconductive Sheets with Extremely High Carrier Mobility and Conduction Anisotropy from Triphenylene-Fused Metal Trigon Conjugates Long Chen, Jangbae Kim, Tomoya Ishizuka, Yoshihito Honsho, Akinori Saeki, Shu Seki, Hyotcherl Ihee and Donglin Jiang pp 7287–7292 DOI: 10.1021/ja901357h Supporting Info |
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Multifunctional Prenylated Peptides for Live Cell Analysis James W. Wollack, Nicholette A. Zeliadt, Daniel G. Mullen, Gregg Amundson, Suzanne Geier, Stacy Falkum, Elizabeth V. Wattenberg, George Barany and Mark D. Distefano pp 7293–7303 DOI: 10.1021/ja805174z Supporting Info |
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Collagen Targeting Using Protein-Functionalized Micelles: The Strength of Multiple Weak Interactions Sanne W. A. Reulen, Patricia Y. W. Dankers, Paul H. H. Bomans, E. W. Meijer and Maarten Merkx pp 7304–7312 DOI: 10.1021/ja807723p Supporting Info |
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Conformational Changes of Channelrhodopsin-2 Ionela Radu, Christian Bamann, Melanie Nack, Georg Nagel, Ernst Bamberg and Joachim Heberle pp 7313–7319 DOI: 10.1021/ja8084274 |
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Mixing and Matching Detergents for Membrane Protein NMR Structure Determination Linda Columbus, Jan Lipfert, Kalyani Jambunathan, Daniel A. Fox, Adelene Y. L. Sim, Sebastian Doniach and Scott A. Lesley pp 7320–7326 DOI: 10.1021/ja808776j Supporting Info |
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General Synthetic Route to Cell-Permeable Block Copolymers via ROMP Erin M. Kolonko, Jason K. Pontrello, Shane L. Mangold and Laura L. Kiessling pp 7327–7333 DOI: 10.1021/ja809284s Supporting Info |
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Directed Evolution of an Enantioselective Epoxide Hydrolase: Uncovering the Source of Enantioselectivity at Each Evolutionary Stage Manfred T. Reetz, Marco Bocola, Li-Wen Wang, Joaquin Sanchis, Annette Cronin, Michael Arand, Jinyu Zou, Alain Archelas, Anne-Lise Bottalla, Agata Naworyta and Sherry L. Mowbray pp 7334–7343 DOI: 10.1021/ja809673d Supporting Info |
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Selective Scanning Tunnelling Microscope Electron-Induced Reactions of Single Biphenyl Molecules on a Si(100) Surface Damien Riedel, Marie-Laure Bocquet, Herv pp 7344–7352 DOI: 10.1021/ja8101133 |
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Inhibition of γ-Secretase Activity by Helical β-Peptide Foldamers Yuki Imamura, Naoto Watanabe, Naoki Umezawa, Takeshi Iwatsubo, Nobuki Kato, Taisuke Tomita and Tsunehiko Higuchi pp 7353–7359 DOI: 10.1021/ja9001458 Supporting Info |
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Aromatic versus Antiaromatic Effect on Photophysical Properties of Conformationally Locked trans-Vinylene-Bridged Hexaphyrins Min-Chul Yoon, Sung Cho, Masaaki Suzuki, Atsuhiro Osuka and Dongho Kim pp 7360–7367 DOI: 10.1021/ja9000536 Supporting Info |
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Ultrasensitive Surface Plasmon Resonance Detection of Trinitrotoluene by a Bis-aniline-Cross-Linked Au Nanoparticles Composite Michael Riskin, Ran Tel-Vered, Oleg Lioubashevski and Itamar Willner pp 7368–7378 DOI: 10.1021/ja9001212 Supporting Info |
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Design of α-Transglucosidases of Controlled Specificity for Programmed Chemoenzymatic Synthesis of Antigenic Oligosaccharides Elise Champion, Isabelle Andr pp 7379–7389 DOI: 10.1021/ja900183h Supporting Info |
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Multiple Independent Binding Sites for Small-Molecule Inhibitors on the Oncoprotein c-Myc Dalia I. Hammoudeh, Ariele Viacava Follis, Edward V. Prochownik and Steven J. Metallo pp 7390–7401 DOI: 10.1021/ja900616b Supporting Info |
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Recognition and Organocatalysis with a Synthetic Cavitand Receptor Fernando R. Pinacho Cris pp 7402–7410 DOI: 10.1021/ja900766b Supporting Info |
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Halogen Photoreductive Elimination from Gold(III) Centers Thomas S. Teets and Daniel G. Nocera pp 7411–7420 DOI: 10.1021/ja9009937 Supporting Info |
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X-ray Crystal Analysis of a TASP: Structural Insights of a Cavitein Dimer Jon O. Freeman, Woo Cheol Lee, Michael E. P. Murphy and John C. Sherman pp 7421–7429 DOI: 10.1021/ja901404w Supporting Info |
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Nonamphiphilic Assembly in Water: Polymorphic Nature, Thread Structure, and Thermodynamic Incompatibility Lei Wu, Jyotsana Lal, Karen A. Simon, Erik A. Burton and Yan-Yeung Luk pp 7430–7443 DOI: 10.1021/ja9015149 Supporting Info |
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Hydrazine Borane: A Promising Hydrogen Storage Material Thomas H pp 7444–7446 DOI: 10.1021/ja9013437 |
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Molecular Recognition on a Cavitand-Functionalized Silicon Surface Elisa Biavardi, Maria Favazza, Alessandro Motta, Ignazio L. Fragalà, Chiara Massera, Luca Prodi, Marco Montalti, Monica Melegari, Guglielmo G. Condorelli and Enrico Dalcanale pp 7447–7455 DOI: 10.1021/ja901678b Supporting Info |
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Highly Ordered Self-Assembly of 1D Nanoparticles in Phospholipids Driven by Curvature and Electrostatic Interaction Tae-Hwan Kim, Shin-Hyun Kang, Changwoo Doe, Jihyun Yu, Jun-Bo Sim, Jehan Kim, Steven R. Kline and Sung-Min Choi pp 7456–7460 DOI: 10.1021/ja901810n Supporting Info |
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A New Perovskite Polytype in the High-Pressure Sequence of BaIrO3 Jin-Guang Cheng, Jos pp 7461–7469 DOI: 10.1021/ja901829e |
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Probing the Folding Transition State Structure of the Villin Headpiece Subdomain via Side Chain and Backbone Mutagenesis Michelle R. Bunagan, Jianmin Gao, Jeffery W. Kelly and Feng Gai pp 7470–7476 DOI: 10.1021/ja901860f Supporting Info |
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Silicon-Containing Dendritic Polymers Mario Gauthier p 7477 DOI: 10.1021/ja9032346 |
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Miniaturization and Mass Spectrometry Evan L. Neidholdt p 7477 DOI: 10.1021/ja903225m |
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Electrochemistry at the Nanoscale Cynthia G. Zoski pp 7477–7478 DOI: 10.1021/ja903285q |
Issue 22
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SERS Not To Be Taken for Granted in the Presence of Oxygen Melek Erol, Yun Han, Scott K. Stanley, Christopher M. Stafford, Henry Du and Svetlana Sukhishvili pp 7480–7481 DOI: 10.1021/ja807458x Supporting Info |
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Reversible Formation and Dissolution of Gold Nanoparticles through Turning On and Off Sequences of UV Light Ki-Hyun Kim, Jong-Uk Kim, Sang-Ho Cha and Jong-Chan Lee pp 7482–7483 DOI: 10.1021/ja8088394 Supporting Info |
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Membrane Proteins Solubilized Intact in Lipid Containing Nanoparticles Bounded by Styrene Maleic Acid Copolymer Timothy J. Knowles, Rachael Finka, Corinne Smith, Yu-Pin Lin, Tim Dafforn and Michael Overduin pp 7484–7485 DOI: 10.1021/ja810046q Supporting Info |
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Synthesis of Unique Ultrathin Lamellar Mesostructured CoSe2−Amine (Protonated) Nanobelts in a Binary Solution Min-Rui Gao, Wei-Tang Yao, Hong-Bin Yao and Shu-Hong Yu pp 7486–7487 DOI: 10.1021/ja900506x Supporting Info |
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Photoinduced Nitric Oxide Release from a Hindered Nitrobenzene Derivative by Two-Photon Excitation Kazuhiro Hishikawa, Hidehiko Nakagawa, Toshiaki Furuta, Kiyoshi Fukuhara, Hiroki Tsumoto, Takayoshi Suzuki and Naoki Miyata pp 7488–7489 DOI: 10.1021/ja8093668 Supporting Info |
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Explanation of the Colossal Detonation Sensitivity of Silicon Pentaerythritol Tetranitrate (Si-PETN) Explosive Wei-Guang Liu, Sergey V. Zybin, Siddharth Dasgupta, Thomas M. Klap pp 7490–7491 DOI: 10.1021/ja809725p Supporting Info |
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Coupling of the R−Cp or Indenyl Ligand with the Diene Moiety of Bis(substituted cyclopentadienyl)- or Bis(indenyl)zirconacyclopentadienes Shenyong Ren, Eri Igarashi, Kiyohiko Nakajima, Ken-ichiro Kanno and Tamotsu Takahashi pp 7492–7493 DOI: 10.1021/ja809401s Supporting Info |
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Nickel-Catalyzed Decarboxylative Carboamination of Alkynes with Isatoic Anhydrides Yasufumi Yoshino, Takuya Kurahashi and Seijiro Matsubara pp 7494–7495 DOI: 10.1021/ja900805y Supporting Info |
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Redox-Linked Structural Changes in Ribonucleotide Reductase A. R. Offenbacher, I. R. Vassiliev, M. R. Seyedsayamdost, J. Stubbe and B. A. Barry pp 7496–7497 DOI: 10.1021/ja901908j Supporting Info |
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Diffusion Coefficients of Biomolecules Using Long-Lived Spin States Puneet Ahuja, Riddhiman Sarkar, Paul R. Vasos and Geoffrey Bodenhausen pp 7498–7499 DOI: 10.1021/ja902030k |
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Robust NMR Screening for Lead Compounds Using Tryptophan-Containing Proteins Michal Bista, Kaja Kowalska, Weronika Janczyk, Alexander D pp 7500–7501 DOI: 10.1021/ja901863h Supporting Info |
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Easily Attachable and Detachable ortho-Directing Agent for Arylboronic Acids in Ruthenium-Catalyzed Aromatic C−H Silylation Hideki Ihara and Michinori Suginome pp 7502–7503 DOI: 10.1021/ja902314v Supporting Info |
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Cyclization of Cross-Conjugated Trienes: The Vinylogous Nazarov Reaction Curtis J. Rieder, Karl J. Winberg and F. G. West pp 7504–7505 DOI: 10.1021/ja9023226 Supporting Info |
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Rhodium-Catalyzed Coupling of 2-Silylphenylboronic Acids with Alkynes Leading to Benzosiloles: Catalytic Cleavage of the Carbon−Silicon Bond in Trialkylsilyl Groups Mamoru Tobisu, Masahiro Onoe, Yusuke Kita and Naoto Chatani pp 7506–7507 DOI: 10.1021/ja9022978 Supporting Info |
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Hydrogen Production by a Hyperthermophilic Membrane-Bound Hydrogenase in Water-Soluble Nanolipoprotein Particles Sarah E. Baker, Robert C. Hopkins, Craig D. Blanchette, Vicki L. Walsworth, Rhoda Sumbad, Nicholas O. Fischer, Edward A. Kuhn, Matt Coleman, Brett A. Chromy, Sonia E. L pp 7508–7509 DOI: 10.1021/ja809251f Supporting Info |
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Synthesis and Two-Photon Spectrum of a Bis(Porphyrin)-Substituted Squaraine Susan A. Odom, Scott Webster, Lazaro A. Padilha, Davorin Peceli, Honghua Hu, Gero Nootz, Sung-Jae Chung, Shino Ohira, Jonathan D. Matichak, Olga V. Przhonska, Alexei D. Kachkovski, Stephen Barlow, Jean-Luc Br pp 7510–7511 DOI: 10.1021/ja901244e Supporting Info |
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Evidence that Biosynthesis of the Neurotoxic Alkaloids Anatoxin-a and Homoanatoxin-a in the Cyanobacterium Oscillatoria PCC 6506 Occurs on a Modular Polyketide Synthase Initiated by l-Proline Annick M pp 7512–7513 DOI: 10.1021/ja9024353 Supporting Info |
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Tailoring Structure−Property Relationships in Dithienosilole−Benzothiadiazole Donor−Acceptor Copolymers Pierre M. Beaujuge, Wojciech Pisula, Hoi Nok Tsao, Stefan Ellinger, Klaus M pp 7514–7515 DOI: 10.1021/ja900519k Supporting Info |
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Intensely Colored Mixed-Valence Iron(II) Iron(III) Formate Analogue of Prussian Blue Exhibits N Karl S. Hagen, Sunil G. Naik, Boi Hanh Huynh, Antonio Masello and George Christou pp 7516–7517 DOI: 10.1021/ja901093b Supporting Info |
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Controlling the Number and Positions of Oligonucleotides on Gold Nanoparticle Surfaces Kenji Suzuki, Kazuo Hosokawa and Mizuo Maeda pp 7518–7519 DOI: 10.1021/ja9011386 Supporting Info |
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Versatile Pd(OTf)2·2H2O-Catalyzed ortho-Fluorination Using NMP as a Promoter Xisheng Wang, Tian-Sheng Mei and Jin-Quan Yu pp 7520–7521 DOI: 10.1021/ja901352k Supporting Info |
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Homogeneous Light-Driven Water Oxidation Catalyzed by a Tetraruthenium Complex with All Inorganic Ligands Yurii V. Geletii, Zhuangqun Huang, Yu Hou, Djamaladdin G. Musaev, Tianquan Lian and Craig L. Hill pp 7522–7523 DOI: 10.1021/ja901373m Supporting Info |
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Postsynthetic Modification Switches an Achiral Framework to Catalytically Active Homochiral Metal−Organic Porous Materials Mainak Banerjee, Sunirban Das, Minyoung Yoon, Hee Jung Choi, Myung Ho Hyun, Se Min Park, Gon Seo and Kimoon Kim pp 7524–7525 DOI: 10.1021/ja901440g Supporting Info |
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Porous Multilayer-Coated AFM Tips for Dip-Pen Nanolithography of Proteins Chien-Ching Wu, Huaping Xu, Cees Otto, David N. Reinhoudt, Rob G. H. Lammertink, Jurriaan Huskens, Vinod Subramaniam and Aldrik H. Velders pp 7526–7527 DOI: 10.1021/ja901756a Supporting Info |
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Cyclocarboamination of Alkynes with Aziridines: Synthesis of 2,3-Dihydropyrroles by a Catalyzed Formal [3 + 2] Cycloaddition Paul A. Wender and Daniel Strand pp 7528–7529 DOI: 10.1021/ja901799s Supporting Info |
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Chemically Labeled Nucleotides and Oligonucleotides Encode DNA for Sensing with Nanopores Vinciane Borsenberger, Nick Mitchell and Stefan Howorka pp 7530–7531 DOI: 10.1021/ja902004s Supporting Info |
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Negishi Coupling of Secondary Alkylzinc Halides with Aryl Bromides and Chlorides Chong Han and Stephen L. Buchwald pp 7532–7533 DOI: 10.1021/ja902046m Supporting Info |
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Generation and Trapping of a Terminal Chlorophosphinidene Complex Matthew P. Duffy and Fran pp 7534–7535 DOI: 10.1021/ja901918e Supporting Info |
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Lanthanum(III) Triflate-Catalyzed Cyclopropanation via Intramolecular Methylene Transfer David J. Hardee and Tristan H. Lambert pp 7536–7537 DOI: 10.1021/ja902137z Supporting Info |
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Full Color Stop Bands in Hybrid Organic/Inorganic Block Copolymer Photonic Gels by Swelling−Freezing Changjoon Kang, Eunjoo Kim, Heeyoel Baek, Kyosung Hwang, Dongwoo Kwak, Youngjong Kang and Edwin L. Thomas pp 7538–7539 DOI: 10.1021/ja9021478 Supporting Info |
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Stimuli-Responsive SERS Nanoparticles: Conformational Control of Plasmonic Coupling and Surface Raman Enhancement Ximei Qian, Jun Li and Shuming Nie pp 7540–7541 DOI: 10.1021/ja902226z Supporting Info |
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Synthesis and Oxygen Reduction Electrocatalytic Property of Pt-on-Pd Bimetallic Heteronanostructures Zhenmeng Peng and Hong Yang pp 7542–7543 DOI: 10.1021/ja902256a Supporting Info |
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Aliphatic C−H Bond Oxidation of Toluene Using Copper Peroxo Complexes That Are Stable at Room Temperature Christian W pp 7544–7545 DOI: 10.1021/ja902327s Supporting Info |
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Complex Polycyclic Lactams from Pericyclic Cascade Reactions of Zincke Aldehydes Sarah E. Steinhardt and Christopher D. Vanderwal pp 7546–7547 DOI: 10.1021/ja902439f Supporting Info |
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Phosphopantetheinyl Transferase Catalyzed Site-Specific Protein Labeling with ADP Conjugated Chemical Probes Yekui Zou and Jun Yin pp 7548–7549 DOI: 10.1021/ja902464v Supporting Info |
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Tuning between Mixing and Reactivity in the Ge−Sn System Using Pressure and Temperature Christophe Guillaume, George Serghiou, Andrew Thomson, Jean-Paul Morniroli, Dan J. Frost, Nicholas Odling and Mohamed Mezouar pp 7550–7551 DOI: 10.1021/ja902466w Supporting Info |
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A Tetrachloro Polyketide Hexahydro-1H-isoindolone, Muironolide A, from the Marine Sponge Phorbas sp. Natural Products at the Nanomole Scale Doralyn S. Dalisay, Brandon I. Morinaka, Colin K. Skepper and Tadeusz F. Molinski pp 7552–7553 DOI: 10.1021/ja9024929 Supporting Info |
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CoV2O6 Single Crystals Grown in a Closed Crucible: Unusual Magnetic Behaviors with Large Anisotropy and 1/3 Magnetization Plateau Zhangzhen He, Jun-Ichi Yamaura, Yutaka Ueda and Wendan Cheng pp 7554–7555 DOI: 10.1021/ja902623b |
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A Tubular Biocontainer: Metal Ion-Induced 1D Assembly of a Molecularly Engineered Chaperonin Shuvendu Biswas, Kazushi Kinbara, Nobuhiro Oya, Noriyuki Ishii, Hideki Taguchi and Takuzo Aida pp 7556–7557 DOI: 10.1021/ja902696q Supporting Info |
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Understanding the Differential Performance of Rh2(esp)2 as a Catalyst for C−H Amination David N. Zalatan and J. Du Bois pp 7558–7559 DOI: 10.1021/ja902893u Supporting Info |
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Nazarov Cyclization Initiated by Peracid Oxidation: The Total Synthesis of (±)-Rocaglamide John A. Malona, Kevin Cariou and Alison J. Frontier pp 7560–7561 DOI: 10.1021/ja9029736 Supporting Info |
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An Isolable NHC-Supported Silanone Yun Xiong, Shenglai Yao and Matthias Driess pp 7562–7563 DOI: 10.1021/ja9031049 Supporting Info |
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Low-Energy Networks of the T-Cage (H2O)24 Cluster and Their Use in Constructing Periodic Unit Cells of the Structure I (sI) Hydrate Lattice Soohaeng Yoo, Mikhail V. Kirov and Sotiris S. Xantheas pp 7564–7566 DOI: 10.1021/ja9011222 Supporting Info |
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Electrostatically Mediated Liposome Fusion and Lipid Exchange with a Nanoparticle-Supported Bilayer for Control of Surface Charge, Drug Containment, and Delivery Juewen Liu, Xingmao Jiang, Carlee Ashley and C. Jeffrey Brinker pp 7567–7569 DOI: 10.1021/ja902039y Supporting Info |
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Relative Stereochemistry Determination and Synthesis of the Major Chlorosulfolipid from Ochromonas danica D. Karl Bedke, Grant M. Shibuya, Alban Pereira, William H. Gerwick, Thomas H. Haines and Christopher D. Vanderwal pp 7570–7572 DOI: 10.1021/ja902138w Supporting Info |
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A Simple Analogue of Tumor-Promoting Aplysiatoxin Is an Antineoplastic Agent Rather Than a Tumor Promoter: Development of a Synthetically Accessible Protein Kinase C Activator with Bryostatin-like Activity Yu Nakagawa, Ryo C. Yanagita, Naoko Hamada, Akira Murakami, Hideyuki Takahashi, Naoaki Saito, Hiroshi Nagai and Kazuhiro Irie pp 7573–7579 DOI: 10.1021/ja808447r Supporting Info |
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Effects of Weak Intermolecular Interactions on the Molecular Isomerism of Tricobalt Metal Chains Rasmus D. Poulsen, Jacob Overgaard, Alexander Schulman, Christina Østergaard, Carlos A. Murillo, Mark A. Spackman and Bo B. Iversen pp 7580–7591 DOI: 10.1021/ja8091032 Supporting Info |
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Femtosecond Time-Resolved Stimulated Raman Reveals the Birth of Bacteriorhodopsin’s J and K Intermediates Sangdeok Shim, Jyotishman Dasgupta and Richard A. Mathies pp 7592–7597 DOI: 10.1021/ja809137x Supporting Info |
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Elucidation of the Proton Transport Mechanism in Human Carbonic Anhydrase II C. Mark Maupin, Robert McKenna, David N. Silverman and Gregory A. Voth pp 7598–7608 DOI: 10.1021/ja8091938 Supporting Info |
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Broad-Spectrum Antimicrobial Peptides by Rational Combinatorial Design and High-Throughput Screening: The Importance of Interfacial Activity Ramesh Rathinakumar, William F. Walkenhorst and William C. Wimley pp 7609–7617 DOI: 10.1021/ja8093247 |
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Molecular Dynamics of Water-Mediated Interactions of a Linear Benzimidazole−Biphenyl Diamidine with the DNA Minor Groove Prashanth Athri and W. David Wilson pp 7618–7625 DOI: 10.1021/ja809249h Supporting Info |
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Rapid in Situ Generation of Two Patterned Chemoselective Surface Chemistries from a Single Hydroxy-Terminated Surface Using Controlled Microfluidic Oxidation Abigail Pulsipher, Nathan P. Westcott, Wei Luo and Muhammad N. Yousaf pp 7626–7632 DOI: 10.1021/ja809380e Supporting Info |
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Versatile Coordination of 2-Pyridinetetramethyldisilazane at Ruthenium: Ru(II) vs Ru(IV) As Evidenced by NMR, X-ray, Neutron, and DFT Studies Mary Grellier, Tahra Ayed, Jean-Claude Barthelat, Alberto Albinati, Sax Mason, Laure Vendier, Yannick Coppel and Sylviane Sabo-Etienne pp 7633–7640 DOI: 10.1021/ja901140v Supporting Info |
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Acid-Induced Amino Side-Chain Interactions and Secondary Structure of Solid Poly-l-lysine Probed by 15N and 13C Solid State NMR and ab Initio Model Calculations Alexandra Dos, Volkmar Schimming, Monique Chan Huot and Hans-Heinrich Limbach pp 7641–7653 DOI: 10.1021/ja901082a Supporting Info |
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Temperature-Induced Ordering of Metal/Adsorbate Structures at Electrochemical Interfaces Christopher A. Lucas, Paul Thompson, Michael Cormack, Alexander Brownrigg, Ben Fowler, Dusan Strmcnik, Vojislav Stamenkovic, Jeff Greeley, Andreas Menzel, Hoydoo You and Nenad M. Markovi pp 7654–7661 DOI: 10.1021/ja9014666 |
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Self-Assembly of Dendronized Triphenylenes into Helical Pyramidal Columns and Chiral Spheres Virgil Percec, Mohammad R. Imam, Mihai Peterca, Daniela A. Wilson, Robert Graf, Hans W. Spiess, Venkatachalapathy S. K. Balagurusamy and Paul A. Heiney pp 7662–7677 DOI: 10.1021/ja8094944 Supporting Info |
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Comparative PCET Study of a Donor−Acceptor Pair Linked by Ionized and Nonionized Asymmetric Hydrogen-Bonded Interfaces Elizabeth R. Young, Joel Rosenthal, Justin M. Hodgkiss and Daniel G. Nocera pp 7678–7684 DOI: 10.1021/ja809777j Supporting Info |
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Spectroscopy and Kinetics of Wild-Type and Mutant Tyrosine Hydroxylase: Mechanistic Insight into O2 Activation Marina S. Chow, Bekir E. Eser, Samuel A. Wilson, Keith O. Hodgson, Britt Hedman, Paul F. Fitzpatrick and Edward I. Solomon pp 7685–7698 DOI: 10.1021/ja810080c Supporting Info |
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Comparative Analysis of the Multicenter, Long Bond in [TCNE]·− and Phenalenyl Radical Dimers: A Unified Description of Multicenter, Long Bonds Fernando Mota, Joel S. Miller and Juan J. Novoa pp 7699–7707 DOI: 10.1021/ja9002298 Supporting Info |
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Fluorescence Patterns from Supramolecular Polymer Assembly and Disassembly for Sensing Metallo- and Nonmetalloproteins Daniella C. Gonz pp 7708–7716 DOI: 10.1021/ja900579g Supporting Info |
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Effect of Surface Ligands on Optical and Electronic Spectra of Semiconductor Nanoclusters Svetlana Kilina, Sergei Ivanov and Sergei Tretiak pp 7717–7726 DOI: 10.1021/ja9005749 Supporting Info |
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Photoinduced Charge Transfer and Electrochemical Properties of Triphenylamine Ih-Sc3N@C80 Donor−Acceptor Conjugates Julio R. Pinz pp 7727–7734 DOI: 10.1021/ja900612g Supporting Info |
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Open-Cage Fullerene-like Graphitic Carbons as Catalysts for Oxidative Dehydrogenation of Isobutane Chengdu Liang, Hong Xie, Viviane Schwartz, Jane Howe, Sheng Dai and Steven H. Overbury pp 7735–7741 DOI: 10.1021/ja900888p |
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Conformational Variability of Benzamidinium-Based Inhibitors Xue Li, Xiao He, Bing Wang and Kenneth Merz, Jr. pp 7742–7754 DOI: 10.1021/ja9010833 Supporting Info |
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Rewritable Glycochips L. G. Harris, W. C. E. Schofield, K. J. Doores, B. G. Davis and J. P. S. Badyal pp 7755–7761 DOI: 10.1021/ja901294r Supporting Info |
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Investigation of the Scope and Regiochemistry of Alkynylboronate Cycloadditions with Sydnones Duncan L. Browne, Jérôme F. Vivat, Andrew Plant, Enrique Gomez-Bengoa and Joseph P. A. Harrity pp 7762–7769 DOI: 10.1021/ja902460n Supporting Info |
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Fundamental Studies of Tungsten Alkylidene Imido Monoalkoxidepyrrolide Complexes Annie J. Jiang, Jeffrey H. Simpson, Peter M pp 7770–7780 DOI: 10.1021/ja9012694 Supporting Info |
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Indirect Effects Modulating the Interaction between DNA and a Cytotoxic Bisnaphthalimide Reveal a Two-Step Binding Process Luis Gonz pp 7781–7791 DOI: 10.1021/ja901505p Supporting Info |
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Highly Efficient Solar Cell Polymers Developed via Fine-Tuning of Structural and Electronic Properties Yongye Liang, Danqin Feng, Yue Wu, Szu-Ting Tsai, Gang Li, Claire Ray and Luping Yu pp 7792–7799 DOI: 10.1021/ja901545q |
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A Biomimetic Potassium Responsive Nanochannel: G-Quadruplex DNA Conformational Switching in a Synthetic Nanopore Xu Hou, Wei Guo, Fan Xia, Fu-Qiang Nie, Hua Dong, Ye Tian, Liping Wen, Lin Wang, Liuxuan Cao, Yang Yang, Jianming Xue, Yanlin Song, Yugang Wang, Dongsheng Liu and Lei Jiang pp 7800–7805 DOI: 10.1021/ja901574c Supporting Info |
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Accurate Measurement of Methyl 13C Chemical Shifts by Solid-State NMR for the Determination of Protein Side Chain Conformation: The Influenza A M2 Transmembrane Peptide as an Example Mei Hong, Tatiana V. Mishanina and Sarah D. Cady pp 7806–7816 DOI: 10.1021/ja901550q Supporting Info |
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Exceptional Sensitivity of Metal−Aryl Bond Energies to ortho-Fluorine Substituents: Influence of the Metal, the Coordination Sphere, and the Spectator Ligands on M−C/H−C Bond Energy Correlations Eric Clot, Claire M pp 7817–7827 DOI: 10.1021/ja901640m Supporting Info |
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Multiple Modes for Coordination of Phenazine to Molybdenum: Ring Fusion Promotes Access to η4-Coordination, Oxidative Addition of Dihydrogen and Hydrogenation of Aromatic Nitrogen Compounds Aaron Sattler, Guang Zhu and Gerard Parkin pp 7828–7838 DOI: 10.1021/ja901896x Supporting Info |
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Max-E47, a Designed Minimalist Protein That Targets the E-Box DNA Site in Vivo and in Vitro Jing Xu, Gang Chen, Antonia T. De Jong, S. Hesam Shahravan and Jumi A. Shin pp 7839–7848 DOI: 10.1021/ja901306q Supporting Info |
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Monitoring Proton Release during Photosynthetic Water Oxidation in Photosystem II by Means of Isotope-Edited Infrared Spectroscopy Hiroyuki Suzuki, Miwa Sugiura and Takumi Noguchi pp 7849–7857 DOI: 10.1021/ja901696m Supporting Info |
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Resting State and Elementary Steps of the Coupling of Aryl Halides with Thiols Catalyzed by Alkylbisphosphine Complexes of Palladium Elsa Alvaro and John F. Hartwig pp 7858–7868 DOI: 10.1021/ja901793w Supporting Info |
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S K-edge XAS and DFT Calculations on Cytochrome P450: Covalent and Ionic Contributions to the Cysteine-Fe Bond and Their Contribution to Reactivity Abhishek Dey, Yonging Jiang, Paul Ortiz de Montellano, Keith O. Hodgson, Britt Hedman and Edward I. Solomon pp 7869–7878 DOI: 10.1021/ja901868q Supporting Info |
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Elucidation of the Phosphate Binding Mode of DING Proteins Revealed by Subangstrom X-ray Crystallography Dorothee Liebschner, Mikael Elias, S pp 7879–7886 DOI: 10.1021/ja901900y Supporting Info |
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C−C Bond Formation via C−H Bond Activation Using an in Situ-Generated Ruthenium Catalyst R pp 7887–7895 DOI: 10.1021/ja9017489 Supporting Info |
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Carbon Dioxide and Methane Transport in DDR Zeolite: Insights from Molecular Simulations into Carbon Dioxide Separations in Small Pore Zeolites Sang Eun Jee and David S. Sholl pp 7896–7904 DOI: 10.1021/ja901483e |
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Synthesis and Reactivity of Phosphine-Stabilized Phosphoranimine Cations, [R3P·PR′2═NSiMe3]+ Keith Huynh, Alan J. Lough, Michelle A. M. Forgeron, Martin Bendle, Alejandro Presa Soto, Roderick E. Wasylishen and Ian Manners pp 7905–7916 DOI: 10.1021/ja900256g Supporting Info |
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Positional Scanning for Peptide Secondary Structure by Systematic Solid-Phase Synthesis of Amino Lactam Peptides Andrew G. Jamieson, Nicolas Boutard, Kim Beauregard, Mandar S. Bodas, Huy Ong, Christiane Quiniou, Sylvain Chemtob and William D. Lubell pp 7917–7927 DOI: 10.1021/ja9010628 Supporting Info |
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Molecular Design of Conductive Polymers To Modulate Superoleophobic Properties Thierry Darmanin and Fr pp 7928–7933 DOI: 10.1021/ja901392s Supporting Info |
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Spin Dynamics in the Negatively Charged Terbium (III) Bis-phthalocyaninato Complex Francesca Branzoli, Pietro Carretta, Marta Filibian, Giorgio Zoppellaro, Michael J. Graf, Jose R. Galan-Mascaros, Olaf Fuhr, Susan Brink and Mario Ruben p 7934 DOI: 10.1021/ja9025424 |
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Springer Handbook of Enzymes, Supplement, Volume S1: Class 1 Oxidoreductases EC 1, 2nd ed p 7935 DOI: 10.1021/ja903515c |
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Compendium of Polymer Terminology and Nomenclature: IUPAC Recommendations 2008 p 7935 DOI: 10.1021/ja903551y |
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Advances in Chemical Physics, Volume 141 David Farrelly pp 7935–7936 DOI: 10.1021/ja903555z |
Issue 23
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Chemistry at the Nano−Bio Interface Thomas E. Mallouk and Peidong Yang pp 7937–7939 DOI: 10.1021/ja9038104 |
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Variation of Excitation Energy Influences the Product Distribution of a Two-Step Electron Transfer: S2 vs S1 Electron Transfer in a Zn(II)porphyrin−Viologen Complex Jonas Petersson, Mattias Eklund, Jan Davidsson and Leif Hammarstr pp 7940–7941 DOI: 10.1021/ja900729j Supporting Info |
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Reversible Single-Crystal-to-Single-Crystal Transformation from Achiral Antiferromagnetic Hexanuclears to a Chiral Ferrimagnetic Double Zigzag Chain Yan-Juan Zhang, Tao Liu, Shinji Kanegawa and Osamu Sato pp 7942–7943 DOI: 10.1021/ja901539y Supporting Info |
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Layered Materials with Coexisting Acidic and Basic Sites for Catalytic One-Pot Reaction Sequences Ken Motokura, Mizuki Tada and Yasuhiro Iwasawa pp 7944–7945 DOI: 10.1021/ja9012003 Supporting Info |
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Highly Symmetric 2D Rhombic Nanoporous Networks Arising from Low Symmetry Amphiphiles Seokhoon Ahn, Christine N. Morrison and Adam J. Matzger pp 7946–7947 DOI: 10.1021/ja901129m Supporting Info |
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Intramolecular Rotation in a Porphyrin Dimer Controls Singlet Oxygen Production Marina K. Kuimova, Milan Balaz, Harry L. Anderson and Peter R. Ogilby pp 7948–7949 DOI: 10.1021/ja901237s Supporting Info |
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Peripherally Dimethyl Isophthalate-Functionalized Poly(benzyl ether) Dendrons: A New Kind of Unprecedented Highly Efficient Organogelators Yu Feng, Zi-Tong Liu, Ji Liu, Yan-Mei He, Qi-Yu Zheng and Qing-Hua Fan pp 7950–7951 DOI: 10.1021/ja901501j Supporting Info |
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Facile Nitrite Reduction and Conversion Cycle of {Fe(NO)}6/7 Species: Chemistry of Iron N-Confused Porphyrin Complexes via Protonation/Deprotonation Wei-Min Ching, Chuan-Hung Chuang, Chih-Wei Wu, Chih-Hsiung Peng and Chen-Hsiung Hung pp 7952–7953 DOI: 10.1021/ja901796j Supporting Info |
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Synthesis and Noncovalent Protein Conjugation of Linear-Hyperbranched PEG-Poly(glycerol) α,ωn-Telechelics Frederik Wurm, Johannes Klos, Hans Joachim R pp 7954–7955 DOI: 10.1021/ja9019148 Supporting Info |
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Copper-Catalyzed Aerobic Oxidative Coupling of Terminal Alkynes with H-Phosphonates Leading to Alkynylphosphonates Yuxing Gao, Gang Wang, Lu Chen, Pengxiang Xu, Yufen Zhao, Yongbo Zhou and Li-Biao Han pp 7956–7957 DOI: 10.1021/ja9023397 Supporting Info |
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What Are the Adsorption Sites for CO on the Reduced TiO2(110)-1 × 1 Surface? Yan Zhao, Zhuo Wang, Xuefeng Cui, Tian Huang, Bing Wang, Yi Luo, Jinlong Yang and Jianguo Hou pp 7958–7959 DOI: 10.1021/ja902259k Supporting Info |
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Controlled Polymerization of a Cyclic Diene Prepared from the Ring-Closing Metathesis of a Naturally Occurring Monoterpene Shingo Kobayashi, Cheng Lu, Thomas R. Hoye and Marc A. Hillmyer pp 7960–7961 DOI: 10.1021/ja9027567 Supporting Info |
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Z-Selective Olefin Metathesis Processes Catalyzed by a Molybdenum Hexaisopropylterphenoxide Monopyrrolide Complex Margaret M. Flook, Annie J. Jiang, Richard R. Schrock, Peter M pp 7962–7963 DOI: 10.1021/ja902738u Supporting Info |
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Dinitrosyl Iron Complexes Relevant to Rieske Cluster Nitrosylation Zachary J. Tonzetich, Loi H. Do and Stephen J. Lippard pp 7964–7965 DOI: 10.1021/ja9030159 Supporting Info |
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Versatile One-Pot Synthesis of Supramolecular Plastics and Self-Healing Rubbers Damien Montarnal, Fran pp 7966–7967 DOI: 10.1021/ja903080c Supporting Info |
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Cycloaddition Reactions of Unactivated Olefins Catalyzed by an Organorhenium Electron-Transfer Mediator Daesung Chong, Michael Stewart and William E. Geiger pp 7968–7969 DOI: 10.1021/ja9032296 Supporting Info |
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Macrocyclic Design Strategies for Small, Stable Parallel β-Sheet Scaffolds Felix Freire and Samuel H. Gellman pp 7970–7972 DOI: 10.1021/ja902210f Supporting Info |
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Anisotropy of Chemical Transformation from In2Se3 to CuInSe2 Nanowires through Solid State Reaction David T. Schoen, Hailin Peng and Yi Cui pp 7973–7975 DOI: 10.1021/ja901086t Supporting Info |
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Nonadditivity of Faradaic Currents and Modification of Capacitance Currents in the Voltammetry of Mixtures of Ferrocene and the Cobaltocenium Cation in Protic and Aprotic Ionic Liquids Muhammad J. A. Shiddiky, Angel. A. J. Torriero, Chuan Zhao, Iko Burgar, Gareth Kennedy and Alan M. Bond pp 7976–7989 DOI: 10.1021/ja8092295 Supporting Info |
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Kinetic, Structural, and EPR Studies Reveal That Aldehyde Oxidoreductase from Desulfovibrio gigas Does Not Need a Sulfido Ligand for Catalysis and Give Evidence for a Direct Mo−C Interaction in a Biological System Teresa Santos-Silva, Felix Ferroni, Anders Thapper, Jacopo Marangon, Pablo J. Gonz pp 7990–7998 DOI: 10.1021/ja809448r Supporting Info |
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Consequences of Conformational Preorganization in Sesquiterpene Biosynthesis: Theoretical Studies on the Formation of the Bisabolene, Curcumene, Acoradiene, Zizaene, Cedrene, Duprezianene, and Sesquithuriferol Sesquiterpenes Young J. Hong and Dean J. Tantillo pp 7999–8015 DOI: 10.1021/ja9005332 Supporting Info |
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Nascent Metal Atom Condensation in Self-Assembled Monolayer Matrices: Coverage-Driven Morphology Transitions from Buried Adlayers to Electrically Active Metal Atom Nanofilaments to Overlayer Clusters during Aluminum Atom Deposition on Alkanethiolate/Gold Monolayers Masato M. Maitani, Thomas A. Daniel, Orlando M. Cabarcos and David L. Allara pp 8016–8029 DOI: 10.1021/ja901376w Supporting Info |
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Reverse Micelle Encapsulation as a Model for Intracellular Crowding Wade D. Van Horn, Mark E. Ogilvie and Peter F. Flynn pp 8030–8039 DOI: 10.1021/ja901871n Supporting Info |
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Catalytic Reactivity of a Meso-N-Substituted Corrole and Evidence for a High-Valent Iron−Oxo Species Amanda J. McGown, William D. Kerber, Hiroshi Fujii and David P. Goldberg pp 8040–8048 DOI: 10.1021/ja809183z |
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Light-Induced Oxidation of Tryptophan and Histidine. Reactivity of Aromatic N-Heterocycles toward Triplet-Excited Flavins Kevin Huvaere and Leif H. Skibsted pp 8049–8060 DOI: 10.1021/ja809039u |
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Efficiency of Energy Transfer from Organic Dye Molecules to CdSe−ZnS Nanocrystals: Nanorods versus Nanodots Mikhail Artemyev, Elena Ustinovich and Igor Nabiev pp 8061–8065 DOI: 10.1021/ja809839h |
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Discovery of Spiro-Piperidine Inhibitors and Their Modulation of the Dynamics of the M2 Proton Channel from Influenza A Virus Jun Wang, Sarah D. Cady, Victoria Balannik, Lawrence H. Pinto, William F. DeGrado and Mei Hong pp 8066–8076 DOI: 10.1021/ja900063s |
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Degree of Rate Control: How Much the Energies of Intermediates and Transition States Control Rates Carsten Stegelmann, Anders Andreasen and Charles T. Campbell pp 8077–8082 DOI: 10.1021/ja9000097 Supporting Info |
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Location of Inhibitors Bound to Group IVA Phospholipase A2 Determined by Molecular Dynamics and Deuterium Exchange Mass Spectrometry John E. Burke, Arneh Babakhani, Alemayehu A. Gorfe, George Kokotos, Sheng Li, Virgil L. Woods, Jr., J. Andrew McCammon and Edward A. Dennis pp 8083–8091 DOI: 10.1021/ja900098y Supporting Info |
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Determinants of K+ vs Na+ Selectivity in Potassium Channels Todor Dudev and Carmay Lim pp 8092–8101 DOI: 10.1021/ja900168k Supporting Info |
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Quantum Dots As Ultrasensitive Nanoactuators and Sensors of Amyloid Aggregation in Live Cells M. Julia Roberti, Marcos Morgan, Guillermo Men pp 8102–8107 DOI: 10.1021/ja900225w Supporting Info |
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Paramagnetic Ions Enable Tuning of Nuclear Relaxation Rates and Provide Long-Range Structural Restraints in Solid-State NMR of Proteins Philippe S. Nadaud, Jonathan J. Helmus, Stefanie L. Kall and Christopher P. Jaroniec pp 8108–8120 DOI: 10.1021/ja900224z Supporting Info |
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Reactivity and Regioselectivity in 1,3-Dipolar Cycloadditions of Azides to Strained Alkynes and Alkenes: A Computational Study Franziska Schoenebeck, Daniel H. Ess, Gavin O. Jones and K. N. Houk pp 8121–8133 DOI: 10.1021/ja9003624 Supporting Info |
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Aromatic Amino Acids as Stepping Stones in Charge Transfer in Respiratory Complex I: An Unusual Mechanism Deduced from Atomistic Theory and Bioinformatics Christian Wittekindt, Michael Schwarz, Thorsten Friedrich and Thorsten Koslowski pp 8134–8140 DOI: 10.1021/ja900352t Supporting Info |
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Effect of Ligand Steric Properties and Halide Identity on the Mechanism for Oxidative Addition of Haloarenes to Trialkylphosphine Pd(0) Complexes Fabiola Barrios-Landeros, Brad P. Carrow and John F. Hartwig pp 8141–8154 DOI: 10.1021/ja900798s Supporting Info |
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Nanoconfined Water in Magnesium-Rich 2:1 Phyllosilicates Nathan W. Ockwig, Jeffery A. Greathouse, Justin S. Durkin, Randall T. Cygan, Luke L. Daemen and Tina M. Nenoff pp 8155–8162 DOI: 10.1021/ja900812m |
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Shear- and UV-Induced Fluorescence Switching in Stilbenic π-Dimer Crystals Powered by Reversible [2 + 2] Cycloaddition Jong Won Chung, Youngmin You, Hyun Sue Huh, Byeong-Kwan An, Seong-Jun Yoon, Se Hun Kim, Soon W. Lee and Soo Young Park pp 8163–8172 DOI: 10.1021/ja900803d Supporting Info |
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Metal-Ion Mutagenesis: Conversion of a Purple Acid Phosphatase from Sweet Potato to a Neutral Phosphatase with the Formation of an Unprecedented Catalytically Competent MnIIMnII Active Site Nata pp 8173–8179 DOI: 10.1021/ja900797u Supporting Info |
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Tuning Charge Transfer Energetics in Reaction Center Mimics via Th-Functionalization of Fullerenes Fabian Sp pp 8180–8195 DOI: 10.1021/ja900675t |
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Bridgehead Lithiation-Substitution of Bridged Ketones, Lactones, Lactams, and Imides: Experimental Observations and Computational Insights Christopher J. Hayes, Nigel S. Simpkins, Douglas T. Kirk, Lee Mitchell, Jerome Baudoux, Alexander J. Blake and Claire Wilson pp 8196–8210 DOI: 10.1021/ja9009875 Supporting Info |
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Biosensing with Nanofluidic Diodes Ivan Vlassiouk, Thomas R. Kozel and Zuzanna S. Siwy pp 8211–8220 DOI: 10.1021/ja901120f Supporting Info |
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Engineering a Unimolecular DNA-Catalytic Probe for Single Lead Ion Monitoring Hui Wang, Youngmi Kim, Haipeng Liu, Zhi Zhu, Suwussa Bamrungsap and Weihong Tan pp 8221–8226 DOI: 10.1021/ja901132y Supporting Info |
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Reactions of α-Nucleophiles with Alkyl Chlorides: Competition between SN2 and E2 Mechanisms and the Gas-Phase α-Effect Stephanie M. Villano, Nicole Eyet, W. Carl Lineberger and Veronica M. Bierbaum pp 8227–8233 DOI: 10.1021/ja9012084 Supporting Info |
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Circular Dichroism Spectrum of Peptides in the Poly(Pro)II Conformation Robert W. Woody pp 8234–8245 DOI: 10.1021/ja901218m Supporting Info |
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Preparation and Use of Ta(CD2But)5 To Probe the Formation of (ButCD2)3Ta═CDBut. Kinetic and Mechanistic Studies of the Conversion of Pentaneopentyltantalum to the Archetypical Alkylidene Complex Julia K. C. Abbott, Liting Li and Zi-Ling Xue pp 8246–8251 DOI: 10.1021/ja901251c Supporting Info |
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Three-Dimensional Structure and Orientation of Rat Islet Amyloid Polypeptide Protein in a Membrane Environment by Solution NMR Spectroscopy Ravi Prakash Reddy Nanga, Jeffrey R. Brender, Jiadi Xu, Kevin Hartman, Vivekanandan Subramanian and Ayyalusamy Ramamoorthy pp 8252–8261 DOI: 10.1021/ja9010095 |
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Palladium Nanoparticles on Graphite Oxide and Its Functionalized Graphene Derivatives as Highly Active Catalysts for the Suzuki−Miyaura Coupling Reaction Gil M. Scheuermann, Luigi Rumi, Peter Steurer, Willi Bannwarth and Rolf M pp 8262–8270 DOI: 10.1021/ja901105a Supporting Info |
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Application of Solid-State 209Bi NMR to the Structural Characterization of Bismuth-Containing Materials Hiyam Hamaed, Michael W. Laschuk, Victor V. Terskikh and Robert W. Schurko pp 8271–8279 DOI: 10.1021/ja901347k Supporting Info |
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Guidelines for the Use of Proton Donors in SmI2 Reactions: Reduction of α-Cyanostilbene Mazal Amiel-Levy and Shmaryahu Hoz pp 8280–8284 DOI: 10.1021/ja9013997 Supporting Info |
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Iridium-N,P-Ligand-Catalyzed Enantioselective Hydrogenation of Diphenylvinylphosphine Oxides and Vinylphosphonates Pradeep Cheruku, Alexander Paptchikhine, Tamara L. Church and Pher G. Andersson pp 8285–8289 DOI: 10.1021/ja901437t Supporting Info |
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Topological Switching between an α−β Parallel Protein and a Remarkably Helical Molten Globule Sanne M. Nabuurs, Adrie H. Westphal, Marije aan den Toorn, Simon Lindhoud and Carlo P. M. van Mierlo pp 8290–8295 DOI: 10.1021/ja9014309 Supporting Info |
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Sulfur Oxygenates of Biomimetics of the Diiron Subsite of the [FeFe]-Hydrogenase Active Site: Properties and Oxygen Damage Repair Possibilities Tianbiao Liu, Bin Li, Michael L. Singleton, Michael B. Hall and Marcetta Y. Darensbourg pp 8296–8307 DOI: 10.1021/ja9016528 Supporting Info |
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Static and Dynamic Properties of Phospholipid Bilayer Nanodiscs Minoru Nakano, Masakazu Fukuda, Takayuki Kudo, Masakazu Miyazaki, Yusuke Wada, Naoya Matsuzaki, Hitoshi Endo and Tetsurou Handa pp 8308–8312 DOI: 10.1021/ja9017013 Supporting Info |
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Synthesis, Crystal Structure, and Magnetic Properties of Bi3Mn4O12(NO3) Oxynitrate Comprising S = 3/2 Honeycomb Lattice Olga Smirnova, Masaki Azuma, Nobuhiro Kumada, Yoshihiro Kusano, Masaaki Matsuda, Yuichi Shimakawa, Takahiro Takei, Yoshinori Yonesaki and Nobukazu Kinomura pp 8313–8317 DOI: 10.1021/ja901922p |
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Geometry and Nanolength Scales versus Interface Interactions: Water Dynamics in AOT Lamellar Structures and Reverse Micelles David E. Moilanen, Emily E. Fenn, Daryl Wong and M. D. Fayer pp 8318–8328 DOI: 10.1021/ja901950b |
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Asymmetric [4 + 3] Cycloadditions between Vinylcarbenoids and Dienes: Application to the Total Synthesis of the Natural Product (−)-5-epi-Vibsanin E Brett D. Schwartz, Justin R. Denton, Yajing Lian, Huw M. L. Davies and Craig M. Williams pp 8329–8332 DOI: 10.1021/ja9019484 Supporting Info |
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Nucleobase-Directed Amyloid Nanotube Assembly Peng Liu, Rong Ni, Anil K. Mehta, W. Seth Childers, Ami Lakdawala, Sai Venkatesh Pingali, Pappannan Thiyagarajan and David G. Lynn p 8333 DOI: 10.1021/ja9021667 |
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Catalysis in Asymmetric Synthesis Ben W. Glasspoole and Cathleen M. Crudden p 8334 DOI: 10.1021/ja9033389 |
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Computational Drug Design: A Guide for Computational and Medicinal Chemists p 8334 DOI: 10.1021/ja903640y |
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Protein Structure, Stability, and Interactions Christopher Bystroff pp 8334–8335 DOI: 10.1021/ja9036498 |
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Anthracycline Chemistry and Biology I: Biological Occurrence and Biosynthesis, Synthesis and Chemistry Waldemar Priebe p 8335 DOI: 10.1021/ja9038483 |
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Mass Spectrometry in Drug Metabolism and Pharmacokinetics Peter T. Kissinger pp 8335–8336 DOI: 10.1021/ja904034f |
Issue 24
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Coordination-Driven Self-Assembly of a Discrete Molecular Cage and an Infinite Chain of Coordination Cages Based on ortho-Linked Oxacalix[2]benzene[2]pyrazine and Oxacalix[2]arene[2]pyrazine Ming-Liang Ma, Xiao-Yan Li and Ke Wen pp 8338–8339 DOI: 10.1021/ja900291w Supporting Info |
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Thiolate S-Oxygenation Controls Nitric Oxide (NO) Photolability of a Synthetic Iron Nitrile Hydratase (Fe-NHase) Model Derived from Mixed Carboxamide/Thiolate Ligand Michael J. Rose, Nolan M. Betterley and Pradip K. Mascharak pp 8340–8341 DOI: 10.1021/ja9004656 Supporting Info |
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Catalytic Synthesis of Amino Acid and Peptide Derivatized Gadonanotubes Yuri Mackeyev, Keith B. Hartman, Jeyarama S. Ananta, Adrian V. Lee and Lon J. Wilson pp 8342–8343 DOI: 10.1021/ja900918x Supporting Info |
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IBiox[(−)-menthyl]: A Sterically Demanding Chiral NHC Ligand Sebastian Würtz, Claudia Lohre, Roland Fröhlich, Klaus Bergander and Frank Glorius pp 8344–8345 DOI: 10.1021/ja901018g Supporting Info |
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Ir-Catalyzed Cross-Coupling of Styrene Derivatives with Allylic Carbonates: Free Amine Assisted Vinyl C−H Bond Activation Hu He, Wen-Bo Liu, Li-Xin Dai and Shu-Li You pp 8346–8347 DOI: 10.1021/ja901384j Supporting Info |
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Mechanistic Investigations of Anaerobic Sulfatase-Maturating Enzyme: Direct Cβ H-Atom Abstraction Catalyzed by a Radical AdoMet Enzyme Alhosna Benjdia, Jérôme Leprince, Corine Sandström, Hubert Vaudry and Olivier Berteau pp 8348–8349 DOI: 10.1021/ja901571p Supporting Info |
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Palladium-Catalyzed Intramolecular Coupling of 2-[(2-Pyrrolyl)silyl]aryl Triflates through 1,2-Silicon Migration Kenji Mochida, Masaki Shimizu and Tamejiro Hiyama pp 8350–8351 DOI: 10.1021/ja901622b Supporting Info |
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Concise Synthesis of Iminocyclitols via Petasis-Type Aminocyclization Zhangyong Hong, Lei Liu, Masakazu Sugiyama, Yu Fu and Chi-Huey Wong pp 8352–8353 DOI: 10.1021/ja901656e Supporting Info |
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Spatial Distribution of Nitrate and Nitrite Anions at the Liquid/Vapor Interface of Aqueous Solutions Matthew A. Brown, Bernd Winter, Manfred Faubel and John C. Hemminger pp 8354–8355 DOI: 10.1021/ja901791v Supporting Info |
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Regiospecific Assembly of Gold Nanoparticles around the Pores of Diatoms: Toward Three-Dimensional Nanoarrays Jeremiah Toster, K. Swaminathan Iyer, Ruslan Burtovyy, Stephen S. O. Burgess, Igor A. Luzinov and Colin L. Raston pp 8356–8357 DOI: 10.1021/ja901806y Supporting Info |
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Iridium/Monodentate Phosphoramidite Catalyzed Asymmetric Hydrogenation of N-Aryl Imines Nataša Mršić, Adriaan J. Minnaard, Ben L. Feringa and Johannes G. de Vries pp 8358–8359 DOI: 10.1021/ja901961y Supporting Info |
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Biosynthesis of the Sesquiterpene Botrydial in Botrytis cinerea. Mechanism and Stereochemistry of the Enzymatic Formation of Presilphiperfolan-8β-ol Chieh-Mei Wang, Russell Hopson, Xin Lin and David E. Cane pp 8360–8361 DOI: 10.1021/ja9021649 Supporting Info |
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Trans-Cyclization of Phosphatidylinositol Catalyzed by Phospholipase C from Streptomyces antibioticus Chuan Bai, Li Zhao, Mario Rebecchi, Ming-Daw Tsai and Karol S. Bruzik pp 8362–8363 DOI: 10.1021/ja902326u Supporting Info |
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A Large-Scale, Wireless Electrochemical Bipolar Electrode Microarray Kwok-Fan Chow, François Mavré, John A. Crooks, Byoung-Yong Chang and Richard M. Crooks pp 8364–8365 DOI: 10.1021/ja902683f Supporting Info |
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Probing Side-Chain Dynamics of a Ribosome-Bound Nascent Chain Using Methyl NMR Spectroscopy Shang-Te Danny Hsu, Lisa D. Cabrita, Paola Fucini, John Christodoulou and Christopher M. Dobson pp 8366–8367 DOI: 10.1021/ja902778n Supporting Info |
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Real-Time Direction Control of Self Fabricating Polyoxometalate-Based Microtubes Geoffrey J. T. Cooper and Leroy Cronin pp 8368–8369 DOI: 10.1021/ja902684b Supporting Info |
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Nucleotide-Responsive Wettability on a Smart Polymer Surface Guangyan Qing, Xing Wang, Harald Fuchs and Taolei Sun pp 8370–8371 DOI: 10.1021/ja9028632 Supporting Info |
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Direct Measurement of Photoinduced Charge Separation Distances in Donor−Acceptor Systems for Artificial Photosynthesis Using OOP-ESEEM Raanan Carmieli, Qixi Mi, Annie Butler Ricks, Emilie M. Giacobbe, Sarah M. Mickley and Michael R. Wasielewski pp 8372–8373 DOI: 10.1021/ja902864h Supporting Info |
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Thermodynamics of Bisphosphonates Binding to Human Bone: A Two-Site Model Sujoy Mukherjee, Cancan Huang, Francisco Guerra, Ke Wang and Eric Oldfield pp 8374–8375 DOI: 10.1021/ja902895p Supporting Info |
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Cation-Triggered Drug Release from a Porous Zinc−Adeninate Metal−Organic Framework Jihyun An, Steven J. Geib and Nathaniel L. Rosi pp 8376–8377 DOI: 10.1021/ja902972w Supporting Info |
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H-Bonding as a Control Element in Stereoselective Ru-Catalyzed Olefin Metathesis Amir H. Hoveyda, Pamela J. Lombardi, Robert V. O’Brien, and Adil R. Zhugralin pp 8378–8379 DOI: 10.1021/ja9030903 Supporting Info |
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Bimetallic Gold−Silver Nanorods Produce Multiple Surface Plasmon Bands Sungwan Kim, Seong Kyu Kim and Sungho Park pp 8380–8381 DOI: 10.1021/ja903093t Supporting Info |
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Newtonian Kinetic Isotope Effects. Observation, Prediction, and Origin of Heavy-Atom Dynamic Isotope Effects Kelmara K. Kelly, Jennifer S. Hirschi and Daniel A. Singleton pp 8382–8383 DOI: 10.1021/ja9031083 Supporting Info |
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A Heterobimetallic Ga/Yb-Schiff Base Complex for Catalytic Asymmetric α-Addition of Isocyanides to Aldehydes Hisashi Mihara, Yingjie Xu, Nicholas E. Shepherd, Shigeki Matsunaga and Masakatsu Shibasaki pp 8384–8385 DOI: 10.1021/ja903158x Supporting Info |
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Heteroepitaxial Ferroelectric ZnSnO3 Thin Film Jong Yeog Son, Geunhee Lee, Moon-Ho Jo, Hyungjun Kim, Hyun M. Jang and Young-Han Shin pp 8386–8387 DOI: 10.1021/ja903133n Supporting Info |
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Acyltransferase Mediated Polyketide Release from a Fungal Megasynthase Xinkai Xie, Michael J. Meehan, Wei Xu, Pieter C. Dorrestein and Yi Tang pp 8388–8389 DOI: 10.1021/ja903203g Supporting Info |
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Broadband “Infinite-Speed” Magic-Angle Spinning NMR Spectroscopy Yan-Yan Hu, E. M. Levin and Klaus Schmidt-Rohr pp 8390–8391 DOI: 10.1021/ja903334p |
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Difluoro-λ3-bromane-Induced Hofmann Rearrangement of Sulfonamides: Synthesis of Sulfamoyl Fluorides Masahito Ochiai, Takuya Okada, Norihiro Tada, Akira Yoshimura, Kazunori Miyamoto and Motoo Shiro pp 8392–8393 DOI: 10.1021/ja903544d Supporting Info |
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A Two-Step, Formal [4 + 2] Approach toward Piperidin-4-ones via Au Catalysis Li Cui, Yu Peng and Liming Zhang pp 8394–8395 DOI: 10.1021/ja903531g Supporting Info |
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Terminal Alkyne Activation by Frustrated and Classical Lewis Acid/Phosphine Pairs Meghan A. Dureen and Douglas W. Stephan pp 8396–8397 DOI: 10.1021/ja903650w Supporting Info |
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Mesoporous Silica Nanoparticle-Based Double Drug Delivery System for Glucose-Responsive Controlled Release of Insulin and Cyclic AMP Yannan Zhao, Brian G. Trewyn, Igor I. Slowing and Victor S.-Y. Lin pp 8398–8400 DOI: 10.1021/ja901831u Supporting Info |
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Synthesis, Structure, Assembly, and Modulation of the CO2 Adsorption Properties of a Zinc-Adeninate Macrocycle Jihyun An, Richard P. Fiorella, Steven J. Geib and Nathaniel L. Rosi pp 8401–8403 DOI: 10.1021/ja901869m Supporting Info |
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Evidence for Pt(II)-Based Molecular Catalysis in the Thermal Reduction of Water into Molecular Hydrogen Kosei Yamauchi, Shigeyuki Masaoka and Ken Sakai pp 8404–8406 DOI: 10.1021/ja902245e Supporting Info |
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Distance Dependence of Plasmon-Enhanced Photocurrent in Dye-Sensitized Solar Cells Stacey D. Standridge, George C. Schatz and Joseph T. Hupp pp 8407–8409 DOI: 10.1021/ja9022072 Supporting Info |
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Homogeneous Catalytic System for Reversible Dehydrogenation−Hydrogenation Reactions of Nitrogen Heterocycles with Reversible Interconversion of Catalytic Species Ryohei Yamaguchi, Chikako Ikeda, Yoshinori Takahashi and Ken-ichi Fujita pp 8410–8412 DOI: 10.1021/ja9022623 Supporting Info |
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Stereoelectronic Effect for the Selectivity in C−H Insertion of Alkylidene Carbenes and Its Application to the Synthesis of Platensimycin Sang Young Yun, Jun-Cheng Zheng and Daesung Lee pp 8413–8415 DOI: 10.1021/ja903526g Supporting Info |
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Stereospecific Formation of the (R)-γ-Hydroxytrimethylene Interstrand N2-dG:N2-dG Cross-Link Arising from the γ-OH-1,N2-Propano-2′-deoxyguanosine Adduct in the 5′-CpG-3′ DNA Sequence Hai Huang, Hye-Young Kim, Ivan D. Kozekov, Young-Jin Cho, Hao Wang, Albena Kozekova, Thomas M. Harris, Carmelo J. Rizzo and Michael P. Stone pp 8416–8424 DOI: 10.1021/ja809543j Supporting Info |
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Radical Reactions with Double Memory of Chirality (2MOC) for the Enantiospecific Synthesis of Adjacent Stereogenic Quaternary Centers in Solution: Cleavage and Bonding Faster than Radical Rotation Marino J. E. Resendiz, Farnosh Family, Kerrian Fuller, Luis M. Campos, Saeed I. Khan, Natalia V. Lebedeva, Malcolm D. E. Forbes and Miguel A. Garcia-Garibay pp 8425–8433 DOI: 10.1021/ja900781n Supporting Info |
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One-Pot Multicomponent Coupling Methods for the Synthesis of Diastereo- and Enantioenriched (Z)-Trisubstituted Allylic Alcohols Michael H. Kerrigan, Sang-Jin Jeon, Young K. Chen, Luca Salvi, Patrick J. Carroll and Patrick J. Walsh pp 8434–8445 DOI: 10.1021/ja809821x Supporting Info |
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Modular Functionalization of Carbon Nanotubes and Fullerenes Wei Zhang, Johannes K. Sprafke, Minglin Ma, Emily Y. Tsui, Stefanie A. Sydlik, Gregory C. Rutledge and Timothy M. Swager pp 8446–8454 DOI: 10.1021/ja810049z Supporting Info |
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Pyramidal and Chiral Groupings of Gold Nanocrystals Assembled Using DNA Scaffolds Alexander J. Mastroianni, Shelley A. Claridge and A. Paul Alivisatos pp 8455–8459 DOI: 10.1021/ja808570g Supporting Info |
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Zeolite-Supported Organorhodium Fragments: Essentially Molecular Surface Chemistry Elucidated with Spectroscopy and Theory Ann J. Liang, Raluca Craciun, Mingyang Chen, T. Glenn Kelly, Philip W. Kletnieks, James F. Haw, David A. Dixon and Bruce C. Gates pp 8460–8473 DOI: 10.1021/ja900041n Supporting Info |
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Contribution of the Closing Base Pair to Exceptional Stability in RNA Tetraloops: Roles for Molecular Mimicry and Electrostatic Factors Joshua M. Blose, David J. Proctor, Narayanan Veeraraghavan, Vinod K. Misra and Philip C. Bevilacqua pp 8474–8484 DOI: 10.1021/ja900065e Supporting Info |
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Exploring the Spatial Distribution and Transport Behavior of Charge Carriers in a Single Titania Nanowire Takashi Tachikawa and Tetsuro Majima pp 8485–8495 DOI: 10.1021/ja900194m Supporting Info |
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Acetal Levulinyl Ester (ALE) Groups for 2′-Hydroxyl Protection of Ribonucleosides in the Synthesis of Oligoribonucleotides on Glass and Microarrays Jeremy G. Lackey, Debbie Mitra, Mark M. Somoza, Franco Cerrina and Masad J. Damha pp 8496–8502 DOI: 10.1021/ja9002074 Supporting Info |
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Helical Vesicles, Segmented Semivesicles, and Noncircular Bilayer Sheets from Solution-State Self-Assembly of ABC Miktoarm Star Terpolymers Weixin Kong, Baohui Li, Qinghua Jin, Datong Ding and An-Chang Shi pp 8503–8512 DOI: 10.1021/ja900405r Supporting Info |
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Catalyzing Racemizations in the Absence of a Cofactor: The Reaction Mechanism in Proline Racemase Amir Rubinstein and Dan Thomas Major pp 8513–8521 DOI: 10.1021/ja900716y Supporting Info |
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Shape Control of Al Nanoclusters by Ligand Size Hongjun Xiang, Joongoo Kang, Su-Huai Wei, Yong-Hyun Kim, Calvin Curtis and Daniel Blake pp 8522–8526 DOI: 10.1021/ja900965w Supporting Info |
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Copper-Responsive Magnetic Resonance Imaging Contrast Agents Emily L. Que, Eliana Gianolio, Suzanne L. Baker, Audrey P. Wong, Silvio Aime and Christopher J. Chang pp 8527–8536 DOI: 10.1021/ja900884j Supporting Info |
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Molecularly Tethered Amphiphiles as 3-D Supramolecular Assembly Platforms: Unlocking a Trapped Conformation Christopher G. Clark, Jr., George A. Floudas, Young Joo Lee, Robert Graf, Hans W. Spiess and Klaus Müllen pp 8537–8547 DOI: 10.1021/ja900999f Supporting Info |
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A Multiscale Scheme for the Simulation of Conformational and Solution Properties of Different Dendrimer Molecules Gustavo Del Río Echenique, Ricardo Rodríguez Schmidt, Juan J. Freire, José G. Hernández Cifre and José García de la Torre pp 8548–8556 DOI: 10.1021/ja901275d Supporting Info |
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Distinct Role of Specific Tryptophans in Facilitating Electron Transfer or as [Fe(IV)=O Trp•] Intermediates in the Peroxidase Reaction of Bulkholderia pseudomallei Catalase-Peroxidase: A Multifrequency EPR Spectroscopy Investigation Julie Colin, Ben Wiseman, Jacek Switala, Peter C. Loewen and Anabella Ivancich pp 8557–8563 DOI: 10.1021/ja901402v Supporting Info |
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Simultaneous measurement of residual dipolar couplings for proteins in complex using the isotopically discriminated NMR approach Wolfgang Bermel, Elena N. Tkach, Alexander G. Sobol and Alexander P. Golovanov pp 8564–8570 DOI: 10.1021/ja901602c Supporting Info |
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Longitudinal-Relaxation-Enhanced NMR Experiments for the Study of Nucleic Acids in Solution Jonathan Farjon, Jérôme Boisbouvier, Paul Schanda, Arthur Pardi, Jean-Pierre Simorre and Bernhard Brutscher pp 8571–8577 DOI: 10.1021/ja901633y |
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FerriBRIGHT: A Rationally Designed Fluorescent Probe for Redox Active Metals Daniel P. Kennedy, Chad M. Kormos and Shawn C. Burdette pp 8578–8586 DOI: 10.1021/ja901653u Supporting Info |
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NMR Detected Hydrogen−Deuterium Exchange Reveals Differential Dynamics of Antibiotic- and Nucleotide-Bound Aminoglycoside Phosphotransferase 3′-IIIa Adrianne L. Norris and Engin H. Serpersu pp 8587–8594 DOI: 10.1021/ja901685h Supporting Info |
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Desulfurization of Thiophene on Au/TiC(001): Au−C Interactions and Charge Polarization José A. Rodriguez, Ping Liu, Yoshiro Takahashi, Kenichi Nakamura, Francesc Viñes and Francesc Illas pp 8595–8602 DOI: 10.1021/ja901522a |
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Investigations of Iridium-Mediated Reversible C−H Bond Cleavage: Characterization of a 16-Electron Iridium(III) Methyl Hydride Complex Wesley H. Bernskoetter, Susan Kloek Hanson, Sara K. Buzak, Zoe Davis, Peter S. White, Rodney Swartz, Karen I. Goldberg and Maurice Brookhart pp 8603–8613 DOI: 10.1021/ja901706b Supporting Info |
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Direct Observation of the Hole Protonation State and Hole Localization Site in DNA-Oligomers Amitava Adhikary, Deepti Khanduri and Michael D. Sevilla pp 8614–8619 DOI: 10.1021/ja9014869 Supporting Info |
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Molecule-Like Eu3+-Dimers Embedded in an Extended System Exhibit Unique Photoluminescence Properties Duarte Ananias, Mariya Kostova, Filipe A. A. Paz, Albano N. C. Neto, Renaldo T. De Moura, Jr., Oscar L. Malta, Luis D. Carlos and João Rocha pp 8620–8626 DOI: 10.1021/ja901820z Supporting Info |
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Alkyl Radicals as Hydrogen Bond Acceptors: Computational Evidence Steen Hammerum pp 8627–8635 DOI: 10.1021/ja901854t Supporting Info |
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Simulation of NMR Data Reveals That Proteins’ Local Structures Are Stabilized by Electronic Polarization Yan Tong, Chang G. Ji, Ye Mei and John Z. H. Zhang pp 8636–8641 DOI: 10.1021/ja901650r Supporting Info |
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Nanosized Hybrid Oligoamide Foldamers: Aromatic Templates for the Folding of Multiple Aliphatic Units David Sánchez-García, Brice Kauffmann, Takahiro Kawanami, Hirotaka Ihara, Makoto Takafuji, Marie-Hélène Delville and Ivan Huc pp 8642–8648 DOI: 10.1021/ja9019758 Supporting Info |
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Spectroscopy and Photochemistry of Triplet Methylpentadiynylidene (Me−C≡C−C̈−C≡C−H) Phillip S. Thomas, Nathan P. Bowling and Robert J. McMahon pp 8649–8659 DOI: 10.1021/ja901977s Supporting Info |
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Ordered Rock-Salt Related Nanoclusters in CaMnO2 Aurea Varela, Susana de Dios, Marina Parras, María Hernando, M. Teresa Fernández-Díaz, Angel R. Landa-Cánovas and José M. González-Calbet pp 8660–8668 DOI: 10.1021/ja901963m |
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Functionalized Dendritic Oligothiophenes: Ruthenium Phthalocyanine Complexes and Their Application in Bulk Heterojunction Solar Cells Markus K. R. Fischer, Ismael López-Duarte, Martijn M. Wienk, M. Victoria Martínez-Díaz, René A. J. Janssen, Peter Bäuerle and Tomás Torres pp 8669–8676 DOI: 10.1021/ja901537d Supporting Info |
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BaHg2Tl2. An Unusual Polar Intermetallic Phase with Strong Differentiation between the Neighboring Elements Mercury and Thallium Jing-Cao Dai, Shalabh Gupta, Olivier Gourdon, Hyun-Jeong Kim and John D. Corbett pp 8677–8682 DOI: 10.1021/ja901865d Supporting Info |
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Structural Characterization of Pt−Pd and Pd−Pt Core−Shell Nanoclusters at Atomic Resolution Sergio I. Sanchez, Matthew W. Small, Jian-min Zuo and Ralph G. Nuzzo pp 8683–8689 DOI: 10.1021/ja9020952 Supporting Info |
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Synthesis of a Simplified Version of Stable Bulky and Rigid Cyclic (Alkyl)(amino)carbenes, and Catalytic Activity of the Ensuing Gold(I) Complex in the Three-Component Preparation of 1,2-Dihydroquinoline Derivatives Xiaoming Zeng, Guido D. Frey, Rei Kinjo, Bruno Donnadieu and Guy Bertrand pp 8690–8696 DOI: 10.1021/ja902051m Supporting Info |
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Dissociation of Water During Formation of Anodic Aluminum Oxide Zixue Su, Michael Bühl and Wuzong Zhou pp 8697–8702 DOI: 10.1021/ja902267b Supporting Info |
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Conjugated Polymer Sensors Built on π-Extended Borasiloxane Cages Wenjun Liu, Maren Pink and Dongwhan Lee pp 8703–8707 DOI: 10.1021/ja902333p Supporting Info |
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Coupling Reactions in Aldehydes Adsorbed on V(100) Single-Crystal Surfaces Min Shen and Francisco Zaera pp 8708–8713 DOI: 10.1021/ja9023379 |
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α′-Hydroxyenones as Mechanistic Probes and Scope-Expanding Surrogates for α,β-Unsaturated Aldehydes in N-Heterocyclic Carbene-Catalyzed Reactions Pei-Chen Chiang, Michael Rommel and Jeffrey W. Bode pp 8714–8718 DOI: 10.1021/ja902143w Supporting Info |
Issue 25
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Genetic Encoding and Labeling of Aliphatic Azides and Alkynes in Recombinant Proteins via a Pyrrolysyl-tRNA Synthetase/tRNACUA Pair and Click Chemistry Duy P. Nguyen, Hrvoje Lusic, Heinz Neumann, Prashant B. Kapadnis, Alexander Deiters and Jason W. Chin pp 8720–8721 DOI: 10.1021/ja900553w Supporting Info |
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Unlocking Ylide Reactivity in the Metal-Catalyzed Allylic Substitution Reaction: Stereospecific Construction of Primary Allylic Amines with Aza-Ylides P. Andrew Evans and Elizabeth A. Clizbe pp 8722–8723 DOI: 10.1021/ja9041302 Supporting Info |
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Control of Bioelectrocatalytic Transformations on DNA Scaffolds Gilad Piperberg, Ofer I. Wilner, Omer Yehezkeli, Ran Tel-Vered and Itamar Willner pp 8724–8725 DOI: 10.1021/ja900718m Supporting Info |
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Nucleophilic Attack of Hydroxide on a MnV Oxo Complex: A Model of the O−O Bond Formation in the Oxygen Evolving Complex of Photosystem II Yan Gao, Torbj pp 8726–8727 DOI: 10.1021/ja901139r Supporting Info |
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Directed Formation of Lipid Membrane Microdomains as High Affinity Sites for His-Tagged Proteins Carl C. Hayden, Jane S. Hwang, Elisa A. Abate, Michael S. Kent and Darryl Y. Sasaki pp 8728–8729 DOI: 10.1021/ja901157c Supporting Info |
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Highly Active and Robust Cp* Iridium Complexes for Catalytic Water Oxidation Jonathan F. Hull, David Balcells, James D. Blakemore, Christopher D. Incarvito, Odile Eisenstein, Gary W. Brudvig and Robert H. Crabtree pp 8730–8731 DOI: 10.1021/ja901270f Supporting Info |
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970 Million Druglike Small Molecules for Virtual Screening in the Chemical Universe Database GDB-13 Lorenz C. Blum and Jean-Louis Reymond pp 8732–8733 DOI: 10.1021/ja902302h Supporting Info |
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Highly Diastereo- and Enantioselective Pd-Catalyzed Cyclopropanation of Acyclic Amides with Substituted Allyl Carbonates Wei Liu, Di Chen, Xia-Zhen Zhu, Xiao-Long Wan and Xue-Long Hou pp 8734–8735 DOI: 10.1021/ja902410w Supporting Info |
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Proton-Catalyzed Oxo−Alkene Coupling: 2-Platinaoxetane Formation Nandita M. Weliange, Endre Szuromi and Paul R. Sharp pp 8736–8737 DOI: 10.1021/ja902180k Supporting Info |
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Fluorescein Redirects a Ruthenium−Octaarginine Conjugate to the Nucleus Cindy A. Puckett and Jacqueline K. Barton pp 8738–8739 DOI: 10.1021/ja9025165 Supporting Info |
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Hydrazides as Tunable Reagents for Alkene Hydroamination and Aminocarbonylation Jean-Gr pp 8740–8741 DOI: 10.1021/ja902558j Supporting Info |
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Bacterial AmpD at the Crossroads of Peptidoglycan Recycling and Manifestation of Antibiotic Resistance Mijoon Lee, Weilie Zhang, Dusan Hesek, Bruce C. Noll, Bill Boggess and Shahriar Mobashery pp 8742–8743 DOI: 10.1021/ja9025566 Supporting Info |
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Atomic Hydrogen Adsorbate Structures on Graphene Richard Balog, Bjarke Jørgensen, Justin Wells, Erik Lægsgaard, Philip Hofmann, Flemming Besenbacher and Liv Hornekær pp 8744–8745 DOI: 10.1021/ja902714h Supporting Info |
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Controlling the Kinetics of Contact Electrification with Patterned Surfaces Samuel W. Thomas III, Sarah J. Vella, Michael D. Dickey, George K. Kaufman and George M. Whitesides pp 8746–8747 DOI: 10.1021/ja902862b Supporting Info |
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Importance of Open Structure of Nonmetal Based Catalyst in Hydrogen Bond Promoted Methanolysis of Activated Amide: Structure Dynamics between Monomer and Dimer Enabling Recombinant Covalent, Dative, and Hydrogen Bonds Shunsuke Oishi, Junichi Yoshimoto and Susumu Saito pp 8748–8749 DOI: 10.1021/ja9029494 Supporting Info |
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Thermal Decay of Rhodopsin: Role of Hydrogen Bonds in Thermal Isomerization of 11-cis Retinal in the Binding Site and Hydrolysis of Protonated Schiff Base Jian Liu, Monica Yun Liu, Jennifer B. Nguyen, Aditi Bhagat, Victoria Mooney and Elsa C. Y. Yan pp 8750–8751 DOI: 10.1021/ja903154u Supporting Info |
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Conformational Switching Induced by Near-Infrared Laser Irradiation Archna Sharma, Igor Reva and Rui Fausto pp 8752–8753 DOI: 10.1021/ja903211f |
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Enantioselective Addition of Thioacetic Acid to Nitroalkenes via N-Sulfinyl Urea Organocatalysis Kyle L. Kimmel, MaryAnn T. Robak and Jonathan A. Ellman pp 8754–8755 DOI: 10.1021/ja903351a Supporting Info |
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Electron-Transfer Photoredox Catalysis: Development of a Tin-Free Reductive Dehalogenation Reaction Jagan M. R. Narayanam, Joseph W. Tucker and Corey R. J. Stephenson pp 8756–8757 DOI: 10.1021/ja9033582 Supporting Info |
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Thiourea-Catalyzed Highly Enantio- and Diastereoselective Additions of Oxindoles to Nitroolefins: Application to the Formal Synthesis of (+)-Physostigmine Tommy Bui, Salahuddin Syed and Carlos F. Barbas, III pp 8758–8759 DOI: 10.1021/ja903520c Supporting Info |
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Alanine-2 Carbonyl is an Oxygen Ligand in Cu2+ Coordination of Alzheimer’s Disease Amyloid-β Peptide − Relevance to N-Terminally Truncated Forms Simon C. Drew, Colin L. Masters and Kevin J. Barnham pp 8760–8761 DOI: 10.1021/ja903669a Supporting Info |
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Stable Phosphonium Sila-ylide with Reactivity as a Sila-Wittig Reagent David Gau, Tsuyoshi Kato, Nathalie Saffon-Merceron, Fernando P. Coss pp 8762–8763 DOI: 10.1021/ja903540b Supporting Info |
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An Unusual P−P Double Bond Formed via Phospha-Wittig Transformation of a Terminal PO Complex Nicholas A. Piro and Christopher C. Cummins pp 8764–8765 DOI: 10.1021/ja903860k Supporting Info |
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A Biomimetic Modular Polymer with Tough and Adaptive Properties Aaron M. Kushner, John D. Vossler, Gregory A. Williams and Zhibin Guan pp 8766–8768 DOI: 10.1021/ja9009666 Supporting Info |
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Quantitative Modelfree Analysis of Urea Binding to Unfolded Ubiquitin Using a Combination of Small Angle X-ray and Neutron Scattering Frank Gabel, Malene Ringkjøbing Jensen, Giuseppe Zacca pp 8769–8771 DOI: 10.1021/ja9013248 Supporting Info |
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Iron-Catalyzed, Hydrogen-Mediated Reductive Cyclization of 1,6-Enynes and Diynes: Evidence for Bis(imino)pyridine Ligand Participation Kevin T. Sylvester and Paul J. Chirik pp 8772–8774 DOI: 10.1021/ja902478p Supporting Info |
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Comparative Study of Hydrogen Sulfide Adsorption in the MIL-53(Al, Cr, Fe), MIL-47(V), MIL-100(Cr), and MIL-101(Cr) Metal−Organic Frameworks at Room Temperature Lomig Hamon, Christian Serre, Thomas Devic, Thierry Loiseau, Franck Millange, G pp 8775–8777 DOI: 10.1021/ja901587t Supporting Info |
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Nickel-Catalyzed Stereoselective Formation of α-2-Deoxy-2-Amino Glycosides Enoch A. Mensah and Hien M. Nguyen pp 8778–8780 DOI: 10.1021/ja903123b Supporting Info |
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In Situ Cross-Linkable High Molecular Weight Hyaluronan−Bisphosphonate Conjugate for Localized Delivery and Cell-Specific Targeting: A Hydrogel Linked Prodrug Approach Oommen P. Varghese, Weilun Sun, J pp 8781–8783 DOI: 10.1021/ja902857b Supporting Info |
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Strong CO2 Binding in a Water-Stable, Triazolate-Bridged Metal−Organic Framework Functionalized with Ethylenediamine Aude Demessence, Deanna M. D’Alessandro, Maw Lin Foo and Jeffrey R. Long pp 8784–8786 DOI: 10.1021/ja903411w Supporting Info |
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Photosynthetic Reaction Center Mimicry: Low Reorganization Energy Driven Charge Stabilization in Self-Assembled Cofacial Zinc Phthalocyanine Dimer−Fullerene Conjugate Francis D’Souza, Eranda Maligaspe, Kei Ohkubo, Melvin E. Zandler, Navaneetha K. Subbaiyan and Shunichi Fukuzumi pp 8787–8797 DOI: 10.1021/ja903467w Supporting Info |
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Highly Efficient Asymmetric Synthesis of Sitagliptin Karl B. Hansen, Yi Hsiao, Feng Xu, Nelo Rivera, Andrew Clausen, Michele Kubryk, Shane Krska, Thorsten Rosner, Bryon Simmons, Jaume Balsells, Nori Ikemoto, Yongkui Sun, Felix Spindler, Christophe Malan, Edward J. J. Grabowski and Joseph D. Armstrong, III. pp 8798–8804 DOI: 10.1021/ja902462q Supporting Info |
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Amide Enolate Additions to Acylsilanes: In Situ Generation of Unusual and Stereoselective Homoenolate Equivalents Robert B. Lettan, II, Chris V. Galliford, Chase C. Woodward and Karl A. Scheidt pp 8805–8814 DOI: 10.1021/ja808811u Supporting Info |
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Mechanism of Ni-Catalyzed Selective C−O Bond Activation in Cross-Coupling of Aryl Esters Zhe Li, Song-Lin Zhang, Yao Fu, Qing-Xiang Guo and Lei Liu pp 8815–8823 DOI: 10.1021/ja810157e Supporting Info |
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Morphology and Electronic Structure of the Oxide Shell on the Surface of Iron Nanoparticles Chongmin Wang, Donald R. Baer, James E. Amonette, Mark H. Engelhard, Jiji Antony and You Qiang pp 8824–8832 DOI: 10.1021/ja900353f Supporting Info |
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Molecularly Imprinted Tunable Binding Sites Based on Conjugated Prosthetic Groups and Ion-Paired Cofactors Kohei Takeda, Atsushi Kuwahara, Kohei Ohmori and Toshifumi Takeuchi pp 8833–8838 DOI: 10.1021/ja9004317 Supporting Info |
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Theoretical Analysis of the Individual Contributions of Chiral Arrays to the Chiroptical Properties of Tris-diamine Ruthenium Chelates Yan Wang, Yuekui Wang, Jianming Wang, Yang Liu and Yitao Yang pp 8839–8847 DOI: 10.1021/ja9004738 Supporting Info |
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Crystal Structures of Cyclohexanone Monooxygenase Reveal Complex Domain Movements and a Sliding Cofactor I. Ahmad Mirza, Brahm J. Yachnin, Shaozhao Wang, Stephan Grosse, H pp 8848–8854 DOI: 10.1021/ja9010578 Supporting Info |
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Iridium-Catalyzed Asymmetric Hydrogenation Yielding Chiral Diarylmethines with Weakly Coordinating or Noncoordinating Substituents P pp 8855–8860 DOI: 10.1021/ja9013375 Supporting Info |
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Synthesis of Trimethylplatinum(IV) Complexes with N,N- and N,O-Heterocyclic Carbene Ligands and Their Reductive C−C Elimination Reactions Ronald Lindner, Christoph Wagner and Dirk Steinborn pp 8861–8874 DOI: 10.1021/ja901264t Supporting Info |
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Storage of Hydrogen, Methane, and Carbon Dioxide in Highly Porous Covalent Organic Frameworks for Clean Energy Applications Hiroyasu Furukawa and Omar M. Yaghi pp 8875–8883 DOI: 10.1021/ja9015765 Supporting Info |
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Depressed Phase Transition in Solution-Grown VO2 Nanostructures Luisa Whittaker, Cherno Jaye, Zugen Fu, Daniel A. Fischer and Sarbajit Banerjee pp 8884–8894 DOI: 10.1021/ja902054w |
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A Five-Center Redox System: Molecular Coupling of Two Noninnocent Imino-o-benzoquinonato-Ruthenium Functions through a π Acceptor Bridge Atanu Kumar Das, Biprajit Sarkar, Jan Fiedler, Stanislav Z pp 8895–8902 DOI: 10.1021/ja901746x Supporting Info |
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Molecular Design, Device Function and Surface Potential of Zwitterionic Electron Injection Layers Huaping Li, Yunhua Xu, Corey V. Hoven, Chunzeng Li, Jung Hwa Seo and Guillermo C. Bazan pp 8903–8912 DOI: 10.1021/ja9018836 Supporting Info |
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Ion-Induced Formation of Charge-Transfer States in Conjugated Polyelectrolytes Justin M. Hodgkiss, Guoli Tu, Sebastian Albert-Seifried, Wilhelm T. S. Huck and Richard H. Friend pp 8913–8921 DOI: 10.1021/ja902167a |
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Host−Guest Interactions between Molecular Clips and Multistate Systems Based on Flavylium Salts Raquel Gomes, A. Jorge Parola, Frank Bastkowski, Jolanta Polkowska and Frank-Gerrit Kl pp 8922–8938 DOI: 10.1021/ja9019098 Supporting Info |
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Hydrogen-Promoted Oxygen Activation by Free Gold Cluster Cations Sandra M. Lang, Thorsten M. Bernhardt, Robert N. Barnett, Bokwon Yoon and Uzi Landman pp 8939–8951 DOI: 10.1021/ja9022368 |
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Toward an n-Type Molecular Wire: Electron Hopping within Linearly Linked Perylenediimide Oligomers Thea M. Wilson, Michael J. Tauber and Michael R. Wasielewski pp 8952–8957 DOI: 10.1021/ja902258g Supporting Info |
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Synthesis, Structure, and Bonding of Weakly Coordinating Anions Based on CN Adducts Arne Bernsdorf, Harald Brand, Robert Hellmann, Martin K pp 8958–8970 DOI: 10.1021/ja902450b Supporting Info |
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Regio- and Enantioselective N-Allylations of Imidazole, Benzimidazole, and Purine Heterocycles Catalyzed by Single-Component Metallacyclic Iridium Complexes Levi M. Stanley and John F. Hartwig pp 8971–8983 DOI: 10.1021/ja902243s Supporting Info |
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Lithium Salt of Tetrahydroxybenzoquinone: Toward the Development of a Sustainable Li-Ion Battery Haiyan Chen, Michel Armand, Matthieu Courty, Meng Jiang, Clare P. Grey, Franck Dolhem, Jean-Marie Tarascon and Philippe Poizot pp 8984–8988 DOI: 10.1021/ja9024897 |
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Borylene-Based Direct Functionalization of Organic Substrates: Synthesis, Characterization, and Photophysical Properties of Novel π-Conjugated Borirenes Holger Braunschweig, Thomas Herbst, Daniela Rais, Sundargopal Ghosh, Thomas Kupfer and Krzysztof Radacki, Andrew G. Crawford, Richard M. Ward and Todd B. Marder, Israel Fern pp 8989–8999 DOI: 10.1021/ja902198z Supporting Info |
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Exploring the Reactivity of Ru-Based Metathesis Catalysts with a π-Acid Ligand Trans to the Ru−Ylidene Bond Albert Poater, Francesco Ragone, Andrea Correa and Luigi Cavallo pp 9000–9006 DOI: 10.1021/ja902552m Supporting Info |
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Design Strategies for Ratiometric Chemosensors: Modulation of Excitation Energy Transfer at the Energy Donor Site Ruslan Guliyev, Ali Coskun and Engin U. Akkaya pp 9007–9013 DOI: 10.1021/ja902584a Supporting Info |
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Discovery of Potent and Practical Antiangiogenic Agents Inspired by Cortistatin A Barbara Czak pp 9014–9019 DOI: 10.1021/ja902601e Supporting Info |
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Probing Single-Molecule Interfacial Geminate Electron−Cation Recombination Dynamics Yuanmin Wang, Xuefei Wang and H. Peter Lu pp 9020–9025 DOI: 10.1021/ja902640q |
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Functionalization of Nine-Atom Deltahedral Zintl Ions with Organic Substituents: Detailed Studies of the Reactions Michael W. Hull and Slavi C. Sevov pp 9026–9037 DOI: 10.1021/ja9025962 Supporting Info |
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Studies for the Synthesis of Xenicane Diterpenes. A Stereocontrolled Total Synthesis of 4-Hydroxydictyolactone David R. Williams, Martin J. Walsh and Nathan A. Miller pp 9038–9045 DOI: 10.1021/ja902677t Supporting Info |
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Quenched Ligand-Directed Tosylate Reagents for One-Step Construction of Turn-On Fluorescent Biosensors Shinya Tsukiji, Hangxiang Wang, Masayoshi Miyagawa, Tomonori Tamura, Yousuke Takaoka and Itaru Hamachi pp 9046–9054 DOI: 10.1021/ja902486c Supporting Info |
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γ-Agostic Species as Key Intermediates in the Vinyl Addition Polymerization of Norbornene with Cationic (allyl)Pd Catalysts: Synthesis and Mechanistic Insights Marc D. Walter, Rebecca A. Moorhouse, Stephanie A. Urbin, Peter S. White and Maurice Brookhart pp 9055–9069 DOI: 10.1021/ja9025598 Supporting Info |
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The Tetracyanopyrazinide Dimer Dianion, [TCNP]22−. 2-Electron 8-Center Bonding Juan J. Novoa, Peter W. Stephens, Mahika Weerasekare, William W. Shum and Joel S. Miller pp 9070–9075 DOI: 10.1021/ja902790q Supporting Info |
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Luminescent Cyclometalated N-Heterocyclic Carbene-Containing Organogold(III) Complexes: Synthesis, Characterization, Electrochemistry, and Photophysical Studies Vonika Ka-Man Au, Keith Man-Chung Wong, Nianyong Zhu and Vivian Wing-Wah Yam pp 9076–9085 DOI: 10.1021/ja9027692 Supporting Info |
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Diffusion-Ordered NMR Spectroscopy in the Structural Characterization of Functionalized Carbon Nanotubes Riccardo Marega, Vincent Aroulmoji, Francesca Dinon, Lisa Vaccari, Silvia Giordani, Alberto Bianco, Erminio Murano and Maurizio Prato pp 9086–9093 DOI: 10.1021/ja902728w Supporting Info |
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In Vivo Formation of Protein Based Aqueous Microcompartments Xin Ge, Andrew J. Conley, Jim E. Brandle, Ray Truant and Carlos D. M. Filipe pp 9094–9099 DOI: 10.1021/ja902890r Supporting Info |
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Enhancement of Energy Utilization in Light-Harvesting Dendrimers by the Pseudorotaxane Formation at Periphery Yi Zeng, Yingying Li, Ming Li, Guoqiang Yang and Yi Li pp 9100–9106 DOI: 10.1021/ja902998g Supporting Info |
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The Temperature-Dependent Structure of Alkylamines and Their Corresponding Alkylammonium-Alkylcarbamates Nataly Belman, Jacob N. Israelachvili, Youli Li, Cyrus R. Safinya, Joel Bernstein and Yuval Golan pp 9107–9113 DOI: 10.1021/ja902944t Supporting Info |
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Seed-Mediated Synthesis of Palladium Nanorods and Branched Nanocrystals and Their Use as Recyclable Suzuki Coupling Reaction Catalysts Yi-Hsiu Chen, Hsiao-Hui Hung and Michael H. Huang pp 9114–9121 DOI: 10.1021/ja903305d Supporting Info |
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Probing the Surface Glass Transition Temperature of Polymer Films via Organic Semiconductor Growth Mode, Microstructure, and Thin-Film Transistor Response Choongik Kim, Antonio Facchetti and Tobin J. Marks pp 9122–9132 DOI: 10.1021/ja902788z Supporting Info |
Issue 26
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Asymmetric 1,4-Dihydroxylation of 1,3-Dienes by Catalytic Enantioselective Diboration Heather E. Burks, Laura T. Kliman and James P. Morken pp 9134–9135 DOI: 10.1021/ja809610h Supporting Info |
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A Superprotein Triangle Driven by Nickel(II) Coordination: Exploiting Non-Natural Metal Ligands in Protein Self-Assembly Robert J. Radford and F. Akif Tezcan pp 9136–9137 DOI: 10.1021/ja9000695 Supporting Info |
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η3-Silapropargyl/Alkynylsilyl Molybdenum Complexes: Synthesis, Structure, and Reactivity toward Methanol Mako Yabe-Yoshida, Chizuko Kabuto, Kuninobu Kabuto, Eunsang Kwon and Hiroyuki Sakaba pp 9138–9139 DOI: 10.1021/ja9005833 Supporting Info |
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Brønsted Base/Lewis Acid Cooperative Catalysis in the Enantioselective Conia-Ene Reaction Ting Yang, Alessandro Ferrali, Filippo Sladojevich, Leonie Campbell and Darren J. Dixon pp 9140–9141 DOI: 10.1021/ja9004859 Supporting Info |
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Digital Analysis of Protein Properties by an Ensemble of DNA Quadruplexes David Margulies and Andrew D. Hamilton pp 9142–9143 DOI: 10.1021/ja900848t Supporting Info |
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Chemical Synthesis of Air-Stable Manganese Nanoparticles James F. Bondi, Karl D. Oyler, Xianglin Ke, Peter Schiffer and Raymond E. Schaak pp 9144–9145 DOI: 10.1021/ja901372q Supporting Info |
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Time-Resolved Study of Surface Spin Effect on Spin−Lattice Relaxation in Fe3O4 Nanocrystals Chih-Hao Hsia, Tai-Yen Chen and Dong Hee Son pp 9146–9147 DOI: 10.1021/ja901484x Supporting Info |
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Solvent-free Fluids Based on Rhombohedral Nanoparticles of Calcium Carbonate Qi Li, Lijie Dong, Wei Deng, Qingming Zhu, Yun Liu and Chuanxi Xiong pp 9148–9149 DOI: 10.1021/ja902197v Supporting Info |
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Reagent-Directed Allylic Quadraselection. Chemoselective Anti- and Syn-Lawton SN2′ Methylation of Seven-Membered Epoxyvinylsulfones Wan Pyo Hong, Ahmad El-Awa and Philip L. Fuchs pp 9150–9151 DOI: 10.1021/ja9017557 Supporting Info |
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Block Copolymer Mediated Synthesis of Dendritic Platinum Nanoparticles Liang Wang and Yusuke Yamauchi pp 9152–9153 DOI: 10.1021/ja902485x Supporting Info |
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Folding DNA Origami from a Double-Stranded Source of Scaffold Bj pp 9154–9155 DOI: 10.1021/ja902569x Supporting Info |
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Fluorescent Cassettes for Monitoring Three-Component Interactions in Vitro and in Living Cells Liangxing Wu, Aurore Loudet, Rola Barhoumi, Robert C. Burghardt and Kevin Burgess pp 9156–9157 DOI: 10.1021/ja9029413 Supporting Info |
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From Thiophene [2]Rotaxane to Polythiophene Polyrotaxane Taichi Ikeda, Masayoshi Higuchi and Dirk G. Kurth pp 9158–9159 DOI: 10.1021/ja902992c Supporting Info |
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Ni(0)-Catalyzed Formation of Azaaluminacyclopentenes via Azanickelacyclopentenes: A Unique Nickel/Aluminum Double Transmetalation Reaction Masato Ohashi, Osamu Kishizaki, Haruo Ikeda and Sensuke Ogoshi pp 9160–9161 DOI: 10.1021/ja903175g Supporting Info |
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Stabilization of Iridium(IV) by Monoanionic Dialkyldiarylguanidinato Ligands Jan-Uwe Rohde and Wei-Tsung Lee pp 9162–9163 DOI: 10.1021/ja9033445 Supporting Info |
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A Streptavidin−Protein Cage Janus Particle for Polarized Targeting and Modular Functionalization Peter A. Suci, Sebyung Kang, Mark Young and Trevor Douglas pp 9164–9165 DOI: 10.1021/ja9035187 Supporting Info |
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A Single Bicontinuous Cubic Phase Induced by Fusion Peptides Marc Fuhrmans, Volker Knecht and Siewert J. Marrink pp 9166–9167 DOI: 10.1021/ja903224q Supporting Info |
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A Homodinuclear Mn(III)2−Schiff Base Complex for Catalytic Asymmetric 1,4-Additions of Oxindoles to Nitroalkenes Yuko Kato, Makoto Furutachi, Zhihua Chen, Harunobu Mitsunuma, Shigeki Matsunaga and Masakatsu Shibasaki pp 9168–9169 DOI: 10.1021/ja903566u Supporting Info |
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Shape Tuning of Type II CdTe-CdSe Colloidal Nanocrystal Heterostructures through Seeded Growth Haizheng Zhong and Gregory D. Scholes pp 9170–9171 DOI: 10.1021/ja903722d Supporting Info |
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Scalable Total Synthesis and Biological Evaluation of Haouamine A and Its Atropisomer Noah Z. Burns, Irina N. Krylova, Rami N. Hannoush and Phil S. Baran pp 9172–9173 DOI: 10.1021/ja903745s Supporting Info |
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Amidine Dications: Isolation and [Fe]-Hydrogenase-Related Hydrogenation Michael J. Corr, Kirsty F. Gibson, Alan R. Kennedy and John A. Murphy pp 9174–9175 DOI: 10.1021/ja9035847 Supporting Info |
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Seven-Coordinate Homoleptic Metal Carbonyls in the Gas Phase Allen M. Ricks, Zach D. Reed and Michael A. Duncan pp 9176–9177 DOI: 10.1021/ja903983u Supporting Info |
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Gold(I)-Catalyzed Enantioselective Ring Expansion of Allenylcyclopropanols Florian Kleinbeck and F. Dean Toste pp 9178–9179 DOI: 10.1021/ja904055z Supporting Info |
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Oxidation of Element 102, Nobelium, with Flow Electrolytic Column Chromatography on an Atom-at-a-Time Scale Atsushi Toyoshima, Yoshitaka Kasamatsu, Kazuaki Tsukada, Masato Asai, Yoshihiro Kitatsuji, Yasuo Ishii, Hayato Toume, Ichiro Nishinaka, Hiromitsu Haba, Kazuhiro Ooe, Wataru Sato, Atsushi Shinohara, Kazuhiko Akiyama and Yuichiro Nagame pp 9180–9181 DOI: 10.1021/ja9030038 Supporting Info |
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Consecutive Intramolecular Hydroamination/Asymmetric Transfer Hydrogenation under Relay Catalysis of an Achiral Gold Complex/Chiral Brønsted Acid Binary System Zhi-Yong Han, Han Xiao, Xiao-Hua Chen and Liu-Zhu Gong pp 9182–9183 DOI: 10.1021/ja903547q Supporting Info |
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ENDOR Spectroscopy Shows That Guanine N1 Binds to [4Fe−4S] Cluster II of the S-Adenosylmethionine-Dependent Enzyme MoaA: Mechanistic Implications Nicholas S. Lees, Petra H pp 9184–9185 DOI: 10.1021/ja903978u Supporting Info |
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Stabilization of Metal−Organic Frameworks with High Surface Areas by the Incorporation of Mesocavities with Microwindows Dan Zhao, Daqiang Yuan, Daofeng Sun and Hong-Cai Zhou pp 9186–9188 DOI: 10.1021/ja901109t Supporting Info |
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Reactivity-Dependent PCR: Direct, Solution-Phase in Vitro Selection for Bond Formation David J. Gorin, Adam S. Kamlet and David R. Liu pp 9189–9191 DOI: 10.1021/ja903084a Supporting Info |
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Making Hydrogen from Water Using a Homogeneous System Without Noble Metals Theodore Lazarides, Theresa McCormick, Pingwu Du, Gengeng Luo, Brian Lindley and Richard Eisenberg pp 9192–9194 DOI: 10.1021/ja903044n Supporting Info |
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Liquid-Phase Synthesis of Block Copolymers Containing Sequence-Ordered Segments Sebastian Pfeifer, Zoya Zarafshani, Nezha Badi and Jean-Fran pp 9195–9197 DOI: 10.1021/ja903635y Supporting Info |
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Radioactivity-Synchronized Fluorescence Enhancement Using a Radionuclide Fluorescence-Quenched Dye Mikhail Y. Berezin, Kevin Guo, Bao Teng, W. Barry Edwards, Carolyn J. Anderson, Olga Vasalatiy, Amir Gandjbakhche, Gary L. Griffiths and Samuel Achilefu pp 9198–9200 DOI: 10.1021/ja903685b Supporting Info |
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Syntheses of PBP Pincer Iridium Complexes: A Supporting Boryl Ligand Yasutomo Segawa, Makoto Yamashita and Kyoko Nozaki pp 9201–9203 DOI: 10.1021/ja9037092 Supporting Info |
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Localized and Sustained Delivery of Silencing RNA from Macroscopic Biopolymer Hydrogels Melissa D. Krebs, Oju Jeon and Eben Alsberg pp 9204–9206 DOI: 10.1021/ja9037615 Supporting Info |
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High-Throughput Screening of Nanoparticle Catalysts Made by Flame Spray Pyrolysis as Hydrocarbon/NO Oxidation Catalysts B. Weidenhof, M. Reiser, K. St pp 9207–9219 DOI: 10.1021/ja809134s Supporting Info |
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One-Step Synthesis of Core−Shell (Ce0.7Zr0.3O2)x(Al2O3)1−x [(Ce0.7Zr0.3O2)@Al2O3] Nanopowders via Liquid-Feed Flame Spray Pyrolysis (LF-FSP) Min Kim and Richard M. Laine pp 9220–9229 DOI: 10.1021/ja9017545 Supporting Info |
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On the Contributions of Diffusion and Thermal Activation to Electron Transfer between Phormidium laminosum Plastocyanin and Cytochrome f: Brownian Dynamics Simulations with Explicit Modeling of Nonpolar Desolvation Interactions and Electron Transfer Events Razif R. Gabdoulline and Rebecca C. Wade pp 9230–9238 DOI: 10.1021/ja809567k |
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Real-Time NMR Investigations of Structural Changes in Silicon Electrodes for Lithium-Ion Batteries Baris Key, Rangeet Bhattacharyya, Mathieu Morcrette, Vincent Sezn pp 9239–9249 DOI: 10.1021/ja8086278 Supporting Info |
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Rapid Cross-Linking of an RNA Internal Loop by the Anticancer Drug Cisplatin Alethia A. Hostetter, Erich G. Chapman and Victoria J. DeRose pp 9250–9257 DOI: 10.1021/ja809637e Supporting Info |
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Aliphatic C−H Bond Activation Initiated by a (μ-η2:η2-Peroxo)dicopper(II) Complex in Comparison with Cumylperoxyl Radical Takahiro Matsumoto, Kei Ohkubo, Kaoru Honda, Akiko Yazawa, Hideki Furutachi, Shuhei Fujinami, Shunichi Fukuzumi and Masatatsu Suzuki pp 9258–9267 DOI: 10.1021/ja809822c Supporting Info |
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Stabilization of Three-Way Junctions of DNA under Molecular Crowding Conditions Sanjukta Muhuri, Kenta Mimura, Daisuke Miyoshi and Naoki Sugimoto pp 9268–9280 DOI: 10.1021/ja900744e Supporting Info |
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Molecular and Morphological Influences on the Open Circuit Voltages of Organic Photovoltaic Devices M. Dolores Perez, Carsten Borek, Stephen R. Forrest and Mark E. Thompson pp 9281–9286 DOI: 10.1021/ja9007722 Supporting Info |
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Single-Molecule Protein Unfolding in Solid State Nanopores David S. Talaga and Jiali Li pp 9287–9297 DOI: 10.1021/ja901088b Supporting Info |
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From Synthesis to Biologics: Preclinical Data on a Chemistry Derived Anticancer Vaccine Jianglong Zhu, Qian Wan, Dongjoo Lee, Guangbin Yang, Maria K. Spassova, Ouathek Ouerfelli, Govind Ragupathi, Payal Damani, Philip O. Livingston and Samuel J. Danishefsky pp 9298–9303 DOI: 10.1021/ja901415s |
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Investigating the Hydrogen-Bonding Model of Urea Denaturation Laura B. Sagle, Yanjie Zhang, Vladislav A. Litosh, Xin Chen, Younhee Cho and Paul S. Cremer pp 9304–9310 DOI: 10.1021/ja9016057 Supporting Info |
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“Clickable” Polymer-Caged Nanobins as a Modular Drug Delivery Platform Sang-Min Lee, Haimei Chen, Thomas V. O’Halloran and SonBinh T. Nguyen pp 9311–9320 DOI: 10.1021/ja9017336 Supporting Info |
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Optimization of FeMoco Maturation on NifEN Janice M. Yoshizawa, Michael A. Blank, Aaron W. Fay, Chi Chung Lee, Jared A. Wiig, Yilin Hu, Keith O. Hodgson, Britt Hedman and Markus W. Ribbe pp 9321–9325 DOI: 10.1021/ja9035225 Supporting Info |
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Real-Time Monitoring of Cell-Free Translation on a Quartz-Crystal Microbalance Shuntaro Takahashi, Masaaki Iida, Hiroyuki Furusawa, Yoshihiro Shimizu, Takuya Ueda and Yoshio Okahata pp 9326–9332 DOI: 10.1021/ja9019947 |
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Temperature Dependence of “Elementary Processes” in Doping Semiconductor Nanocrystals Dingan Chen, Ranjani Viswanatha, Grace L. Ong, Renguo Xie, Mahalingam Balasubramaninan and Xiaogang Peng pp 9333–9339 DOI: 10.1021/ja9018644 Supporting Info |
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Anisotropic Magnetic Behavior of Anionic Ce@C82 Carbene Adducts Yuta Takano, Motoki Aoyagi, Michio Yamada, Hidefumi Nikawa, Zdenek Slanina, Naomi Mizorogi, Midori O. Ishitsuka, Takahiro Tsuchiya, Yutaka Maeda, Takeshi Akasaka, Tatsuhisa Kato and Shigeru Nagase pp 9340–9346 DOI: 10.1021/ja902106a Supporting Info |
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Escherichia coli Allows Efficient Modular Incorporation of Newly Isolated Quinomycin Biosynthetic Enzyme into Echinomycin Biosynthetic Pathway for Rational Design and Synthesis of Potent Antibiotic Unnatural Natural Product Kenji Watanabe, Kinya Hotta, Mino Nakaya, Alex P. Praseuth, Clay C. C. Wang, Daiki Inada, Kosaku Takahashi, Eri Fukushi, Hiroki Oguri and Hideaki Oikawa pp 9347–9353 DOI: 10.1021/ja902261a Supporting Info |
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DNA Repair and DNA Triplet Repeat Expansion: The Impact of Abasic Lesions on Triplet Repeat DNA Energetics Jens V pp 9354–9360 DOI: 10.1021/ja902161e Supporting Info |
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A Non-Chromatographic Method for the Purification of a Bivalently Active Monoclonal IgG Antibody from Biological Fluids Ba pp 9361–9367 DOI: 10.1021/ja9023836 Supporting Info |
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Universal Translators for Nucleic Acid Diagnosis John M. Picuri, Brian M. Frezza and M. Reza Ghadiri pp 9368–9377 DOI: 10.1021/ja902490x Supporting Info |
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trans-2 Addition Pattern to Power Charge Transfer in Dendronized Metalloporphyrin C60 Conjugates Fabian Sp pp 9378–9388 DOI: 10.1021/ja9029686 Supporting Info |
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One-Pot Synthesis of Platinum-Based Nanoparticles Incorporated into Mesoporous Niobium Oxide−Carbon Composites for Fuel Cell Electrodes M. Christopher Orilall, Futoshi Matsumoto, Qin Zhou, Hiroaki Sai, H pp 9389–9395 DOI: 10.1021/ja903296r Supporting Info |
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Crystalline Ultrasmooth Self-Assembled Monolayers of Alkylsilanes for Organic Field-Effect Transistors Yutaka Ito, Ajay A. Virkar, Stefan Mannsfeld, Joon Hak Oh, Michael Toney, Jason Locklin and Zhenan Bao pp 9396–9404 DOI: 10.1021/ja9029957 Supporting Info |
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Intrinsic Dipole-Field-Driven Mesoscale Crystallization of Core−Shell ZnO Mesocrystal Microspheres Z. Liu, X. D. Wen, X. L. Wu, Y. J. Gao, H. T. Chen, J. Zhu and P. K. Chu pp 9405–9412 DOI: 10.1021/ja9039136 Supporting Info |
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Design, Synthesis, and Investigation of Protein Kinase C Inhibitors: Total Syntheses of (+)-Calphostin D, (+)-Phleichrome, Cercosporin, and New Photoactive Perylenequinones Barbara J. Morgan, Sangeeta Dey, Steven W. Johnson and Marisa C. Kozlowski pp 9413–9425 DOI: 10.1021/ja902324j Supporting Info |
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Designing 3-D Molecular Stars William Tiznado, Nancy Perez-Peralta, Rafael Islas, Alejandro Toro-Labbe, Jesus M. Ugalde and Gabriel Merino pp 9426–9431 DOI: 10.1021/ja903694d Supporting Info |
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Asymmetric Synthesis of Indolines through Intramolecular Shifting of Aromatic Sulfinyl Groups. Role of the π,π-Stacking Interactions in these Unusual SNAr Processes Jos pp 9432–9441 DOI: 10.1021/ja8096527 Supporting Info |
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Structure of Triplet Propynylidene (HCCCH) as Probed by IR, UV/vis, and EPR Spectroscopy of Isotopomers Randal A. Seburg, Eric V. Patterson and Robert J. McMahon pp 9442–9455 DOI: 10.1021/ja901606a Supporting Info |
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Photoacid for Extremely Long-Lived and Reversible pH-Jumps Rui M. D. Nunes, Marta Pineiro and Luis G. Arnaut pp 9456–9462 DOI: 10.1021/ja901930c Supporting Info |
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Caged Progesterone: A New Tool for Studying Rapid Nongenomic Actions of Progesterone Funda Kilic, Nachiket D. Kashikar, Reinhard Schmidt, Luis Alvarez, Luru Dai, Ingo Weyand, Burkhard Wiesner, Normann Goodwin, Volker Hagen and U. Benjamin Kaupp p 9463 DOI: 10.1021/ja902938k |
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Water Overcomes Methyl Group Directing Effects in Epoxide-Opening Cascades Christopher J. Morten and Timothy F. Jamison p 9463 DOI: 10.1021/ja903581c |
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Palladium Catalyzed Tandem Ring Opening−Ring Closing Reaction of Diazabicyclic Alkenes: A Facile One Pot Strategy for Cyclopentannulation of Heterocycles Jubi John, Indu U., Eringathodi Suresh and K. V. Radhakrishnan p 9463 DOI: 10.1021/ja9031715 Supporting Info |
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Water − From Interfaces to the Bulk. Faraday Discussions, Volume 141 p 9464 DOI: 10.1021/ja903648j |
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Nucleic Acid−Metal Ion Interactions Richard L. Karpel pp 9464–9465 DOI: 10.1021/ja9043483 |
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Electrochemical Surface Modification: Thin Films, Functionalization and Characterization. From the series, Advances in Electrochemical Science and Engineering, Volume 10 Keith J. Stine pp 9465–9466 DOI: 10.1021/ja9040434 |
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Annual Review of Physical Chemistry, Vol. 60 p 9466 DOI: 10.1021/ja904760c |
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Electrocatalysis: Theory and Experiment at the Interface. Faraday Discussions, Vol. 140 p 9466 DOI: 10.1021/ja904745u |
Issue 27
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Molybdenum Nitride Complexes with Ph3SiO Ligands Are Exceedingly Practical and Tolerant Precatalysts for Alkyne Metathesis and Efficient Nitrogen Transfer Agents Martin Bindl, Robert Stade, Eike K. Heilmann, Alexandre Picot, Richard Goddard and Alois F pp 9468–9470 DOI: 10.1021/ja903259g Supporting Info |
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Cobalt−Dinitrogen Complexes with Weakened N−N Bonds Keying Ding, Aaron W. Pierpont, William W. Brennessel, Gudrun Lukat-Rodgers, Kenton R. Rodgers, Thomas R. Cundari, Eckhard Bill and Patrick L. Holland pp 9471–9472 DOI: 10.1021/ja808783u Supporting Info |
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Aldehyde Selective Wacker Oxidations of Phthalimide Protected Allylic Amines: A New Catalytic Route to β3-Amino Acids Barbara Weiner, Alejandro Baeza, Thomas Jerphagnon and Ben L. Feringa pp 9473–9474 DOI: 10.1021/ja902591g Supporting Info |
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Protein Autoproteolysis: Conformational Strain Linked to the Rate of Peptide Cleavage by the pH Dependence of the N → O Acyl Shift Reaction Denny G. A. Johansson, G pp 9475–9477 DOI: 10.1021/ja9010817 Supporting Info |
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Energy Transfer in a Mechanically Trapped Exciplex Jeremy K. Klosterman, Munetaka Iwamura, Tahei Tahara and Makoto Fujita pp 9478–9479 DOI: 10.1021/ja901674g Supporting Info |
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Automated Assignment in Selectively Methyl-Labeled Proteins Yingqi Xu, Minhao Liu, Peter J. Simpson, Rivka Isaacson, Ernesto Cota, Jan Marchant, Daiwen Yang, Xiaodong Zhang, Paul Freemont and Stephen Matthews pp 9480–9481 DOI: 10.1021/ja9020233 Supporting Info |
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Carborane-Based Pincers: Synthesis and Structure of SeBSe and SBS Pd(II) Complexes Alexander M. Spokoyny, Matthew G. Reuter, Charlotte L. Stern, Mark A. Ratner, Tamar Seideman and Chad A. Mirkin pp 9482–9483 DOI: 10.1021/ja902526k Supporting Info |
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Detecting Weak Interactions between Au− and Gas Molecules: A Photoelectron Spectroscopic and Ab Initio Study Yi Gao, Wei Huang, Jeffrey Woodford, Lai-Sheng Wang and Xiao Cheng Zeng pp 9484–9485 DOI: 10.1021/ja903043d Supporting Info |
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BaNbO(IO3)5: A New Polar Material with a Very Large SHG Response Chuan-Fu Sun, Chun-Li Hu, Xiang Xu, Ji-Bei Ling, Ting Hu, Fang Kong, Xi-Fa Long and Jiang-Gao Mao pp 9486–9487 DOI: 10.1021/ja9030566 Supporting Info |
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Palladium-Catalyzed Carboamination of Alkenes Promoted by N-Fluorobenzenesulfonimide via C−H Activation of Arenes Carolyn F. Rosewall, Paul A. Sibbald, Dmitry V. Liskin and Forrest E. Michael pp 9488–9489 DOI: 10.1021/ja9031659 Supporting Info |
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Chemical Shift Anisotropy of Imino 15N Nuclei in Watson−Crick Base Pairs from Magic Angle Spinning Liquid Crystal NMR and Nuclear Spin Relaxation Alexander Grishaev, Lishan Yao, Jinfa Ying, Arthur Pardi and Ad Bax pp 9490–9491 DOI: 10.1021/ja903244s Supporting Info |
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Isoreticular Metalation of Metal−Organic Frameworks Christian J. Doonan, William Morris, Hiroyasu Furukawa and Omar M. Yaghi pp 9492–9493 DOI: 10.1021/ja903251e Supporting Info |
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Nuclear Magnetic Resonance Signaling of Molecular Chiral Information Using an Achiral Reagent Atsuomi Shundo, Jan Labuta, Jonathan P. Hill, Shinsuke Ishihara and Katsuhiko Ariga pp 9494–9495 DOI: 10.1021/ja903371d Supporting Info |
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Hydrogen-Bonding Recognition-Induced Color Change of Gold Nanoparticles for Visual Detection of Melamine in Raw Milk and Infant Formula Kelong Ai, Yanlan Liu and Lehui Lu pp 9496–9497 DOI: 10.1021/ja9037017 Supporting Info |
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Impact of NHC Ligand Conformation and Solvent Concentration on the Ruthenium-Catalyzed Ring-Closing Metathesis Reaction Michele Gatti, Ludovic Vieille-Petit, Xinjun Luan, Ronaldo Mariz, Emma Drinkel, Anthony Linden and Reto Dorta pp 9498–9499 DOI: 10.1021/ja903554v Supporting Info |
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CO Assistance in Ligand Exchange of a Ruthenium Racemization Catalyst: Identification of an Acyl Intermediate Jenny B. Åberg, Jonas Nyhl pp 9500–9501 DOI: 10.1021/ja9038455 Supporting Info |
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Quaternary Alloy Semiconductor Nanobelts with Bandgap Spanning the Entire Visible Spectrum Anlian Pan, Ruibin Liu, Minghua Sun and Cun-Zheng Ning pp 9502–9503 DOI: 10.1021/ja904137m Supporting Info |
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Bi3Mn3O11: A New KSbO3-Type Random Ferrimagnet with High TC Alexei A. Belik and Eiji Takayama-Muromachi pp 9504–9505 DOI: 10.1021/ja904215h Supporting Info |
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The R46Q, R131Q and R154H Polymorphs of Human DNA Glycosylase/β-Lyase hOgg1 Severely Distort the Active Site and DNA Recognition Site but do not Cause Unfolding Peter C. Anderson and Valerie Daggett pp 9506–9515 DOI: 10.1021/ja809726e |
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Elucidating the Mechanism of Lipid Membrane-Induced IAPP Fibrillogenesis and Its Inhibition by the Red Wine Compound Resveratrol: A Synchrotron X-ray Reflectivity Study Florian Evers, Christoph Jeworrek, Sebastian Tiemeyer, Katrin Weise, Daniel Sellin, Michael Paulus, Bernd Struth, Metin Tolan and Roland Winter pp 9516–9521 DOI: 10.1021/ja8097417 Supporting Info |
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Using the Experimentally Determined Components of the Overall Rotational Diffusion Tensor To Restrain Molecular Shape and Size in NMR Structure Determination of Globular Proteins and Protein−Protein Complexes Yaroslav Ryabov, Jeong-Yong Suh, Alexander Grishaev, G. Marius Clore and Charles D. Schwieters pp 9522–9531 DOI: 10.1021/ja902336c Supporting Info |
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Determination of the Solution-Bound Conformation of an Amino Acid Binding Protein by NMR Paramagnetic Relaxation Enhancement: Use of a Single Flexible Paramagnetic Probe with Improved Estimation of Its Sampling Space Guillermo A. Bermejo, Marie-Paule Strub, Chien Ho and Nico Tjandra pp 9532–9537 DOI: 10.1021/ja902436g |
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Advanced Monte Carlo Approach To Study Evolution of Quartz Surface during the Dissolution Process Shikha Nangia and Barbara J. Garrison pp 9538–9546 DOI: 10.1021/ja901305y |
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Desulfinylation of Prop-2-enesulfinic Acid: Experimental Results and Mechanistic Theoretical Analysis Adri pp 9547–9561 DOI: 10.1021/ja901565s Supporting Info |
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Detection of Bacterial Spores with Lanthanide−Macrocycle Binary Complexes Morgan L. Cable, James P. Kirby, Dana J. Levine, Micah J. Manary, Harry B. Gray and Adrian Ponce pp 9562–9570 DOI: 10.1021/ja902291v Supporting Info |
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Probing the Dynamics of the P1 Helix within the Tetrahymena Group I Intron Xuesong Shi, Emilia T. Mollova, Goran Pljevalj pp 9571–9578 DOI: 10.1021/ja902797j Supporting Info |
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Solvation and Hydrogen Bonding in Alanine- and Glycine-Containing Dipeptides Probed Using Solution- and Solid-State NMR Spectroscopy Manasi P. Bhate, Jaie C. Woodard and Manish A. Mehta pp 9579–9589 DOI: 10.1021/ja902917s Supporting Info |
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Hydroxyphosphine Ligand for Nickel-Catalyzed Cross-Coupling through Nickel/Magnesium Bimetallic Cooperation Naohiko Yoshikai, Hirokazu Matsuda and Eiichi Nakamura pp 9590–9599 DOI: 10.1021/ja903091g Supporting Info |
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Synthetic Efficiency in Enzyme Mechanisms Involving Carbocations: Aristolochene Synthase Rudolf K. Allemann, Neil J. Young, Shuhua Ma, Donald G. Truhlar and Jiali Gao p 9600 DOI: 10.1021/ja904281h |
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Chemistry of Boryllithium: Synthesis, Structure, and Reactivity Yasutomo Segawa, Yuta Suzuki, Makoto Yamashita and Kyoko Nozaki p 9600 DOI: 10.1021/ja903763a Supporting Info |
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Selective Ion Passage through Functionalized Graphene Nanopores Kyaw Sint, Boyang Wang and Petr Kr p 9600 DOI: 10.1021/ja903655u Supporting Info |
Issue 28
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Chiral-Auxiliary-Mediated Asymmetric Synthesis of Tris-Heteroleptic Ruthenium Polypyridyl Complexes Lei Gong, Seann P. Mulcahy, Klaus Harms and Eric Meggers pp 9602–9603 DOI: 10.1021/ja9031665 Supporting Info |
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Possible Origin of Electronic Effects in Rh(I)-Catalyzed Enantioselective Hydrogenation Hai-Chen Wu, Shafida Abd Hamid, Jin-Quan Yu and Jonathan B. Spencer pp 9604–9605 DOI: 10.1021/ja903089f Supporting Info |
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Accelerated Multidimensional NMR Data Acquisition by Varying the Pulse Sequence Repetition Time Slobodan Macura pp 9606–9607 DOI: 10.1021/ja9011063 Supporting Info |
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Identification, Characterization, and Bioconversion of a New Intermediate in Valanimycin Biosynthesis Ram P. Garg, Lawrence B. Alemany, Sean Moran and Ronald J. Parry pp 9608–9609 DOI: 10.1021/ja901243p Supporting Info |
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Nucleophile Generation via Decarboxylation: Asymmetric Construction of Contiguous Trisubstituted and Quaternary Stereocenters through a Cu(I)-Catalyzed Decarboxylative Mannich-Type Reaction Liang Yin, Motomu Kanai and Masakatsu Shibasaki pp 9610–9611 DOI: 10.1021/ja9036675 Supporting Info |
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α-Hydroxyalkyl Heterocycles via Chiral Allylic Boronates: Pd-Catalyzed Borylation Leading to a Formal Enantioselective Isomerization of Allylic Ether and Amine Stéphanie Lessard, Feng Peng and Dennis G. Hall pp 9612–9613 DOI: 10.1021/ja903946f Supporting Info |
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Organocatalytic Asymmetric Formal [3 + 2] Cycloaddition with in Situ-Generated N-Carbamoyl Nitrones Claudio Gioia, Francesco Fini, Andrea Mazzanti, Luca Bernardi and Alfredo Ricci pp 9614–9615 DOI: 10.1021/ja902458m Supporting Info |
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Evolution of Proteins with Genetically Encoded “Chemical Warheads” Chang C. Liu, Antha V. Mack, Eric M. Brustad, Jeremy H. Mills, Dan Groff, Vaughn V. Smider and Peter G. Schultz pp 9616–9617 DOI: 10.1021/ja902985e Supporting Info |
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Formation of [Ru(NHC)4(η2-O2)H]+: An Unusual, High Frequency Hydride Chemical Shift and Facile, Reversible Coordination of O2 L. Jonas L. Häller, Elena Mas-Marzá, Aitor Moreno, John P. Lowe, Stuart A. Macgregor, Mary F. Mahon, Paul S. Pregosin and Michael K. Whittlesey pp 9618–9619 DOI: 10.1021/ja9039345 Supporting Info |
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Controllable Columnar Organization of Positively Charged Polycyclic Aromatic Hydrocarbons by Choice of Counterions Dongqing Wu, Wojciech Pisula, Volker Enkelmann, Xinliang Feng and Klaus Müllen pp 9620–9621 DOI: 10.1021/ja902420u Supporting Info |
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Immunological Response from an Entirely Carbohydrate Antigen: Design of Synthetic Vaccines Based on Tn−PS A1 Conjugates Ravindra A. De Silva, Qianli Wang, Tristan Chidley, Dananjaya K. Appulage and Peter R. Andreana pp 9622–9623 DOI: 10.1021/ja902607a Supporting Info |
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Narrow-Band Absorption-Enhanced Quantum Dot/J-Aggregate Conjugates Brian J. Walker, Gautham P. Nair, Lisa F. Marshall, Vladimir Bulović and Moungi G. Bawendi pp 9624–9625 DOI: 10.1021/ja902813q Supporting Info |
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Differential Charge Polarization of Axial Histidines in Bacterial Reaction Centers Balances the Asymmetry of the Special Pair A. Alia, Piotr K. Wawrzyniak, Geertje J. Janssen, Francesco Buda, Jörg Matysik and Huub J. M. de Groot pp 9626–9627 DOI: 10.1021/ja9028507 Supporting Info |
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Formation of Protocell-like Vesicles in a Thermal Diffusion Column Itay Budin, Raphael J. Bruckner and Jack W. Szostak pp 9628–9629 DOI: 10.1021/ja9029818 Supporting Info |
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Fluorescent Lifetime Trajectories of a Single Fluorophore Reveal Reaction Intermediates During Transcription Initiation Maria Sorokina, Hye-Ran Koh, Smita S. Patel and Taekjip Ha pp 9630–9631 DOI: 10.1021/ja902861f Supporting Info |
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Competing Magnetism and Superconductivity in NaxCoO2 at Half Doping Manuel Bañobre-López, Francisco Rivadulla, M. Arturo López-Quintela and José Rivas pp 9632–9633 DOI: 10.1021/ja8100177 Supporting Info |
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Formation of Two- and Three-Dimensional Hybrid Mesostructures from Branched Siloxane Molecules Shigeru Sakamoto, Atsushi Shimojima, Keiichi Miyasaka, Juanfang Ruan, Osamu Terasaki and Kazuyuki Kuroda pp 9634–9635 DOI: 10.1021/ja903176k Supporting Info |
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Metal-Directed Synthesis of Enantiomerially Pure Dimetallic Lanthanide Luminescent Triple-Stranded Helicates Floriana Stomeo, Christophe Lincheneau, Joseph P. Leonard, John E. O’Brien, Robert D. Peacock, Colin P. McCoy and Thorfinnur Gunnlaugsson pp 9636–9637 DOI: 10.1021/ja9032204 Supporting Info |
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Synthesis of Periodic Mesoporous Coesite Paritosh Mohanty, Yingwei Fei and Kai Landskron pp 9638–9639 DOI: 10.1021/ja903286m Supporting Info |
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A Highly Reactive P450 Model Compound I Seth R. Bell and John T. Groves pp 9640–9641 DOI: 10.1021/ja903394s Supporting Info |
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Preparation and Crystal Growth of Na24Si136 Matt Beekman, Michael Baitinger, Horst Borrmann, Walter Schnelle, Katrin Meier, George S. Nolas and Yuri Grin pp 9642–9643 DOI: 10.1021/ja903362b Supporting Info |
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Turning MIL-53(Al) Redox-Active by Functionalization of the Bridging OH-Group with 1,1′-Ferrocenediyl-Dimethylsilane Mikhail Meilikhov, Kirill Yusenko and Roland A. Fischer pp 9644–9645 DOI: 10.1021/ja903918s Supporting Info |
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Ultrafast Time-Resolved Infrared Spectroscopy Study of the Photochemistry of N,N-Diethyldiazoacetamide: Rearrangement in the Excited State Yunlong Zhang, Gotard Burdziński, Jacek Kubicki and Matthew S. Platz pp 9646–9647 DOI: 10.1021/ja904009x Supporting Info |
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Total Synthesis of (−)-Himandrine Mohammad Movassaghi, Meiliana Tjandra and Jun Qi pp 9648–9650 DOI: 10.1021/ja903790y Supporting Info |
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Mechanism of Benzoquinone-Promoted Palladium-Catalyzed Oxidative Cross-Coupling Reactions Kami L. Hull and Melanie S. Sanford pp 9651–9653 DOI: 10.1021/ja901952h Supporting Info |
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Resonance Chemical Imaging of Polythiophene/Fullerene Photovoltaic Thin Films: Mapping Morphology-Dependent Aggregated and Unaggregated C═C Species Yongqian Gao and John K. Grey pp 9654–9662 DOI: 10.1021/ja900636z Supporting Info |
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Oxidation Unzipping of Stable Nanographenes into Joint Spin-Rich Fragments Xingfa Gao, Lu Wang, Yuhki Ohtsuka, De-en Jiang, Yuliang Zhao, Shigeru Nagase and Zhongfang Chen pp 9663–9669 DOI: 10.1021/ja902878w Supporting Info |
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Intramolecular Hydroamination of Aminoalkenes by Calcium and Magnesium Complexes: A Synthetic and Mechanistic Study Mark R. Crimmin, Merle Arrowsmith, Anthony G. M. Barrett, Ian J. Casely, Michael S. Hill and Panayiotis A. Procopiou pp 9670–9685 DOI: 10.1021/ja9003377 Supporting Info |
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Modeling the Multivalent Recognition between Dendritic Molecules and DNA: Understanding How Ligand “Sacrifice” and Screening Can Enhance Binding Giovanni M. Pavan, Andrea Danani, Sabrina Pricl and David K. Smith pp 9686–9694 DOI: 10.1021/ja901174k |
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Modular Nucleic Acid Assembled p/MHC Microarrays for Multiplexed Sorting of Antigen-Specific T Cells Gabriel A. Kwong, Caius G. Radu, Kiwook Hwang, Chengyi J. Shu, Chao Ma, Richard C. Koya, Begonya Comin-Anduix, Sine Reker Hadrup, Ryan C. Bailey, Owen N. Witte, Ton N. Schumacher, Antoni Ribas and James R. Heath pp 9695–9703 DOI: 10.1021/ja9006707 Supporting Info |
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Nature of Molecular Interactions of Peptides with Gold, Palladium, and Pd−Au Bimetal Surfaces in Aqueous Solution Hendrik Heinz, Barry L. Farmer, Ras B. Pandey, Joseph M. Slocik, Soumya S. Patnaik, Ruth Pachter and Rajesh R. Naik pp 9704–9714 DOI: 10.1021/ja900531f Supporting Info |
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Characterization of Dispersed Heteropoly Acid on Mesoporous Zeolite Using Solid-State 31P NMR Spin−Lattice Relaxation Kake Zhu, Jianzhi Hu, Xiaoyan She, Jun Liu, Zimin Nie, Yong Wang, Charles H. F. Peden and Ja Hun Kwak pp 9715–9721 DOI: 10.1021/ja901317r |
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Efficient Charge Transport in DNA Diblock Oligomers Josh Vura-Weis, Michael R. Wasielewski, Arun K. Thazhathveetil and Frederick D. Lewis pp 9722–9727 DOI: 10.1021/ja9015217 Supporting Info |
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Gyromagnetic Imaging: Dynamic Optical Contrast Using Gold Nanostars with Magnetic Cores Qingshan Wei, Hyon-Min Song, Alexei P. Leonov, Jacob A. Hale, Dongmyung Oh, Quy K. Ong, Kenneth Ritchie and Alexander Wei pp 9728–9734 DOI: 10.1021/ja901562j Supporting Info |
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Structure−activity Relationships among Random Nylon-3 Copolymers That Mimic Antibacterial Host-Defense Peptides Brendan P. Mowery, Alexandra H. Lindner, Bernard Weisblum, Shannon S. Stahl and Samuel H. Gellman pp 9735–9745 DOI: 10.1021/ja901613g Supporting Info |
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Locus-Specific Microemulsion Catalysts for Sulfur Mustard (HD) Chemical Warfare Agent Decontamination Ian A. Fallis, Peter C. Griffiths, Terence Cosgrove, Cecile A. Dreiss, Norman Govan, Richard K. Heenan, Ian Holden, Robert L. Jenkins, Stephen J. Mitchell, Stuart Notman, Jamie A. Platts, James Riches and Thomas Tatchell pp 9746–9755 DOI: 10.1021/ja901872y Supporting Info |
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Functional Group Tolerant Kumada−Corriu−Tamao Coupling of Nonactivated Alkyl Halides with Aryl and Heteroaryl Nucleophiles: Catalysis by a Nickel Pincer Complex Permits the Coupling of Functionalized Grignard Reagents Oleg Vechorkin, Valérie Proust and Xile Hu pp 9756–9766 DOI: 10.1021/ja9027378 Supporting Info |
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Rational Design of Ligands Targeting Triplet Repeating Transcripts That Cause RNA Dominant Disease: Application to Myotonic Muscular Dystrophy Type 1 and Spinocerebellar Ataxia Type 3 Alexei Pushechnikov, Melissa M. Lee, Jessica L. Childs-Disney, Krzysztof Sobczak, Jonathan M. French, Charles A. Thornton and Matthew D. Disney pp 9767–9779 DOI: 10.1021/ja9020149 Supporting Info |
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Quantum Mechanical/Molecular Mechanical and Density Functional Theory Studies of a Prototypical Zinc Peptidase (Carboxypeptidase A) Suggest a General Acid−General Base Mechanism Dingguo Xu and Hua Guo pp 9780–9788 DOI: 10.1021/ja9027988 Supporting Info |
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Homoconjugation/Homoaromaticity in Main Group Inorganic Molecules Qin Zhang, Shiping Yue, Xin Lu, Zhongfang Chen, Rongbin Huang, Lansun Zheng and Paul von Ragué Schleyer pp 9789–9799 DOI: 10.1021/ja9029285 Supporting Info |
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Light-Driven Release from Polymeric Microcapsules Functionalized with Bacteriorhodopsin Svetlana Erokhina, Lucia Benassi, Paolo Bianchini, Alberto Diaspro, Victor Erokhin and M. P. Fontana pp 9800–9804 DOI: 10.1021/ja903066s |
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Free Radical Polymers with Tunable and Selective Bio- and Chemical Degradability Jos M. J. Paulusse, Roey J. Amir, Richard A. Evans and Craig J. Hawker pp 9805–9812 DOI: 10.1021/ja903245p Supporting Info |
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Temperature Dependence of Blue Phosphorescent Cyclometalated Ir(III) Complexes Tissa Sajoto, Peter I. Djurovich, Arnold B. Tamayo, Jonas Oxgaard, William A. Goddard, III and Mark E. Thompson pp 9813–9822 DOI: 10.1021/ja903317w Supporting Info |
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Coordination Assemblies of [Mn4] Single-Molecule Magnets Linked by Photochromic Ligands: Photochemical Control of the Magnetic Properties Masakazu Morimoto, Hitoshi Miyasaka, Masahiro Yamashita and Masahiro Irie pp 9823–9835 DOI: 10.1021/ja903366d Supporting Info |
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Probing the Electronic Stability of Multiply Charged Anions: Sulfonated Pyrene Tri- and Tetraanions Xue-Bin Wang, Alina P. Sergeeva, Xiao-Peng Xing, Maria Massaouti, Tatjana Karpuschkin, Oliver Hampe, Alexander I. Boldyrev, Manfred M. Kappes and Lai-Sheng Wang pp 9836–9842 DOI: 10.1021/ja903615g Supporting Info |
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Synthesis and Characterization of a Carbon Nanotube−Dendron Series for Efficient siRNA Delivery M. Antonia Herrero, Francesca M. Toma, Khuloud T. Al-Jamal, Kostas Kostarelos, Alberto Bianco, Tatiana Da Ros, Fouzia Bano, Loredana Casalis, Giacinto Scoles and Maurizio Prato pp 9843–9848 DOI: 10.1021/ja903316z Supporting Info |
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Ion-Exchangeable, Electronically Conducting Layered Perovskite Oxyfluorides Yoji Kobayashi, Mingliang Tian, Miharu Eguchi and Thomas E. Mallouk pp 9849–9855 DOI: 10.1021/ja9040829 Supporting Info |
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Carbon Materials for Catalysis Edward Furimsky pp 9856–9857 DOI: 10.1021/ja903808y |
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Wörterbuch Labor/Laboratory Dictionary, Deutsch-Englisch/English-German, 2. Auflage, 2nd ed pp 9857–9857 DOI: 10.1021/ja9048916 |
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The Power of Functional Resins in Organic Synthesis Benedetto Corain, Fernando Formaggio, Marco Zecca and Andrea Biffis, Karel Jerabek pp 9857–9858 DOI: 10.1021/ja9041737 |
Issue 29
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An α/β-Peptide Helix Bundle with a Pure β3-Amino Acid Core and a Distinctive Quaternary Structure Michael W. Giuliano, W. Seth Horne and Samuel H. Gellman pp 9860–9861 DOI: 10.1021/ja8099294 Supporting Info |
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Fluorinated Acid Amplifiers for EUV Lithography Seth Kruger, Sri Revuru, Craig Higgins, Sarah Gibbons, Daniel A. Freedman, Wang Yueh, Todd R. Younkin and Robert L. Brainard pp 9862–9863 DOI: 10.1021/ja901448d Supporting Info |
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A Free Energy Pathway for the Interaction of the SRY Protein with Its Binding Site on DNA from Atomistic Simulations Benjamin Bouvier and Richard Lavery pp 9864–9865 DOI: 10.1021/ja901761a Supporting Info |
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Single-Molecule Imaging of an in Vitro-Evolved RNA Aptamer Reveals Homogeneous Ligand Binding Kinetics Mark P. Elenko, Jack W. Szostak and Antoine M. van Oijen pp 9866–9867 DOI: 10.1021/ja901880v Supporting Info |
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A 2-Aminobenzimidazole That Inhibits and Disperses Gram-Positive Biofilms through a Zinc-Dependent Mechanism Steven A. Rogers, Robert W. Huigens III and Christian Melander pp 9868–9869 DOI: 10.1021/ja9024676 Supporting Info |
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Highly Ordered Gold Nanotubes Using Thiols at a Cleavable Block Copolymer Interface Ja-Hyoung Ryu, Soojin Park, Bokyung Kim, Akamol Klaikherd, Thomas P. Russell and S. Thayumanavan pp 9870–9871 DOI: 10.1021/ja902567p Supporting Info |
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FLEth RNA Intercalating Probe Is a Convenient Reporter for Small Interfering RNAs Ingrid M. van der Wiel, Jenny Cheng, Roger Koukiekolo, Rodney K. Lyn, Nathan Stevens, Naphtali O’Connor, Nicholas J. Turro and John Paul Pezacki pp 9872–9873 DOI: 10.1021/ja902636m Supporting Info |
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Concerted Proton−Electron Transfer in a Ruthenium Terpyridyl-Benzoate System with a Large Separation between the Redox and Basic Sites Virginia W. Manner and James M. Mayer pp 9874–9875 DOI: 10.1021/ja902942g Supporting Info |
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Energy Level Alignment in CdS Quantum Dot Sensitized Solar Cells Using Molecular Dipoles Menny Shalom, Sven R pp 9876–9877 DOI: 10.1021/ja902770k Supporting Info |
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Sortase-Catalyzed Peptide−Glycosylphosphatidylinositol Analogue Ligation Xueqing Guo, Qianli Wang, Benjamin M. Swarts and Zhongwu Guo pp 9878–9879 DOI: 10.1021/ja903231v Supporting Info |
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Hybrid Cavitand Capsule with Hydrogen Bonds and Metal−Ligand Coordination Bonds: Guest Encapsulation with Anion Assistance Masamichi Yamanaka, Naoaki Toyoda and Kenji Kobayashi pp 9880–9881 DOI: 10.1021/ja903253c Supporting Info |
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Enantioselective Hydrogenation of N−H Imines Guohua Hou, Francis Gosselin, Wei Li, J. Christopher McWilliams, Yongkui Sun, Mark Weisel, Paul D. O’Shea, Cheng-yi Chen, Ian W. Davies and Xumu Zhang pp 9882–9883 DOI: 10.1021/ja903319r Supporting Info |
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15N−1H Scalar Coupling Perturbation: An Additional Probe for Measuring Structural Changes Due to Ligand Binding Junhe Ma, James M. Gruschus and Nico Tjandra pp 9884–9885 DOI: 10.1021/ja903552q Supporting Info |
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Pd(0)/PR3-Catalyzed Intermolecular Arylation of sp3 C−H Bonds Masayuki Wasa, Keary M. Engle and Jin-Quan Yu pp 9886–9887 DOI: 10.1021/ja903573p Supporting Info |
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Square Tetrapalladium Sheet Sandwich Complexes: Cyclononatetraenyl as a Versatile Face-Capping Ligand Tetsuro Murahashi, Ryou Inoue, Kentaro Usui and Sensuke Ogoshi pp 9888–9889 DOI: 10.1021/ja903679f Supporting Info |
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Graphene as a Substrate To Suppress Fluorescence in Resonance Raman Spectroscopy Liming Xie, Xi Ling, Yuan Fang, Jin Zhang and Zhongfan Liu pp 9890–9891 DOI: 10.1021/ja9037593 Supporting Info |
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What is the Rate of the Csp2−Csp2 Reductive Elimination Step? Revealing an Unusually Fast Ni-Catalyzed Negishi-Type Oxidative Coupling Reaction Liqun Jin, Hua Zhang, Peng Li, John R. Sowa, Jr and Aiwen Lei pp 9892–9893 DOI: 10.1021/ja903833u Supporting Info |
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Room-Temperature Hydrogen Generation from Hydrous Hydrazine for Chemical Hydrogen Storage Sanjay Kumar Singh, Xin-Bo Zhang and Qiang Xu pp 9894–9895 DOI: 10.1021/ja903869y Supporting Info |
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Chalcogenide Chemistry in Ionic Liquids: Nonlinear Optical Wave-Mixing Properties of the Double-Cubane Compound [Sb7S8Br2](AlCl4)3 Qichun Zhang, In Chung, Joon I. Jang, John B. Ketterson and Mercouri G. Kanatzidis pp 9896–9897 DOI: 10.1021/ja903881m Supporting Info |
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Thermal Effects of Water Intrusion in Hydrophobic Nanoporous Materials Thomas Karbowiak, Christian Paulin, Anthony Ballandras, Guy Weber and Jean-Pierre Bellat pp 9898–9899 DOI: 10.1021/ja903954h |
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Palladium-Catalyzed Enantioselective α-Arylation and α-Vinylation of Oxindoles Facilitated by an Axially Chiral P-Stereogenic Ligand Alexander M. Taylor, Ryan A. Altman and Stephen L. Buchwald pp 9900–9901 DOI: 10.1021/ja903880q Supporting Info |
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η5-1,2,3-Trisilacyclopentadienyl - A Ligand for Transition Metal Complexes: Rhodium Half-Sandwich and Ruthenium Sandwich Hiroyuki Yasuda, Vladimir Ya. Lee and Akira Sekiguchi pp 9902–9903 DOI: 10.1021/ja9038664 Supporting Info |
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Electrochemical Isotope Effect and Lithium Isotope Separation Jay R. Black, Grant Umeda, Bruce Dunn, William F. McDonough and Abby Kavner pp 9904–9905 DOI: 10.1021/ja903926x Supporting Info |
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Rational Designs for Highly Proton-Conductive Metal−Organic Frameworks Masaaki Sadakiyo, Teppei Yamada and Hiroshi Kitagawa pp 9906–9907 DOI: 10.1021/ja9040016 Supporting Info |
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Electrochemical Gate-Controlled Charge Transport in Graphene in Ionic Liquid and Aqueous Solution Fang Chen, Quan Qing, Jilin Xia, Jinghong Li and Nongjian Tao pp 9908–9909 DOI: 10.1021/ja9041862 Supporting Info |
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Solvothermal Reduction of Chemically Exfoliated Graphene Sheets Hailiang Wang, Joshua Tucker Robinson, Xiaolin Li and Hongjie Dai pp 9910–9911 DOI: 10.1021/ja904251p Supporting Info |
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Is There a Ni-Methyl Intermediate in the Mechanism of Methyl-Coenzyme M Reductase? Shi-lu Chen, Vladimir Pelmenschikov, Margareta R. A. Blomberg and Per E. M. Siegbahn pp 9912–9913 DOI: 10.1021/ja904301f Supporting Info |
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Rhenium-Catalyzed Regioselective Alkylation of Phenols Yoichiro Kuninobu, Takashi Matsuki and Kazuhiko Takai pp 9914–9915 DOI: 10.1021/ja904360k Supporting Info |
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Synthesis and Spectroscopic Studies on Azo-Dye Derivatives of Polymetallic Lanthanide Complexes: Using Diazotization to Link Metal Complexes Together Matteo P. Placidi, Aaron Joseph L. Villaraza, Louise S. Natrajan, Daniel Sykes, Alan M. Kenwright and Stephen Faulkner pp 9916–9917 DOI: 10.1021/ja904362f Supporting Info |
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Complexation of Nitrous Oxide by Frustrated Lewis Pairs Edwin Otten, Rebecca C. Neu and Douglas W. Stephan pp 9918–9919 DOI: 10.1021/ja904377v Supporting Info |
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Conjugation of Colloidal Clusters and Chains by Capillary Condensation Fan Li and Andreas Stein pp 9920–9921 DOI: 10.1021/ja904591a Supporting Info |
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Structural Basis of Cyanide Inhibition of Ni, Fe-Containing Carbon Monoxide Dehydrogenase Jae-Hun Jeoung and Holger Dobbek pp 9922–9923 DOI: 10.1021/ja9046476 Supporting Info |
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(E)-2-Boryl-1,3-butadiene Derivatives of the 10-TMS-9-BBDs: Highly Selective Reagents for the Asymmetric Synthesis of anti-1,2-Disubstituted 3,4-Pentadien-1-ols Javier R. Gonz pp 9924–9925 DOI: 10.1021/ja9047202 Supporting Info |
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Dynamic Interactions between Fast Microscale Rotors Yang Wang, Shih-to Fei, Young-Moo Byun, Paul E. Lammert, Vincent H. Crespi, Ayusman Sen and Thomas E. Mallouk pp 9926–9927 DOI: 10.1021/ja904827j Supporting Info |
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Positively Charged Base Surrogate for Highly Stable “Base Pairing” through Electrostatic and Stacking Interactions Hiromu Kashida, Hidehiro Ito, Taiga Fujii, Takamitsu Hayashi and Hiroyuki Asanuma pp 9928–9930 DOI: 10.1021/ja9013002 Supporting Info |
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Revisiting the IspH Catalytic System in the Deoxyxylulose Phosphate Pathway: Achieving High Activity Youli Xiao, Lisa Chu, Yiannis Sanakis and Pinghua Liu pp 9931–9933 DOI: 10.1021/ja903778d Supporting Info |
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Dendritic Chain Reaction Eran Sella and Doron Shabat pp 9934–9936 DOI: 10.1021/ja903032t Supporting Info |
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Three-Dimensional Biomimetic Mineralization of Dense Hydrogel Templates Gao Liu, Dacheng Zhao, Antoni P. Tomsia, Andrew M. Minor, Xiangyun Song and Eduardo Saiz pp 9937–9939 DOI: 10.1021/ja903817z Supporting Info |
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Preparation and Optical Properties of Fullerene/Ferrocene Hybrid Hexagonal Nanosheets and Large-Scale Production of Fullerene Hexagonal Nanosheets Takatsugu Wakahara, Marappan Sathish, Kun’ichi Miyazawa, Chunping Hu, Yoshitaka Tateyama, Yoshihiro Nemoto, Toshio Sasaki and Osamu Ito pp 9940–9944 DOI: 10.1021/ja901032b Supporting Info |
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Structure-Based Rationale for Selectivity in the Asymmetric Allylic Alkylation of Cycloalkenyl Esters Employing the Trost ‘Standard Ligand’ (TSL): Isolation, Analysis and Alkylation of the Monomeric form of the Cationic η3-Cyclohexenyl Complex [(η3-c-C6H9)Pd(TSL)]+ Craig P. Butts, Emane Filali, Guy C. Lloyd-Jones, Per-Ola Norrby, David A. Sale and York Schramm pp 9945–9957 DOI: 10.1021/ja8099757 Supporting Info |
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Hydrogenation of the α,β-Unsaturated Aldehydes Acrolein, Crotonaldehyde, and Prenal over Pt Single Crystals: A Kinetic and Sum-Frequency Generation Vibrational Spectroscopy Study Christopher J. Kliewer, Marco Bieri and Gabor A. Somorjai pp 9958–9966 DOI: 10.1021/ja8092532 |
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Direct Observation of Lanthanide(III)-Phthalocyanine Molecules on Au(111) by Using Scanning Tunneling Microscopy and Scanning Tunneling Spectroscopy and Thin-Film Field-Effect Transistor Properties of Tb(III)- and Dy(III)-Phthalocyanine Molecules Keiichi Katoh, Yusuke Yoshida, Masahiro Yamashita, Hitoshi Miyasaka, Brian K. Breedlove, Takashi Kajiwara, Shinya Takaishi, Naoto Ishikawa, Hironari Isshiki, Yan Feng Zhang, Tadahiro Komeda, Masakazu Yamagishi and Jun Takeya pp 9967–9976 DOI: 10.1021/ja902349t Supporting Info |
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Electron Ionization Dissociation of Singly and Multiply Charged Peptides Y. M. Eva Fung, Christopher M. Adams and Roman A. Zubarev pp 9977–9985 DOI: 10.1021/ja8087407 |
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Thiol-Selective Fluorogenic Probes for Labeling and Release Vu Hong, Alexander A. Kislukhin and M. G. Finn pp 9986–9994 DOI: 10.1021/ja809345d Supporting Info |
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Hydrogen-Bonding-Assisted Self-Doping in Tetrathiafulvalene (TTF) Conductor Yuka Kobayashi, Mayu Yoshioka, Kazuhiko Saigo, Daisuke Hashizume and Takashi Ogura pp 9995–10002 DOI: 10.1021/ja809425b Supporting Info |
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Catalytic Transamidation Reactions Compatible with Tertiary Amide Metathesis under Ambient Conditions Nickeisha A. Stephenson, Jiang Zhu, Samuel H. Gellman and Shannon S. Stahl pp 10003–10008 DOI: 10.1021/ja8094262 |
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Surface Raman Spectroscopy of the Interface of Tris-(8-hydroxyquinoline) Aluminum with Mg Robert J. Davis and Jeanne E. Pemberton pp 10009–10014 DOI: 10.1021/ja808021d Supporting Info |
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Regioselectivity in the Reductive Bond Cleavage of Diarylalkylsulfonium Salts: Variation with Driving Force and Structure of Sulfuranyl Radical Intermediates Jack A. Kampmeier, AKM Mansurul Hoque, Franklin D. Saeva, Donald K. Wedegaertner, Pia Thomsen, Saif Ullah, Jacob Krake and Torben Lund pp 10015–10022 DOI: 10.1021/ja809918k Supporting Info |
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Controllable Molecular Modulation of Conductivity in Silicon-Based Devices Tao He, David A. Corley, Meng Lu, Neil Halen Di Spigna, Jianli He, David P. Nackashi, Paul D. Franzon and James M. Tour pp 10023–10030 DOI: 10.1021/ja9002537 Supporting Info |
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Structure of a Nickel Chaperone, HypA, from Helicobacter pylori Reveals Two Distinct Metal Binding Sites Wei Xia, Hongyan Li, Kong-Hung Sze and Hongzhe Sun pp 10031–10040 DOI: 10.1021/ja900543y Supporting Info |
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Unusual Phosphorus−Phosphorus Double Bond Contraction upon Mono- and Di-auration of a Diphosphene David V. Partyka, Marlena P. Washington, Thomas G. Gray, James B. Updegraff III, John F. Turner, II and John D. Protasiewicz pp 10041–10048 DOI: 10.1021/ja900813v Supporting Info |
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Measuring Densities of Solids and Liquids Using Magnetic Levitation: Fundamentals Katherine A. Mirica, Sergey S. Shevkoplyas, Scott T. Phillips, Malancha Gupta and George M. Whitesides pp 10049–10058 DOI: 10.1021/ja900920s Supporting Info |
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Control and Characterization of Cyclopentene Unimolecular Dissociation on Si(100) with Scanning Tunneling Microscopy Nathan L. Yoder, James S. Fakonas and Mark C. Hersam pp 10059–10065 DOI: 10.1021/ja9010546 Supporting Info |
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Reactions between Aromatic Hydrocarbons and Heterocycles: Covalent and Proton-Bound Dimer Cations of Benzene/Pyridine M. Samy El-Shall, Yehia M. Ibrahim, Edreese H. Alsharaeh, Michael Meot-Ner (Mautner) and Simon P. Watson pp 10066–10076 DOI: 10.1021/ja901130d Supporting Info |
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Synthesis of a BODIPY Library and Its Application to the Development of Live Cell Glucagon Imaging Probe Jun-Seok Lee, Nam-young Kang, Yun Kyung Kim, Animesh Samanta, Suihan Feng, Hyeong Kyu Kim, Marc Vendrell, Jung Hwan Park and Young-Tae Chang pp 10077–10082 DOI: 10.1021/ja9011657 Supporting Info |
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Response of Small-Scale, Methyl Rotors to Protein−Ligand Association: A Simulation Analysis of Calmodulin−Peptide Binding Marimuthu Krishnan and Jeremy C. Smith pp 10083–10091 DOI: 10.1021/ja901276n Supporting Info |
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Interaction of Radical Pairs Through-Bond and Through-Space: Scope and Limitations of the Point−Dipole Approximation in Electron Paramagnetic Resonance Spectroscopy Christoph Riplinger, Joseph P. Y. Kao, Gerald M. Rosen, Velavan Kathirvelu, Gareth R. Eaton, Sandra S. Eaton, Andrei Kutateladze and Frank Neese pp 10092–10106 DOI: 10.1021/ja901150j Supporting Info |
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A Bifunctional Molecule as an Artificial Flavin Mononucleotide Cyclase and a Chemosensor for Selective Fluorescent Detection of Flavins Hyun-Woo Rhee, So Jung Choi, Sang Ho Yoo, Yong Oh Jang, Hun Hee Park, Rosa Mar pp 10107–10112 DOI: 10.1021/ja9018012 Supporting Info |
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Solid-State and Solution NMR Studies of the CAP-Gly Domain of Mammalian Dynactin and Its Interaction with Microtubules Shangjin Sun, Amanda Siglin, John C. Williams and Tatyana Polenova pp 10113–10126 DOI: 10.1021/ja902003u Supporting Info |
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Investigation of the Physicochemical Changes Preceding Zeolite Nucleation in a Sodium-Rich Aluminosilicate Gel Lama Itani, Yong Liu, Weiping Zhang, Krassimir N. Bozhilov, Luc Delmotte and Valentin Valtchev pp 10127–10139 DOI: 10.1021/ja902088f Supporting Info |
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Quasi-2D XY Magnetic Properties and Slow Relaxation in a Body Centered Metal Organic Network of [Co4] Clusters Partha Mahata, Srinivasan Natarajan, Pierre Panissod and Marc Drillon pp 10140–10150 DOI: 10.1021/ja9017539 Supporting Info |
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Examination of Enzymatic H-Tunneling through Kinetics and Dynamics Jigar N. Bandaria, Christopher M. Cheatum and Amnon Kohen pp 10151–10155 DOI: 10.1021/ja902120t Supporting Info |
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Introduction of Methionines in the Gas Channel Makes [NiFe] Hydrogenase Aero-Tolerant S pp 10156–10164 DOI: 10.1021/ja9018258 Supporting Info |
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Templating Molecular Arrays in Amyloid’s Cross-β Grooves W. Seth Childers, Anil K. Mehta, Kun Lu and David G. Lynn pp 10165–10172 DOI: 10.1021/ja902332s Supporting Info |
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Probing Conformers and Adsorption Footprints at the Single-Molecule Level in a Highly Organized Amino Acid Assembly of (S)-Proline on Cu(110) Matthew Forster, Matthew S. Dyer, Mats Persson and Rasmita Raval pp 10173–10181 DOI: 10.1021/ja9020364 Supporting Info |
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Lamellar Envelopes of Semiconductor Nanocrystals Anna Lee, Neil A. Coombs, Ilya Gourevich, Eugenia Kumacheva and Gregory D. Scholes pp 10182–10188 DOI: 10.1021/ja902218q Supporting Info |
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A Simple and Effective Strategy To Increase the Sensitivity of Fluorescence Probes in Living Cells Saki Izumi, Yasuteru Urano, Kenjiro Hanaoka, Takuya Terai and Tetsuo Nagano pp 10189–10200 DOI: 10.1021/ja902511p Supporting Info |
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Revealing a Second Transmetalation Step in the Negishi Coupling and Its Competition with Reductive Elimination: Improvement in the Interpretation of the Mechanism of Biaryl Syntheses Qiang Liu, Yu Lan, Jing Liu, Gang Li, Yun-Dong Wu and Aiwen Lei pp 10201–10210 DOI: 10.1021/ja903277d Supporting Info |
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A Combined Theoretical and Experimental Study of the Ammonia Tunnel in Carbamoyl Phosphate Synthetase Yubo Fan, Liliya Lund, Qiang Shao, Yi-Qin Gao and Frank M. Raushel pp 10211–10219 DOI: 10.1021/ja902557r Supporting Info |
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Physical Basis of Metal-Binding Specificity in Escherichia coli NikR Christine M. Phillips, Paul S. Nerenberg, Catherine L. Drennan and Collin M. Stultz pp 10220–10228 DOI: 10.1021/ja9026314 Supporting Info |
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Direct Electron Transfer to a Metalloenzyme Redox Center Coordinated to a Monolayer-Protected Cluster Jose M. Abad, Mhairi Gass, Andrew Bleloch and David J. Schiffrin pp 10229–10236 DOI: 10.1021/ja9026693 Supporting Info |
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Permeation of Membranes by Ribose and Its Diastereomers Chenyu Wei and Andrew Pohorille pp 10237–10245 DOI: 10.1021/ja902531k |
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Synthesis and Characterization of Na5M2+xSn10−x (x ≈ 0.5, M = Zn, Hg)—A Doped Tetrahedral Framework Structure Sim pp 10246–10252 DOI: 10.1021/ja902664c Supporting Info |
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Importance of C−N Bond Rotation in N-Acyl Oxazolidinones in their SmI2-Promoted Coupling to Acrylamides Rolf H. Taaning, Karl B. Lindsay, Birgit Schiøtt, Kim Daasbjerg and Troels Skrydstrup pp 10253–10262 DOI: 10.1021/ja903401y Supporting Info |
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Control of the Molecular Orientation of Membrane-Anchored Biomimetic Glycopolymers Kamil Godula, Marissa L. Umbel, David Rabuka, Zsofia Botyanszki, Carolyn R. Bertozzi and Raghuveer Parthasarathy pp 10263–10268 DOI: 10.1021/ja903114g Supporting Info |
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Reactions of Group III Biheterocyclic Complexes Colin T. Carver, Diego Benitez, Kevin L. Miller, Bryan N. Williams, Ekaterina Tkatchouk, William A. Goddard, III and Paula L. Diaconescu pp 10269–10278 DOI: 10.1021/ja902794w Supporting Info |
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High-Field EPR and Magnetic Susceptibility Studies on Binuclear and Tetranuclear Copper Trifluoroacetate Complexes. X-ray Structure Determination of Three Tetranuclear Quinoline Adducts of Copper(II) Trifluoroacetate Andrew Ozarowski, Iwona B. Szyma pp 10279–10292 DOI: 10.1021/ja902695y Supporting Info |
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Length-Dependent Convergence and Saturation Behavior of Electrochemical, Linear Optical, Quadratic Nonlinear Optical, and Cubic Nonlinear Optical Properties of Dipolar Alkynylruthenium Complexes with Oligo(phenyleneethynylene) Bridges Bandar Babgi, Luca Rigamonti, Marie P. Cifuentes, T. Christopher Corkery, Michael D. Randles, Torsten Schwich, Simon Petrie, Robert Stranger, Ayele Teshome, Inge Asselberghs, Koen Clays, Marek Samoc and Mark G. Humphrey pp 10293–10307 DOI: 10.1021/ja902793z Supporting Info |
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Imino-oxy Acetic Acid Dealkylation as Evidence for an Inner-Sphere Alcohol Intermediate in the Reaction Catalyzed by Peptidylglycine α-Hydroxylating Monooxygenase Neil R. McIntyre, Edward W. Lowe, Jr. and David J. Merkler pp 10308–10319 DOI: 10.1021/ja902716d Supporting Info |
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Colorimetric Split G-Quadruplex Probes for Nucleic Acid Sensing: Improving Reconstituted DNAzyme’s Catalytic Efficiency via Probe Remodeling Shizuka Nakayama and Herman O. Sintim pp 10320–10333 DOI: 10.1021/ja902951b Supporting Info |
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Total Synthesis of N-Acetylglucosamine-1,6-anhydro-N-acetylmuramylpentapeptide and Evaluation of Its Turnover by AmpD from Escherichia coli Dusan Hesek, Mijoon Lee, Weilie Zhang, Bruce C. Noll and Shahriar Mobashery p 10334 DOI: 10.1021/ja904230q |
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A Collagen-Mimic Dendrimer Capable of Controlled Release Chie Kojima, Sayako Tsumura, Atsushi Harada and Kenji Kono p 10334 DOI: 10.1021/ja904242j |
Issue 30
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Porous Coordination Polymer with Pyridinium Cationic Surface, [Zn2(tpa)2(cpb)] Masakazu Higuchi, Daisuke Tanaka, Satoshi Horike, Hirotoshi Sakamoto, Kohei Nakamura, Yohei Takashima, Yuh Hijikata, Nobuhiro Yanai, Jungeun Kim, Kenichi Kato, Yoshiki Kubota, Masaki Takata and Susumu Kitagawa pp 10336–10337 DOI: 10.1021/ja900373v Supporting Info |
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Ir Doping-Induced Superconductivity in the SmFeAsO System Yong Liang Chen, Cui Hua Cheng, Ya Jing Cui, Han Zhang, Yong Zhang, Ye Yang and Yong Zhao pp 10338–10339 DOI: 10.1021/ja901065p Supporting Info |
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Microfluidic Concentration-Enhanced Cellular Kinase Activity Assay Jeong Hoon Lee, Benjamin D. Cosgrove, Douglas A. Lauffenburger and Jongyoon Han pp 10340–10341 DOI: 10.1021/ja902594f Supporting Info |
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Optical Activity and Chiral Memory of Thiol-Capped CdTe Nanocrystals Takuya Nakashima, Yuki Kobayashi and Tsuyoshi Kawai pp 10342–10343 DOI: 10.1021/ja902800f Supporting Info |
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High-Precision Selective Deposition of Catalyst for Facile Localized Growth of Single-Walled Carbon Nanotubes Rong Xiang, Tianzhun Wu, Erik Einarsson, Yuji Suzuki, Yoichi Murakami, Junichiro Shiomi and Shigeo Maruyama pp 10344–10345 DOI: 10.1021/ja902904v Supporting Info |
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Macroporous Silicon Oxycarbide Fibers with Luffa-like Superhydrophobic Shells Ping Lu, Qing Huang, Baodan Liu, Yoshio Bando, You-Lo Hsieh and Amiya K. Mukherjee pp 10346–10347 DOI: 10.1021/ja902757a Supporting Info |
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Hyperbranched Polymers with a Degree of Branching of 100% Prepared by Catalyst Transfer Suzuki−Miyaura Polycondensation Weiguo Huang, Linjie Su and Zhishan Bo pp 10348–10349 DOI: 10.1021/ja9033846 Supporting Info |
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Nickel-Catalyzed Direct Conjugate Addition of Simple Alkenes to Enones Sensuke Ogoshi, Toshifumi Haba and Masato Ohashi pp 10350–10351 DOI: 10.1021/ja903510u Supporting Info |
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[Ln(DPA)3]3− Is a Convenient Paramagnetic Shift Reagent for Protein NMR Studies Xun-Cheng Su, Haobo Liang, Karin V. Loscha and Gottfried Otting pp 10352–10353 DOI: 10.1021/ja9034957 Supporting Info |
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Mild and Selective Deuteration and Isomerization of Alkenes by a Bifunctional Catalyst and Deuterium Oxide G pp 10354–10355 DOI: 10.1021/ja903519a Supporting Info |
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Reverse pH-Dependence of Chromophore Protonation Explains the Large Stokes Shift of the Red Fluorescent Protein mKeima Sebastien Violot, Philippe Carpentier, Laurent Blanchoin and Dominique Bourgeois pp 10356–10357 DOI: 10.1021/ja903695n Supporting Info |
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Characterization of Structurally Unusual Diiron NxHy Complexes Caroline T. Saouma, Peter M pp 10358–10359 DOI: 10.1021/ja903967z Supporting Info |
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Chemoselective Ligation in the Functionalization of Polysaccharide-Based Particles Tristan T. Beaudette, Joel A. Cohen, Eric M. Bachelder, Kyle E. Broaders, Jessica L. Cohen, Edgar G. Engleman and Jean M. J. Fr pp 10360–10361 DOI: 10.1021/ja903984s Supporting Info |
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Reconstruction of Cu(100) Electrode Surfaces during Hydrogen Evolution Hisayoshi Matsushima, Andriy Taranovskyy, Christian Haak, Yvonne Gr pp 10362–10363 DOI: 10.1021/ja904033t Supporting Info |
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Allenes in Asymmetric Catalysis: Asymmetric Ring Opening of meso-Epoxides Catalyzed by Allene-Containing Phosphine Oxides Xiaotao Pu, Xiangbing Qi and Joseph M. Ready pp 10364–10365 DOI: 10.1021/ja9041127 Supporting Info |
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All-Carbon Quaternary Centers via Ruthenium-Catalyzed Hydroxymethylation of 2-Substituted Butadienes Mediated by Formaldehyde: Beyond Hydroformylation Tomas Smejkal, Hoon Han, Bernhard Breit and Michael J. Krische pp 10366–10367 DOI: 10.1021/ja904124b Supporting Info |
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Zeolitic Imidazolate Frameworks for Kinetic Separation of Propane and Propene Kunhao Li, David H. Olson, Jonathan Seidel, Thomas J. Emge, Hongwei Gong, Heping Zeng and Jing Li pp 10368–10369 DOI: 10.1021/ja9039983 Supporting Info |
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Asymmetric Synthesis of (+)-Polyanthellin A Matthew J. Campbell and Jeffrey S. Johnson pp 10370–10371 DOI: 10.1021/ja904136q Supporting Info |
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Octapi Interactions: Self-Assembly of a Pd-Based [2]Catenane Driven by Eightfold π Interactions Jinzhen Lu, David R. Turner, Lindsay P. Harding, Lindsay T. Byrne, Murray V. Baker and Stuart R. Batten pp 10372–10373 DOI: 10.1021/ja9041912 Supporting Info |
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Highly Efficient Photoproduction of Charge-Separated States in Donor−Acceptor-Linked Bis(acetylide) Platinum Complexes Shuichi Suzuki, Ryoji Sugimura, Masatoshi Kozaki, Kazutoshi Keyaki, Koichi Nozaki, Noriaki Ikeda, Kimio Akiyama and Keiji Okada pp 10374–10375 DOI: 10.1021/ja904241r Supporting Info |
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Biosynthesis of Salinosporamides from α,β-Unsaturated Fatty Acids: Implications for Extending Polyketide Synthase Diversity Yuan Liu, Christopher Hazzard, Alessandra S. Eust pp 10376–10377 DOI: 10.1021/ja9042824 Supporting Info |
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Star Polymers via Cross-Linking Amphiphilic Macroinitiators by AGET ATRP in Aqueous Media Wenwen Li and Krzysztof Matyjaszewski pp 10378–10379 DOI: 10.1021/ja904204g Supporting Info |
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Re-evaluating the Gibbs Analysis of Surface Tension at the Air/Water Interface Fredric M. Menger, Lei Shi and Syed A. A. Rizvi pp 10380–10381 DOI: 10.1021/ja9044289 |
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Ring-Opening Polymerization of 19-Electron [2]Cobaltocenophanes: A Route to High-Molecular-Weight, Water-Soluble Polycobaltocenium Polyelectrolytes Ulrich F. J. Mayer, Joe B. Gilroy, Dermot O’Hare and Ian Manners pp 10382–10383 DOI: 10.1021/ja903513e Supporting Info |
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Asymmetric Total Synthesis of (−)-Plicatic Acid via a Highly Enantioselective and Diastereoselective Nucleophilic Epoxidation of Acyclic Trisubstitued Olefins Bing-Feng Sun, Ran Hong, Yan-Biao Kang and Li Deng pp 10384–10385 DOI: 10.1021/ja9039407 Supporting Info |
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Aromatic Heterocycles as Activating Groups for Asymmetric Conjugate Addition Reactions. Enantioselective Copper-Catalyzed Reduction of 2-Alkenylheteroarenes Leszek Rupnicki, Aakarsh Saxena and Hon Wai Lam pp 10386–10387 DOI: 10.1021/ja904365h Supporting Info |
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A Crystallizable Dinuclear Tuck-In-Tuck-Over Tuck-Over Dialkyl Tren Uranium Complex and Double Dearylation of BPh4− To Give the BPh2-Functionalized Metallocycle [U{N(CH2CH2NSiMe3)2(CH2CH2NSiMe2CHBPh2)}(THF)] Benedict M. Gardner, Jonathan McMaster, William Lewis, Alexander J. Blake and Stephen T. Liddle pp 10388–10389 DOI: 10.1021/ja904459q Supporting Info |
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Cr(III)(salen)Cl Catalyzed Enantioselective Intramolecular Addition of Tertiary Enamides to Ketones: A General Access to Enantioenriched 1H-Pyrrol-2(3H)-one Derivatives Bearing a Hydroxylated Quaternary Carbon Atom Luo Yang, De-Xian Wang, Zhi-Tang Huang and Mei-Xiang Wang pp 10390–10391 DOI: 10.1021/ja904534t Supporting Info |
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Probing Ultrafast Internal Conversion through Conical Intersection via Time-Energy Map of Photoelectron Angular Anisotropy Takuya Horio, Takao Fuji, Yoshi-Ichi Suzuki and Toshinori Suzuki pp 10392–10393 DOI: 10.1021/ja904780b Supporting Info |
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Exceptional Stability and High Hydrogen Uptake in Hydrogen-Bonded Metal−Organic Cubes Possessing ACO and AST Zeolite-like Topologies Dorina F. Sava, Victor Ch. Kravtsov, Juergen Eckert, Jarrod F. Eubank, Farid Nouar and Mohamed Eddaoudi pp 10394–10396 DOI: 10.1021/ja903287v Supporting Info |
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Isolated Seven-Coordinate Ru(IV) Dimer Complex with [HOHOH]− Bridging Ligand as an Intermediate for Catalytic Water Oxidation Lele Duan, Andreas Fischer, Yunhua Xu and Licheng Sun pp 10397–10399 DOI: 10.1021/ja9034686 Supporting Info |
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Supramolecular Patterns Controlled by Electron Interference and Direct Intermolecular Interactions Yongfeng Wang, Xin Ge, Carlos Manzano, J pp 10400–10402 DOI: 10.1021/ja903506s Supporting Info |
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Walking a Supramolecular Tightrope: A Self-Assembled Dodecamer from an 8-Aryl-2′-deoxyguanosine Derivative Mar pp 10403–10405 DOI: 10.1021/ja9040384 Supporting Info |
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Reduced Uranium Complexes: Synthetic and DFT Study of the Role of π Ligation in the Stabilization of Uranium Species in a Formal Low-Valent State Ilia Korobkov, Serge Gorelsky and Sandro Gambarotta pp 10406–10420 DOI: 10.1021/ja9002525 Supporting Info |
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Anisotropic Fermi Couplings Due to Large Unquenched Orbital Angular Momentum: Q-Band 1H, 14N, and 11B ENDOR of Bis(trispyrazolylborate) Cobalt(II) William K. Myers, Charles P. Scholes and David L. Tierney pp 10421–10429 DOI: 10.1021/ja900866y Supporting Info |
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Reduced or Diminished Stabilization of the Telomere G-Quadruplex and Inhibition of Telomerase by Small Chemical Ligands under Molecular Crowding Condition Zhao Chen, Ke-wei Zheng, Yu-hua Hao and Zheng Tan pp 10430–10438 DOI: 10.1021/ja9010749 Supporting Info |
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Fabrication and Electronic Characterization of Single Molecular Junction Devices: A Comprehensive Approach Jianfeng Zhou, Fan Chen and Bingqian Xu pp 10439–10446 DOI: 10.1021/ja900989a Supporting Info |
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Switchable Molecular Conductivity Ke Wang, Norma L. Rangel, Subrata Kundu, Juan C. Sotelo, Roberto M. Tovar, Jorge M. Seminario and Hong Liang pp 10447–10451 DOI: 10.1021/ja901156x Supporting Info |
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Anion-Driven Conformational Polymorphism in Homochiral Helical Coordination Polymers Guozan Yuan, Chengfeng Zhu, Yan Liu, Weimin Xuan and Yong Cui pp 10452–10460 DOI: 10.1021/ja901154p Supporting Info |
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Noninnocent Behavior of Ancillary Ligands: Apparent Trans Coupling of a Saturated N-Heterocyclic Carbene Unit with an Ethyl Ligand Mediated by Nickel Tobias Steinke, Bryan K. Shaw, Howard Jong, Brian O. Patrick, Michael D. Fryzuk and Jennifer C. Green pp 10461–10466 DOI: 10.1021/ja901346g Supporting Info |
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Antiplatelet and Thermally Responsive Poly(N-isopropylacrylamide) Surface with Nanoscale Topography Li Chen, Mingjie Liu, Hao Bai, Peipei Chen, Fan Xia, Dong Han and Lei Jiang pp 10467–10472 DOI: 10.1021/ja9019935 Supporting Info |
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Reaction Mechanisms for the CO Oxidation on Au/CeO2 Catalysts: Activity of Substitutional Au3+/Au+ Cations and Deactivation of Supported Au+ Adatoms Matteo Farnesi Camellone and Stefano Fabris pp 10473–10483 DOI: 10.1021/ja902109k Supporting Info |
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Synthesis, Characterization, and Photoinduced Electron Transfer Processes of Orthogonal Ruthenium Phthalocyanine−Fullerene Assemblies M. Salom pp 10484–10496 DOI: 10.1021/ja902471w Supporting Info |
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Binding and Inactivation Mechanism of a Humanized Fatty Acid Amide Hydrolase by α-Ketoheterocycle Inhibitors Revealed from Cocrystal Structures Mauro Mileni, Joie Garfunkle, Jessica K. DeMartino, Benjamin F. Cravatt, Dale L. Boger and Raymond C. Stevens pp 10497–10506 DOI: 10.1021/ja902694n |
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Determination of Multicomponent Protein Structures in Solution Using Global Orientation and Shape Restraints Jinbu Wang, Xiaobing Zuo, Ping Yu, In-Ja L. Byeon, Jinwon Jung, Xiaoxia Wang, Marzena Dyba, Soenke Seifert, Charles D. Schwieters, Jun Qin, Angela M. Gronenborn and Yun-Xing Wang pp 10507–10515 DOI: 10.1021/ja902528f Supporting Info |
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Defining Active Catalyst Structure and Reaction Pathways from ab Initio Molecular Dynamics and Operando XAFS: Dehydrogenation of Dimethylaminoborane by Rhodium Clusters Roger Rousseau, Gregory K. Schenter, John L. Fulton, John C. Linehan, Mark H. Engelhard and Thomas Autrey pp 10516–10524 DOI: 10.1021/ja901480u Supporting Info |
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Identifying the Local Structures Formed during Lithiation of the Conversion Material, Iron Fluoride, in a Li Ion Battery: A Solid-State NMR, X-ray Diffraction, and Pair Distribution Function Analysis Study Naoko Yamakawa, Meng Jiang, Baris Key and Clare P. Grey pp 10525–10536 DOI: 10.1021/ja902639w Supporting Info |
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Aromatic π-Systems More Curved Than C60. The Complete Family of All Indenocorannulenes Synthesized by Iterative Microwave-Assisted Intramolecular Arylations Brian D. Steinberg, Edward A. Jackson, Alexander S. Filatov, Atsushi Wakamiya, Marina A. Petrukhina and Lawrence T. Scott pp 10537–10545 DOI: 10.1021/ja9031852 Supporting Info |
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Alternating Ring-Opening Metathesis Copolymerization of Amino Acid Derived Norbornene Monomers Carrying Nonprotected Carboxy and Amino Groups Based on Acid−Base Interaction Sutthira Sutthasupa, Masashi Shiotsuki, Toshio Masuda and Fumio Sanda pp 10546–10551 DOI: 10.1021/ja903248c Supporting Info |
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Quantitative Evaluation of Metal−Molecule Contact Stability at the Single-Molecule Level Makusu Tsutsui, Masateru Taniguchi and Tomoji Kawai pp 10552–10556 DOI: 10.1021/ja902871d Supporting Info |
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“Breathing” Vesicles Shaoyong Yu, Tony Azzam, Isabelle Rouiller and Adi Eisenberg pp 10557–10566 DOI: 10.1021/ja902869q Supporting Info |
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Proton-Coupled Electron Transfer in Photosystem II: Proton Inventory of a Redox Active Tyrosine David L. Jenson and Bridgette A. Barry pp 10567–10573 DOI: 10.1021/ja902896e |
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Cross-Linked Hyperbranched Polyglycerols as Hosts for Selective Binding of Guest Molecules Ewelina Burakowska, Jordan R. Quinn, Steven C. Zimmerman and Rainer Haag pp 10574–10580 DOI: 10.1021/ja902597h |
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Asymmetric Organocatalytic Formal Alkynylation and Alkenylation of α,β-Unsaturated Aldehydes Martin Nielsen, Christian Borch Jacobsen, M pp 10581–10586 DOI: 10.1021/ja903920j Supporting Info |
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Total Synthesis and Biological Evaluation of Cortistatins A and J and Analogues Thereof K. C. Nicolaou, Xiao-Shui Peng, Ya-Ping Sun, Damien Polet, Bin Zou, Chek Shik Lim and David Y.-K. Chen pp 10587–10597 DOI: 10.1021/ja902939t Supporting Info |
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Topotactic Reduction As a Route to New Close-Packed Anion Deficient Perovskites: Structure and Magnetism of 4H-BaMnO2+x Joke Hadermann, Artem M. Abakumov, Josephine J. Adkin and Michael A. Hayward pp 10598–10604 DOI: 10.1021/ja903216d Supporting Info |
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2D−3D Transition for Cationic and Anionic Gold Clusters: A Kinetic Energy Density Functional Study Lara Ferrighi, Bjørk Hammer and Georg K. H. Madsen pp 10605–10609 DOI: 10.1021/ja903069x Supporting Info |
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Covalent Inhibition of Bacterial Quorum Sensing Neri Amara, Roi Mashiach, Dotan Amar, Pnina Krief, St pp 10610–10619 DOI: 10.1021/ja903292v Supporting Info |
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A Reduction Pathway in the Synthesis of PbSe Nanocrystal Quantum Dots Jin Joo, Jeffrey M. Pietryga, John A. McGuire, Sea-Ho Jeon, Darrick J. Williams, Hsing-Lin Wang and Victor I. Klimov pp 10620–10628 DOI: 10.1021/ja903445f |
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Quantitative Production of Compound I from a Cytochrome P450 Enzyme at Low Temperatures. Kinetics, Activation Parameters, and Kinetic Isotope Effects for Oxidation of Benzyl Alcohol Qin Wang, Xin Sheng, John H. Horner and Martin Newcomb pp 10629–10636 DOI: 10.1021/ja9031105 Supporting Info |
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Porous Hollow Fe3O4 Nanoparticles for Targeted Delivery and Controlled Release of Cisplatin Kai Cheng, Sheng Peng, Chenjie Xu and Shouheng Sun pp 10637–10644 DOI: 10.1021/ja903300f Supporting Info |
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Synthesis of Cu-Doped InP Nanocrystals (d-dots) with ZnSe Diffusion Barrier as Efficient and Color-Tunable NIR Emitters Renguo Xie and Xiaogang Peng pp 10645–10651 DOI: 10.1021/ja903558r Supporting Info |
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Endo-Selective Enyne Ring-Closing Metathesis Promoted by Stereogenic-at-Mo Monoalkoxide and Monoaryloxide Complexes. Efficient Synthesis of Cyclic Dienes Not Accessible through Reactions with Ru Carbenes Yeon-Ju Lee, Richard R. Schrock and Amir H. Hoveyda pp 10652–10661 DOI: 10.1021/ja904098h Supporting Info |
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Metal−Organic Frameworks Impregnated with Magnesium-Decorated Fullerenes for Methane and Hydrogen Storage Aaron W. Thornton, Kate M. Nairn, James M. Hill, Anita J. Hill and Matthew R. Hill pp 10662–10669 DOI: 10.1021/ja9036302 Supporting Info |
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Fluorescent Single-Walled Carbon Nanotubes Following the 1,3-Dipolar Cycloaddition of Pyridinium Ylides Mustafa K. Bayazit and Karl S. Coleman pp 10670–10676 DOI: 10.1021/ja903712f Supporting Info |
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Protein Hydration Dynamics and Molecular Mechanism of Coupled Water−Protein Fluctuations Luyuan Zhang, Yi Yang, Ya-Ting Kao, Lijuan Wang and Dongping Zhong pp 10677–10691 DOI: 10.1021/ja902918p Supporting Info |
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A Suite of Activity-Based Probes for Human Cytochrome P450 Enzymes Aaron T. Wright, Joongyu D. Song and Benjamin F. Cravatt pp 10692–10700 DOI: 10.1021/ja9037609 Supporting Info |
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Rationalizing the Reactivity of Frustrated Lewis Pairs: Thermodynamics of H2 Activation and the Role of Acid−Base Properties Tibor Andr pp 10701–10710 DOI: 10.1021/ja903878z Supporting Info |
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Memory of Chirality of Tertiary Aromatic Amides: A Simple and Efficient Method for the Enantioselective Synthesis of Quaternary α-Amino Acids Mathieu Branca, S pp 10711–10718 DOI: 10.1021/ja9039604 Supporting Info |
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Mechanism of Helix Induction in Poly(4-carboxyphenyl isocyanide) with Chiral Amines and Memory of the Macromolecular Helicity and Its Helical Structures Yoko Hase, Kanji Nagai, Hiroki Iida, Katsuhiro Maeda, Noriaki Ochi, Kyoichi Sawabe, Koichi Sakajiri, Kento Okoshi and Eiji Yashima pp 10719–10732 DOI: 10.1021/ja904128d Supporting Info |
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Green Electrogenerated Chemiluminescence of Highly Fluorescent Benzothiadiazole and Fluorene Derivatives Khalid M. Omer, Sung-Yu Ku, Ken-Tsung Wong and Allen J. Bard pp 10733–10741 DOI: 10.1021/ja904135y Supporting Info |
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Selective C−H Activation of Haloalkanes using a Rhodiumtrispyrazolylborate Complex Andrew J. Vetter, Ryan D. Rieth, William W. Brennessel and William D. Jones pp 10742–10752 DOI: 10.1021/ja9002316 Supporting Info |
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Differential Binding of Co(II) and Zn(II) to Metallo-β-Lactamase Bla2 from Bacillus anthracis Megan J. Hawk, Robert M. Breece, Christine E. Hajdin, Katherine M. Bender, Zhenxin Hu, Alison L. Costello, Brian Bennett, David L. Tierney and Michael W. Crowder pp 10753–10762 DOI: 10.1021/ja900296u Supporting Info |
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Diphosphines with Strongly Polarized P−P Bonds: Hybrids between Covalent Molecules and Donor−Acceptor Adducts with Flexible Molecular Structures Sebastian Burck, Kathrin G pp 10763–10774 DOI: 10.1021/ja903156p Supporting Info |
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Predictable and Regioselective Insertion of Internal Unsymmetrical Alkynes in Rhodium-Catalyzed Cycloadditions with Alkenyl Isocyanates Rebecca Keller Friedman and Tomislav Rovis pp 10775–10782 DOI: 10.1021/ja903899c Supporting Info |
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Photoelectron Spectroscopy of Lanthanide−Silicon Cluster Anions LnSin− (3 ≤ n ≤ 13; Ln = Ho, Gd, Pr, Sm, Eu, Yb): Prospect for Magnetic Silicon-Based Clusters Andrej Grubisic, Yeon Jae Ko, Haopeng Wang and Kit H. Bowen pp 10783–10790 DOI: 10.1021/ja805205r |
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Introduction to Fluorescence Sensing Julie A. Stenken p 10791 DOI: 10.1021/ja903152j |
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Handbook of Asymmetric Heterogeneous Catalysis Stefan France pp 10791–10792 DOI: 10.1021/ja9042388 |
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High-Field EPR Spectroscopy on Proteins and Their Model Systems: Characterization of Transient Paramagnetic States John H. Enemark and Arnold M. Raitsimring pp 10792–10793 DOI: 10.1021/ja905234z |
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Iridium Complexes in Organic Synthesis Jonathan M. J. Williams pp 10793–10794 DOI: 10.1021/ja905514p |
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Springer Handbook of Enzymes, Supplement, Volume S2: Class 2 Transferases, EC 2.1-2.7.10, 2nd ed p 10794 DOI: 10.1021/ja905553y |
Issue 31
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Enantioselective Brønsted Acid-Catalyzed N-Acyliminium Cyclization Cascades Michael E. Muratore, Chloe A. Holloway, Adam W. Pilling, R. Ian Storer, Graham Trevitt and Darren J. Dixon pp 10796–10797 DOI: 10.1021/ja9024885 Supporting Info |
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EPR Spectroscopic Trapping of the Active Species of Nonheme Iron-Catalyzed Oxidation Oleg Y. Lyakin, Konstantin P. Bryliakov, George J. P. Britovsek and Evgenii P. Talsi pp 10798–10799 DOI: 10.1021/ja902659c Supporting Info |
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Site-Specific N- and C-Terminal Labeling of a Single Polypeptide Using Sortases of Different Specificity John M. Antos, Guo-Liang Chew, Carla P. Guimaraes, Nicholas C. Yoder, Gijsbert M. Grotenbreg, Maximilian Wei-Lin Popp and Hidde L. Ploegh pp 10800–10801 DOI: 10.1021/ja902681k Supporting Info |
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Band Gap Control in Conjugated Oligomers via Lewis Acids Gregory C. Welch, Robert Coffin, Jeff Peet and Guillermo C. Bazan pp 10802–10803 DOI: 10.1021/ja902789w Supporting Info |
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Three-Coordinate and Four-Coordinate Cobalt Hydride Complexes That React with Dinitrogen Keying Ding, William W. Brennessel and Patrick L. Holland pp 10804–10805 DOI: 10.1021/ja902812y Supporting Info |
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Pd(II)-Catalyzed Amination of C−H Bonds Using Single-Electron or Two-electron Oxidants Tian-Sheng Mei, Xisheng Wang and Jin-Quan Yu pp 10806–10807 DOI: 10.1021/ja904709b Supporting Info |
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Selective Radical Addition with a Designed Heterobifunctional Halide: A Primary Study toward Sequence-Controlled Polymerization upon Template Effect Shohei Ida, Takaya Terashima, Makoto Ouchi and Mitsuo Sawamoto pp 10808–10809 DOI: 10.1021/ja9031314 Supporting Info |
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Synthesis of Highly Strained π-Bowls from Sumanene Toru Amaya, Takuto Nakata and Toshikazu Hirao pp 10810–10811 DOI: 10.1021/ja9031693 Supporting Info |
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Anisotropic Growth of One-Dimensional Silver Rod−Needle and Plate−Belt Heteronanostructures Induced by Twins and hcp Phase Xiao Shuang Shen, Guan Zhong Wang, Xun Hong, Xing Xie, Wei Zhu and Da Peng Li pp 10812–10813 DOI: 10.1021/ja903389s Supporting Info |
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Systematic Improvement in Charge Carrier Mobility of Air Stable Triarylamine Copolymers Weimin Zhang, Jeremy Smith, Rick Hamilton, Martin Heeney, James Kirkpatrick, Kigook Song, Scott E. Watkins, Thomas Anthopoulos and Iain McCulloch pp 10814–10815 DOI: 10.1021/ja9034818 Supporting Info |
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Transverse-Dephasing Optimized Homonuclear J-Decoupling in Solid-State NMR Spectroscopy of Uniformly 13C-Labeled Proteins S pp 10816–10817 DOI: 10.1021/ja903542h Supporting Info |
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gem-Dichlorocyclopropanes as Abundant and Efficient Mechanophores in Polybutadiene Copolymers under Mechanical Stress Jeremy M. Lenhardt, Ashley L. Black and Stephen L. Craig pp 10818–10819 DOI: 10.1021/ja9036548 Supporting Info |
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Frustrated Rotations in Single-Molecule Junctions Young S. Park, Jonathan R. Widawsky, Maria Kamenetska, Michael L. Steigerwald, Mark S. Hybertsen, Colin Nuckolls and Latha Venkataraman pp 10820–10821 DOI: 10.1021/ja903731m Supporting Info |
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Cationic Rhodium(I)−dppf Complex-Catalyzed Olefin Isomerization/Propargyl Claisen Rearrangement/Carbonyl Migration Cascade Ken Tanaka, Eri Okazaki and Yu Shibata pp 10822–10823 DOI: 10.1021/ja9038449 Supporting Info |
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Rhenium-Catalyzed Addition of Carbonyl Compounds to the Carbon−Nitrogen Triple Bonds of Nitriles: α-C−H Activation of Carbonyl Compounds Hikaru Takaya, Masatsugu Ito and Shun-Ichi Murahashi pp 10824–10825 DOI: 10.1021/ja9036669 Supporting Info |
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Low-Temperature Solution-Processed Amorphous Indium Tin Oxide Field-Effect Transistors Hyun Sung Kim, Myung-Gil Kim, Young-Geun Ha, Mercouri G. Kanatzidis, Tobin J. Marks and Antonio Facchetti pp 10826–10827 DOI: 10.1021/ja903886r Supporting Info |
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Gold Nanoparticles Functionalized with Gadolinium Chelates as High-Relaxivity MRI Contrast Agents Lo pp 10828–10829 DOI: 10.1021/ja904094t Supporting Info |
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High Resolution Heteronuclear Correlation NMR Spectroscopy of an Antimicrobial Peptide in Aligned Lipid Bilayers: Peptide−Water Interactions at the Water−Bilayer Interface Riqiang Fu, Eric D. Gordon, Daniel J. Hibbard and Myriam Cotten pp 10830–10831 DOI: 10.1021/ja903999g Supporting Info |
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Measuring the Signs of 1Hα Chemical Shift Differences Between Ground and Excited Protein States by Off-Resonance Spin-Lock R1ρ NMR Spectroscopy Renate Auer, Philipp Neudecker, D. Ranjith Muhandiram, Patrik Lundstr pp 10832–10833 DOI: 10.1021/ja904315m Supporting Info |
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Observation of NMR Signals from Proteins Introduced into Living Mammalian Cells by Reversible Membrane Permeabilization Using a Pore-Forming Toxin, Streptolysin O Shinji Ogino, Satoshi Kubo, Ryo Umemoto, Shuxian Huang, Noritaka Nishida and Ichio Shimada pp 10834–10835 DOI: 10.1021/ja904407w Supporting Info |
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Synthesis and Reversible Control of the Fluorescent Properties of a Divalent Tin Dipyrromethene Junji Kobayashi, Tomokatsu Kushida and Takayuki Kawashima pp 10836–10837 DOI: 10.1021/ja904470m Supporting Info |
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Remote-Control Photoswitching Using NIR Light Carl-Johan Carling, John-Christopher Boyer and Neil R. Branda pp 10838–10839 DOI: 10.1021/ja904746s Supporting Info |
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Ethenolysis Reactions Catalyzed by Imido Alkylidene Monoaryloxide Monopyrrolide (MAP) Complexes of Molybdenum Smaranda C. Marinescu, Richard R. Schrock, Peter M pp 10840–10841 DOI: 10.1021/ja904786y Supporting Info |
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Catalytic Asymmetric Synthesis of α-Alkylidene-β-hydroxy Esters via Dynamic Kinetic Asymmetric Transformation Involving Ba-Catalyzed Direct Aldol Reaction Akitake Yamaguchi, Shigeki Matsunaga and Masakatsu Shibasaki pp 10842–10843 DOI: 10.1021/ja904575e Supporting Info |
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TBDPS and Br-TBDPS Protecting Groups as Efficient Aryl Group Donors in Pd-Catalyzed Arylation of Phenols and Anilines Chunhui Huang and Vladimir Gevorgyan pp 10844–10845 DOI: 10.1021/ja904791y Supporting Info |
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Similar Energetic Contributions of Packing in the Core of Membrane and Water-Soluble Proteins Nathan H. Joh, Amit Oberai, Duan Yang, Julian P. Whitelegge and James U. Bowie pp 10846–10847 DOI: 10.1021/ja904711k Supporting Info |
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Total Synthesis and Structural Revision of (±)-Tricholomalides A and B Zhang Wang, Sun-Joon Min and Samuel J. Danishefsky pp 10848–10849 DOI: 10.1021/ja9049433 Supporting Info |
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A B−B Bond-Containing Polycyclic π-Electron System: Dithieno-1,2-dihydro-1,2-diborin and Its Dianion Atsushi Wakamiya, Kenji Mori, Takafumi Araki and Shigehiro Yamaguchi pp 10850–10851 DOI: 10.1021/ja905007s Supporting Info |
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Isomerization Polymerization of 4-Alkylcyclopentenes Catalyzed by Pd Complexes: Hydrocarbon Polymers with Isotactic-Type Stereochemistry and Liquid-Crystalline Properties Takeshi Okada, Daisuke Takeuchi, Atsushi Shishido, Tomiki Ikeda and Kohtaro Osakada pp 10852–10853 DOI: 10.1021/ja904150w Supporting Info |
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To Switch or Not To Switch: The Effects of Potassium and Sodium Ions on α-Poly-l-glutamate Conformations in Aqueous Solutions Maxim V. Fedorov, Jonathan M. Goodman and Stephan Schumm pp 10854–10856 DOI: 10.1021/ja9030374 Supporting Info |
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A New Photoactive Crystalline Highly Porous Titanium(IV) Dicarboxylate Meenakshi Dan-Hardi, Christian Serre, Th pp 10857–10859 DOI: 10.1021/ja903726m Supporting Info |
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Tuning the Shape and Catalytic Activity of Fe Nanocrystals from Rhombic Dodecahedra and Tetragonal Bipyramids to Cubes by Electrochemistry Yan-Xin Chen, Sheng-Pei Chen, Zhi-You Zhou, Na Tian, Yan-Xia Jiang, Shi-Gang Sun, Yong Ding and Zhong Lin Wang pp 10860–10862 DOI: 10.1021/ja904225q Supporting Info |
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Size Control of Arsenic Trioxide Nanocrystals Grown in Nanowells Eun-Ah You, Richard W. Ahn, Min Hyung Lee, Meera R. Raja, Thomas V. O’Halloran and Teri W. Odom pp 10863–10865 DOI: 10.1021/ja902117b Supporting Info |
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Mesoporous Films and Polymer Brushes Helping Each Other To Modulate Ionic Transport in Nanoconfined Environments. An Interesting Example of Synergism in Functional Hybrid Assemblies Alejandra Calvo, Basit Yameen, Federico J. Williams, Galo J.A.A. Soler-Illia and Omar Azzaroni pp 10866–10868 DOI: 10.1021/ja9031067 Supporting Info |
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Highly Sensitive and Selective Gold(I) Recognition by a Metalloregulator in Ralstonia metallidurans Xing Jian, Erik C. Wasinger, Jenny V. Lockard, Lin X. Chen and Chuan He pp 10869–10871 DOI: 10.1021/ja904279n Supporting Info |
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Catalytic Asymmetric Intermolecular Stetter Reaction of Heterocyclic Aldehydes with Nitroalkenes: Backbone Fluorination Improves Selectivity Daniel A. DiRocco, Kevin M. Oberg, Derek M. Dalton and Tomislav Rovis pp 10872–10874 DOI: 10.1021/ja904375q Supporting Info |
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Enantioselective α-Trifluoromethylation of Aldehydes via Photoredox Organocatalysis David A. Nagib, Mark E. Scott and David W. C. MacMillan pp 10875–10877 DOI: 10.1021/ja9053338 Supporting Info |
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Formation of a Unique End-to-End Stacked Pair of G-Quadruplexes in the hTERT Core Promoter with Implications for Inhibition of Telomerase by G-Quadruplex-Interactive Ligands SunMi L. Palumbo, Scot W. Ebbinghaus and Laurence H. Hurley pp 10878–10891 DOI: 10.1021/ja902281d Supporting Info |
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Microwave-Assisted Synthesis of Thiophene Fluorophores, Labeling and Multilabeling of Monoclonal Antibodies, and Long Lasting Staining of Fixed Cells Massimo Zambianchi, Francesca Di Maria, Antonella Cazzato, Giuseppe Gigli, Manuel Piacenza, Fabio Della Sala and Giovanna Barbarella pp 10892–10900 DOI: 10.1021/ja902416s Supporting Info |
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Monoiron Hydrogenase Catalysis: Hydrogen Activation with the Formation of a Dihydrogen, Fe−Hδ−···Hδ+−O, Bond and Methenyl-H4MPT+ Triggered Hydride Transfer Xinzheng Yang and Michael B. Hall pp 10901–10908 DOI: 10.1021/ja902689n Supporting Info |
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Unveiling How Stereoelectronic Factors Affect Kinetics and Thermodynamics of Protonation Regiochemistry in [FeFe] Hydrogenase Synthetic Models: A DFT Investigation Giuseppe Zampella, Piercarlo Fantucci and Luca De Gioia pp 10909–10917 DOI: 10.1021/ja902727z Supporting Info |
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Modeling Metal Cation-Phosphate Interactions in Nucleic Acids: Activated Dissociation of Mg+, Al+, Cu+, and Zn+ Complexes of Triethyl Phosphate Chunhai Ruan and M. T. Rodgers pp 10918–10928 DOI: 10.1021/ja8092357 Supporting Info |
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Charge Density and Electrostatic Interactions of Fidarestat, an Inhibitor of Human Aldose Reductase Bertrand Fournier, El-Eulmi Bendeif, Beno pp 10929–10941 DOI: 10.1021/ja8095015 Supporting Info |
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A Porous Coordination Polymer Exhibiting Reversible Single-Crystal to Single-Crystal Substitution Reactions at Mn(II) Centers by Nitrile Guest Molecules Madhab C. Das and Parimal K. Bharadwaj pp 10942–10949 DOI: 10.1021/ja9006035 Supporting Info |
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Missing Metallofullerene with C80 Cage Hidefumi Nikawa, Tomoya Yamada, Baopeng Cao, Naomi Mizorogi, Zdenek Slanina, Takahiro Tsuchiya, Takeshi Akasaka, Kenji Yoza and Shigeru Nagase pp 10950–10954 DOI: 10.1021/ja900972r Supporting Info |
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New Palladium(II) Complex of P,S-Containing Hybrid Calixphyrin. Theoretical Study of Electronic Structure and Reactivity for Oxidative Addition Noriaki Ochi, Yoshihide Nakao, Hirofumi Sato, Yoshihiro Matano, Hiroshi Imahori and Shigeyoshi Sakaki pp 10955–10963 DOI: 10.1021/ja901166a Supporting Info |
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Nickel-Catalyzed Carbocyanation of Alkynes with Allyl Cyanides Yasuhiro Hirata, Tomoya Yukawa, Natsuko Kashihara, Yoshiaki Nakao and Tamejiro Hiyama pp 10964–10973 DOI: 10.1021/ja901374v Supporting Info |
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Detailed Study of C−O and C−C Bond-Forming Reductive Elimination from Stable C2N2O2−Ligated Palladium(IV) Complexes Joy M. Racowski, Allison R. Dick and Melanie S. Sanford pp 10974–10983 DOI: 10.1021/ja9014474 Supporting Info |
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Multilength-Scale Chemical Patterning of Self-Assembled Monolayers by Spatially Controlled Plasma Exposure: Nanometer to Centimeter Range Meng-Hsien Lin, Chi-Fan Chen, Hung-Wei Shiu, Chia-Hao Chen and Shangjr Gwo pp 10984–10991 DOI: 10.1021/ja901619h Supporting Info |
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Directed Assembly of PEGylated-Peptide Coatings for Infection-Resistant Titanium Metal Xiaojuan Khoo, Paul Hamilton, George A. O’Toole, Brian D. Snyder, Daniel J. Kenan and Mark W. Grinstaff pp 10992–10997 DOI: 10.1021/ja9020827 Supporting Info |
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Dynamic Interplay between Spin-Crossover and Host−Guest Function in a Nanoporous Metal−Organic Framework Material Peter D. Southon, Lang Liu, Elizabeth A. Fellows, David J. Price, Gregory J. Halder, Karena W. Chapman, Boujemaa Moubaraki, Keith S. Murray, Jean-Fran pp 10998–11009 DOI: 10.1021/ja902187d Supporting Info |
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Charge Density-Dependent Modifications of Hydration Shell Waters by Hofmeister Ions Feng Guo and Joel M. Friedman pp 11010–11018 DOI: 10.1021/ja902240j Supporting Info |
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Conduction Pathway of π-Stacked Ethylbenzene Molecular Wires on Si(100) Manuel Smeu, Robert A. Wolkow and Hong Guo pp 11019–11026 DOI: 10.1021/ja902641m Supporting Info |
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Flash Reduction and Patterning of Graphite Oxide and Its Polymer Composite Laura J. Cote, Rodolfo Cruz-Silva and Jiaxing Huang pp 11027–11032 DOI: 10.1021/ja902348k Supporting Info |
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Combined High-Resolution Neutron and X-ray Analysis of Inhibited Elastase Confirms the Active-Site Oxyanion Hole but Rules against a Low-Barrier Hydrogen Bond Taro Tamada, Takayoshi Kinoshita, Kazuo Kurihara, Motoyasu Adachi, Takashi Ohhara, Keisuke Imai, Ryota Kuroki and Toshiji Tada pp 11033–11040 DOI: 10.1021/ja9028846 Supporting Info |
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Toward an Artificial Golgi: Redesigning the Biological Activities of Heparan Sulfate on a Digital Microfluidic Chip Jeffrey G. Martin, Megha Gupta, Yongmei Xu, Srinivas Akella, Jian Liu, Jonathan S. Dordick and Robert J. Linhardt pp 11041–11048 DOI: 10.1021/ja903038d Supporting Info |
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Palladium-Catalyzed Coupling of Ammonia with Aryl Chlorides, Bromides, Iodides, and Sulfonates: A General Method for the Preparation of Primary Arylamines Giang D. Vo and John F. Hartwig pp 11049–11061 DOI: 10.1021/ja903049z Supporting Info |
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Searching for Microporous, Strongly Basic Catalysts: Experimental and Calculated 29Si NMR Spectra of Heavily Nitrogen-Doped Y Zeolites Fulya Dogan, Karl D. Hammond, Geoffrey A. Tompsett, Hua Huo, W. Curtis Conner, Jr., Scott M. Auerbach and Clare P. Grey pp 11062–11079 DOI: 10.1021/ja9031133 Supporting Info |
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Structure−Performance Correlations in Vapor Phase Deposited Self-Assembled Nanodielectrics for Organic Field-Effect Transistors Sara A. DiBenedetto, David L. Frattarelli, Antonio Facchetti, Mark A. Ratner and Tobin J. Marks pp 11080–11090 DOI: 10.1021/ja902751e Supporting Info |
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Protonated Benzene Dimer: An Experimental and Ab Initio Study Shamik Chakraborty, Reza Omidyan, Ivan Alata, Iben B. Nielsen, Claude Dedonder, Michel Broquier and Christophe Jouvet pp 11091–11097 DOI: 10.1021/ja903181k |
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Effects of Ligand Composition on the Oxidative Carbonylation of Toluene to Toluic Acid Catalyzed by Rh(III) Complexes Joseph Zakzeski, Andrew Behn, Martin Head-Gordon and Alexis T. Bell pp 11098–11105 DOI: 10.1021/ja903278n Supporting Info |
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Ordered and Oriented Supramolecular n/p-Heterojunction Surface Architectures: Completion of the Primary Color Collection Ravuri S. K. Kishore, Oksana Kel, Natalie Banerji, Daniel Emery, Guillaume Bollot, Jiri Mareda, Alberto Gomez-Casado, Pascal Jonkheijm, Jurriaan Huskens, Plinio Maroni, Michal Borkovec, Eric Vauthey, Naomi Sakai and Stefan Matile pp 11106–11116 DOI: 10.1021/ja9030648 Supporting Info |
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The Building Blocks of Cellulose: The Intrinsic Conformational Structures of Cellobiose, Its Epimer, Lactose, and Their Singly Hydrated Complexes Emilio J. Cocinero, David P. Gamblin, Benjamin G. Davis and John P. Simons pp 11117–11123 DOI: 10.1021/ja903322w Supporting Info |
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CdSe Quantum Dot Sensitized Solar Cells. Shuttling Electrons Through Stacked Carbon Nanocups Blake Farrow and Prashant V. Kamat pp 11124–11131 DOI: 10.1021/ja903337c Supporting Info |
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Scope and Mechanism of Interstrand Cross-Link Formation by the C4′-Oxidized Abasic Site Jonathan T. Sczepanski, Aaron C. Jacobs, Ananya Majumdar and Marc M. Greenberg pp 11132–11139 DOI: 10.1021/ja903404v Supporting Info |
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Dynamics of Imidazolium Ionic Liquids from a Combined Dielectric Relaxation and Optical Kerr Effect Study: Evidence for Mesoscopic Aggregation David A. Turton, Johannes Hunger, Alexander Stoppa, Glenn Hefter, Andreas Thoman, Markus Walther, Richard Buchner and Klaas Wynne pp 11140–11146 DOI: 10.1021/ja903315v |
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Scalable Synthesis of Few-Layer Graphene Ribbons with Controlled Morphologies by a Template Method and Their Applications in Nanoelectromechanical Switches Dacheng Wei, Yunqi Liu, Hongliang Zhang, Liping Huang, Bin Wu, Jianyi Chen and Gui Yu pp 11147–11154 DOI: 10.1021/ja903092k Supporting Info |
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How a Single-Point Mutation in Horseradish Peroxidase Markedly Enhances Enantioselectivity Eugene Antipov, Art E. Cho and Alexander M. Klibanov pp 11155–11160 DOI: 10.1021/ja903482u |
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Synthesis and Structure of PNP-Supported Iridium Silyl and Silylene Complexes: Catalytic Hydrosilation of Alkenes Elisa Calimano and T. Don Tilley pp 11161–11173 DOI: 10.1021/ja903737j Supporting Info |
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Viral Capsid DNA Aptamer Conjugates as Multivalent Cell-Targeting Vehicles Gary J. Tong, Sonny C. Hsiao, Zachary M. Carrico and Matthew B. Francis pp 11174–11178 DOI: 10.1021/ja903857f Supporting Info |
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A Realistic Description of the Charge Carrier Wave Function in Microcrystalline Polymer Semiconductors D. L. Cheung, D. P. McMahon and A. Troisi pp 11179–11186 DOI: 10.1021/ja903843c Supporting Info |
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Total Synthesis of (+)-Lyconadin A and Related Compounds via Oxidative C−N Bond Formation Scott P. West, Alakesh Bisai, Andrew D. Lim, Raja R. Narayan and Richmond Sarpong pp 11187–11194 DOI: 10.1021/ja903868n Supporting Info |
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Isolation of Dysprosium and Yttrium Complexes of a Three-Electron Reduction Product in the Activation of Dinitrogen, the (N2)3− Radical William J. Evans, Ming Fang, Ga pp 11195–11202 DOI: 10.1021/ja9036753 Supporting Info |
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Carbon−Carbon Coupling of C(sp3)−F Bonds Using Alumenium Catalysis Weixing Gu, Mason R. Haneline, Christos Douvris and Oleg V. Ozerov pp 11203–11212 DOI: 10.1021/ja903927c Supporting Info |
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Cubane-Type Co4S4 Clusters: Synthesis, Redox Series, and Magnetic Ground States Liang Deng, Eckhard Bill, Karl Wieghardt and R. H. Holm pp 11213–11221 DOI: 10.1021/ja903847a Supporting Info |
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Octanuclear Copper(I) Clusters Inscribed in a Se12 Icosahedron: Anion-Induced Modulation of the Core Size and Symmetry C. W. Liu, Bijay Sarkar, Yao-Jheng Huang, Ping-Kuei Liao, Ju-Chun Wang, Jean-Yves Saillard and Samia Kahlal pp 11222–11233 DOI: 10.1021/ja904089t Supporting Info |
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Synthetic and Mechanistic Studies of Pd-Catalyzed C−H Arylation with Diaryliodonium Salts: Evidence for a Bimetallic High Oxidation State Pd Intermediate Nicholas R. Deprez and Melanie S. Sanford pp 11234–11241 DOI: 10.1021/ja904116k Supporting Info |
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Mixed Valence Europium Nitridosilicate Eu2SiN3 Martin Zeuner, Sandro Pagano, Philipp Matthes, Daniel Bichler, Dirk Johrendt, Thomas Harmening, Rainer P pp 11242–11248 DOI: 10.1021/ja9040237 Supporting Info |
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Monomeric Copper(I), Silver(I), and Gold(I) Alkyne Complexes and the Coinage Metal Family Group Trends H. V. Rasika Dias, Jaime A. Flores, Jiang Wu and Peter Kroll pp 11249–11255 DOI: 10.1021/ja904232v Supporting Info |
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N-Heterocyclic Carbene Boryl Radicals: A New Class of Boron-Centered Radical Shau-Hua Ueng, Andrey Solovyev, Xinting Yuan, Steven J. Geib, Louis Fensterbank, Emmanuel Lac pp 11256–11262 DOI: 10.1021/ja904103x Supporting Info |
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Kinetic Hydrogen/Deuterium Effects in the Direct Hydrogenation of Ketones Catalyzed by a Well-Defined Ruthenium Diphosphine Diamine Complex Marco Zimmer-De Iuliis and Robert H. Morris pp 11263–11269 DOI: 10.1021/ja9043104 Supporting Info |
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Enhanced Base Pairing and Replication Efficiency of Thiothymidines, Expanded-size Variants of Thymidine Herman O. Sintim and Eric T. Kool p 11270 DOI: 10.1021/ja905423u Supporting Info |
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Overhauser Dynamic Nuclear Polarization To Study Local Water Dynamics Brandon D. Armstrong and Songi Han p 11270 DOI: 10.1021/ja904317z |
Issue 32
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Electrochemistry of Undoped Diamond Nanoparticles: Accessing Surface Redox States Katherine B. Holt, Daren J. Caruana and Enrique J. Mill pp 11272–11273 DOI: 10.1021/ja902216n Supporting Info |
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Triggered Self-Assembly of Simple Dynamic Covalent Surfactants Christophe B. Minkenberg, Louw Florusse, Rienk Eelkema, Ger J. M. Koper and Jan H. van Esch pp 11274–11275 DOI: 10.1021/ja902808q Supporting Info |
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Facile Synthesis of Superparamagnetic Fluorescent Fe3O4/ZnS Hollow Nanospheres Zhenxuan Wang, Limin Wu, Min Chen and Shuxue Zhou pp 11276–11277 DOI: 10.1021/ja903246e Supporting Info |
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Insights on Nuclease Mechanism: The Role of Proximal Ammonium Group on Phosphate Esters Cleavage Renato Bonomi, Giacomo Saielli, Umberto Tonellato, Paolo Scrimin and Fabrizio Mancin pp 11278–11279 DOI: 10.1021/ja9033236 Supporting Info |
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Stereoselective Synthesis of α-Alkyl-β-keto Imides via Asymmetric Redox C−C Bond Formation between α-Alkyl-α-diazocarbonyl Compounds and Aldehydes Takuya Hashimoto, Hisashi Miyamoto, Yuki Naganawa and Keiji Maruoka pp 11280–11281 DOI: 10.1021/ja903500w Supporting Info |
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Shape-Dependent Confinement in Ultrasmall Zero-, One-, and Two-Dimensional PbS Nanostructures Somobrata Acharya, D. D. Sarma, Yuval Golan, Sucheta Sengupta and Katsuhiko Ariga pp 11282–11283 DOI: 10.1021/ja903539d Supporting Info |
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Hydrogen-Bonding Asymmetric Metal Catalysis with α-Amino Acids: A Simple and Tunable Approach to High Enantioinduction Yingdong Lu, Tim C. Johnstone and Bruce A. Arndtsen pp 11284–11285 DOI: 10.1021/ja904185b Supporting Info |
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Enzyme Promotes the Hydrogelation from a Hydrophobic Small Molecule Jie Gao, Huaimin Wang, Ling Wang, Jingyu Wang, Deling Kong and Zhimou Yang pp 11286–11287 DOI: 10.1021/ja9042142 Supporting Info |
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Heterolytic Reduction of Fatty Acid Hydroperoxides by Cytochrome c/Cardiolipin Complexes: Antioxidant Function in Mitochondria Natalia A. Belikova, Yulia Y. Tyurina, Grigory Borisenko, Vladimir Tyurin, Alejandro K. Samhan Arias, Naveena Yanamala, Paul Georg Furtm pp 11288–11289 DOI: 10.1021/ja904343c Supporting Info |
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One- to Two-Electron Reduction of an [FeFe]-Hydrogenase Active Site Mimic: The Critical Role of Fluxionality of the [2Fe2S] Core Greg A. N. Felton, Benjamin J. Petro, Richard S. Glass, Dennis L. Lichtenberger and Dennis H. Evans pp 11290–11291 DOI: 10.1021/ja904520x Supporting Info |
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[123]Tetramantane: Parent of a New Family of σ-Helicenes Peter R. Schreiner, Andrey A. Fokin, Hans Peter Reisenauer, Boryslav A. Tkachenko, Elem pp 11292–11293 DOI: 10.1021/ja904527g Supporting Info |
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Multiphoton Writing of Three-Dimensional Fluidic Channels within a Porous Matrix Jyh-Tsung Lee, Matthew C. George, Jeffrey S. Moore and Paul V. Braun pp 11294–11295 DOI: 10.1021/ja904554m Supporting Info |
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Metal-Free Phenanthrenequinone Cyclotrimer as an Effective Heterogeneous Catalyst Jian Zhang, Xuan Wang, Qi Su, Linjie Zhi, Arne Thomas, Xinliang Feng, Dang Sheng Su, Robert Schl pp 11296–11297 DOI: 10.1021/ja9046735 Supporting Info |
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Nickel-Catalyzed Ring-Opening Hydroacylation of Methylenecyclopropanes: Synthesis of γ,δ-Unsaturated Ketones from Aldehydes Hiroki Taniguchi, Toshimichi Ohmura and Michinori Suginome pp 11298–11299 DOI: 10.1021/ja9046894 Supporting Info |
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CdSe/AsS Core−Shell Quantum Dots: Preparation and Two-Photon Fluorescence Junzhong Wang, Ming Lin, Yongli Yan, Zhe Wang, Paul C. Ho and Kian Ping Loh pp 11300–11301 DOI: 10.1021/ja904675a Supporting Info |
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Au@ZIF-8: CO Oxidation over Gold Nanoparticles Deposited to Metal−Organic Framework Hai-Long Jiang, Bo Liu, Tomoki Akita, Masatake Haruta, Hiroaki Sakurai and Qiang Xu pp 11302–11303 DOI: 10.1021/ja9047653 Supporting Info |
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Heme/O2/•NO Nitric Oxide Dioxygenase (NOD) Reactivity: Phenolic Nitration via a Putative Heme-Peroxynitrite Intermediate Mark P. Schopfer, Biplab Mondal, Dong-Heon Lee, Amy A. N. Sarjeant and Kenneth D. Karlin pp 11304–11305 DOI: 10.1021/ja904832j Supporting Info |
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Slow Transition between Two β-Strand Registers Is Dictated by Protein Unfolding Matthew R. Evans and Kevin H. Gardner pp 11306–11307 DOI: 10.1021/ja9048338 Supporting Info |
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Carbon Dots for Optical Imaging in Vivo Sheng-Tao Yang, Li Cao, Pengju G. Luo, Fushen Lu, Xin Wang, Haifang Wang, Mohammed J. Meziani, Yuanfang Liu, Gang Qi and Ya-Ping Sun pp 11308–11309 DOI: 10.1021/ja904843x Supporting Info |
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Palladium-Catalyzed Aromatic C−H Halogenation with Hydrogen Halides by Means of Electrochemical Oxidation Fumitoshi Kakiuchi, Takuya Kochi, Hitoshi Mutsutani, Noboru Kobayashi, Seiya Urano, Mitsuo Sato, Shigeru Nishiyama and Takamasa Tanabe pp 11310–11311 DOI: 10.1021/ja9049228 Supporting Info |
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Enantioselective, Iridium-Catalyzed Monoallylation of Ammonia Mark J. Pouy, Levi M. Stanley and John F. Hartwig pp 11312–11313 DOI: 10.1021/ja905059r Supporting Info |
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Enantiospecific Photochemical Norrish/Yang Type II Reaction of Nonbiaryl Atropchiral α-Oxoamides in Solution—Axial to Point Chirality Transfer Anoklase Jean-Luc Ayitou, Josepha L. Jesuraj, Nilotpal Barooah, Angel Ugrinov and J. Sivaguru pp 11314–11315 DOI: 10.1021/ja9050586 Supporting Info |
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Direct Asymmetric Reductive Amination Dietrich Steinhuebel, Yongkui Sun, Kazuhiko Matsumura, Noboru Sayo and Takao Saito pp 11316–11317 DOI: 10.1021/ja905143m Supporting Info |
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Bond Activation, Substrate Addition and Catalysis by an Isolable Two-Coordinate Pd(0) Bis-Isocyanide Monomer Liezel A. Labios, Matthew D. Millard, Arnold L. Rheingold and Joshua S. Figueroa pp 11318–11319 DOI: 10.1021/ja905338x Supporting Info |
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Bond Breaks of Nucleotides by Dissociative Electron Transfer of Nonequilibrium Prehydrated Electrons: A New Molecular Mechanism for Reductive DNA Damage Chun-Rong Wang, Jenny Nguyen and Qing-Bin Lu pp 11320–11322 DOI: 10.1021/ja902675g |
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Peculiar Stability of Amino Acids and Peptides from a Radical Perspective Zachary I. Watts and Christopher J. Easton pp 11323–11325 DOI: 10.1021/ja9027583 Supporting Info |
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Reaction Regimes on the Synthesis of Hollow Particles by the Kirkendall Effect Andreu Cabot, Maria Ib pp 11326–11328 DOI: 10.1021/ja903751p Supporting Info |
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Prediction of Breathing and Gate-Opening Transitions Upon Binary Mixture Adsorption in Metal−Organic Frameworks Fran pp 11329–11331 DOI: 10.1021/ja904123f Supporting Info |
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Enantioselective Aldehyde α-Nitroalkylation via Oxidative Organocatalysis Jonathan E. Wilson, Anthony D. Casarez and David W. C. MacMillan pp 11332–11334 DOI: 10.1021/ja904504j Supporting Info |
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α,γ-Peptide Nanotube Templating of One-Dimensional Parallel Fullerene Arrangements C pp 11335–11337 DOI: 10.1021/ja904548q Supporting Info |
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Combining Molecular Dynamics with Bayesian Analysis To Predict and Evaluate Ligand-Binding Mutations in Influenza Hemagglutinin Peter M. Kasson, Daniel L. Ensign and Vijay S. Pande pp 11338–11340 DOI: 10.1021/ja904557w Supporting Info |
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Experimental and Computational Evaluation of Forces Directing the Association of Transmembrane Helices Yao Zhang, Daniel W. Kulp, James D. Lear and William F. DeGrado pp 11341–11343 DOI: 10.1021/ja904625b Supporting Info |
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Dual-Controlled Nanoparticles Exhibiting AND Logic Sarah Angelos, Ying-Wei Yang, Niveen M. Khashab, J. Fraser Stoddart and Jeffrey I. Zink pp 11344–11346 DOI: 10.1021/ja9042752 Supporting Info |
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Templated Synthesis of Peptide Nucleic Acids via Sequence-Selective Base-Filling Reactions Jennifer M. Heemstra and David R. Liu pp 11347–11349 DOI: 10.1021/ja904712t Supporting Info |
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A Concise Synthesis of Berkelic Acid Inspired by Combining the Natural Products Spicifernin and Pulvilloric Acid Christopher F. Bender, Francis K. Yoshimoto, Christopher L. Paradise and Jef K. De Brabander pp 11350–11352 DOI: 10.1021/ja905387r Supporting Info |
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Live Cell Cytotoxicity Studies: Documentation of the Interactions of Antitumor Active Dirhodium Compounds with Nuclear DNA J. Dafhne Aguirre, Alfredo M. Angeles-Boza, Abdellatif Chouai, Jean-Philippe Pellois, Claudia Turro and Kim R. Dunbar pp 11353–11360 DOI: 10.1021/ja9021717 Supporting Info |
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Multiple Core−Shell Functionalized Colloidal Mesoporous Silica Nanoparticles Valentina Cauda, Axel Schlossbauer, Johann Kecht, Andreas Z pp 11361–11370 DOI: 10.1021/ja809346n Supporting Info |
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Triplet Excimer Formation in Platinum-Based Phosphors: A Theoretical Study of the Roles of Pt−Pt Bimetallic Interactions and Interligand π−π Interactions Dongwook Kim and Jean-Luc Br pp 11371–11380 DOI: 10.1021/ja809924t Supporting Info |
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Electrostatic Charging of Hydrophilic Particles Due to Water Adsorption Rubia F. Gouveia and Fernando Galembeck pp 11381–11386 DOI: 10.1021/ja900704f Supporting Info |
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A New Gadolinium-Based MRI Zinc Sensor Ana C. Esqueda, Jorge A. L pp 11387–11391 DOI: 10.1021/ja901875v Supporting Info |
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Can One Predict Changes from SN1 to SN2 Mechanisms? Thanh Binh Phan, Christoph Nolte, Shinjiro Kobayashi, Armin R. Ofial and Herbert Mayr pp 11392–11401 DOI: 10.1021/ja903207b Supporting Info |
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Regiospecific and Stereoselective Syntheses of (±) Morphine, Codeine, and Thebaine via a Highly Stereocontrolled Intramolecular 4 + 2 Cycloaddition Leading to a Phenanthrofuran System Gilbert Stork, Ayako Yamashita, Julian Adams, Gary R. Schulte, Richard Chesworth, Yoji Miyazaki and Jay J. Farmer pp 11402–11406 DOI: 10.1021/ja9038505 Supporting Info |
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Hexacationic Dendriphos Ligands in the Pd-Catalyzed Suzuki−Miyaura Cross-Coupling Reaction: Scope and Mechanistic Studies Dennis J. M. Snelders, Gerard van Koten and Robertus J. M. Klein Gebbink pp 11407–11416 DOI: 10.1021/ja904042h Supporting Info |
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Unprecedentedly High Selective Adsorption of Gas Mixtures in rho Zeolite-like Metal−Organic Framework: A Molecular Simulation Study Ravichandar Babarao and Jianwen Jiang pp 11417–11425 DOI: 10.1021/ja901061j Supporting Info |
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Understanding Structure−Mobility Relations for Perylene Tetracarboxydiimide Derivatives Valentina Marcon, Dag W. Breiby, Wojciech Pisula, Julie Dahl, James Kirkpatrick, Sameer Patwardhan, Ferdinand Grozema and Denis Andrienko pp 11426–11432 DOI: 10.1021/ja900963v Supporting Info |
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Real-Time Electrochemical Monitoring of the Polymerase Chain Reaction by Mediated Redox Catalysis Thibaut Def pp 11433–11441 DOI: 10.1021/ja901368m Supporting Info |
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Structures of Protonated Dipeptides: The Role of Arginine in Stabilizing Salt Bridges James S. Prell, Jeremy T. O’Brien, Jeffrey D. Steill, Jos Oomens and Evan R. Williams pp 11442–11449 DOI: 10.1021/ja901870d Supporting Info |
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Unraveling Atomic Positions in an Oxide Spinel with Two Jahn−Teller Ions: Local Structure Investigation of CuMn2O4 Daniel P. Shoemaker, Jun Li and Ram Seshadri pp 11450–11457 DOI: 10.1021/ja902096h |
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C-Lysine Conjugates: pH-Controlled Light-Activated Reagents for Efficient Double-Stranded DNA Cleavage with Implications for Cancer Therapy Wang-Yong Yang, Boris Breiner, Serguei V. Kovalenko, Chi Ben, Mani Singh, Shauna N. LeGrand, Qing-Xiang Amy Sang, Geoffrey F. Strouse, John A. Copland and Igor V. Alabugin pp 11458–11470 DOI: 10.1021/ja902140m Supporting Info |
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Fast Electron-Transfer Kinetics Probed in Nanofluidic Channels Marcel A. G. Zevenbergen, Bernhard L. Wolfrum, Edgar D. Goluch, Pradyumna S. Singh and Serge G. Lemay pp 11471–11477 DOI: 10.1021/ja902331u Supporting Info |
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Switchable Perfomance of an l-Proline-Derived Basic Catalyst Controlled by Supramolecular Gelation Francisco Rodr pp 11478–11484 DOI: 10.1021/ja902589f Supporting Info |
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NMR Spectroscopic Elucidation of the B−Z Transition of a DNA Double Helix Induced by the Zα Domain of Human ADAR1 Young-Min Kang, Jongchul Bang, Eun-Hae Lee, Hee-Chul Ahn, Yeo-Jin Seo, Kyeong Kyu Kim, Yang-Gyun Kim, Byong-Seok Choi and Joon-Hwa Lee pp 11485–11491 DOI: 10.1021/ja902654u Supporting Info |
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Homodimerization and Heterodimerization of Minimal Zinc(II)-Binding-Domain Peptides of T-Cell Proteins CD4, CD8α, and Lck Alisa M. Davis and Jeremy M. Berg pp 11492–11497 DOI: 10.1021/ja9028928 |
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Primary Role of the Electrostatic Contributions in a Rational Growth of Hysteresis Loop in Spin-Crossover Fe(II) Complexes Mika pp 11498–11502 DOI: 10.1021/ja9031677 |
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Infrared Spectroscopy of Fragments of Protonated Peptides: Direct Evidence for Macrocyclic Structures of b5 Ions Undine Erlekam, Benjamin J. Bythell, Debora Scuderi, Michael Van Stipdonk, B pp 11503–11508 DOI: 10.1021/ja903390r Supporting Info |
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Mechanistic Aspects of the Copolymerization of CO2 with Epoxides Using a Thermally Stable Single-Site Cobalt(III) Catalyst Wei-Min Ren, Zhong-Wen Liu, Ye-Qian Wen, Rong Zhang and Xiao-Bing Lu pp 11509–11518 DOI: 10.1021/ja9033999 Supporting Info |
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Large Metal Ions in a Relatively Small Fullerene Cage: The Structure of Gd3N@C2(22010)-C78 Departs from the Isolated Pentagon Rule Christine M. Beavers, Manuel N. Chaur, Marilyn M. Olmstead, Luis Echegoyen and Alan L. Balch pp 11519–11524 DOI: 10.1021/ja903741r Supporting Info |
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Solution Structures of Lithium Enolates of Cyclopentanone, Cyclohexanone, Acetophenones, and Benzyl Ketones. Triple Ions and Higher Lithiate Complexes Kristopher J. Kolonko, Margaret M. Biddle, Ilia A. Guzei and Hans J. Reich pp 11525–11534 DOI: 10.1021/ja903479p Supporting Info |
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Photoaffinity Labeling via Nitrenium Ion Chemistry: Protonation of the Nitrene Derived from 4-Amino-3-nitrophenyl Azide to Afford Reactive Nitrenium Ion Pairs Valentyna Voskresenska, R. Marshall Wilson, Maxim Panov, Alexander N. Tarnovsky, Jeanette A. Krause, Shubham Vyas, Arthur H. Winter and Christopher M. Hadad pp 11535–11547 DOI: 10.1021/ja902224m Supporting Info |
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Triplet States of the Nonlinear Optical Chromophore DCM in Single Crystals of Potassium Hydrogen Phthalate and Their Relationship to Single-Molecule Dark States Antonio Barbon, Eric D. Bott, Marina Brustolon, Marianna Fabris, Bart Kahr, Werner Kaminsky, Philip J. Reid, Susanna M. Wong, Kristin L. Wustholz and Roberto Zanr pp 11548–11557 DOI: 10.1021/ja903284y Supporting Info |
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Substrate-Selective Supramolecular Tandem Assays: Monitoring Enzyme Inhibition of Arginase and Diamine Oxidase by Fluorescent Dye Displacement from Calixarene and Cucurbituril Macrocycles Werner M. Nau, Garima Ghale, Andreas Hennig, H pp 11558–11570 DOI: 10.1021/ja904165c Supporting Info |
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A Push-Button Molecular Switch Jason M. Spruell, Walter F. Paxton, John-Carl Olsen, Diego Ben pp 11571–11580 DOI: 10.1021/ja904104c Supporting Info |
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Highly Conserved Histidine Plays a Dual Catalytic Role in Protein Splicing: A pKa Shift Mechanism Zhenming Du, Philip T. Shemella, Yangzhong Liu, Scott A. McCallum, Brian Pereira, Saroj K. Nayak, Georges Belfort, Marlene Belfort and Chunyu Wang pp 11581–11589 DOI: 10.1021/ja904318w Supporting Info |
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Structure and Spectroscopy of Oxyluciferin, the Light Emitter of the Firefly Bioluminescence Pan pp 11590–11605 DOI: 10.1021/ja904309q Supporting Info |
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Photonic Amplification by a Singlet-State Quantum Chain Reaction in the Photodecarbonylation of Crystalline Diarylcyclopropenones Gregory Kuzmanich, Matthew N. Gard and Miguel A. Garcia-Garibay pp 11606–11614 DOI: 10.1021/ja9043449 Supporting Info |
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Proton-Coupled Electron Transfer of Ruthenium(III)−Pterin Complexes: A Mechanistic Insight Soushi Miyazaki, Takahiko Kojima, James M. Mayer and Shunichi Fukuzumi pp 11615–11624 DOI: 10.1021/ja904386r Supporting Info |
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Stereogenic-at-Metal Zn- and Al-Based N-Heterocyclic Carbene (NHC) Complexes as Bifunctional Catalysts in Cu-Free Enantioselective Allylic Alkylations Yunmi Lee, Bo Li and Amir H. Hoveyda pp 11625–11633 DOI: 10.1021/ja904654j Supporting Info |
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RNA-Mediated Control of Metal Nanoparticle Shape Lina A. Gugliotti, Daniel L. Feldheim and Bruce E. Eaton p 11634 DOI: 10.1021/ja9053477 |
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Strained Hydrocarbons: Beyond the van’t Hoff and LeBel Hypothesis Jerome A. Berson p 11635 DOI: 10.1021/ja905486p |
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Functional Nucleic Acids for Analytical Applications Jennifer S. Brodbelt pp 11635–11636 DOI: 10.1021/ja905562z |
Issue 33
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Internal Return of Carbon Dioxide in Decarboxylation: Catalysis of Separation and 12C/13C Kinetic Isotope Effects Scott O. C. Mundle, Steven Rathgeber, Georges Lacrampe-Couloume, Barbara Sherwood Lollar and Ronald Kluger pp 11638–11639 DOI: 10.1021/ja902686h |
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Enantioselective α-Arylation of Aldehydes via Organo-SOMO Catalysis. An Ortho-Selective Arylation Reaction Based on an Open-Shell Pathway Jay C. Conrad, Jongrock Kong, Brian N. Laforteza and David W. C. MacMillan pp 11640–11641 DOI: 10.1021/ja9026902 Supporting Info |
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Motion of the Zinc Ions in Catalysis by a Dizinc Metallo-β-Lactamase Robert M. Breece, Zhenxin Hu, Brian Bennett, Michael W. Crowder and David L. Tierney pp 11642–11643 DOI: 10.1021/ja902534b Supporting Info |
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Site-Specific Two-Color Protein Labeling for FRET Studies Using Split Inteins Jin-Yi Yang and Wei Yuan Yang pp 11644–11645 DOI: 10.1021/ja9030215 Supporting Info |
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Template-Directed Synthesis of a Covalent Organic Capsule Based on a 3 nm-Sized Metallocapsule Shuichi Hiraoka, Yoshitaka Yamauchi, Ryo Arakane and Mitsuhiko Shionoya pp 11646–11647 DOI: 10.1021/ja903324r Supporting Info |
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Catalytic Enantioselective Synthesis of α,β-Diamino Acid Derivatives Le Li, Madhu Ganesh and Daniel Seidel pp 11648–11649 DOI: 10.1021/ja9034494 Supporting Info |
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A {Co32} Nanosphere Supported by p-tert-Butylthiacalix[4]arene Yanfeng Bi, Xiu-Teng Wang, Wuping Liao, Xiaofei Wang, Xinwu Wang, Hongjie Zhang and Song Gao pp 11650–11651 DOI: 10.1021/ja9034939 Supporting Info |
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Highly Versatile Rare Earth Tantalate Pyrochlore Nanophosphors May Nyman, Mark A. Rodriguez, Lauren E. Shea-Rohwer, James E. Martin and Paula P. Provencio pp 11652–11653 DOI: 10.1021/ja903823w Supporting Info |
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Gold-Catalyzed [3+3]-Annulation of Azomethine Imines with Propargyl Esters Nathan D. Shapiro, Yun Shi and F. Dean Toste pp 11654–11655 DOI: 10.1021/ja903863b Supporting Info |
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Pinpointing the Extent of Electronic Delocalization in the Re(I)-to-Tetrazine Charge-Separated Excited State Using Time-Resolved Infrared Spectroscopy Guifeng Li, Kumar Parimal, Shubham Vyas, Christopher M. Hadad, Amar H. Flood and Ksenija D. Glusac pp 11656–11657 DOI: 10.1021/ja903901n Supporting Info |
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Fe-g-C3N4-Catalyzed Oxidation of Benzene to Phenol Using Hydrogen Peroxide and Visible Light Xiufang Chen, Jinshui Zhang, Xianzhi Fu, Markus Antonietti and Xinchen Wang pp 11658–11659 DOI: 10.1021/ja903923s Supporting Info |
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Four-Component Domino Reaction Leading to Multifunctionalized Quinazolines Bo Jiang, Shu-Jiang Tu, Parminder Kaur, Walter Wever and Guigen Li pp 11660–11661 DOI: 10.1021/ja904011s Supporting Info |
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Cold Denaturation and Aggregation: A Comparative NMR Study of Titin I28 in Bulk and in a Confined Environment Domenico Sanfelice, Teodorico Tancredi, Anastasia Politou, Annalisa Pastore and Piero A. Temussi pp 11662–11663 DOI: 10.1021/ja904462n |
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Catalytic Asymmetric Synthesis of Chiral Tertiary Organoboronic Esters through Conjugate Boration of β-Substituted Cyclic Enones I-Hon Chen, Liang Yin, Wataru Itano, Motomu Kanai and Masakatsu Shibasaki pp 11664–11665 DOI: 10.1021/ja9045839 Supporting Info |
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Mass Spectrometric Identification of Au68(SR)34 Molecular Gold Nanoclusters with 34-Electron Shell Closing Amala Dass pp 11666–11667 DOI: 10.1021/ja904713f Supporting Info |
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Multiplex Single-Nucleotide Polymorphism Typing by Nanoparticle-Coupled DNA-Templated Reactions Xuejia Xue, Wei Xu, Feng Wang and Xiaogang Liu pp 11668–11669 DOI: 10.1021/ja904728v Supporting Info |
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Biofuel Cell Logically Controlled by Antigen−Antibody Recognition: Towards Immune-Regulated Bioelectronic Devices Tsz Kin Tam, Guinevere Strack, Marcos Pita and Evgeny Katz pp 11670–11671 DOI: 10.1021/ja9048459 Supporting Info |
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Synthesis of Cu2ZnSnS4 Nanocrystal Ink and Its Use for Solar Cells Qijie Guo, Hugh W. Hillhouse and Rakesh Agrawal pp 11672–11673 DOI: 10.1021/ja904981r Supporting Info |
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Decarboxylation via Addition of Water to a Carboxyl Group: Acid Catalysis of Pyrrole-2-Carboxylic Acid Scott O. C. Mundle and Ronald Kluger pp 11674–11675 DOI: 10.1021/ja905196n |
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Spatial Control of Crystal Nucleation in Agarose Gel Carla Duffus, Philip J. Camp and Andrew J. Alexander pp 11676–11677 DOI: 10.1021/ja905232m |
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Total Synthesis of Etnangien Pengfei Li, Jun Li, Fatih Arikan, Wiebke Ahlbrecht, Michael Dieckmann and Dirk Menche pp 11678–11679 DOI: 10.1021/ja9056163 Supporting Info |
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Identification of a Radical Intermediate in the Enzymatic Reduction of Oxygen by a Small Laccase Armand W.J.W. Tepper, Sergey Milikisyants, Silvia Sottini, Erik Vijgenboom, Edgar J.J. Groenen and Gerard W. Canters pp 11680–11682 DOI: 10.1021/ja900751c Supporting Info |
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High-Affinity Peptide-Based Collagen Targeting Using Synthetic Phage Mimics: From Phage Display to Dendrimer Display Brett A. Helms, Sanne W. A. Reulen, Sebastiaan Nijhuis, Peggy T. H. M. de Graaf-Heuvelmans, Maarten Merkx and E. W. Meijer pp 11683–11685 DOI: 10.1021/ja902285m Supporting Info |
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Transition-State Charge Transfer Reveals Electrophilic, Ambiphilic, and Nucleophilic Carbon−Hydrogen Bond Activation Daniel H. Ess, Robert J. Nielsen, William A. Goddard III and Roy A. Periana pp 11686–11688 DOI: 10.1021/ja902748c Supporting Info |
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Selective Attachment of Antibodies to the Edges of Gold Nanostructures for Enhanced Localized Surface Plasmon Resonance Biosensing Srinivas R. Beeram and Francis P. Zamborini pp 11689–11691 DOI: 10.1021/ja904387j Supporting Info |
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Nitric Oxide Switches on the Photoluminescence of Molecularly Engineered Quantum Dots Suhua Wang, Ming-Yong Han and Dejian Huang pp 11692–11694 DOI: 10.1021/ja904824w Supporting Info |
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Supramolecular Rhombic Grids Formed from Bimolecular Building Blocks Neng-Fang She, Meng Gao, Xiang-Gao Meng, Guang-Fu Yang, Johannes A. A. W. Elemans, An-Xin Wu and Lyle Isaacs pp 11695–11697 DOI: 10.1021/ja904920r Supporting Info |
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Isolable Photoreactive Polysilyl Radicals Gregory Molev, Boris Tumanskii, Dennis Sheberla, Mark Botoshansky, Dmitry Bravo-Zhivotovskii and Yitzhak Apeloig pp 11698–11700 DOI: 10.1021/ja905097b Supporting Info |
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A Catalytic, Brønsted Base Strategy for Intermolecular Allylic C−H Amination Sean A. Reed, Anthony R. Mazzotti and M. Christina White pp 11701–11706 DOI: 10.1021/ja903939k Supporting Info |
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Allylic C−H Amination for the Preparation of syn-1,3-Amino Alcohol Motifs Grant T. Rice and M. Christina White pp 11707–11711 DOI: 10.1021/ja9054959 Supporting Info |
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Detection of Free Monomeric Silver(I) and Gold(I) Cyanides, AgCN and AuCN: Microwave Spectra and Molecular Structure Toshiaki Okabayashi, Emi Y. Okabayashi, Fumi Koto, Toshimasa Ishida and Mitsutoshi Tanimoto pp 11712–11718 DOI: 10.1021/ja808153g Supporting Info |
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Porphyrin Arrays Responsive to Additives. Fluorescence Tuning Takeshi Yamamura, Shingo Suzuki, Tomotaka Taguchi, Akira Onoda, Toshiaki Kamachi and Ichiro Okura pp 11719–11726 DOI: 10.1021/ja809851d Supporting Info |
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Engineered Symmetric Connectivity of Secondary Structure Elements Highlights Malleability of Protein Folding Pathways Ylva Ivarsson, Carlo Travaglini-Allocatelli, Maurizio Brunori and Stefano Gianni pp 11727–11733 DOI: 10.1021/ja900438b |
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Catalytic Reactions of Carbene Precursors on Bulk Gold Metal Yibo Zhou, Brian G. Trewyn, Robert J. Angelici and L. Keith Woo pp 11734–11743 DOI: 10.1021/ja900653s Supporting Info |
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Confined-Plume Chemical Deposition: Rapid Synthesis of Crystalline Coatings of Known Hard or Superhard Materials on Inorganic or Organic Supports by Resonant IR Decomposition of Molecular Precursors Borislav L. Ivanov, Matthew S. Wellons and Charles M. Lukehart pp 11744–11750 DOI: 10.1021/ja901570s Supporting Info |
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The Molecular Mechanism of the Catalase Reaction Mercedes Alfonso-Prieto, Xevi Biarn pp 11751–11761 DOI: 10.1021/ja9018572 Supporting Info |
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89Y and 13C NMR Cluster and Carbon Cage Studies of an Yttrium Metallofullerene Family, Y3N@C2n (n = 40−43) Wujun Fu, Liaosa Xu, Hugo Azurmendi, Jiechao Ge, Tim Fuhrer, Tianming Zuo, Jonathan Reid, Chunying Shu, Kim Harich and Harry C. Dorn pp 11762–11769 DOI: 10.1021/ja902286v Supporting Info |
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On the Mechanism of Lewis Base Catalyzed Aldol Addition Reactions: Kinetic and Spectroscopic Investigations Using Rapid-Injection NMR Scott E. Denmark, Brian M. Eklov, Peter J. Yao and Martin D. Eastgate pp 11770–11787 DOI: 10.1021/ja902474j Supporting Info |
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Relaxation Dynamics of Pseudomonas aeruginosa ReI(CO)3(α-diimine)(HisX)+ (X = 83, 107, 109, 124, 126)CuII Azurins Ana Mar pp 11788–11800 DOI: 10.1021/ja902744s Supporting Info |
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Solid-State NMR Investigations of the Immobilization of a BF4− Salt of a Palladium(II) Complex on Silica Jerzy W. Wiench, Christophe Michon, Arkady Ellern, Paul Hazendonk, Adriana Iuga, Robert J. Angelici and Marek Pruski pp 11801–11810 DOI: 10.1021/ja902982u Supporting Info |
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Substrate Binding Mechanism of HIV-1 Protease from Explicit-Solvent Atomistic Simulations Fabio Pietrucci, Fabrizio Marinelli, Paolo Carloni and Alessandro Laio pp 11811–11818 DOI: 10.1021/ja903045y Supporting Info |
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Electroluminescence from Charge Transfer States in Polymer Solar Cells Kristofer Tvingstedt, Koen Vandewal, Abay Gadisa, Fengling Zhang, Jean Manca and Olle Ingan pp 11819–11824 DOI: 10.1021/ja903100p |
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Breathing Motions of a Respiratory Protein Revealed by Molecular Dynamics Simulations Mariano Andrea Scorciapino, Arturo Robertazzi, Mariano Casu, Paolo Ruggerone and Matteo Ceccarelli pp 11825–11832 DOI: 10.1021/ja9028473 Supporting Info |
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Quantum Mechanical Design and Structure of the Li@B10H14 Basket with a Remarkably Enhanced Electro-Optical Response Shabbir Muhammad, Hongliang Xu, Yi Liao, Yuhe Kan and Zhongmin Su pp 11833–11840 DOI: 10.1021/ja9032023 Supporting Info |
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Tuning Polymer Thickness: Synthesis and Scaling Theory of Homologous Series of Dendronized Polymers Yifei Guo, Jacco D. van Beek, Baozhong Zhang, Martin Colussi, Peter Walde, Afang Zhang, Martin Kr pp 11841–11854 DOI: 10.1021/ja9032132 Supporting Info |
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Direct Interaction between Amphotericin B and Ergosterol in Lipid Bilayers As Revealed by 2H NMR Spectroscopy Nobuaki Matsumori, Kazuaki Tahara, Hiroko Yamamoto, Atsushi Morooka, Mototsugu Doi, Tohru Oishi and Michio Murata pp 11855–11860 DOI: 10.1021/ja9033473 Supporting Info |
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31P MAS Refocused INADEQUATE Spin−Echo (REINE) NMR Spectroscopy: Revealing J Coupling and Chemical Shift Two-Dimensional Correlations in Disordered Solids Paul Guerry, Mark E. Smith and Steven P. Brown pp 11861–11874 DOI: 10.1021/ja902238s Supporting Info |
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Exocyclic Delocalization at the Expense of Aromaticity in 3,5-bis(π-Donor) Substituted Pyrazolium Ions and Corresponding Cyclic Bent Allenes Israel Fern pp 11875–11881 DOI: 10.1021/ja903396e Supporting Info |
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Matching Active Site and Substrate Structures for an RNA Editing Reaction Subhash Pokharel, Prasanna Jayalath, Olena Maydanovych, Rena A. Goodman, Selina C. Wang, Dean J. Tantillo and Peter A. Beal pp 11882–11891 DOI: 10.1021/ja9034076 Supporting Info |
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Photochemical Generation and the Reactivity of o-Naphthoquinone Methides in Aqueous Solutions Selvanathan Arumugam and Vladimir V. Popik pp 11892–11899 DOI: 10.1021/ja9031924 Supporting Info |
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Structural Flexibility Enhances the Reactivity of the Bioremediator Glycerophosphodiesterase by Fine-Tuning Its Mechanism of Hydrolysis Kieran S. Hadler, Nata pp 11900–11908 DOI: 10.1021/ja903534f Supporting Info |
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Characteristic Spin−Orbit Induced 1H(CH2) Chemical Shifts upon Deprotonation of Group 9 Polyamine Aqua and Alcohol Complexes Marja Hyv pp 11909–11918 DOI: 10.1021/ja903637m Supporting Info |
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Photoinitiated Charge Transport through π-Stacked Electron Conduits in Supramolecular Ordered Assemblies of Donor−Acceptor Triads Joseph E. Bullock, Raanan Carmieli, Sarah M. Mickley, Josh Vura-Weis and Michael R. Wasielewski pp 11919–11929 DOI: 10.1021/ja903903q Supporting Info |
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Alkylsubstituted Thienothiophene Semiconducting Materials: Structure−Property Relationships Mingqian He, Jianfeng Li, Michael L. Sorensen, Feixia Zhang, Robert R. Hancock, Hon Hang Fong, Vladimir A. Pozdin, Detlef-M. Smilgies and George G. Malliaras pp 11930–11938 DOI: 10.1021/ja903895s Supporting Info |
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Measurement of Methyl Axis Orientations in Invisible, Excited States of Proteins by Relaxation Dispersion NMR Spectroscopy Andrew J. Baldwin, D. Flemming Hansen, Pramodh Vallurupalli and Lewis E. Kay pp 11939–11948 DOI: 10.1021/ja903896p Supporting Info |
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Highly Selective Biaryl Cross-Coupling Reactions between Aryl Halides and Aryl Grignard Reagents: A New Catalyst Combination of N-Heterocyclic Carbenes and Iron, Cobalt, and Nickel Fluorides Takuji Hatakeyama, Sigma Hashimoto, Kentaro Ishizuka and Masaharu Nakamura pp 11949–11963 DOI: 10.1021/ja9039289 Supporting Info |
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Fundamental Reaction Mechanism and Free Energy Profile for (−)-Cocaine Hydrolysis Catalyzed by Cocaine Esterase Junjun Liu, Adel Hamza and Chang-Guo Zhan pp 11964–11975 DOI: 10.1021/ja903990p Supporting Info |
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The Use of Differential Receptors to Pattern Peptide Phosphorylation Tianzhi Zhang, Nicola Y. Edwards, Marco Bonizzoni and Eric V. Anslyn pp 11976–11984 DOI: 10.1021/ja9041675 Supporting Info |
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Nitroxyl Radical Plus Hydroxylamine Pseudo Self-Exchange Reactions: Tunneling in Hydrogen Atom Transfer Adam Wu, Elizabeth A. Mader, Ayan Datta, David A. Hrovat, Weston Thatcher Borden and James M. Mayer pp 11985–11997 DOI: 10.1021/ja904400d Supporting Info |
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Scope and Mechanism of Intramolecular Aziridination of Cyclopent-3-enyl-methylamines to 1-Azatricyclo[2.2.1.02,6]heptanes with Lead Tetraacetate Huayou Hu, Juan A. Faraldos and Robert M. Coates pp 11998–12006 DOI: 10.1021/ja9044136 Supporting Info |
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Influence of Temperature on Low-Power Upconversion in Rubbery Polymer Blends Tanya N. Singh-Rachford, Joseph Lott, Christoph Weder and Felix N. Castellano pp 12007–12014 DOI: 10.1021/ja904696n Supporting Info |
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Total Synthesis of (±)-Merrilactone A Wei He, Jie Huang, Xiufeng Sun and Alison J. Frontier p 12015 DOI: 10.1021/ja905598b |
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Pyridinium 1,1′-Binaphthyl-2,2′-disulfonates as Highly Effective Chiral Brønsted Acid−Base Combined Salt Catalysts for Enantioselective Mannich-Type Reaction Manabu Hatano, Toshikatsu Maki, Katsuhiko Moriyama, Manabu Arinobe and Kazuaki Ishihara p 12015 DOI: 10.1021/ja904923u Supporting Info |
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Alternative Solvents for Green Chemistry Douglas M. Fox p 12016 DOI: 10.1021/ja9058469 |
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Metal Ions in Life Sciences, Volume 6. Metal−Carbon Bonds in Enzymes and Cofactors Andreas Mayr pp 12016–12017 DOI: 10.1021/ja9059766 |
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Aptamers in Bioanalysis Marit Nilsen-Hamilton p 12018 DOI: 10.1021/ja906077x |
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Nano and Microsensors for Chemical and Biological Terrorism Surveillance Kevin D. Ausman pp 12018–12019 DOI: 10.1021/ja906082x |
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Flash Chemistry: Fast Organic Chemistry in Microsystems Klavs F. Jensen pp 12019–12020 DOI: 10.1021/ja906118k |
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Superacid Chemistry, 2nd ed. Ted Sorensen p 12020 DOI: 10.1021/ja906130f |
Issue 34
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Noninvasive Sialic Acid Detection at Cell Membrane by Using Phenylboronic Acid Modified Self-Assembled Monolayer Gold Electrode Akira Matsumoto, Naoko Sato, Kazunori Kataoka and Yuji Miyahara pp 12022–12023 DOI: 10.1021/ja902964m Supporting Info |
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In Vitro Mutasynthesis of Lantibiotic Analogues Containing Nonproteinogenic Amino Acids Matthew R. Levengood, Patrick J. Knerr, Trent J. Oman and Wilfred A. van der Donk pp 12024–12025 DOI: 10.1021/ja903239s Supporting Info |
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TiOPc Molecular Dislocation Networks as Nanotemplates for C60 Cluster Arrays Yinying Wei, Steven W. Robey and Janice E. Reutt-Robey pp 12026–12027 DOI: 10.1021/ja903055w Supporting Info |
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Stoichiometric Control of Multiple Different Tectons in Coordination-Driven Self-Assembly: Preparation of Fused Metallacyclic Polygons Junseong Lee, Koushik Ghosh and Peter J. Stang pp 12028–12029 DOI: 10.1021/ja903330j Supporting Info |
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Buckled Membranes in Mixed-Valence Ionic Amphiphile Vesicles Megan A. Greenfield, Liam C. Palmer, Graziano Vernizzi, Monica Olvera de la Cruz and Samuel I. Stupp pp 12030–12031 DOI: 10.1021/ja903546y Supporting Info |
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Demonstration of Surface-Enhanced Raman Scattering by Tunable, Plasmonic Gallium Nanoparticles Pae C Wu, Christopher G. Khoury, Tong-Ho Kim, Yang Yang, Maria Losurdo, Giuseppe V. Bianco, Tuan Vo-Dinh, April S. Brown and Henry O. Everitt pp 12032–12033 DOI: 10.1021/ja903321z |
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Effect of Surface Charge on the Vibrational Dynamics of Interfacial Water Ali Eftekhari-Bafrooei and Eric Borguet pp 12034–12035 DOI: 10.1021/ja903340e Supporting Info |
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Facet-Selective Epitaxial Growth of Heterogeneous Nanostructures of Semiconductor and Metal: ZnO Nanorods on Ag Nanocrystals Feng-Ru Fan, Yong Ding, De-Yu Liu, Zhong-Qun Tian and Zhong Lin Wang pp 12036–12037 DOI: 10.1021/ja9036324 Supporting Info |
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Observation of Cellular Cholesterol Efflux at Microcavity Electrodes Danjun Fang, Dechen Jiang, Hui Lu, Hillel J. Chiel, Thomas J. Kelley and James D. Burgess pp 12038–12039 DOI: 10.1021/ja903684f Supporting Info |
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Atomic Plane-Selective Deposition of Gold Nanoparticles on Metal Oxide Crystals Exploiting Preferential Adsorption of Additives Carrie G. Read, Ellen M. P. Steinmiller and Kyoung-Shin Choi pp 12040–12041 DOI: 10.1021/ja9036884 Supporting Info |
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Formation of Nitric Oxide from Nitrite by the Ferriheme b Protein Nitrophorin 7 Chunmao He and Markus Knipp pp 12042–12043 DOI: 10.1021/ja9040362 Supporting Info |
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Control of F-Doping in Pnictide High-Temperature Superconductors Gianluca A. Artioli, Lorenzo Malavasi, M. Cristina Mozzati and Yuri Diaz Fernandez pp 12044–12045 DOI: 10.1021/ja904126h Supporting Info |
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One-Dimensional Organometallic Molecular Wires via Assembly of Rh(CO)2Cl(amine): Chemical Control of Interchain Distances and Optical Properties Kwonho Jang, Il Gu Jung, Hye Jin Nam, Duk-Young Jung and Seung Uk Son pp 12046–12047 DOI: 10.1021/ja904247e Supporting Info |
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Cross-Medal Arrays of Ta-Doped Rutile Titania Xianfeng Yang, Jian Chen, Li Gong, Mingmei Wu and Jimmy C. Yu pp 12048–12049 DOI: 10.1021/ja904337x Supporting Info |
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Isoquinoline Synthesis via Rhodium-Catalyzed Oxidative Cross-Coupling/Cyclization of Aryl Aldimines and Alkynes Nicolas Guimond and Keith Fagnou pp 12050–12051 DOI: 10.1021/ja904380q Supporting Info |
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Surface Display of Redox Enzymes in Microbial Fuel Cells Simon Fishilevich, Liron Amir, Yearit Fridman, Amir Aharoni and Lital Alfonta pp 12052–12053 DOI: 10.1021/ja9042017 Supporting Info |
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Solution-Based Synthesis and Characterization of Cu2ZnSnS4 Nanocrystals Shannon C. Riha, Bruce A. Parkinson and Amy L. Prieto pp 12054–12055 DOI: 10.1021/ja9044168 Supporting Info |
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Palladium-Catalyzed Regio-, Diastereo-, and Enantioselective Benzylic Allylation of 2-Substituted Pyridines Barry M. Trost and David A. Thaisrivongs pp 12056–12057 DOI: 10.1021/ja904441a Supporting Info |
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Autonomously Oscillating Viscosity in Microgel Dispersions Daisuke Suzuki, Hajime Taniguchi and Ryo Yoshida pp 12058–12059 DOI: 10.1021/ja904677g Supporting Info |
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Integral Membrane Proteins in Nanodiscs Can Be Studied by Solution NMR Spectroscopy Julian M. Gl pp 12060–12061 DOI: 10.1021/ja904897p Supporting Info |
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Solvent Programmable Polymers Based on Restricted Rotation Yagang Zhang, Judith M. Lavin and Ken D. Shimizu pp 12062–12063 DOI: 10.1021/ja904234w Supporting Info |
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O-GlcNAc Peptide Epoxyketones Are Recognized by Mammalian Proteasomes Martin D. Witte, Bogdan I. Florea, Martijn Verdoes, Oloruntosin Adeyanju, Gijs A. Van der Marel and Herman S. Overkleeft pp 12064–12065 DOI: 10.1021/ja901231w Supporting Info |
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Location of the Yttrium Atom in Y@C82 and Its Influence on the Reactivity of Cage Carbons Xing Lu, Hidefumi Nikawa, Lai Feng, Takahiro Tsuchiya, Yutaka Maeda, Takeshi Akasaka, Naomi Mizorogi, Zdenek Slanina and Shigeru Nagase pp 12066–12067 DOI: 10.1021/ja905001w Supporting Info |
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Introduction of Cationic Charge into DNA Near the Major Groove Edge of a Guanine•Cytosine Base Pair: Characterization of Oligodeoxynucleotides Substituted with 7-Aminomethyl-7-deaza-2′-deoxyguanosine Manjori Ganguly, Ruo-Wen Wang, Luis A. Marky and Barry Gold pp 12068–12069 DOI: 10.1021/ja904930p Supporting Info |
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Nickel-Catalyzed Reaction of Arylzinc Reagents with N-Aromatic Heterocycles: A Straightforward Approach to C−H Bond Arylation of Electron-Deficient Heteroaromatic Compounds Mamoru Tobisu, Isao Hyodo and Naoto Chatani pp 12070–12071 DOI: 10.1021/ja9053509 Supporting Info |
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Total Synthesis and Structure Revision of the (−)-Maduropeptin Chromophore Kazuo Komano, Satoshi Shimamura, Yutaro Norizuki, Donglin Zhao, Chizuko Kabuto, Itaru Sato and Masahiro Hirama pp 12072–12073 DOI: 10.1021/ja905397p Supporting Info |
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Organic Reactions Promoted by Mucin Glycoproteins Natalie Shraga, Bogdan Belgorodsky and Michael Gozin pp 12074–12075 DOI: 10.1021/ja9040626 Supporting Info |
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Total Synthesis and Structural Revision of TMG-chitotriomycin, a Specific Inhibitor of Insect and Fungal β-N-Acetylglucosaminidases You Yang, Yao Li and Biao Yu pp 12076–12077 DOI: 10.1021/ja9055245 Supporting Info |
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Ni-Catalyzed Sonogashira Coupling of Nonactivated Alkyl Halides: Orthogonal Functionalization of Alkyl Iodides, Bromides, and Chlorides Oleg Vechorkin, Delphine Barmaz, Val pp 12078–12079 DOI: 10.1021/ja906040t Supporting Info |
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Equatorial Anomeric Triflates from Mannuronic Acid Esters Marthe T. C. Walvoort, Gerrit Lodder, Jaroslaw Mazurek, Herman S. Overkleeft, Jeroen D. C. Cod pp 12080–12081 DOI: 10.1021/ja905008p Supporting Info |
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Chemical Sensing Based on Catalytic Nanomotors: Motion-Based Detection of Trace Silver Daniel Kagan, Percy Calvo-Marzal, Shankar Balasubramanian, Sirilak Sattayasamitsathit, Kalayil Manian Manesh, Gerd-Uwe Flechsig and Joseph Wang pp 12082–12083 DOI: 10.1021/ja905142q Supporting Info |
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Total Synthesis of ent-Dioxepandehydrothyrsiferol via a Bromonium-Initiated Epoxide-Opening Cascade Jessica Tanuwidjaja, Sze-Sze Ng and Timothy F. Jamison pp 12084–12085 DOI: 10.1021/ja9052366 Supporting Info |
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Double-Shelled Nanocapsules of V2O5-Based Composites as High-Performance Anode and Cathode Materials for Li Ion Batteries Jun Liu, Hui Xia, Dongfeng Xue and Li Lu pp 12086–12087 DOI: 10.1021/ja9053256 Supporting Info |
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Strand Invasion of Extended, Mixed-Sequence B-DNA by γPNAs Gaofei He, Srinivas Rapireddy, Raman Bahal, Bichismita Sahu and Danith H. Ly pp 12088–12090 DOI: 10.1021/ja900228j Supporting Info |
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Fluorinated Lipid Constructs Permit Facile Passage of Molecular Cargo into Living Cells Laila Dafik, Venkateshwarlu Kalsani, Anthony Kar Lun Leung and Krishna Kumar pp 12091–12093 DOI: 10.1021/ja902777d Supporting Info |
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Marinopyrrole A Target Elucidation by Acyl Dye Transfer Chambers C. Hughes, Yu-Liang Yang, Wei-Ting Liu, Pieter C. Dorrestein, James J. La Clair and William Fenical pp 12094–12096 DOI: 10.1021/ja903149u Supporting Info |
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Direct Observation of Millisecond to Second Motions in Proteins by Dipolar CODEX NMR Spectroscopy Alexey Krushelnitsky, Eduardo deAzevedo, Rasmus Linser, Bernd Reif, Kay Saalw pp 12097–12099 DOI: 10.1021/ja9038888 Supporting Info |
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Triazole−Au(I) Complexes: A New Class of Catalysts with Improved Thermal Stability and Reactivity for Intermolecular Alkyne Hydroamination Haifeng Duan, Sujata Sengupta, Jeffrey L. Petersen, Novruz G. Akhmedov and Xiaodong Shi pp 12100–12102 DOI: 10.1021/ja9041093 Supporting Info |
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Allylic Ethers as Educts for Suzuki−Miyaura Couplings in Water at Room Temperature Takashi Nishikata and Bruce H. Lipshutz pp 12103–12105 DOI: 10.1021/ja905082c Supporting Info |
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Guest Tunable Structure and Spin Crossover Properties in a Nanoporous Coordination Framework Material Suzanne M. Neville, Gregory J. Halder, Karena W. Chapman, Martin B. Duriska, Boujemaa Moubaraki, Keith S. Murray and Cameron J. Kepert pp 12106–12108 DOI: 10.1021/ja905360g Supporting Info |
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Total Synthesis of (+)-Sorangicin A Amos B. Smith, III, Shuzhi Dong, Jehrod B. Brenneman and Richard J. Fox pp 12109–12111 DOI: 10.1021/ja906115a Supporting Info |
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Counterion-Dependent Valence Tautomerization of Ferrocenyl-Conjugated Pyrylium Salts Mio Kondo, Maai Uchikawa, Kosuke Namiki, Wen-Wei Zhang, Shoko Kume, Eiji Nishibori, Hiroyuki Suwa, Shinobu Aoyagi, Makoto Sakata, Masaki Murata, Yoshio Kobayashi and Hiroshi Nishihara pp 12112–12124 DOI: 10.1021/ja900393e Supporting Info |
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Trends in Covalency for d- and f-Element Metallocene Dichlorides Identified Using Chlorine K-Edge X-ray Absorption Spectroscopy and Time-Dependent Density Functional Theory Stosh A. Kozimor, Ping Yang, Enrique R. Batista, Kevin S. Boland, Carol J. Burns, David L. Clark, Steven D. Conradson, Richard L. Martin, Marianne P. Wilkerson and Laura E. Wolfsberg pp 12125–12136 DOI: 10.1021/ja9015759 Supporting Info |
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Reversible Transformation of a Stable Monomeric Silicon(II) Compound into a Stable Disilene by Phase Transfer: Experimental and Theoretical Studies of the System {[(Me3Si)2N](Me5C5)Si }n with n = 1,2 Peter Jutzi, Andreas Mix, Beate Neumann, Britta Rummel, Wolfgang W. Schoeller, Hans-Georg Stammler and A. B. Rozhenko pp 12137–12143 DOI: 10.1021/ja902153u Supporting Info |
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Nanoscale Zirconia as a Nonmetallic Catalyst for Graphitization of Carbon and Growth of Single- and Multiwall Carbon Nanotubes Stephen A. Steiner, III, Theodore F. Baumann, Bernhard C. Bayer, Raoul Blume, Marcus A. Worsley, Warren J. MoberlyChan, Elisabeth L. Shaw, Robert Schl pp 12144–12154 DOI: 10.1021/ja902913r Supporting Info |
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Peroxo-Type Intermediates in Class I Ribonucleotide Reductase and Related Binuclear Non-Heme Iron Enzymes Kasper P. Jensen, Caleb B. Bell,, III, Michael D. Clay and Edward I. Solomon pp 12155–12171 DOI: 10.1021/ja809983g Supporting Info |
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Synthesis, Structure, Bonding, and Properties of the Oxide Carbide ScAlOC, a New Type of Compound Melanie Schroeder and Harald Hillebrecht pp 12172–12179 DOI: 10.1021/ja900206h Supporting Info |
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Ionization of N2O4 in Contact with Water: Mechanism, Time Scales and Atmospheric Implications Yifat Miller, Barbara J. Finlayson-Pitts and R. Benny Gerber pp 12180–12185 DOI: 10.1021/ja900350g |
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Characterization of the Proximal Ligand in the P420 Form of Inducible Nitric Oxide Synthase Joseph Sabat, Dennis J. Stuehr, Syun-Ru Yeh and Denis L. Rousseau pp 12186–12192 DOI: 10.1021/ja901016a |
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Mechanistic Study of the sPLA2-Mediated Hydrolysis of a Thio-ester Pro Anticancer Ether Lipid Lars Linderoth, Peter Fristrup, Martin Hansen, Fredrik Melander, Robert Madsen, Thomas L. Andresen and G pp 12193–12200 DOI: 10.1021/ja901412j Supporting Info |
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Single Molecule Probing of the Local Segmental Relaxation Dynamics in Polymer above the Glass Transition Temperature Els Braeken, Gert De Cremer, Philippe Marsal, G pp 12201–12210 DOI: 10.1021/ja901636v |
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Mass-Produced Nanogap Sensor Arrays for Ultrasensitive Detection of DNA Somenath Roy, Xiaojun Chen, Mo-Huang Li, Yanfen Peng, Franklin Anariba and Zhiqiang Gao pp 12211–12217 DOI: 10.1021/ja901704t Supporting Info |
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Self-Association and Electron Transfer in Donor−Acceptor Dyads Connected by meta-Substituted Oligomers Agust pp 12218–12229 DOI: 10.1021/ja9024269 Supporting Info |
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Correlating Particle Size and Shape of Supported Ru/γ-Al2O3 Catalysts with NH3 Decomposition Activity Ayman M. Karim, Vinay Prasad, Giannis Mpourmpakis, William W. Lonergan, Anatoly I. Frenkel, Jingguang G. Chen and Dionisios G. Vlachos pp 12230–12239 DOI: 10.1021/ja902587k Supporting Info |
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Influence of Biaryl Phosphine Structure on C−N and C−C Bond Formation Ramendra Pratap, Damon Parrish, Padmaja Gunda, D. Venkataraman and Mahesh K. Lakshman pp 12240–12249 DOI: 10.1021/ja902679b Supporting Info |
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Spontaneous Room Temperature Elongation of CdS and Ag2S Nanorods via Oriented Attachment Catriona O’Sullivan, Robert D. Gunning, Ambarish Sanyal, Christopher A. Barrett, Hugh Geaney, Fathima R. Laffir, Shafaat Ahmed and Kevin M. Ryan pp 12250–12257 DOI: 10.1021/ja902860t Supporting Info |
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Distributive and Directional Behavior of Lantibiotic Synthetases Revealed by High-Resolution Tandem Mass Spectrometry M. Violet Lee, Leigh Anne Furgerson Ihnken, Young Ok You, Amanda L. McClerren, Wilfred A. van der Donk and Neil L. Kelleher pp 12258–12264 DOI: 10.1021/ja9033507 Supporting Info |
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Optical Detection of Disordered Water within a Protein Cavity Robert A. Goldbeck, Marlisa L. Pillsbury, Russell A. Jensen, Juan L. Mendoza, Rosa L. Nguyen, John S. Olson, Jayashree Soman, David S. Kliger and Raymond M. Esquerra pp 12265–12272 DOI: 10.1021/ja903409j |
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Reactivity of Glass-Embedded Met Hemoglobin Derivatives toward External NO: Implications for Nitrite-Mediated Production of Bioactive NO Mahantesh S. Navati and Joel M. Friedman pp 12273–12279 DOI: 10.1021/ja903364h Supporting Info |
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Reactions of an Intramolecular Frustrated Lewis Pair with Unsaturated Substrates: Evidence for a Concerted Olefin Addition Reaction Cornelia M. M pp 12280–12289 DOI: 10.1021/ja903511s Supporting Info |
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Origin of Photocatalytic Activity of Nitrogen-Doped TiO2 Nanobelts Jin Wang, De Nyago Tafen, James P. Lewis, Zhanglian Hong, Ayyakkannu Manivannan, Mingjia Zhi, Ming Li and Nianqiang Wu pp 12290–12297 DOI: 10.1021/ja903781h Supporting Info |
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UV-Induced Ligand Exchange in MHC Class I Protein Crystals Patrick H. N. Celie, Mireille Toebes, Boris Rodenko, Huib Ovaa, Anastassis Perrakis and Ton N. M. Schumacher pp 12298–12304 DOI: 10.1021/ja9037559 Supporting Info |
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Class I Major Histocompatibility Complexes Loaded by a Periodate Trigger Boris Rodenko, Mireille Toebes, Patrick H. N. Celie, Anastassis Perrakis, Ton N. M. Schumacher and Huib Ovaa pp 12305–12313 DOI: 10.1021/ja9037565 Supporting Info |
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Origins of the Distortions in the Base Pair Step Adjacent to Platinum Anticancer Drug−DNA Adducts. Fundamental NMR Solution Studies Utilizing Right-Handed Cross-Link Models Having 5′- and 3′-Flanking Residues Jamil S. Saad, Giovanni Natile and Luigi G. Marzilli pp 12314–12324 DOI: 10.1021/ja903787m Supporting Info |
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Terminal Protection of Small-Molecule-Linked DNA for Sensitive Electrochemical Detection of Protein Binding via Selective Carbon Nanotube Assembly Zhan Wu, Zhen Zhen, Jian-Hui Jiang, Guo-Li Shen and Ru-Qin Yu pp 12325–12332 DOI: 10.1021/ja9038054 Supporting Info |
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Topologically Ordered Amorphous Silica Obtained from the Collapsed Siliceous Zeolite, Silicalite-1-F: A Step toward “Perfect” Glasses Julien Haines, Claire Levelut, Aude Isambert, Philippe H pp 12333–12338 DOI: 10.1021/ja904054v |
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Social Self-Sorting: Alternating Supramolecular Oligomer Consisting of Isomers Naoki Tomimasu, Akira Kanaya, Yoshinori Takashima, Hiroyasu Yamaguchi and Akira Harada pp 12339–12343 DOI: 10.1021/ja903988c Supporting Info |
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Iridium Phosphite−Oxazoline Catalysts for the Highly Enantioselective Hydrogenation of Terminal Alkenes Javier Mazuela, J. Johan Verendel, Mercedes Coll, Benjam pp 12344–12353 DOI: 10.1021/ja904152r Supporting Info |
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Oxysterol-Induced Rearrangement of the Liquid-Ordered Phase: A Possible Link to Alzheimer’s Disease? Hideyuki Mitomo, Wen-Hua Chen and Steven L. Regen pp 12354–12357 DOI: 10.1021/ja904308y Supporting Info |
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Shape-Selective Enantioselective Hydrogenation on Pt Nanoparticles Erik Schmidt, Angelo Vargas, Tamas Mallat and Alfons Baiker pp 12358–12367 DOI: 10.1021/ja9043328 Supporting Info |
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Enhanced Optical Activity by Achiral Rod-Like Molecules Nanosegregated in the B4 Structure of Achiral Bent-Core Molecules Taketo Otani, Fumito Araoka, Ken Ishikawa and Hideo Takezoe pp 12368–12372 DOI: 10.1021/ja904447b Supporting Info |
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Molecular Simulation of Electric Double-Layer Capacitors Based on Carbon Nanotube Forests Lu Yang, Brian H. Fishbine, Albert Migliori and Lawrence R. Pratt pp 12373–12376 DOI: 10.1021/ja9044554 Supporting Info |
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Growth Patterns and Shape Development of Zeolite Nanocrystals in Confined Syntheses Won Cheol Yoo, Sandeep Kumar, R. Lee Penn, Michael Tsapatsis and Andreas Stein pp 12377–12383 DOI: 10.1021/ja904466v Supporting Info |
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A Mechanistic Investigation on Copolymerization of Ethylene with Polar Monomers Using a Cyclophane-Based Pd(II) α-Diimine Catalyst Chris S. Popeney and Zhibin Guan pp 12384–12393 DOI: 10.1021/ja904471v Supporting Info |
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Critical Role of External Axial Ligands in Chirality Amplification of trans-Cyclohexane-1,2-diamine in Salen Complexes Takuya Kurahashi, Masahiko Hada and Hiroshi Fujii pp 12394–12405 DOI: 10.1021/ja904635n Supporting Info |
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Total Synthesis and Structure−Activity Investigation of the Marine Natural Product Neopeltolide Daniel W. Custar, Thomas P. Zabawa, John Hines, Craig M. Crews and Karl A. Scheidt pp 12406–12414 DOI: 10.1021/ja904604x Supporting Info |
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Exceptionally High Acetylene Uptake in a Microporous Metal−Organic Framework with Open Metal Sites Shengchang Xiang, Wei Zhou, Jose M. Gallegos, Yun Liu and Banglin Chen pp 12415–12419 DOI: 10.1021/ja904782h Supporting Info |
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Infochemistry: Encoding Information as Optical Pulses Using Droplets in a Microfluidic Device Michinao Hashimoto, Ji Feng, Roger L. York, Audrey K. Ellerbee, Greg Morrison, Samuel W. Thomas III, L. Mahadevan and George M. Whitesides pp 12420–12429 DOI: 10.1021/ja904788m Supporting Info |
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Ligand Mapping on Protein Surfaces by the 3D-RISM Theory: Toward Computational Fragment-Based Drug Design Takashi Imai, Koji Oda, Andriy Kovalenko, Fumio Hirata and Akinori Kidera pp 12430–12440 DOI: 10.1021/ja905029t Supporting Info |
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Electric Bistability in Pentacene Film-Based Transistor Embedding Gold Nanoparticles Chiao-Wei Tseng and Yu-Tai Tao pp 12441–12450 DOI: 10.1021/ja904882m |
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Formation of Silicon-Based Molecular Electronic Structures Using Flip-Chip Lamination Mariona Coll, Lauren H. Miller, Lee J. Richter, Daniel R. Hines, Oana D. Jurchescu, Nadine Gergel-Hackett, Curt A. Richter and Christina A. Hacker pp 12451–12457 DOI: 10.1021/ja901646j Supporting Info |
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Exploring Photoreactions between Polyazaaromatic Ru(II) Complexes and Biomolecules by Chemically Induced Dynamic Nuclear Polarization Measurements Sandrine Perrier, Epiphanie Mugeniwabagara, Andr pp 12458–12465 DOI: 10.1021/ja9024287 Supporting Info |
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High-Resolution Cryogenic-Electron Microscopy Reveals Details of a Hexagonal-to-Bicontinuous Cubic Phase Transition in Mesoporous Silica Synthesis Liora Omer, Sharon Ruthstein, Daniella Goldfarb and Yeshayahu Talmon pp 12466–12473 DOI: 10.1021/ja903178f Supporting Info |
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Experimental Thermodynamics of High Temperature Transformations in Single-Walled Carbon Nanotube Bundles Daniele Gozzi, Alessandro Latini and Laura Lazzarini pp 12474–12482 DOI: 10.1021/ja904294z |
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Practical Catalytic Asymmetric Synthesis of Diaryl-, Aryl Heteroaryl-, and Diheteroarylmethanols Luca Salvi, Jeung Gon Kim and Patrick J. Walsh pp 12483–12493 DOI: 10.1021/ja9046747 Supporting Info |
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ZnO-Templated Synthesis of Wurtzite-Type ZnS and ZnSe Nanoparticles Farah Dawood and Raymond E. Schaak p 12494 DOI: 10.1021/ja9058316 |
Issue 35
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Contemporary Chemical Sciences and JACS Perspectives Peter J. Stang p 12496 DOI: 10.1021/ja903812n |
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Synthesis at the Interface of Chemistry and Biology Xu Wu and Peter G. Schultz pp 12497–12515 DOI: 10.1021/ja9026067 Supporting Info |
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Diastereoselective Heterogeneous Bromination of Stilbene in a Porous Metal−Organic Framework Simon C. Jones and Christina A. Bauer pp 12516–12517 DOI: 10.1021/ja900893p Supporting Info |
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Photoinduced, Family-Specific, Site-Selective Cleavage of TIM-Barrel Proteins Nicola Floyd, Neil J. Oldham, Christopher J. Eyles, Stephen Taylor, Dmitry A. Filatov, Mark Brouard and Benjamin G. Davis pp 12518–12519 DOI: 10.1021/ja9026105 Supporting Info |
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Efficient Energy Transfer within Self-Assembling Peptide Fibers: A Route to Light-Harvesting Nanomaterials Kevin J. Channon, Glyn L. Devlin and Cait E. MacPhee pp 12520–12521 DOI: 10.1021/ja902825j |
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G-Quadruplex DNA Bound by a Synthetic Ligand is Highly Dynamic Prakrit V. Jena, Pravin S. Shirude, Burak Okumus, Katta Laxmi-Reddy, Fr pp 12522–12523 DOI: 10.1021/ja903408r Supporting Info |
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De Novo Synthesis of Modified Saxitoxins for Sodium Ion Channel Study Brian M. Andresen and J. Du Bois pp 12524–12525 DOI: 10.1021/ja904179f Supporting Info |
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ON/OFF Red Emission from Azaporphine in a Coordination Cage in Water Kosuke Ono, Jeremy K. Klosterman, Michito Yoshizawa, Kentaro Sekiguchi, Tahei Tahara and Makoto Fujita pp 12526–12527 DOI: 10.1021/ja904875y Supporting Info |
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Catalyst-Free Synthesis of Oligoanilines and Polyaniline Nanofibers Using H2O2 Sumedh P. Surwade, Srikanth Rao Agnihotra, Vineet Dua, Neha Manohar, Sujit Jain, Srikanth Ammu and Sanjeev K. Manohar pp 12528–12529 DOI: 10.1021/ja905014e Supporting Info |
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Use of a High Electron-Affinity Molybdenum Dithiolene Complex to p-Dope Hole-Transport Layers Yabing Qi, Tissa Sajoto, Stephen Barlow, Eung-Gun Kim, Jean-Luc Br pp 12530–12531 DOI: 10.1021/ja904939g Supporting Info |
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Synthesis and Structure of Chemically Stable Metal−Organic Polyhedra Zheng Lu, Carolyn B. Knobler, Hiroyasu Furukawa, Bo Wang, Guannan Liu and Omar M. Yaghi pp 12532–12533 DOI: 10.1021/ja905101s Supporting Info |
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Journey from Mo−Mo Quadruple Bonds to Quintuple Bonds Yi-Chou Tsai, Hong-Zhang Chen, Chie-Chieh Chang, Jen-Shiang K. Yu, Gene-Hsiang Lee, Yu Wang and Ting-Shen Kuo pp 12534–12535 DOI: 10.1021/ja905035f Supporting Info |
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EPR Detection of an O2 Surrogate Bound to Heme cn of the Cytochrome b6f Complex Anna I. Twigg, Danas Baniulis, William A. Cramer and Michael P. Hendrich pp 12536–12537 DOI: 10.1021/ja905171c Supporting Info |
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Interfacial Widths of Conjugated Polymer Bilayers Cheng Wang, Andres Garcia, Hongping Yan, Karen E. Sohn, Alexander Hexemer, Thuc-Quyen Nguyen, Guillermo C. Bazan, Edward J. Kramer and Harald Ade pp 12538–12539 DOI: 10.1021/ja905293m Supporting Info |
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Shape and Size Effects of ZnO Nanocrystals on Photocatalytic Activity Anna Mclaren, Teresa Valdes-Solis, Guoqiang Li and Shik Chi Tsang pp 12540–12541 DOI: 10.1021/ja9052703 Supporting Info |
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Synthesis of Water-Soluble 2,2′-Diphenyl-1-Picrylhydrazyl Nanoparticles: A New Standard for Electron Paramagnetic Resonance Spectroscopy Ou Chen, Jiaqi Zhuang, Fabrizio Guzzetta, Jared Lynch, Alexander Angerhofer and Y. Charles Cao pp 12542–12543 DOI: 10.1021/ja905395u Supporting Info |
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New Ferroelectrics Based on Divalent Metal Ion Alum Wen Zhang, Li-Zhuang Chen, Ren-Gen Xiong, Takayoshi Nakamura and Songping D. Huang pp 12544–12545 DOI: 10.1021/ja905399x Supporting Info |
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A New Reaction Motif: “Homo-SN2′-Like” Direct Nucleophilic Addition to Neutral η3-Allylmolybdenum Complexes. Total Synthesis of the Antimalarial (+)-Isofebrifugine Wenyong Chen and Lanny S. Liebeskind pp 12546–12547 DOI: 10.1021/ja9056322 Supporting Info |
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Pairing Geometry of the Hydrophobic Thymine Analogue 2,4-Difluorotoluene in Duplex DNA as Analyzed by X-ray Crystallography Pradeep S. Pallan and Martin Egli pp 12548–12549 DOI: 10.1021/ja905739j Supporting Info |
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Catalytic Enantioselective Allylation of Dienals through the Intermediacy of Unsaturated π-Allyl Complexes Ping Zhang and James P. Morken pp 12550–12551 DOI: 10.1021/ja9058537 Supporting Info |
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Rhodium-Catalyzed Highly Enantioselective Direct Intermolecular Hydroacylation of 1,1-Disubstituted Alkenes with Unfunctionalized Aldehydes Yu Shibata and Ken Tanaka pp 12552–12553 DOI: 10.1021/ja905908z Supporting Info |
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Synthesis of Cu2ZnSnS4 Nanocrystals for Use in Low-Cost Photovoltaics Chet Steinhagen, Matthew G. Panthani, Vahid Akhavan, Brian Goodfellow, Bonil Koo and Brian A. Korgel pp 12554–12555 DOI: 10.1021/ja905922j |
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Asymmetric Tandem Wittig Rearrangement/Aldol Reactions Natalie C. Giampietro, Jeff W. Kampf and John P. Wolfe pp 12556–12557 DOI: 10.1021/ja905930s Supporting Info |
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Slow Magnetic Relaxation in a Trigonal Prismatic Uranium(III) Complex Jeffrey D. Rinehart and Jeffrey R. Long pp 12558–12559 DOI: 10.1021/ja906012u Supporting Info |
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Oxaziridine-Mediated Intramolecular Amination of sp3-Hybridized C−H Bonds Charles P. Allen, Tamas Benkovics, Amanda K. Turek and Tehshik P. Yoon pp 12560–12561 DOI: 10.1021/ja906183g Supporting Info |
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A Concise Total Synthesis of Saliniketal B Jun Liu and Jef K. De Brabander pp 12562–12563 DOI: 10.1021/ja9061757 Supporting Info |
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Production of Octaketide Polyenes by the Calicheamicin Polyketide Synthase CalE8: Implications for the Biosynthesis of Enediyne Core Structures Katherine Belecki, Jason M. Crawford and Craig A. Townsend pp 12564–12566 DOI: 10.1021/ja904391r Supporting Info |
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Expression of Sensitized Eu3+ Luminescence at a Multivalent Interface Shu-Han Hsu, M. Deniz Yilmaz, Christian Blum, Vinod Subramaniam, David N. Reinhoudt, Aldrik H. Velders and Jurriaan Huskens pp 12567–12569 DOI: 10.1021/ja904747p Supporting Info |
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Mn(III)-Mediated Reactions of Cyclopropanols with Vinyl Azides: Synthesis of Pyridine and 2-Azabicyclo[3.3.1]non-2-en-1-ol Derivatives Yi-Feng Wang and Shunsuke Chiba pp 12570–12572 DOI: 10.1021/ja905110c Supporting Info |
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Characterization of Iron−Carbonyl-Protected Gold Clusters Olga Lopez-Acevedo, Jyri Rintala, Suvi Virtanen, Cristina Femoni, Cristina Tiozzo, Henrik Gr pp 12573–12575 DOI: 10.1021/ja905182g Supporting Info |
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Improved Dienophilicity of Nitrocycloalkenes: Prospects for the Development of a trans-Diels−Alder Paradigm Woo Han Kim, Jun Hee Lee and Samuel J. Danishefsky pp 12576–12578 DOI: 10.1021/ja9058926 Supporting Info |
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Polymeric Ladderphanes Chih-Ming Chou, Shern-Long Lee, Chih-Hsien Chen, Akkattu Thankappan Biju, Hsian-Wen Wang, Yi-Lin Wu, Guo-Fu Zhang, Kuang-Wei Yang, Tsong-Shin Lim, Min-Jie Huang, Po-Yu Tsai, Kin-Chuan Lin, Shou-Ling Huang, Chun-hsien Chen and Tien-Yau Luh pp 12579–12585 DOI: 10.1021/ja9035362 Supporting Info |
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Molecular Dynamics at Constant pH and Reduction Potential: Application to Cytochrome c3 Miguel Machuqueiro and Ant pp 12586–12594 DOI: 10.1021/ja808463e Supporting Info |
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Self-Assembly from the Gas-Phase: Design and Implementation of Small-Molecule Chromophore Precursors with Large Nonlinear Optical Responses David Frattarelli, Michele Schiavo, Antonio Facchetti, Mark A. Ratner and Tobin J. Marks pp 12595–12612 DOI: 10.1021/ja900131y Supporting Info |
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Mechanistic Insights on the Copolymerization of Polar Vinyl Monomers with Neutral Ni(II) Catalysts Andreas Berkefeld, Matthias Drexler, Heiko M. M pp 12613–12622 DOI: 10.1021/ja901360b Supporting Info |
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Near-Infrared Continuous-Wave Light Driving a Two-Photon Photochromic Reaction with the Assistance of Localized Surface Plasmon Yasuyuki Tsuboi, Ryosuke Shimizu, Tatsuya Shoji and Noboru Kitamura pp 12623–12627 DOI: 10.1021/ja9016655 |
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A Small Molecule That Disrupts G-Quadruplex DNA Structure and Enhances Gene Expression Zo pp 12628–12633 DOI: 10.1021/ja901892u Supporting Info |
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A Redox Non-Innocent Ligand Controls the Life Time of a Reactive Quartet Excited State - An MCSCF Study of [Ni(H)(OH)]+ Yavuz Dede, Xinhao Zhang, Maria Schlangen, Helmut Schwarz and Mu-Hyun Baik pp 12634–12642 DOI: 10.1021/ja902093f Supporting Info |
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π-Conjugated Multidonor/Acceptor Arrays of Fullerene−Cobaltadithiolene−Tetrathiafulvalene: From Synthesis and Structure to Electronic Interactions Yutaka Matsuo, Masashi Maruyama, S. Shankara Gayathri, Tomoya Uchida, Dirk M. Guldi, Hideo Kishida, Arao Nakamura and Eiichi Nakamura pp 12643–12649 DOI: 10.1021/ja902312q Supporting Info |
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Lateral Diffusion of Membrane Proteins Sivaramakrishnan Ramadurai, Andrea Holt, Victor Krasnikov, Geert van den Bogaart, J. Antoinette Killian and Bert Poolman pp 12650–12656 DOI: 10.1021/ja902853g Supporting Info |
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Noncovalent Synthesis of Shape-Persistent Cyclic Hexamers from Ditopic Hydrazide-Based Supramolecular Synthons and Asymmetric Induction of Supramolecular Chirality Yong Yang, Min Xue, Jun-Feng Xiang and Chuan-Feng Chen pp 12657–12663 DOI: 10.1021/ja9029335 Supporting Info |
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Ammoniated Electrons Stabilized at the Surface of MgO Mario Chiesa, Elio Giamello and Sabine Van Doorslaer pp 12664–12670 DOI: 10.1021/ja903179b |
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High Fidelity Base Pairing at the 3′-Terminus Amritraj Patra and Clemens Richert pp 12671–12681 DOI: 10.1021/ja9033654 Supporting Info |
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Enzymatic Hydrolysis of Trilactone Siderophores: Where Chiral Recognition Occurs in Enterobactin and Bacillibactin Iron Transport Rebecca J. Abergel, Anna M. Zawadzka, Trisha M. Hoette and Kenneth N. Raymond pp 12682–12692 DOI: 10.1021/ja903051q Supporting Info |
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Direct Spectroscopic Observation of Large Quenching of First-Order Orbital Angular Momentum with Bending in Monomeric, Two-Coordinate Fe(II) Primary Amido Complexes and the Profound Magnetic Effects of the Absence of Jahn− and Renner−Teller Distortions in Rigorously Linear Coordination W. Alexander Merrill, Troy A. Stich, Marcin Brynda, Gregory J. Yeagle, James C. Fettinger, Raymond De Hont, William M. Reiff, Charles E. Schulz, R. David Britt and Philip P. Power pp 12693–12702 DOI: 10.1021/ja903439t Supporting Info |
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High Oxidation State Rhodium and Iridium Bis(silyl)dihydride Complexes Supported by a Chelating Pyridyl-Pyrrolide Ligand Jennifer L. McBee, Jose Escalada and T. Don Tilley pp 12703–12713 DOI: 10.1021/ja9035169 Supporting Info |
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Molecular View of Cholesterol Flip-Flop and Chemical Potential in Different Membrane Environments W. F. Drew Bennett, Justin L. MacCallum, Marlon J. Hinner, Siewert J. Marrink and D. Peter Tieleman pp 12714–12720 DOI: 10.1021/ja903529f Supporting Info |
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Long-Term Improvements to Photoluminescence and Dispersion Stability by Flowing SDS-SWNT Suspensions through Microfluidic Channels Carlos A. Silvera-Batista, Philip Weinberg, Jason E. Butler and Kirk J. Ziegler pp 12721–12728 DOI: 10.1021/ja903705k Supporting Info |
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Reversing the Thermal Stability of a Molecular Switch on a Gold Surface: Ring-Opening Reaction of Nitrospiropyran Marten Piantek, Gunnar Schulze, Matthias Koch, Katharina J. Franke, Felix Leyssner, Alex Kr pp 12729–12735 DOI: 10.1021/ja901238p Supporting Info |
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Helices, Chirality and Interpenetration: the Versatility and Remarkable Interconversion of Silver−Copper Cyanide Frameworks Ann M. Chippindale and Simon J. Hibble pp 12736–12744 DOI: 10.1021/ja903841e Supporting Info |
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Measurement of Methyl Group Motional Parameters of Invisible, Excited Protein States by NMR Spectroscopy D. Flemming Hansen, Pramodh Vallurupalli and Lewis E. Kay pp 12745–12754 DOI: 10.1021/ja903897e Supporting Info |
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Improving Electrocatalysts for O2 Reduction by Fine-Tuning the Pt−Support Interaction: Pt Monolayer on the Surfaces of a Pd3Fe(111) Single-Crystal Alloy Wei-Ping Zhou, Xiaofang Yang, Miomir B. Vukmirovic, Bruce E. Koel, Jiao Jiao, Guowen Peng, Manos Mavrikakis and Radoslav R. Adzic pp 12755–12762 DOI: 10.1021/ja9039746 |
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Single Gold Nanoparticles Counter: An Ultrasensitive Detection Platform for One-Step Homogeneous Immunoassays and DNA Hybridization Assays Chao Xie, Fagong Xu, Xiangyi Huang, Chaoqing Dong and Jicun Ren pp 12763–12770 DOI: 10.1021/ja903873n Supporting Info |
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Mechanism and Transition State Structure of Aryl Methylphosphonate Esters Doubly Coordinated to a Dinuclear Cobalt(III) Center Guoqiang Feng, Eric A. Tanifum, Harry Adams, Alvan C. Hengge and Nicholas H. Williams pp 12771–12779 DOI: 10.1021/ja904134n Supporting Info |
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Role of Nanoparticle Valency in the Nondestructive Magnetic-Relaxation-Mediated Detection and Magnetic Isolation of Cells in Complex Media Charalambos Kaittanis, Santimukul Santra and J. Manuel Perez pp 12780–12791 DOI: 10.1021/ja9041077 Supporting Info |
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A Pillared-Layer Coordination Polymer with a Rotatable Pillar Acting as a Molecular Gate for Guest Molecules Joobeom Seo, Ryotaro Matsuda, Hirotoshi Sakamoto, Charlotte Bonneau and Susumu Kitagawa pp 12792–12800 DOI: 10.1021/ja904363b Supporting Info |
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Hydrogen/Deuterium Exchange Mass Spectrometry with Top-Down Electron Capture Dissociation for Characterizing Structural Transitions of a 17 kDa Protein Jingxi Pan, Jun Han, Christoph H. Borchers and Lars Konermann pp 12801–12808 DOI: 10.1021/ja904379w |
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Heme Regulation of Human Cystathionine β-Synthase Activity: Insights from Fluorescence and Raman Spectroscopy Colin L. Weeks, Sangita Singh, Peter Madzelan, Ruma Banerjee and Thomas G. Spiro pp 12809–12816 DOI: 10.1021/ja904468w Supporting Info |
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Fluorescent Asymmetrically Cobalt-Tipped CdSe@CdS Core@Shell Nanorod Heterostructures Exhibiting Room-Temperature Ferromagnetic Behavior Sasanka Deka, Andrea Falqui, Giovanni Bertoni, Claudio Sangregorio, Giordano Poneti, Giovanni Morello, Milena De Giorgi, Cinzia Giannini, Roberto Cingolani, Liberato Manna and P. Davide Cozzoli pp 12817–12828 DOI: 10.1021/ja904493c Supporting Info |
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Alkylation of Dinitrogen in [(HIPTNCH2CH2)3N]Mo Complexes (HIPT = 3,5-(2,4,6-i-Pr3C6H2)2C6H3) Thomas Kupfer and Richard R. Schrock pp 12829–12837 DOI: 10.1021/ja904535f |
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No Confinement Needed: Observation of a Metastable Hydrophobic Wetting Two-Layer Ice on Graphene Greg A. Kimmel, Jesper Matthiesen, Marcel Baer, Christopher J. Mundy, Nikolay G. Petrik, R. Scott Smith, Zdenek Dohn pp 12838–12844 DOI: 10.1021/ja904708f |
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Unique Tautomeric and Recognition Properties of Thioketothymines? Ignacio Faustino, Anna Avi pp 12845–12853 DOI: 10.1021/ja904880y Supporting Info |
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Concise Syntheses of the Natural Products (+)-Sylvaticin and (+)-cis-Sylvaticin Timothy J. Donohoe, Robert M. Harris, Oliver Williams, Gr pp 12854–12861 DOI: 10.1021/ja9049959 Supporting Info |
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Springer Handbook of Enzymes: Supplement Volume S3, Class 2 Transferases, EC 2.7.11.1—2.7.11.16, 2nd ed. p 12862 DOI: 10.1021/ja906433x |
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CRC Handbook of Chemistry and Physics, 2009−2010, 90th ed. p 12862 DOI: 10.1021/ja906434c |
Issue 36
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Long-Range Alignments of Single Fullerenes by Site-Selective Inclusion into a Double-Cavity 2D Open Network Luc Piot, Fabien Silly, Ludovic Tortech, Yohann Nicolas, Philippe Blanchard, Jean Roncali and Denis Fichou pp 12864–12865 DOI: 10.1021/ja902621t Supporting Info |
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Inhibitory Substrate Binding Site of Human Indoleamine 2,3-Dioxygenase Changyuan Lu, Yu Lin and Syun-Ru Yeh pp 12866–12867 DOI: 10.1021/ja9029768 Supporting Info |
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Visible Light Responsive Nitrogen Doped Anatase TiO2 Sheets with Dominant {001} Facets Derived from TiN Gang Liu, Hua Gui Yang, Xuewen Wang, Lina Cheng, Jian Pan, Gao Qing (Max) Lu and Hui-Ming Cheng pp 12868–12869 DOI: 10.1021/ja903463q Supporting Info |
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[5mCCTCTCTCC]4: An i-Motif Tetramer with Intercalated T•T Pairs Muriel Canalia and Jean-Louis Leroy pp 12870–12871 DOI: 10.1021/ja903210t Supporting Info |
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Group-Transfer Reactions of Nickel−Carbene and −Nitrene Complexes with Organoazides and Nitrous Oxide that Form New C═N, C═O, and N═N Bonds Nicole D. Harrold, Rory Waterman, Gregory L. Hillhouse and Thomas R. Cundari pp 12872–12873 DOI: 10.1021/ja904370h Supporting Info |
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Direct versus Hydrogen-Assisted CO Dissociation Sharan Shetty, Antonius P. J. Jansen and Rutger A. van Santen pp 12874–12875 DOI: 10.1021/ja9044482 Supporting Info |
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Mediated Electrochemical Oxidation of a Fully Encapsulated Redox Active Center Dagmara Podkoscielny, Suresh Gadde and Angel E. Kaifer pp 12876–12877 DOI: 10.1021/ja9045108 Supporting Info |
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Use of Local Alignment Tensors for the Determination of Relative Configurations in Organic Compounds Christina M. Thiele, Arnold Maliniak and Baltzar Stevensson pp 12878–12879 DOI: 10.1021/ja904536b Supporting Info |
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A Double TROSY hNCAnH Experiment for Efficient Assignment of Large and Challenging Proteins Dominique P. Frueh, Haribabu Arthanari, Alexander Koglin, Christopher T. Walsh and Gerhard Wagner pp 12880–12881 DOI: 10.1021/ja9046685 Supporting Info |
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Chiral Phosphoric Acid-Governed Anti-Diastereoselective and Enantioselective Hetero-Diels−Alder Reaction of Glyoxylate Norie Momiyama, Hideaki Tabuse and Masahiro Terada pp 12882–12883 DOI: 10.1021/ja904749x Supporting Info |
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Selective Covalent Bond Formation in Polypeptide Ions via Gas-Phase Ion/Ion Reaction Chemistry Hongling Han and Scott A. McLuckey pp 12884–12885 DOI: 10.1021/ja904812d Supporting Info |
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A Pd(II)-Catalyzed Ring-Expansion Reaction of Cyclic 2-Azidoalcohol Derivatives: Synthesis of Azaheterocycles Shunsuke Chiba, Yan-Jun Xu and Yi-Feng Wang pp 12886–12887 DOI: 10.1021/ja9049564 Supporting Info |
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A Ring-Opening Metathesis Polymerization Route to Alkaline Anion Exchange Membranes: Development of Hydroxide-Conducting Thin Films from an Ammonium-Functionalized Monomer Timothy J. Clark, Nicholas J. Robertson, Henry A. Kostalik IV, Emil B. Lobkovsky, Paul F. Mutolo, H pp 12888–12889 DOI: 10.1021/ja905242r Supporting Info |
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A Bulky Bis-Pocket Manganese(V)−Oxo Corrole Complex: Observation of Oxygen Atom Transfer between Triply Bonded MnV≡O and Alkene Hai-Yang Liu, Fei Yam, Yu-Tao Xie, Xiao-Yuan Li and Chi K. Chang pp 12890–12891 DOI: 10.1021/ja905153r Supporting Info |
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Recyclable Nanobiocatalyst for Enantioselective Sulfoxidation: Facile Fabrication and High Performance of Chloroperoxidase-Coated Magnetic Nanoparticles with Iron Oxide Core and Polymer Shell Wen Wang, Yi Xu, Daniel I. C. Wang and Zhi Li pp 12892–12893 DOI: 10.1021/ja905477j Supporting Info |
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Externally Initiated Regioregular P3HT with Controlled Molecular Weight and Narrow Polydispersity Hugo A. Bronstein and Christine K. Luscombe pp 12894–12895 DOI: 10.1021/ja9054977 Supporting Info |
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An Efficient Route to Highly Organized, Tunable Macroporous−Mesoporous Alumina Jean-Philippe Dacquin, J pp 12896–12897 DOI: 10.1021/ja9056486 Supporting Info |
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Pd-Catalyzed Conversion of Aryl Chlorides, Triflates, and Nonaflates to Nitroaromatics Brett P. Fors and Stephen L. Buchwald pp 12898–12899 DOI: 10.1021/ja905768k Supporting Info |
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Controlled Growth of Monodisperse Self-Supported Superparamagnetic Nanostructures of Spherical and Rod-Like CoFe2O4 Nanocrystals Ningzhong Bao, Liming Shen, Yu-Hsiang A. Wang, Jianxing Ma, Dipanjan Mazumdar and Arunava Gupta pp 12900–12901 DOI: 10.1021/ja905811h Supporting Info |
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Conformational Flexibility of a Rotaxane Thread Probed by Electronic Spectroscopy in Helium Nanodroplets Szymon Smolarek, Anouk M. Rijs, Jeffrey S. Hannam, David A. Leigh, Marcel Drabbels and Wybren J. Buma pp 12902–12903 DOI: 10.1021/ja905973v |
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[4+2] Cycloaddition of o-Xylylenes with Imines Using Palladium Catalyst Satoshi Ueno, Masakazu Ohtsubo and Ryoichi Kuwano pp 12904–12905 DOI: 10.1021/ja905988e Supporting Info |
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Heavier Group 2 Metals and Intermolecular Hydroamination: A Computational and Synthetic Assessment Anthony G. M. Barrett, Christine Brinkmann, Mark R. Crimmin, Michael S. Hill, Patricia Hunt and Panayiotis A. Procopiou pp 12906–12907 DOI: 10.1021/ja905615a Supporting Info |
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Direct Raman Measurement of an Elevated Base pKa in the Active Site of a Small Ribozyme in a Precatalytic Conformation Man Guo, Robert C. Spitale, Rosaria Volpini, Jolanta Krucinska, Gloria Cristalli, Paul R. Carey and Joseph E. Wedekind pp 12908–12909 DOI: 10.1021/ja9060883 Supporting Info |
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Allene Synthesis via C−C Fragmentation: Method and Mechanistic Insight Robert V. Kolakowski, Madhuri Manpadi, Yue Zhang, Thomas J. Emge and Lawrence J. Williams pp 12910–12911 DOI: 10.1021/ja906189h Supporting Info |
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pH Clock-Operated Mechanized Nanoparticles Sarah Angelos, Niveen M. Khashab, Ying-Wei Yang, Ali Trabolsi, Hussam A. Khatib, J. Fraser Stoddart and Jeffrey I. Zink pp 12912–12914 DOI: 10.1021/ja9010157 Supporting Info |
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Iron-Catalyzed 1,4-Hydroboration of 1,3-Dienes Jessica Y. Wu, Beno pp 12915–12917 DOI: 10.1021/ja9048493 Supporting Info |
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Reductive and Brominative Termination of Alkenol Cyclization in Aerobic Cobalt-Catalyzed Reactions Dominik Schuch, Patrick Fries, Maike D pp 12918–12920 DOI: 10.1021/ja904577c Supporting Info |
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Genetic Incorporation of a Small, Environmentally Sensitive, Fluorescent Probe into Proteins in Saccharomyces cerevisiae Hyun Soo Lee, Jiantao Guo, Edward A. Lemke, Romerson D. Dimla and Peter G. Schultz pp 12921–12923 DOI: 10.1021/ja904896s Supporting Info |
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Thio FCMA Intermediates as Strong Acyl Donors: A General Solution to the Formation of Complex Amide Bonds Yu Rao, Xuechen Li and Samuel J. Danishefsky pp 12924–12926 DOI: 10.1021/ja906005j Supporting Info |
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Tuning the Sign of Photoinduced Changes in Magnetization: Spin Transitions in the Ternary Metal Prussian Blue Analogue NaαNi1−xCox[Fe(CN)6]β·nH2O Daniel M. Pajerowski, Justin E. Gardner, Daniel R. Talham and Mark W. Meisel pp 12927–12936 DOI: 10.1021/ja9012672 Supporting Info |
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2,3-Anhydrosugars in Glycoside Bond Synthesis: Mechanism of 2-Deoxy-2-thioaryl Glycoside Formation Dianjie Hou, Hashem A. Taha and Todd L. Lowary pp 12937–12948 DOI: 10.1021/ja9029945 Supporting Info |
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Design and NMR-Based Screening of LEF, a Library of Chemical Fragments with Different Local Environment of Fluorine Anna Vulpetti, Ulrich Hommel, Gregory Landrum, Richard Lewis and Claudio Dalvit pp 12949–12959 DOI: 10.1021/ja905207t Supporting Info |
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Enhanced Photostability of Genetically Encodable Fluoromodules Based on Fluorogenic Cyanine Dyes and a Promiscuous Protein Partner Nathaniel I. Shank, Kimberly J. Zanotti, Frederick Lanni, Peter B. Berget and Bruce A. Armitage pp 12960–12969 DOI: 10.1021/ja9016864 Supporting Info |
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Coupled Decomposition of Four-Dimensional NOESY Spectra Sebastian Hiller, Ilghis Ibraghimov, Gerhard Wagner and Vladislav Y. Orekhov pp 12970–12978 DOI: 10.1021/ja902012x |
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Direct Detection of the Oxygen Rebound Intermediates, Ferryl Mb and NO2, in the Reaction of metMyoglobin with Peroxynitrite Jia Su and John T. Groves pp 12979–12988 DOI: 10.1021/ja902473r Supporting Info |
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The Role of Gold Adatoms and Stereochemistry in Self-Assembly of Methylthiolate on Au(111) Oleksandr Voznyy, Jan J. Dubowski, J. T. Yates, Jr. and Peter Maksymovych pp 12989–12993 DOI: 10.1021/ja902629y Supporting Info |
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Two-Photon Absorbing Nanocrystal Sensors for Ratiometric Detection of Oxygen Emily J. McLaurin, Andrew B. Greytak, Moungi G. Bawendi and Daniel G. Nocera pp 12994–13001 DOI: 10.1021/ja902712b Supporting Info |
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Complex Adsorption of Short Linear Alkanes in the Flexible Metal-Organic-Framework MIL-53(Fe) P. L. Llewellyn, P. Horcajada, G. Maurin, T. Devic, N. Rosenbach, S. Bourrelly, C. Serre, D. Vincent, S. Loera-Serna, Y. Filinchuk and G. F pp 13002–13008 DOI: 10.1021/ja902740r Supporting Info |
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Large Effect of a Small Substitution: Competition of Dehydration with Charge Retention and Coulomb Explosion in Gaseous [(bipyR)Au(μ-O)2Au(bipyR)]2+ Dications Eric C. Tyo, A. W. Castleman, Jr., Detlef Schr pp 13009–13019 DOI: 10.1021/ja902773b |
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Gold-Catalyzed [4C+2C] Cycloadditions of Allenedienes, including an Enantioselective Version with New Phosphoramidite-Based Catalysts: Mechanistic Aspects of the Divergence between [4C+3C] and [4C+2C] Pathways Isaac Alonso, Beatriz Trillo, Fernando L pp 13020–13030 DOI: 10.1021/ja905415r Supporting Info |
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CD-Spectroscopy As a Powerful Tool for Investigating the Mode of Action of Unmodified Drugs in Live Cells Lutz F. Tietze, Birgit Krewer, Felix Major and Ingrid Schuberth pp 13031–13036 DOI: 10.1021/ja902767f |
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Rate Constants for Peroxidation of Polyunsaturated Fatty Acids and Sterols in Solution and in Liposomes Libin Xu, Todd A. Davis and Ned A. Porter pp 13037–13044 DOI: 10.1021/ja9029076 Supporting Info |
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Modeling Dinitrogen Activation by Lithium: A Mechanistic Investigation of the Cleavage of N2 by Stepwise Insertion into Small Lithium Clusters Debjani Roy, Armando Navarro-Vazquez and Paul. v. R. Schleyer pp 13045–13053 DOI: 10.1021/ja902980j Supporting Info |
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Mechanism of Ethanol Synthesis from Syngas on Rh(111) YongMan Choi and Ping Liu pp 13054–13061 DOI: 10.1021/ja903013x Supporting Info |
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Tailoring Bicomponent Supramolecular Nanoporous Networks: Phase Segregation, Polymorphism, and Glasses at the Solid−Liquid Interface Carlos-Andres Palma, Jonas Bjork, Massimo Bonini, Matthew S. Dyer, Anna Llanes-Pallas, Davide Bonifazi, Mats Persson and Paolo Samor pp 13062–13071 DOI: 10.1021/ja9032428 Supporting Info |
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Acquisition of a Potent and Selective TC-PTP Inhibitor via a Stepwise Fluorophore-Tagged Combinatorial Synthesis and Screening Strategy Sheng Zhang, Lan Chen, Yong Luo, Andrea Gunawan, David S. Lawrence and Zhong-Yin Zhang pp 13072–13079 DOI: 10.1021/ja903733z Supporting Info |
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New Insights into ETS-10 and Titanate Quantum Wire: A Comprehensive Characterization Nak Cheon Jeong, Young Ju Lee, Jung-Hyun Park, Hyunjin Lim, Chae-Ho Shin, Hyeonsik Cheong and Kyung Byung Yoon pp 13080–13092 DOI: 10.1021/ja903638v Supporting Info |
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A Replicable Tetrahedral Nanostructure Self-Assembled from a Single DNA Strand Zhe Li, Bryan Wei, Jeanette Nangreave, Chenxiang Lin, Yan Liu, Yongli Mi and Hao Yan pp 13093–13098 DOI: 10.1021/ja903768f Supporting Info |
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Pattern-Based Recognition of Thiols and Metals Using a Single Squaraine Indicator Himali S. Hewage and Eric V. Anslyn pp 13099–13106 DOI: 10.1021/ja904045n Supporting Info |
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Context-Independent, Temperature-Dependent Helical Propensities for Amino Acid Residues Robert J. Moreau, Christian R. Schubert, Khaled A. Nasr, Marianna T pp 13107–13116 DOI: 10.1021/ja904271k Supporting Info |
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Conjugated Polymer/Porphyrin Complexes for Efficient Energy Transfer and Improving Light-Activated Antibacterial Activity Chengfen Xing, Qingling Xu, Hongwei Tang, Libing Liu and Shu Wang pp 13117–13124 DOI: 10.1021/ja904492x |
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Pattern-Based Recognition for the Rapid Determination of Identity, Concentration, and Enantiomeric Excess of Subtly Different Threo Diols Shagufta H. Shabbir, Leo A. Joyce, Gabriella M. da Cruz, Vincent M. Lynch, Steven Sorey and Eric V. Anslyn pp 13125–13131 DOI: 10.1021/ja904545d Supporting Info |
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Quinone Methides Tethered to Naphthalene Diimides as Selective G-Quadruplex Alkylating Agents Marco Di Antonio, Filippo Doria, Sara N. Richter, Carolina Bertipaglia, Mariella Mella, Claudia Sissi, Manlio Palumbo and Mauro Freccero pp 13132–13141 DOI: 10.1021/ja904876q Supporting Info |
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Lithium Phenolates Solvated by Tetrahydrofuran and 1,2-Dimethoxyethane: Structure Determination Using the Method of Continuous Variation Timothy S. De Vries, Anandarup Goswami, Lara R. Liou, Jocelyn M. Gruver, Emily Jayne and David B. Collum pp 13142–13154 DOI: 10.1021/ja9047784 Supporting Info |
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Identification of the Structural Phases of CexZr1−xO2 by Eu(III) Luminescence Studies Tiziano Montini, Adolfo Speghini, Loredana De Rogatis, Barbara Lorenzut, Marco Bettinelli, Mauro Graziani and Paolo Fornasiero pp 13155–13160 DOI: 10.1021/ja905158p Supporting Info |
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X-ray Emission Spectroscopy To Study Ligand Valence Orbitals in Mn Coordination Complexes Grigory Smolentsev, Alexander V. Soldatov, Johannes Messinger, Kathrin Merz, Thomas Weyherm pp 13161–13167 DOI: 10.1021/ja808526m |
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Synthesis, Structures, and Electronic Properties of [8Fe-7S] Cluster Complexes Modeling the Nitrogenase P-Cluster Yasuhiro Ohki, Motosuke Imada, Ayuro Murata, Yusuke Sunada, Shun Ohta, Masaru Honda, Takahiro Sasamori, Norihiro Tokitoh, Motomi Katada and Kazuyuki Tatsumi pp 13168–13178 DOI: 10.1021/ja9055036 Supporting Info |
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Fluorescent Lifetime Trajectories of a Single Fluorophore Reveal Reaction Intermediates During Transcription Initiation Maria Sorokina, Hye-Ran Koh, Smita S. Patel and Taekjip Ha p 13179 DOI: 10.1021/ja906682a |
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MestRe Nova Mark Robert Willcott p 13180 DOI: 10.1021/ja906709t |
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Electron Paramagnetic Resonance: A Practitioner’s Toolkit John McCracken p 13181 DOI: 10.1021/ja906788y |
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Microarrays: Preparation, Microfluidics, Detection Methods, and Biological Applications Peter Wentzell pp 13181–13182 DOI: 10.1021/ja906602u |
Issue 37
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Isoprenoid Biosynthesis via the MEP Pathway: In Vivo M Myriam Seemann, Karnjapan Janthawornpong, Julia Schweizer, Lars H. B pp 13184–13185 DOI: 10.1021/ja9012408 Supporting Info |
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Shape and Release Control of a Peptide Decorated Vesicle through pH Sensitive Orthogonal Supramolecular Interactions Frank Versluis, Itsuro Tomatsu, Seda Kehr, Carlo Fregonese, Armand W.J.W. Tepper, Marc C. A. Stuart, Bart Jan Ravoo, Roman I. Koning and Alexander Kros pp 13186–13187 DOI: 10.1021/ja9026264 Supporting Info |
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RNA-Mediated Electron Transfer: Double Exponential Distance Dependence Kenji Maie, Kazuyuki Miyagi, Tadao Takada, Mitsunobu Nakamura and Kazushige Yamana pp 13188–13189 DOI: 10.1021/ja902647j Supporting Info |
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“Too Small, Too Big, and Just Right” − Optical Sensing of Molecular Conformations in Self-Assembled Capsules Mark R. Ams, Dariush Ajami, Stephen L. Craig, Jye-Shane Yang and Julius Rebek, Jr. pp 13190–13191 DOI: 10.1021/ja903198v Supporting Info |
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Effect of Highly Fluorinated Amino Acids on Protein Stability at a Solvent-Exposed Position on an Internal Strand of Protein G B1 Domain Hsien-Po Chiu, Bashkim Kokona, Robert Fairman and Richard P. Cheng pp 13192–13193 DOI: 10.1021/ja903631h Supporting Info |
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Nickel-Catalyzed Cycloaddition of Salicylic Acid Ketals to Alkynes via Elimination of Ketones Akihiro Ooguri, Kenichiro Nakai, Takuya Kurahashi and Seijiro Matsubara pp 13194–13195 DOI: 10.1021/ja904068p Supporting Info |
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Photoreduction of Prussian Blue Intercalated into Titania Nanosheet Ultrathin Films Takashi Yamamoto, Naoki Saso, Yasushi Umemura and Yasuaki Einaga pp 13196–13197 DOI: 10.1021/ja9041274 Supporting Info |
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Metal−Organic Frameworks As Templates for Nanoscale NaAlH4 Raghunandan K. Bhakta, Julie L. Herberg, Benjamin Jacobs, Aaron Highley, Richard Behrens, Jr., Nathan W. Ockwig, Jeffery A. Greathouse and Mark D. Allendorf pp 13198–13199 DOI: 10.1021/ja904431x Supporting Info |
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Electrocatalytic Activity of Nitrogen-Doped Carbon Nanotube Cups Yifan Tang, Brett L. Allen, Douglas R. Kauffman and Alexander Star pp 13200–13201 DOI: 10.1021/ja904595t Supporting Info |
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Metal−Molecule−Metal Junctions via PFPE Assisted Nanotransfer Printing (nTP) onto Self-Assembled Monolayers Jeremy R. Niskala and Wei You pp 13202–13203 DOI: 10.1021/ja9047152 Supporting Info |
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Self-Aligned Supported Lipid Bilayers for Patterning the Cell−Substrate Interface Keyue Shen, Jones Tsai, Peng Shi and Lance C. Kam pp 13204–13205 DOI: 10.1021/ja904721h Supporting Info |
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Grafting and Coloring onto Silver Nanoparticles by Photoinduced Surface Modification Hucheng Zhang, Liwei Zhang and Jianji Wang pp 13206–13207 DOI: 10.1021/ja9047416 Supporting Info |
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Construction of Highly Reactive Probes for Abasic Site Detection by Introduction of an Aromatic and a Guanidine Residue into an Aminooxy Group Naoshi Kojima, Toshie Takebayashi, Akiko Mikami, Eiko Ohtsuka and Yasuo Komatsu pp 13208–13209 DOI: 10.1021/ja904767k Supporting Info |
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Pt-Catalyzed Enantioselective Diboration of Terminal Alkenes with B2(pin)2 Laura T. Kliman, Scott N. Mlynarski and James P. Morken pp 13210–13211 DOI: 10.1021/ja9047762 Supporting Info |
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Excited State Proton Transfer in the Red Fluorescent Protein mKeima J. Nathan Henderson, Maire F. Osborn, Nayden Koon, Rinat Gepshtein, Dan Huppert and S. James Remington pp 13212–13213 DOI: 10.1021/ja904665x Supporting Info |
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Cobalt Catalyzed Functionalization of Unactivated Alkenes: Regioselective Reductive C−C Bond Forming Reactions Boris Gaspar and Erick M. Carreira pp 13214–13215 DOI: 10.1021/ja904856k Supporting Info |
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Free Transport of Water and CO2 in Nonporous Hydrophobic Clarithromycin Form II Crystals Jian Tian, Praveen K. Thallapally, Scott J. Dalgarno and Jerry L. Atwood pp 13216–13217 DOI: 10.1021/ja904658p Supporting Info |
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ATR-SEIRAS Investigation of the Fermi Level of Pt Cocatalyst on a GaN Photocatalyst for Hydrogen Evolution under Irradiation Masaaki Yoshida, Akira Yamakata, Kazuhiro Takanabe, Jun Kubota, Masatoshi Osawa and Kazunari Domen pp 13218–13219 DOI: 10.1021/ja904991p Supporting Info |
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Polyelectrolyte Synthesis and in Situ Complex Formation in Ionic Liquids Martin Gericke, Tim Liebert and Thomas Heinze pp 13220–13221 DOI: 10.1021/ja905003r Supporting Info |
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π-Conjugated Phosphasilenes Stabilized by Fused-Ring Bulky Groups Baolin Li, Tsukasa Matsuo, Daisuke Hashizume, Hiroyuki Fueno, Kazuyoshi Tanaka and Kohei Tamao pp 13222–13223 DOI: 10.1021/ja9051153 Supporting Info |
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Norepinephrine: Material-Independent, Multifunctional Surface Modification Reagent Sung Min Kang, Junsung Rho, Insung S. Choi, Phillip B. Messersmith and Haeshin Lee pp 13224–13225 DOI: 10.1021/ja905183k Supporting Info |
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Catalytic Enantioselective Intramolecular Redox Reactions: Ring-Fused Tetrahydroquinolines Sandip Murarka, Indubhusan Deb, Chen Zhang and Daniel Seidel pp 13226–13227 DOI: 10.1021/ja905213f Supporting Info |
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13C−13C Correlation Spectroscopy of Membrane-Associated Influenza Virus Fusion Peptide Strongly Supports a Helix-Turn-Helix Motif and Two Turn Conformations Yan Sun and David P. Weliky pp 13228–13229 DOI: 10.1021/ja905198q Supporting Info |
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From Average to Local Structure: A Rietveld and an Atomic Pair Distribution Function (PDF) Study of Selenium Clusters in Zeolite-NdY A. M. Milinda Abeykoon, Wolfgang Donner, Michela Brunelli, Miguel Castro-Colin, Allan J. Jacobson and Simon C. Moss pp 13230–13231 DOI: 10.1021/ja905164e Supporting Info |
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Intelligent Medical Diagnostics via Molecular Logic Tania Konry and David R. Walt pp 13232–13233 DOI: 10.1021/ja905125b Supporting Info |
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Effect of Contrast Agent Charge on Visualization of Articular Cartilage Using Computed Tomography: Exploiting Electrostatic Interactions for Improved Sensitivity Neel S. Joshi, Prashant N. Bansal, Rachel C. Stewart, Brian D. Snyder and Mark W. Grinstaff pp 13234–13235 DOI: 10.1021/ja9053306 Supporting Info |
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Synthesis of Vicinal Dimethyl Chirons by Asymmetric Hydrogenation of Trisubstituted Alkenes Jian Zhao and Kevin Burgess pp 13236–13237 DOI: 10.1021/ja905458n Supporting Info |
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Facile Formation of Dehydroalanine From S-Nitrosocysteines Hua Wang, Jiming Zhang and Ming Xian pp 13238–13239 DOI: 10.1021/ja905558w Supporting Info |
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Modular Design of Peptide Fibrillar Nano- to Microstructures Maxim G. Ryadnov, Angelo Bella, Samuel Timson and Derek N. Woolfson pp 13240–13241 DOI: 10.1021/ja905539h Supporting Info |
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Monodisperse Co-oligomer Approach toward Nanostructured Films with Alternating Donor−Acceptor Lamellae Laju Bu, Xiaoyang Guo, Bo Yu, Yao Qu, Zhiyuan Xie, Donghang Yan, Yanhou Geng and Fosong Wang pp 13242–13243 DOI: 10.1021/ja905980w Supporting Info |
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Total Synthesis of Alkaloid (±)-G. B. 13 Using a Rh(I)-Catalyzed Ketone Hydroarylation and Late-Stage Pyridine Reduction Kimberly K. Larson and Richmond Sarpong pp 13244–13245 DOI: 10.1021/ja9063487 Supporting Info |
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Corey−Chaykovsky Epoxidation of Twisted Amides: Synthesis and Reactivity of Bridged Spiro-epoxyamines Michal Szostak and Jeffrey Aub pp 13246–13247 DOI: 10.1021/ja906471q Supporting Info |
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Surface-Mediated DNA Self-Assembly Xuping Sun, Seung Hyeon Ko, Chuan Zhang, Alexander E. Ribbe and Chengde Mao pp 13248–13249 DOI: 10.1021/ja906475w Supporting Info |
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Enantioselective Rhodium-Catalyzed [4+2+2] Cycloaddition of Dienyl Isocyanates for the Synthesis of Bicyclic Azocine Rings Robert T. Yu, Rebecca Keller Friedman and Tomislav Rovis pp 13250–13251 DOI: 10.1021/ja906641d Supporting Info |
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Reaction Intermediates of CO Oxidation on Gas Phase Pd4 Clusters: A Density Functional Study Bulumoni Kalita and Ramesh C. Deka pp 13252–13254 DOI: 10.1021/ja904119b |
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Versatile Synthesis and Rational Design of Caged Morpholinos Xiaohu Ouyang, Ilya A. Shestopalov, Surajit Sinha, Genhua Zheng, Cameron L. W. Pitt, Wen-Hong Li, Andrew J. Olson and James K. Chen pp 13255–13269 DOI: 10.1021/ja809933h Supporting Info |
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Hydration of Alkaline Earth Metal Dications: Effects of Metal Ion Size Determined Using Infrared Action Spectroscopy Matthew F. Bush, Jeremy T. O’Brien, James S. Prell, Chih-Che Wu, Richard J. Saykally and Evan R. Williams pp 13270–13277 DOI: 10.1021/ja901011x Supporting Info |
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Mechanism of Hg−C Protonolysis in the Organomercurial Lyase MerB Jerry M. Parks, Hong Guo, Cory Momany, Liyuan Liang, Susan M. Miller, Anne O. Summers and Jeremy C. Smith pp 13278–13285 DOI: 10.1021/ja9016123 Supporting Info |
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Development of a Fluorescent-Tagged Kinase Assay System for the Detection and Characterization of Allosteric Kinase Inhibitors Jeffrey R. Simard, Matth pp 13286–13296 DOI: 10.1021/ja902010p Supporting Info |
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Structure and Dynamics of Monomer−Template Complexation: An Explanation for Molecularly Imprinted Polymer Recognition Site Heterogeneity Bj pp 13297–13304 DOI: 10.1021/ja902087t Supporting Info |
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Flow Linear Dichroism of Some Prototypical Proteins Benjamin M. Bulheller, Alison Rodger, Matthew R. Hicks, Timothy R. Dafforn, Louise C. Serpell, Karen E. Marshall, Elizabeth H. C. Bromley, Patrick J. S. King, Kevin J. Channon, Derek N. Woolfson and Jonathan D. Hirst pp 13305–13314 DOI: 10.1021/ja902662e Supporting Info |
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Environment-Friendly Photolithography Using Poly(N-isopropylacrylamide)-Based Thermoresponsive Photoresists Leonid Ionov and Stefan Diez pp 13315–13319 DOI: 10.1021/ja902660s |
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Instability of Cationic Gold Nanoparticle Bioconjugates: The Role of Citrate Ions Isaac Ojea-Jim pp 13320–13327 DOI: 10.1021/ja902894s Supporting Info |
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Directly Relating Reduction Energies of Gaseous Eu(H2O)n3+, n = 55−140, to Aqueous Solution: The Absolute SHE Potential and Real Proton Solvation Energy William A. Donald, Ryan D. Leib, Maria Demireva, Jeremy T. O’Brien, James S. Prell and Evan R. Williams pp 13328–13337 DOI: 10.1021/ja902815v Supporting Info |
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Mesomorphic Imidazolium Salts: New Vectors for Efficient siRNA Transfection William Dobbs, Beno pp 13338–13346 DOI: 10.1021/ja903028f Supporting Info |
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Direct Observation of Tug-of-War during the Folding of a Mutually Exclusive Protein Qing Peng and Hongbin Li pp 13347–13354 DOI: 10.1021/ja903480j Supporting Info |
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Influence of Oxygenation on the Reactivity of Ruthenium−Thiolato Bonds in Arene Anticancer Complexes: Insights from XAS and DFT Thamayanthy Sriskandakumar, Holm Petzold, Pieter C. A. Bruijnincx, Abraha Habtemariam, Peter J. Sadler and Pierre Kennepohl pp 13355–13361 DOI: 10.1021/ja903405z Supporting Info |
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Spontaneous Transfer of Parahydrogen Derived Spin Order to Pyridine at Low Magnetic Field Kevin D. Atkinson, Michael J. Cowley, Paul I. P. Elliott, Simon B. Duckett, Gary G. R. Green, Joaqu pp 13362–13368 DOI: 10.1021/ja903601p Supporting Info |
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Mechanism of Montmorillonite Catalysis in the Formation of RNA Oligomers Prakash C. Joshi, Michael F. Aldersley, John W. Delano and James P. Ferris pp 13369–13374 DOI: 10.1021/ja9036516 |
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Length Dependence for Intramolecular Energy Transfer in Three- and Four-Color Donor−Spacer−Acceptor Arrays Anthony Harriman, Laura J. Mallon, Kristopher J. Elliot, Alexandre Haefele, Gilles Ulrich and Raymond Ziessel pp 13375–13386 DOI: 10.1021/ja9038856 Supporting Info |
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Understanding the Torquoselectivity in 8π-Electrocyclic Cascade Reactions: Synthesis of Fenestradienes versus Cyclooctatrienes Catherine Hulot, Shadi Amiri, Ga pp 13387–13398 DOI: 10.1021/ja903914r Supporting Info |
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A G-Rich Sequence within the c-kit Oncogene Promoter Forms a Parallel G-Quadruplex Having Asymmetric G-Tetrad Dynamics Shang-Te Danny Hsu, Peter Varnai, Anthony Bugaut, Anthony P. Reszka, Stephen Neidle and Shankar Balasubramanian pp 13399–13409 DOI: 10.1021/ja904007p Supporting Info |
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Enhancement of Hydrogen Adsorption in Metal−Organic Frameworks by the Incorporation of the Sulfonate Group and Li Cations. A Multiscale Computational Study Andreas Mavrandonakis, Emmanouel Klontzas, Emmanuel Tylianakis and George E. Froudakis pp 13410–13414 DOI: 10.1021/ja9043888 |
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Probing Synergy between Two Catalytic Strategies in the Glycoside Hydrolase O-GlcNAcase Using Multiple Linear Free Energy Relationships Ian R. Greig, Matthew S. Macauley, Ian H. Williams and David J. Vocadlo pp 13415–13422 DOI: 10.1021/ja904506u Supporting Info |
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Spectroscopic Identification of the Resonance-Stabilized cis- and trans-1-Vinylpropargyl Radicals Neil J. Reilly, Masakazu Nakajima, Tyler P. Troy, Nahid Chalyavi, Kieran A. Duncan, Klaas Nauta, Scott H. Kable and Timothy W. Schmidt pp 13423–13429 DOI: 10.1021/ja904521c Supporting Info |
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Implementation of High Resolution 43Ca Solid State NMR Spectroscopy: Toward the Elucidation of Calcium Sites in Biological Materials Danielle Laurencin, Christel Gervais, Alan Wong, Cristina Coelho, Francesco Mauri, Dominique Massiot, Mark E. Smith and Christian Bonhomme pp 13430–13440 DOI: 10.1021/ja904553q Supporting Info |
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Synthesis and Optical Spectroscopy of Oligo(1,6-heptadiynes) with a Single Basic Structure Prepared through Adamantylimido-Based Molybdenum Wittig and Metathesis Chemistry Corina Scriban, Bryan S. Amagai, Elizabeth A. Stemmler, Ronald L. Christensen and Richard R. Schrock pp 13441–13452 DOI: 10.1021/ja904541b |
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Proton-Coupled Oxygen Reduction at Liquid−Liquid Interfaces Catalyzed by Cobalt Porphine Imren Hatay, Bin Su, Fei Li, Manuel Alejandro M pp 13453–13459 DOI: 10.1021/ja904569p Supporting Info |
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Transforming Carbon Nanotube Devices into Nanoribbon Devices Zengxing Zhang, Zhengzong Sun, Jun Yao, Dmitry V. Kosynkin and James M. Tour pp 13460–13463 DOI: 10.1021/ja9045923 Supporting Info |
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Energetics of C−H Bond Activation of Fluorinated Aromatic Hydrocarbons Using a [Tp′Rh(CNneopentyl)] Complex Meagan E. Evans, Catherine L. Burke, Sornanong Yaibuathes, Eric Clot, Odile Eisenstein and William D. Jones pp 13464–13473 DOI: 10.1021/ja905057w Supporting Info |
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On the XeF+/H2O System: Synthesis and Characterization of the Xenon(II) Oxide Fluoride Cation, FXeOXeFXeF+ Michael Gerken, Matthew D. Moran, H pp 13474–13489 DOI: 10.1021/ja905060v Supporting Info |
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Chemically Converted Graphene Induced Molecular Flattening of 5,10,15,20-Tetrakis(1-methyl-4-pyridinio)porphyrin and Its Application for Optical Detection of Cadmium(II) Ions Yuxi Xu, Lu Zhao, Hua Bai, Wenjing Hong, Chun Li and Gaoquan Shi pp 13490–13497 DOI: 10.1021/ja905032g Supporting Info |
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Formation of the Calcium/Poly(3-Hexylthiophene) Interface: Structure and Energetics Junfa Zhu, Fabian Bebensee, Wolfgang Hieringer, Wei Zhao, Jack H. Baricuatro, Jason A. Farmer, Yun Bai, Hans-Peter Steinr pp 13498–13507 DOI: 10.1021/ja904844c Supporting Info |
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Crystal Structure of Ammonia Monohydrate Phase II A. Dominic Fortes, Emmanuelle Suard, Marie-H pp 13508–13515 DOI: 10.1021/ja9052569 Supporting Info |
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Oxalate-Bridged Bimetallic Complexes {NH(prol)3}[MCr(ox)3] (M = MnII, FeII, CoII; NH(prol)3+ = Tri(3-hydroxypropyl)ammonium) Exhibiting Coexistent Ferromagnetism and Proton Conduction Hisashi pp 13516–13522 DOI: 10.1021/ja905368d Supporting Info |
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Stereospecific Synthesis of threo- and erythro-β-Hydroxyglutamic Acid During Kutzneride Biosynthesis Matthias Strieker, Elizabeth M. Nolan, Christopher T. Walsh and Mohamed A. Marahiel pp 13523–13530 DOI: 10.1021/ja9054417 Supporting Info |
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Iridium Phosphinidene Complexes: A Comparison with Iridium Imido Complexes in Their Reaction with Isocyanides Halil Aktas, Jos Mulder, Frans J. J. de Kanter, J. Chris Slootweg, Marius Schakel, Andreas W. Ehlers, Martin Lutz, Anthony L. Spek and Koop Lammertsma pp 13531–13537 DOI: 10.1021/ja9048509 Supporting Info |
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Metalloporphycenes: Synthesis and Characterization of (Pentamethylcyclopentadienyl)ruthenium Sitting-Atop and π-Complexes Luciano Cuesta, Elizabeth Karnas, Vincent M. Lynch, Ping Chen, Jing Shen, Karl M. Kadish, Kei Ohkubo, Shunichi Fukuzumi and Jonathan L. Sessler pp 13538–13547 DOI: 10.1021/ja905284d Supporting Info |
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Asymmetry of the “Strongest” OHO Hydrogen Bond, in the Monoanion of (±)-α,α′-Di-tert-butylsuccinate Charles L. Perrin, Jonathan S. Lau, Yeong-Joon Kim, Phaneendrasai Karri, Curtis Moore and Arnold L. Rheingold pp 13548–13554 DOI: 10.1021/ja905806h Supporting Info |
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Synthesis and Characterization of Nucleobase−Carbon Nanotube Hybrids Prabhpreet Singh, Jitendra Kumar, Francesca Maria Toma, Jesus Raya, Maurizio Prato, Bruno Fabre, Sandeep Verma and Alberto Bianco pp 13555–13562 DOI: 10.1021/ja905041b Supporting Info |
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Asymmetric Synthesis of Diamine Derivatives via Sequential Palladium and Rhodium Catalysis Barry M. Trost, Sushant Malhotra, David E. Olson, Autumn Maruniak and J. Du Bois p 13563 DOI: 10.1021/ja906124t |
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Degree of Rate Control: How Much the Energies of Intermediates and Transition States Control Rates Carsten Stegelmann, Anders Andreasen and Charles T. Campbell p 13563 DOI: 10.1021/ja9065199 |
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AMPAC 9 Rainer Glaser p 13564 DOI: 10.1021/ja906885v |
Issue 38
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Zirconium Complex of an [OSSO]-Type Diphenolate Ligand Bearing trans-1,2-Cyclooctanediylbis(thio) Core: Synthesis, Structure, and Isospecific 1-Hexene Polymerization Akihiko Ishii, Tomoyuki Toda, Norio Nakata and Tsukasa Matsuo pp 13566–13567 DOI: 10.1021/ja903369q Supporting Info |
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Rapid and Efficient Induction of an Endogenous Cell Signaling Event by Subcellular Targeting of a Synthetic Ligand Shuhei Hashiro, Shinya Tsukiji and Teruyuki Nagamune pp 13568–13569 DOI: 10.1021/ja903706t Supporting Info |
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Gas-Phase Deprotonation of p-Hydroxybenzoic Acid Investigated by IR Spectroscopy: Solution-Phase Structure Is Retained upon ESI Jeffrey D. Steill and Jos Oomens pp 13570–13571 DOI: 10.1021/ja903877v Supporting Info |
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A Direct White-Light-Emitting Metal−Organic Framework with Tunable Yellow-to-White Photoluminescence by Variation of Excitation Light Ming-Sheng Wang, Sheng-Ping Guo, Yan Li, Li-Zhen Cai, Jian-Ping Zou, Gang Xu, Wei-Wei Zhou, Fa-Kun Zheng and Guo-Cong Guo pp 13572–13573 DOI: 10.1021/ja903947b Supporting Info |
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A Two-Dimensional DNA Array: The Three-Layer Logpile Jonathan Malo, James C. Mitchell and Andrew J. Turberfield pp 13574–13575 DOI: 10.1021/ja9042593 Supporting Info |
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Enzyme-Instructed Molecular Self-assembly Confers Nanofibers and a Supramolecular Hydrogel of Taxol Derivative Yuan Gao, Yi Kuang, Zu-Feng Guo, Zhihong Guo, Isaac J. Krauss and Bing Xu pp 13576–13577 DOI: 10.1021/ja904411z Supporting Info |
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Structure, Magnetism, and Ionic Conductivity of the Gigantic {Mo176}-Wheel Assembly: Na15Fe3Co16[Mo176O528H3(H2O)80]Cl27·450H2O Hiroyuki Imai, Tomoyuki Akutagawa, Fumito Kudo, Mitsuhiro Ito, Kazuhiro Toyoda, Shin-ichiro Noro, Leroy Cronin and Takayoshi Nakamura pp 13578–13579 DOI: 10.1021/ja9048042 Supporting Info |
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Hydrogen Bonding Controls Excited-State Decay of the Photoactive Yellow Protein Chromophore Martial Boggio-Pasqua, Michael A. Robb and Gerrit Groenhof pp 13580–13581 DOI: 10.1021/ja904932x Supporting Info |
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One-Pot Synthesis of Brush-Like Polymers via Integrated Ring-Opening Metathesis Polymerization and Polymerization of Amino Acid N-Carboxyanhydrides Hua Lu, Jing Wang, Yao Lin and Jianjun Cheng pp 13582–13583 DOI: 10.1021/ja903425x Supporting Info |
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Metal−Ligand Cooperation in H2 Production and H2O Decomposition on a Ru(II) PNN Complex: The Role of Ligand Dearomatization−Aromatization Jun Li, Yoshihito Shiota and Kazunari Yoshizawa pp 13584–13585 DOI: 10.1021/ja905073s Supporting Info |
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Chemicals On Demand with Phototriggerable Microcapsules Stefan J. Pastine, David Okawa, Alex Zettl and Jean M. J. Fr pp 13586–13587 DOI: 10.1021/ja905378v Supporting Info |
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Sodium Tetraarylborates as Effective Nucleophiles in Rhodium/Diene-Catalyzed 1,4-Addition to β,β-Disubstituted α,β-Unsaturated Ketones: Catalytic Asymmetric Construction of Quaternary Carbon Stereocenters Ryo Shintani, Yosuke Tsutsumi, Makoto Nagaosa, Takahiro Nishimura and Tamio Hayashi pp 13588–13589 DOI: 10.1021/ja905432x Supporting Info |
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Structurally Selective Geminate Rebinding Dynamics of Solvent-Caged Radicals Studied with Nonequilibrium Infrared Echo Spectroscopy Carlos R. Baiz, Robert McCanne and Kevin J. Kubarych pp 13590–13591 DOI: 10.1021/ja905459y Supporting Info |
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Dual Native Chemical Ligation at Lysine Renliang Yang, Kalyan Kumar Pasunooti, Fupeng Li, Xue-Wei Liu and Chuan-Fa Liu pp 13592–13593 DOI: 10.1021/ja905491p Supporting Info |
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Hydrogen-Bonding-Assisted Self-Assembly: Monodisperse Hollow Nanoparticles Made Easy Zaicheng Sun, Feng Bai, Huimeng Wu, Samantha K. Schmitt, Daniel M. Boye and Hongyou Fan pp 13594–13595 DOI: 10.1021/ja905240w Supporting Info |
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Modular Synthesis of 1H-Indenes, Dihydro-s-Indacene, and Diindenoindacene—a Carbon-Bridged p-Phenylenevinylene Congener Xiaozhang Zhu, Chikahiko Mitsui, Hayato Tsuji and Eiichi Nakamura pp 13596–13597 DOI: 10.1021/ja905626b Supporting Info |
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Temperature Controlled Dispersion of Carbon Nanotubes in Water with Pyrene-Functionalized Poly(N-cyclopropylacrylamide) Krishna C. Etika, Florian D. Jochum, Patrick Theato and Jaime C. Grunlan pp 13598–13599 DOI: 10.1021/ja905803f Supporting Info |
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Concurrent Tandem Living Radical Polymerization: Gradient Copolymers via In Situ Monomer Transformation with Alcohols Kazuhiro Nakatani, Takaya Terashima and Mitsuo Sawamoto pp 13600–13601 DOI: 10.1021/ja9058348 Supporting Info |
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Ultrafast UV−Visible and Infrared Spectroscopic Observation of a Singlet Vinylcarbene and the Intramolecular Cyclopropenation Reaction Yunlong Zhang, Jacek Kubicki and Matthew S. Platz pp 13602–13603 DOI: 10.1021/ja905992p Supporting Info |
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Nanocluster Size Evolution Studied by Mass Spectrometry in Room Temperature Au25(SR)18 Synthesis Asantha C. Dharmaratne, Thomas Krick and Amala Dass pp 13604–13605 DOI: 10.1021/ja906087a Supporting Info |
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Nine-Step Enantioselective Total Synthesis of (+)-Minfiensine Spencer B. Jones, Bryon Simmons and David W. C. MacMillan pp 13606–13607 DOI: 10.1021/ja906472m Supporting Info |
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A Long-Lived, Substrate-Hydroxylating Peroxodiiron(III/III) Intermediate in the Amine Oxygenase, AurF, from Streptomyces thioluteus Victoria Korneeva Korboukh, Ning Li, Eric W. Barr, J. Martin Bollinger, Jr. and Carsten Krebs pp 13608–13609 DOI: 10.1021/ja9064969 Supporting Info |
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Microfluidic Device for Single-Molecule Experiments with Enhanced Photostability Edward A. Lemke, Yann Gambin, Virginia Vandelinder, Eric M. Brustad, Hsiao-Wei Liu, Peter G. Schultz, Alex Groisman and Ashok A. Deniz pp 13610–13612 DOI: 10.1021/ja9027023 Supporting Info |
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Selective Bifunctional Modification of a Non-catenated Metal−Organic Framework Material via “Click” Chemistry Tendai Gadzikwa, Omar K. Farha, Christos D. Malliakas, Mercouri G. Kanatzidis, Joseph T. Hupp and SonBinh T. Nguyen pp 13613–13615 DOI: 10.1021/ja904189d Supporting Info |
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Targeting a Homogeneously Glycosylated Antibody Fc To Bind Cancer Cells Using a Synthetic Receptor Ligand Junpeng Xiao, Rui Chen, Mark A. Pawlicki and Thomas J. Tolbert pp 13616–13618 DOI: 10.1021/ja9045179 Supporting Info |
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Thiolate-Protected Au20(SR)16 Cluster: Prolate Au8 Core with New [Au3(SR)4] Staple Motif Yong Pei, Yi Gao, Nan Shao and Xiao Cheng Zeng pp 13619–13621 DOI: 10.1021/ja905359b Supporting Info |
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Unexpected Formation of a Cyclopentadienylruthenium Alkoxycarbonyl Complex with a Coordinated C═C Bond Jenny B. Åberg, Madeleine C. Warner and Jan-E. B pp 13622–13624 DOI: 10.1021/ja905741w Supporting Info |
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Multiferroic Behavior Associated with an Order−Disorder Hydrogen Bonding Transition in Metal−Organic Frameworks (MOFs) with the Perovskite ABX3 Architecture Prashant Jain, Vasanth Ramachandran, Ronald J. Clark, Hai Dong Zhou, Brian H. Toby, Naresh S. Dalal, Harold W. Kroto and Anthony K. Cheetham pp 13625–13627 DOI: 10.1021/ja904156s Supporting Info |
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Asymmetric Synthesis of Functionalized Cyclopentanones via a Multicatalytic Secondary Amine/N-Heterocyclic Carbene Catalyzed Cascade Sequence Stephen P. Lathrop and Tomislav Rovis pp 13628–13630 DOI: 10.1021/ja905342e Supporting Info |
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Switching and Extension of a [c2]Daisy-Chain Dimer Polymer Paul G. Clark, Michael W. Day and Robert H. Grubbs pp 13631–13633 DOI: 10.1021/ja905924u Supporting Info |
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Electronic Structure of Te/Sb/Ge and Sb/Te/Ge Multi Layer Films Using Photoelectron Spectroscopy Ju Heyuck Baeck, Young-kun Ann, Kwang-Ho Jeong, Mann-Ho Cho, Dae-Hong Ko, Jae-Hee Oh and Hongsik Jeong pp 13634–13638 DOI: 10.1021/ja901596h Supporting Info |
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pH-Induced Aggregation of Gold Nanoparticles for Photothermal Cancer Therapy Jutaek Nam, Nayoun Won, Ho Jin, Hyokyun Chung and Sungjee Kim pp 13639–13645 DOI: 10.1021/ja902062j Supporting Info |
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Quantitative Glycomics from Fluidic Glycan Microarrays X.-Y. Zhu, Bryan Holtz, Yini Wang, Lai-Xi Wang, Paul E. Orndorff and Athena Guo pp 13646–13650 DOI: 10.1021/ja902783n Supporting Info |
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Probing the Dynamics of a Protein Hydrophobic Core by Deuteron Solid-State Nuclear Magnetic Resonance Spectroscopy Liliya Vugmeyster, Dmitry Ostrovsky, Joseph J. Ford, Sarah D. Burton, Andrew S. Lipton, Gina L. Hoatson and Robert L. Vold pp 13651–13658 DOI: 10.1021/ja902977u Supporting Info |
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Continuous-Wave and Pulsed EPR Characterization of the [2Fe−2S](Cys)3(His)1 Cluster in Rat MitoNEET Toshio Iwasaki, Rimma I. Samoilova, Asako Kounosu, Daijiro Ohmori and Sergei A. Dikanov pp 13659–13667 DOI: 10.1021/ja903228w Supporting Info |
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Peptide Synthesis in Aqueous Environments: The Role of Extreme Conditions on Peptide Bond Formation and Peptide Hydrolysis Eduard Schreiner, Nisanth N. Nair and Dominik Marx pp 13668–13675 DOI: 10.1021/ja9032742 Supporting Info |
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Synthetic Chloride Channel Regulates Cell Membrane Potentials and Voltage-Gated Calcium Channels Xiang Li, Bing Shen, Xiao-Qiang Yao and Dan Yang pp 13676–13680 DOI: 10.1021/ja902352g Supporting Info |
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Ionic-Type Reactivity of 1,3-Dibora-2,4-diphosphoniocyclobutane-1,3-diyls: Regio- and Stereoselective Addition of Hydracids Gad Fuks, Nathalie Saffon, Laurent Maron, Guy Bertrand and Didier Bourissou pp 13681–13689 DOI: 10.1021/ja903746p Supporting Info |
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Dynamics of Reassembled Thioredoxin Studied by Magic Angle Spinning NMR: Snapshots from Different Time Scales Jun Yang, Maria Luisa Tasayco and Tatyana Polenova pp 13690–13702 DOI: 10.1021/ja9037802 Supporting Info |
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Probing Surface Accessibility of Proteins Using Paramagnetic Relaxation in Solid-State NMR Spectroscopy Rasmus Linser, Uwe Fink and Bernd Reif pp 13703–13708 DOI: 10.1021/ja903892j Supporting Info |
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Importance of Ligand Reorganization Free Energy in Protein−Ligand Binding-Affinity Prediction Chao-Yie Yang, Haiying Sun, Jianyong Chen, Zaneta Nikolovska-Coleska and Shaomeng Wang pp 13709–13721 DOI: 10.1021/ja9039373 Supporting Info |
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Enhanced In situ Continuous-Flow MAS NMR for Reaction Kinetics in the Nanocages Shutao Xu, Weiping Zhang, Xianchun Liu, Xiuwen Han and Xinhe Bao pp 13722–13727 DOI: 10.1021/ja904304h Supporting Info |
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Cis−Trans Proline Isomerization Effects on Collagen Triple-Helix Stability Are Limited Nan Dai and Felicia A. Etzkorn pp 13728–13732 DOI: 10.1021/ja904177k Supporting Info |
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Atmospheric Heterogeneous Stereochemistry Grace Y. Stokes, Ehow H. Chen, Avram M. Buchbinder, Walter F. Paxton, Alison Keeley and Franz M. Geiger pp 13733–13737 DOI: 10.1021/ja904206t Supporting Info |
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Leaving Group Assistance in the La3+-Catalyzed Cleavage of Dimethyl (o-Methoxycarbonyl)aryl Phosphate Triesters in Methanol David R. Edwards, C. Tony Liu, Graham E. Garrett, Alexei A. Neverov and R. Stan Brown pp 13738–13748 DOI: 10.1021/ja904659e Supporting Info |
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Determination of Structure and Phase Transition of Light Element Nanocomposites in Mesoporous Silica: Case study of NH3BH3 in MCM-41 Hyunjeong Kim, Abhi Karkamkar, Tom Autrey, Peter Chupas and Thomas Proffen pp 13749–13755 DOI: 10.1021/ja904901d Supporting Info |
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The Pyrrolobenzodiazepine Dimer SJG-136 Forms Sequence-Dependent Intrastrand DNA Cross-Links and Monoalkylated Adducts in Addition to Interstrand Cross-Links Khondaker M. Rahman, Andrew S. Thompson, Colin H. James, Mathangi Narayanaswamy and David E. Thurston pp 13756–13766 DOI: 10.1021/ja902986x Supporting Info |
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A Comparison of 4f vs 5f Metal−Metal Bonds in (CpSiMe3)3M−ECp* (M = Nd, U; E = Al, Ga; Cp* = C5Me5): Synthesis, Thermodynamics, Magnetism, and Electronic Structure Stefan G. Minasian, Jamin L. Krinsky, Jeffrey D. Rinehart, Roy Copping, Tolek Tyliszczak, Markus Janousch, David K. Shuh and John Arnold pp 13767–13783 DOI: 10.1021/ja904565j Supporting Info |
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Study of the S1 Excited State of para-Methoxy-3-phenyl-3-methyl Diazirine by Ultrafast Time Resolved UV−Vis and IR Spectroscopies and Theory Yunlong Zhang, Gotard Burdzinski, Jacek Kubicki, Shubham Vyas, Christopher M. Hadad, Michel Sliwa, Olivier Poizat, Guy Buntinx and Matthew S. Platz pp 13784–13790 DOI: 10.1021/ja9046119 Supporting Info |
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Neighboring Amide Participation in Thioether Oxidation: Relevance to Biological Oxidation Richard S. Glass, Gordon L. Hug, Christian Sch pp 13791–13805 DOI: 10.1021/ja904895u Supporting Info |
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Gold Nanoparticle Based Label-Free SERS Probe for Ultrasensitive and Selective Detection of Trinitrotoluene Samuel S. R. Dasary, Anant Kumar Singh, Dulal Senapati, Hongtao Yu and Paresh Chandra Ray pp 13806–13812 DOI: 10.1021/ja905134d |
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i-Motif Quadruplex DNA-Based Biosensor for Distinguishing Single- and Multiwalled Carbon Nanotubes Yinghua Peng, Xiaohui Wang, Yi Xiao, Lingyan Feng, Chao Zhao, Jinsong Ren and Xiaogang Qu pp 13813–13818 DOI: 10.1021/ja9051763 Supporting Info |
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Organocatalytic Synthesis of Spiro[pyrrolidin-3,3′-oxindoles] with High Enantiopurity and Structural Diversity Xiao-Hua Chen, Qiang Wei, Shi-Wei Luo, Han Xiao and Liu-Zhu Gong pp 13819–13825 DOI: 10.1021/ja905302f Supporting Info |
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Anatomy of One-Dimensional Cocrystals: Randomness into Order Seokhoon Ahn and Adam J. Matzger pp 13826–13832 DOI: 10.1021/ja905418u Supporting Info |
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Layered Double Hydroxides as Highly Efficient Photocatalysts for Visible Light Oxygen Generation from Water Cl pp 13833–13839 DOI: 10.1021/ja905467v Supporting Info |
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Modification of Symmetrically Substituted Phthalocyanines Using Click Chemistry: Phthalocyanine Nanostructures by Nanoimprint Lithography Xiaochun Chen, Jayan Thomas, Palash Gangopadhyay, Robert A. Norwood, N. Peyghambarian and Dominic V. McGrath pp 13840–13843 DOI: 10.1021/ja905683g Supporting Info |
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Tandem Mass Spectrometry of Thiolate-Protected Au Nanoparticles NaxAu25(SC2H4Ph)18−y(S(C2H4O)5CH3)y Christina A. Fields-Zinna, Jason S. Sampson, Matthew C. Crowe, Joseph B. Tracy, Joseph F. Parker, Alexander M. deNey, David C. Muddiman and Royce W. Murray pp 13844–13851 DOI: 10.1021/ja905787y Supporting Info |
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Probing Flexibility in Porphyrin-Based Molecular Wires Using Double Electron Electron Resonance Janet E. Lovett, Markus Hoffmann, Arjen Cnossen, Alexander T. J. Shutter, Hannah J. Hogben, John E. Warren, Sofia I. Pascu, Christopher W. M. Kay, Christiane R. Timmel and Harry L. Anderson pp 13852–13859 DOI: 10.1021/ja905796z Supporting Info |
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anti-Selective Catalytic Asymmetric Nitroaldol Reaction via a Heterobimetallic Heterogeneous Catalyst Tatsuya Nitabaru, Akihiro Nojiri, Makoto Kobayashi, Naoya Kumagai and Masakatsu Shibasaki pp 13860–13869 DOI: 10.1021/ja905885z Supporting Info |
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Alternating and Random Copolymerization of Isoprene and Ethylene Catalyzed by Cationic Half-Sandwich Scandium Alkyls Xiaofang Li, Masayoshi Nishiura, Lihong Hu, Kyouichi Mori and Zhaomin Hou pp 13870–13882 DOI: 10.1021/ja9056213 Supporting Info |
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Site-Specific Incorporation of the Mucin-Type N-Acetylgalactosamine-α-O-threonine into Protein in Escherichia coli Ran Xu, Sarah R. Hanson, Zhiwen Zhang, Yu-Ying Yang, Peter G. Schultz and Chi-Huey Wong p 13883 DOI: 10.1021/ja906705a |
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Organic Reactions, Volume 73 Sherry R. Chemler p 13884 DOI: 10.1021/ja906882y |
Issue 39
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Development of New Conjugated Polymers with Donor−π-Bridge−Acceptor Side Chains for High Performance Solar Cells Fei Huang, Kung-Shih Chen, Hin-Lap Yip, Steven K. Hau, Orb Acton, Yong Zhang, Jingdong Luo and Alex K.-Y. Jen pp 13886–13887 DOI: 10.1021/ja9066139 Supporting Info |
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Palladium-Catalyzed Alkenylation of Quinoline-N-oxides via C−H Activation under External-Oxidant-Free Conditions Junliang Wu, Xiuling Cui, Lianmei Chen, Guojie Jiang and Yangjie Wu pp 13888–13889 DOI: 10.1021/ja902762a Supporting Info |
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Exploring Ion Permeation Energetics in Gramicidin A Using Polarizable Charge Equilibration Force Fields Sandeep Patel, Joseph E. Davis and Brad A. Bauer pp 13890–13891 DOI: 10.1021/ja902903m Supporting Info |
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Electronic Relaxation Dynamics in Isolated and Aggregated Hollow Gold Nanospheres Kenneth L. Knappenberger, Jr., Adam M. Schwartzberg, Anne-Marie Dowgiallo and Casey A. Lowman pp 13892–13893 DOI: 10.1021/ja903086g Supporting Info |
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Fast and Accurate Predictions of Protein NMR Chemical Shifts from Interatomic Distances Kai J. Kohlhoff, Paul Robustelli, Andrea Cavalli, Xavier Salvatella and Michele Vendruscolo pp 13894–13895 DOI: 10.1021/ja903772t Supporting Info |
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Significance of Nonstatistical Dynamics in Organic Reaction Mechanisms: Time-Dependent Stereoselectivity in Cyclopentyne−Alkene Cycloadditions David R. Glowacki, Stephen P. Marsden and Michael J. Pilling pp 13896–13897 DOI: 10.1021/ja9043054 Supporting Info |
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Development of a Titanium Dioxide-Supported Platinum Catalyst with Ultrahigh Stability for Polymer Electrolyte Membrane Fuel Cell Applications Sheng-Yang Huang, Prabhu Ganesan, Sehkyu Park and Branko N. Popov pp 13898–13899 DOI: 10.1021/ja904810h Supporting Info |
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Ion Pairing in Ethanol/Water Solution Probed by Electrophoretic and Diffusion NMR Fredrik Hallberg, Istv pp 13900–13901 DOI: 10.1021/ja904959y Supporting Info |
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Multiple Ultrafast, Broadband 2D NMR Spectra of Hyperpolarized Natural Products Patrick Giraudeau, Yoav Shrot and Lucio Frydman pp 13902–13903 DOI: 10.1021/ja905096f Supporting Info |
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Oxidatively Damaged Nucleobases in Duplex DNA Oligomers: Reaction at Thymine−Thymine Mispairs Joshy Joseph and Gary B. Schuster pp 13904–13905 DOI: 10.1021/ja9055917 Supporting Info |
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Conditional RNA Interference Mediated by Allosteric Ribozyme Deepak Kumar, Chung-Il An and Yohei Yokobayashi pp 13906–13907 DOI: 10.1021/ja905596t Supporting Info |
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Polymeric Monosaccharide Receptors Responsive at Neutral pH Kyoung Taek Kim, Jeroen J. L. M. Cornelissen, Roeland J. M. Nolte and Jan C. M. van Hest pp 13908–13909 DOI: 10.1021/ja905652w Supporting Info |
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Dioxygen Activation by Mononuclear Nonheme Iron(II) Complexes Generates Iron−Oxygen Intermediates in the Presence of an NADH Analogue and Proton Seungwoo Hong, Yong-Min Lee, Woonsup Shin, Shunichi Fukuzumi and Wonwoo Nam pp 13910–13911 DOI: 10.1021/ja905691f Supporting Info |
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Chelating N-Heterocyclic Carbene Alkoxide as a Supporting Ligand for PdII/IV C−H Bond Functionalization Catalysis Polly L. Arnold, Melanie S. Sanford and Stephen M. Pearson pp 13912–13913 DOI: 10.1021/ja905713t Supporting Info |
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Protein Unfolding with a Steric Trap Tracy M. Blois, Heedeok Hong, Tae H. Kim and James U. Bowie pp 13914–13915 DOI: 10.1021/ja905725n Supporting Info |
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Controlled Formation of Concave Tetrahedral/Trigonal Bipyramidal Palladium Nanocrystals Xiaoqing Huang, Shaoheng Tang, Huihui Zhang, Zhiyou Zhou and Nanfeng Zheng pp 13916–13917 DOI: 10.1021/ja9059409 Supporting Info |
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Quantum Monte Carlo Simulation of Nanoscale MgH2 Cluster Thermodynamics Zhigang Wu, Mark D. Allendorf and Jeffrey C. Grossman pp 13918–13919 DOI: 10.1021/ja905639m Supporting Info |
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Unexpected Long-Term Instability of ZnO Nanowires “Protected” by a TiO2 Shell Yang Yang, Dong Sik Kim, Yong Qin, Andreas Berger, Roland Scholz, Hyunbin Kim, Mato Knez and Ulrich G pp 13920–13921 DOI: 10.1021/ja906120a Supporting Info |
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Highly Enantioselective Alkenylation of Glyoxylate with Vinylsilane Catalyzed by Chiral Dicationic Palladium(II) Complexes Kohsuke Aikawa, Y pp 13922–13923 DOI: 10.1021/ja906164p Supporting Info |
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Carbon Monoxide and Nitrogen Monoxide Ligand Dynamics in Synthetic Heme and Heme−Copper Complex Systems Heather R. Lucas, Gerald J. Meyer and Kenneth D. Karlin pp 13924–13925 DOI: 10.1021/ja906172c Supporting Info |
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General Approach for Monolayer Formation of Covalently Attached Aryl Groups Through Electrografting of Arylhydrazines Kristoffer Malmos, Joseph Iruthayaraj, Steen U. Pedersen and Kim Daasbjerg pp 13926–13927 DOI: 10.1021/ja905919u Supporting Info |
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A Short Enantioselective Total Synthesis of the Fundamental Pentacyclic Triterpene Lupeol Karavadhi Surendra and E. J. Corey pp 13928–13929 DOI: 10.1021/ja906335u Supporting Info |
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Aromatic Cation Activation of Alcohols: Conversion to Alkyl Chlorides Using Dichlorodiphenylcyclopropene Brendan D. Kelly and Tristan H. Lambert pp 13930–13931 DOI: 10.1021/ja906520p Supporting Info |
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Mechanism of Dimethylallyltryptophan Synthase: Evidence for a Dimethylallyl Cation Intermediate in an Aromatic Prenyltransferase Reaction Louis Y. P. Luk and Martin E. Tanner pp 13932–13933 DOI: 10.1021/ja906485u Supporting Info |
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Crystallographic Tailoring of Graphene by Nonmetal SiOx Nanoparticles Libo Gao, Wencai Ren, Bilu Liu, Zhong-Shuai Wu, Chuanbin Jiang and Hui-Ming Cheng pp 13934–13936 DOI: 10.1021/ja906610e Supporting Info |
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Broadband Carbon-13 Correlation Spectra of Microcrystalline Proteins in Very High Magnetic Fields Markus Weingarth, Geoffrey Bodenhausen and Piotr Tekely pp 13937–13939 DOI: 10.1021/ja9036143 Supporting Info |
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Hyperthermal O-Atom Exchange Reaction O2 + CO2 through a CO4 Intermediate Laurence Y. Yeung, Mitchio Okumura, Jeffrey T. Paci, George C. Schatz, Jianming Zhang and Timothy K. Minton pp 13940–13942 DOI: 10.1021/ja903944k Supporting Info |
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Hetero-Epitaxial Anion Exchange Yields Single-Crystalline Hollow Nanoparticles Jungwon Park, Haimei Zheng, Young-wook Jun and A. Paul Alivisatos pp 13943–13945 DOI: 10.1021/ja905732q Supporting Info |
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Homogeneity of Phytochrome Cph1 Vibronic Absorption Revealed by Resonance Raman Intensity Analysis Katelyn M. Spillane, Jyotishman Dasgupta, J. Clark Lagarias and Richard A. Mathies pp 13946–13948 DOI: 10.1021/ja905822m Supporting Info |
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Enzymatically Triggered Self-Assembly of Block Copolymers Roey J. Amir, Sheng Zhong, Darrin J. Pochan and Craig J. Hawker pp 13949–13951 DOI: 10.1021/ja9060917 Supporting Info |
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Structure−Reactivity Effects on Primary Deuterium Isotope Effects on Protonation of Ring-Substituted α-Methoxystyrenes Wing-Yin Tsang and John P. Richard pp 13952–13962 DOI: 10.1021/ja905080e Supporting Info |
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Theoretical Analysis of Kinetic Isotope Effects on Proton Transfer Reactions between Substituted α-Methoxystyrenes and Substituted Acetic Acids Kin-Yiu Wong, John P. Richard and Jiali Gao pp 13963–13971 DOI: 10.1021/ja905081x Supporting Info |
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Facile Photochemical Synthesis and Characterization of Highly Fluorescent Silver Nanoparticles Luca Maretti, Paul S. Billone, Yun Liu and Juan C. Scaiano pp 13972–13980 DOI: 10.1021/ja900201k Supporting Info |
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Subtle Balance of Ligand Steric Effects in Stille Transmetalation Alireza Ariafard and Brian F. Yates pp 13981–13991 DOI: 10.1021/ja9007134 Supporting Info |
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Low Temperature 65Cu NMR Spectroscopy of the Cu+ Site in Azurin Andrew S. Lipton, Robert W. Heck, Wibe A. de Jong, Amy R. Gao, Xiongjian Wu, Adrienne Roehrich, Gerard S. Harbison and Paul D. Ellis pp 13992–13999 DOI: 10.1021/ja901308v Supporting Info |
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Frustration of Magnetic and Ferroelectric Long-Range Order in Bi2Mn4/3Ni2/3O6 John B. Claridge, Helen Hughes, Craig A. Bridges, Mathieu Allix, Matthew R. Suchomel, Hongjun Niu, Xiaojun Kuang, Matthew J. Rosseinsky, Natalia Bellido, Dominique Grebille, Olivier Perez, Charles Simon, Denis Pelloquin, Stephen J. Blundell, Tom Lancaster, Peter J. Baker, Francis L. Pratt and P. Shiv Halasyamani pp 14000–14017 DOI: 10.1021/ja902424x Supporting Info |
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Accurate Determination of Order Parameters from 1H,15N Dipolar Couplings in MAS Solid-State NMR Experiments Veniamin Chevelkov, Uwe Fink and Bernd Reif pp 14018–14022 DOI: 10.1021/ja902649u Supporting Info |
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Predicted Trends of Core−Shell Preferences for 132 Late Transition-Metal Binary-Alloy Nanoparticles Lin-Lin Wang and Duane D. Johnson pp 14023–14029 DOI: 10.1021/ja903247x |
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Characterization and Mechanistic Studies of DesII: A Radical S-Adenosyl-l-methionine Enzyme Involved in the Biosynthesis of TDP-d-Desosamine Ping-Hui Szu, Mark W. Ruszczycky, Sei-hyun Choi, Feng Yan and Hung-wen Liu pp 14030–14042 DOI: 10.1021/ja903354k |
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A White-Light-Emitting Molecule: Frustrated Energy Transfer between Constituent Emitting Centers Sanghyuk Park, Ji Eon Kwon, Se Hun Kim, Jangwon Seo, Kyeongwoon Chung, Sun-Young Park, Du-Jeon Jang, Bego pp 14043–14049 DOI: 10.1021/ja902533f Supporting Info |
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Domain Insertion Effectively Regulates the Mechanical Unfolding Hierarchy of Elastomeric Proteins: Toward Engineering Multifunctional Elastomeric Proteins Qing Peng and Hongbin Li pp 14050–14056 DOI: 10.1021/ja903589t Supporting Info |
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Proton-Driven Amide Bond-Cleavage Pathways of Gas-Phase Peptide Ions Lacking Mobile Protons Benjamin J. Bythell, S pp 14057–14065 DOI: 10.1021/ja903883z Supporting Info |
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Biologically Functional Cationic Phospholipid−Gold Nanoplasmonic Carriers of RNA Somin Eunice Lee, Darryl Y. Sasaki, Thomas D. Perroud, Daniel Yoo, Kamlesh D. Patel and Luke P. Lee pp 14066–14074 DOI: 10.1021/ja904326j Supporting Info |
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Controlled Delivery Systems Using Antibody-Capped Mesoporous Nanocontainers Estela Climent, Andrea Bernardos, Ram pp 14075–14080 DOI: 10.1021/ja904456d Supporting Info |
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Controlling Peptide Folding with Repulsive Interactions between Phosphorylated Amino Acids and Tryptophan Alexander J. Riemen and Marcey L. Waters pp 14081–14087 DOI: 10.1021/ja9047575 Supporting Info |
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Mechanistic Studies on the Formation of Linear Polyethylene Chain Catalyzed by Palladium Phosphine−Sulfonate Complexes: Experiment and Theoretical Studies Shusuke Noda, Akifumi Nakamura, Takuya Kochi, Lung Wa Chung, Keiji Morokuma and Kyoko Nozaki pp 14088–14100 DOI: 10.1021/ja9047398 Supporting Info |
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Base-Promoted Ammonia Borane Hydrogen-Release Daniel W. Himmelberger, Chang Won Yoon, Martin E. Bluhm, Patrick J. Carroll and Larry G. Sneddon pp 14101–14110 DOI: 10.1021/ja905015x Supporting Info |
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The Influence of Protein Dynamics on the Success of Computational Enzyme Design Jory Z. Ruscio, Jonathan E. Kohn, K. Aurelia Ball and Teresa Head-Gordon pp 14111–14115 DOI: 10.1021/ja905396s Supporting Info |
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AAA−DDD Triple Hydrogen Bond Complexes Barry A. Blight, Amaya Camara-Campos, Smilja Djurdjevic, Martin Kaller, David A. Leigh, Fiona M. McMillan, Hamish McNab and Alexandra M. Z. Slawin pp 14116–14122 DOI: 10.1021/ja906061v Supporting Info |
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Syntheses, Structures, and Coordination Chemistry of Phosphole-Containing Hybrid Calixphyrins: Promising Macrocyclic P,N2,X-Mixed Donor Ligands for Designing Reactive Transition Metal Complexes Yoshihiro Matano, Tooru Miyajima, Noriaki Ochi, Takashi Nakabuchi, Motoo Shiro, Yoshihide Nakao, Shigeyoshi Sakaki and Hiroshi Imahori p 14123 DOI: 10.1021/ja907161j Supporting Info |
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Metal Complex−DNA Interactions Eric C. Long pp 14124–14125 DOI: 10.1021/ja907261x |
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Quinone Methides. Wiley Series of Reactive Intermediates in Chemistry and Biology, Volume 1 Vladimir Popik pp 14125–14126 DOI: 10.1021/ja907034g |
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Metal Ions in Life Sciences, Volume 5: Metallothionein and Related Chelators Dean Wilcox p 14126 DOI: 10.1021/ja907058z |
Issue 40
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A Crystalline Germanate with Mesoporous 30-Ring Channels Xiaoyan Ren, Yi Li, Qinhe Pan, Jihong Yu, Ruren Xu and Ying Xu pp 14128–14129 DOI: 10.1021/ja902413j Supporting Info |
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Texture of Lipid Bilayer Domains Uffe Bernchou, Jonathan Brewer, Henrik S. Midtiby, John. H. Ipsen, Luis A. Bagatolli and Adam C. Simonsen pp 14130–14131 DOI: 10.1021/ja903375m Supporting Info |
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Raman Spectroscopy and Cage Occupancy of Hydrogen Clathrate Hydrate from First-Principle Calculations Jianwei Wang, Hailong Lu and John A. Ripmeester pp 14132–14133 DOI: 10.1021/ja904140y Supporting Info |
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Aggregation Kinetics of Macrocycles Detected by Magnetic Birefringence Jeroen C. Gielen, An Ver Heyen, Svetlana Klyatskaya, Willem Vanderlinden, Sigurd H pp 14134–14135 DOI: 10.1021/ja904816m Supporting Info |
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Tunability of Supramolecular Kagome Lattices of Magnetic Phthalocyanines Using Graphene-Based Moir Jinhai Mao, Haigang Zhang, Yuhang Jiang, Yi Pan, Min Gao, Wende Xiao and H.-J. Gao pp 14136–14137 DOI: 10.1021/ja904907z Supporting Info |
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One-Sample Approach to Determine the Relative Orientations of Proteins in Ternary and Binary Complexes from Residual Dipolar Coupling Measurements Marco Tonelli, Larry R. Masterson, Gabriel Cornilescu, John L. Markley and Gianluigi Veglia pp 14138–14139 DOI: 10.1021/ja904766g Supporting Info |
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Phage-Induced Alignment of Membrane Proteins Enables the Measurement and Structural Analysis of Residual Dipolar Couplings with Dipolar Waves and λ-Maps Sang Ho Park, Woo Sung Son, Rishi Mukhopadhyay, Homayoun Valafar and Stanley J. Opella pp 14140–14141 DOI: 10.1021/ja905640d Supporting Info |
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A Delicate Balance between sp2 and sp3 C−H Bond Activation: A Pt(II) Complex with a Dual Agostic Interaction Sarah H. Crosby, Guy J. Clarkson and Jonathan P. Rourke pp 14142–14143 DOI: 10.1021/ja905046n Supporting Info |
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PEGylated Nanoceria as Radical Scavenger with Tunable Redox Chemistry Ajay S. Karakoti, Sanjay Singh, Amit Kumar, Maura Malinska, Satyanarayana V. N. T. Kuchibhatla, Krzysztof Wozniak, William T. Self and Sudipta Seal pp 14144–14145 DOI: 10.1021/ja9051087 Supporting Info |
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Single-Molecule Junctions with Strong Molecule−Electrode Coupling Masateru Taniguchi, Makusu Tsutsui, Kohei Shoji, Hideki Fujiwara and Tomoji Kawai pp 14146–14147 DOI: 10.1021/ja905248e Supporting Info |
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A Solid-State Deuterium NMR and Sum-Frequency Generation Study of the Side-Chain Dynamics of Peptides Adsorbed onto Surfaces Nicholas F. Breen, Tobias Weidner, Kun Li, David G. Castner and Gary P. Drobny pp 14148–14149 DOI: 10.1021/ja905382m Supporting Info |
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Semiconstant-Time P,H-COSY NMR: Analysis of Complex Mixtures of Phospholipids Originating from Helicobacter pylori Katja Petzold, Annelie Olofsson, Anna Arnqvist, Gerhard Gr pp 14150–14151 DOI: 10.1021/ja905282h Supporting Info |
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Electronic Coulombic Coupling of Excitation-Energy Transfer in Xanthorhodopsin Kazuhiro J. Fujimoto and Shigehiko Hayashi pp 14152–14153 DOI: 10.1021/ja905697n Supporting Info |
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Water−Gas Shift Reaction Catalyzed by Redox Enzymes on Conducting Graphite Platelets Oliver Lazarus, Thomas W. Woolerton, Alison Parkin, Michael J. Lukey, Erwin Reisner, Javier Seravalli, Elizabeth Pierce, Stephen W. Ragsdale, Frank Sargent and Fraser A. Armstrong pp 14154–14155 DOI: 10.1021/ja905797w Supporting Info |
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Noncovalent Metal−Metal Interactions: The Crucial Role of London Dispersion in a Bimetallic Indenyl System Tobias Schwabe, Stefan Grimme and Jean-Pierre Djukic pp 14156–14157 DOI: 10.1021/ja905617g Supporting Info |
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Pearling of Lipid Vesicles Induced by Nanoparticles Yan Yu and Steve Granick pp 14158–14159 DOI: 10.1021/ja905900h |
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All-Polymer Photovoltaic Devices of Poly(3-(4-n-octyl)-phenylthiophene) from Grignard Metathesis (GRIM) Polymerization Thomas W. Holcombe, Claire H. Woo, David F.J. Kavulak, Barry C. Thompson and Jean M. J. Fr pp 14160–14161 DOI: 10.1021/ja9059359 Supporting Info |
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Group-4 Transition-Metal Boryl Complexes: Syntheses, Structures, Boron−Metal Bonding Properties, and Application as a Polymerization Catalyst Tomomi Terabayashi, Takashi Kajiwara, Makoto Yamashita and Kyoko Nozaki pp 14162–14163 DOI: 10.1021/ja905950g Supporting Info |
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An Unsymmetric Oxo/Imido-Bridged Germanium-Centered Singlet Diradicaloid Xinping Wang, Yang Peng, Marilyn M. Olmstead, James C. Fettinger and Philip P. Power pp 14164–14165 DOI: 10.1021/ja906053y Supporting Info |
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Electrogenerated Chemiluminescence of Soliton Waves in Conjugated Polymers Ya-Lan Chang, Rodrigo E. Palacios, Jiun-Tai Chen, Keith J. Stevenson, Song Guo, William M. Lackowski and Paul F. Barbara pp 14166–14167 DOI: 10.1021/ja9066018 Supporting Info |
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Catalytic Hydrogenation of Carbon Dioxide Using Ir(III)−Pincer Complexes Ryo Tanaka, Makoto Yamashita and Kyoko Nozaki pp 14168–14169 DOI: 10.1021/ja903574e Supporting Info |
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Site Preferences of Fluoride Guest Ions in the Calcium Silicate Phases of Portland Cement from 29Si{19F} CP-REDOR NMR Spectroscopy Thuan T. Tran, Duncan Herfort, Hans J. Jakobsen and Jørgen Skibsted pp 14170–14171 DOI: 10.1021/ja905223d Supporting Info |
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Ligand-Enhanced Reduction of Perchlorate in Water with Heterogeneous Re−Pd/C Catalysts Keith D. Hurley, Yunxia Zhang and John R. Shapley pp 14172–14173 DOI: 10.1021/ja905446t Supporting Info |
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Stereoselective Synthesis of γ-Substituted (Z)-Allylic Boranes via Kinetically Controlled Hydroboration of Allenes with 10-TMS-9-borabicyclo[3.3.2]decane Jeremy Kister, Amy C. DeBaillie, Ricardo Lira and William R. Roush pp 14174–14175 DOI: 10.1021/ja905494c Supporting Info |
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N-Heterocyclic Carbene-Catalyzed Generation of α,β-Unsaturated Acyl Imidazoliums: Synthesis of Dihydropyranones by their Reaction with Enolates Sarah J. Ryan, Lisa Candish and David W. Lupton pp 14176–14177 DOI: 10.1021/ja905501z Supporting Info |
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Resolution of Planar Chiral Cationic (η6-Arene)tricarbonylmanganese Complexes Antoine Eloi, Fran pp 14178–14179 DOI: 10.1021/ja905712k Supporting Info |
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Biomimetic Conformation-Specific Assembly of Proteins at Artificial Binding Sites Nanopatterned on Silicon Roberto de la Rica and Hiroshi Matsui pp 14180–14181 DOI: 10.1021/ja905932e Supporting Info |
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Insertions of Silylenes into Vinyl Epoxides: Diastereoselective Synthesis of Functionalized, Optically Active trans-Dioxasilacyclooctenes Michel Pr pp 14182–14183 DOI: 10.1021/ja906204a Supporting Info |
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Enzyme-Triggered Disassembly of Dendrimer-Based Amphiphilic Nanocontainers Malar A. Azagarsamy, Punidha Sokkalingam and S. Thayumanavan pp 14184–14185 DOI: 10.1021/ja906162u Supporting Info |
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Efficient Near-IR Hyperthermia and Intense Nonlinear Optical Imaging Contrast on the Gold Nanorod-in-Shell Nanostructures Kuo-Wei Hu, Tzu-Ming Liu, Kuei-Yi Chung, Keng-Shiang Huang, Chien-Tai Hsieh, Chi-Kuang Sun and Chen-Sheng Yeh pp 14186–14187 DOI: 10.1021/ja9062772 Supporting Info |
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Total Syntheses of Isodomoic Acids G and H Scott E. Denmark, Jack Hung-Chang Liu and Joseck M. Muhuhi pp 14188–14189 DOI: 10.1021/ja9063475 Supporting Info |
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N-Heterocyclic Carbene-Catalyzed Hydroacylation of Unactivated Double Bonds Keiichi Hirano, Akkattu T. Biju, Isabel Piel and Frank Glorius pp 14190–14191 DOI: 10.1021/ja906361g Supporting Info |
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Development of a Sila-Friedel−Crafts Reaction and Its Application to the Synthesis of Dibenzosilole Derivatives Shunsuke Furukawa, Junji Kobayashi and Takayuki Kawashima pp 14192–14193 DOI: 10.1021/ja906566r Supporting Info |
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Genetically Encoding N Duy P. Nguyen, Maria M. Garcia Alai, Prashant B. Kapadnis, Heinz Neumann and Jason W. Chin pp 14194–14195 DOI: 10.1021/ja906603s Supporting Info |
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Crystal Structures of Cisplatin Bound to a Human Copper Chaperone Amie K. Boal and Amy C. Rosenzweig pp 14196–14197 DOI: 10.1021/ja906363t Supporting Info |
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Intramolecular Electron Arrangement with a Rotative Trigger Shoko Kume, Kuniharu Nomoto, Tetsuro Kusamoto and Hiroshi Nishihara pp 14198–14199 DOI: 10.1021/ja906684g Supporting Info |
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Upconversion Luminescence of Monodisperse CaF2:Yb3+/Er3+ Nanocrystals Guofeng Wang, Qing Peng and Yadong Li pp 14200–14201 DOI: 10.1021/ja906732y Supporting Info |
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Formal [4 + 2] Cycloaddition of Donor−Acceptor Cyclobutanes and Aldehydes: Stereoselective Access to Substituted Tetrahydropyrans Andrew T. Parsons and Jeffrey S. Johnson pp 14202–14203 DOI: 10.1021/ja906755e Supporting Info |
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Effect of GC Base Pairs on Charge Transfer through DNA Hairpins: The Importance of Electrostatic Interactions Ferdinand C. Grozema, Stefano Tonzani, Yuri A. Berlin, George C. Schatz, Laurens D. A. Siebbeles and Mark A. Ratner pp 14204–14205 DOI: 10.1021/ja906863k Supporting Info |
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Quadrupole-Central-Transition 17O NMR Spectroscopy of Protein−Ligand Complexes in Solution Jianfeng Zhu, Irene C. M. Kwan and Gang Wu pp 14206–14207 DOI: 10.1021/ja906881n Supporting Info |
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Iridium Doped Silica−PEG Nanoparticles: Enabling Electrochemiluminescence of Neutral Complexes in Aqueous Media Simone Zanarini, Enrico Rampazzo, Sara Bonacchi, Riccardo Juris, Massimo Marcaccio, Marco Montalti, Francesco Paolucci and Luca Prodi pp 14208–14209 DOI: 10.1021/ja906666e Supporting Info |
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Preparation of the [(DippNP)2(P4)2]2+-Dication by the Reaction of [DippNPCl]2 and a Lewis Acid with P4 Michael H. Holthausen and Jan J. Weigand pp 14210–14211 DOI: 10.1021/ja906878q Supporting Info |
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A Mammalian Reductive Deiodinase has Broad Power to Dehalogenate Chlorinated and Brominated Substrates Patrick M. McTamney and Steven E. Rokita pp 14212–14213 DOI: 10.1021/ja906642n Supporting Info |
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Why the Chromyl Bond Is Stronger Than the Perchromyl Bond in High-Valent Oxochromium(IV,V) Complexes of Tris(pentafluorophenyl)corrole Roman S. Czernuszewicz, Vicky Mody, Arkadiusz Czader, Michał Gał pp 14214–14215 DOI: 10.1021/ja906393r Supporting Info |
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Catalytic Asymmetric Synthesis of Palmerolide A via Organoboron Methodology Marlin Penner, Vivek Rauniyar, Ludwig T. Kaspar and Dennis G. Hall pp 14216–14217 DOI: 10.1021/ja906429c Supporting Info |
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Iridium(III) Catalyzed Diastereo- and Enantioselective C−H Bond Functionalization Hidehiro Suematsu and Tsutomu Katsuki pp 14218–14219 DOI: 10.1021/ja9065267 Supporting Info |
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Spin Trapping of Radicals Other Than the •OH Radical upon Reduction of the Anticancer Agent Tirapazamine by Cytochrome P450 Reductase Sujata S. Shinde, Michael P. Hay, Adam V. Patterson, William A. Denny and Robert F. Anderson pp 14220–14221 DOI: 10.1021/ja906860a Supporting Info |
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Seeing through Macromolecules: T2-Filtered NMR for the Purity Assay of Functionalized Nanosystems and the Screening of Biofluids Federico Rastrelli, Satadru Jha and Fabrizio Mancin pp 14222–14224 DOI: 10.1021/ja904737r Supporting Info |
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Hole-Transporting Periodic Mesostructured Organosilica Norihiro Mizoshita, Masamichi Ikai, Takao Tani and Shinji Inagaki pp 14225–14227 DOI: 10.1021/ja9050263 Supporting Info |
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Facile Organization of Colloidal Particles into Large, Perfect One- and Two-Dimensional Arrays by Dry Manual Assembly on Patterned Substrates Nguyen Nguyen Khanh and Kyung Byung Yoon pp 14228–14230 DOI: 10.1021/ja905534k Supporting Info |
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Asymmetric Carbon−Carbon Bond Formation γ to a Carbonyl Group: Phosphine-Catalyzed Addition of Nitromethane to Allenes Sean W. Smith and Gregory C. Fu pp 14231–14233 DOI: 10.1021/ja9061823 Supporting Info |
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Rhodium and Iridium Amido Complexes Supported by Silyl Pincer Ligation: Ammonia N−H Bond Activation by a [PSiP]Ir Complex Erin Morgan, Darren F. MacLean, Robert McDonald and Laura Turculet pp 14234–14236 DOI: 10.1021/ja906646v Supporting Info |
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Cell-Targeted Self-Assembled DNA Nanostructures Alexey Y. Koyfman, Gary B. Braun and Norbert O. Reich pp 14237–14239 DOI: 10.1021/ja9015638 Supporting Info |
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Impact of Nonnatural Amino Acid Mutagenesis on the in Vivo Function and Binding Modes of a Transcriptional Activator Chinmay Y. Majmudar, Lori W. Lee, Jody K. Lancia, Adaora Nwokoye, Qian Wang, Amberlyn M. Wands, Lei Wang and Anna K. Mapp pp 14240–14242 DOI: 10.1021/ja904378z Supporting Info |
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Intramolecular Amide Stacking and Its Competition with Hydrogen Bonding in a Small Foldamer William H. James III, Christian W. M pp 14243–14245 DOI: 10.1021/ja9054965 Supporting Info |
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Double Metallocene Nanowires Xiaojun Wu and Xiao Cheng Zeng pp 14246–14248 DOI: 10.1021/ja904912z Supporting Info |
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Periodic Mesoporous Organosilica with a Hexagonally Pillared Lamellar Structure Hyung Ik Lee, Ji Man Kim and Galen D. Stucky pp 14249–14251 DOI: 10.1021/ja905245u Supporting Info |
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Relating Mechanical Properties and Chemical Bonding in an Inorganic−Organic Framework Material: A Single−Crystal Nanoindentation Study Jin Chong Tan, Joshua D. Furman and Anthony K. Cheetham pp 14252–14254 DOI: 10.1021/ja9060307 Supporting Info |
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Cell-Directed Localization and Orientation of a Functional Foreign Transmembrane Protein within a Silica Nanostructure Eric C. Carnes, Jason C. Harper, Carlee E. Ashley, DeAnna M. Lopez, Lina M. Brinker, Juewen Liu, Seema Singh, Susan M. Brozik and C. Jeffrey Brinker pp 14255–14257 DOI: 10.1021/ja906055m Supporting Info |
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Identification of the ADP-Ribosylation Sites in the PARP-1 Automodification Domain: Analysis and Implications Zhihua Tao, Peng Gao and Hung-wen Liu pp 14258–14260 DOI: 10.1021/ja906135d Supporting Info |
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Postsynthetic Modifications of Iron-Carboxylate Nanoscale Metal−Organic Frameworks for Imaging and Drug Delivery Kathryn M. L. Taylor-Pashow, Joseph Della Rocca, Zhigang Xie, Sylvie Tran and Wenbin Lin pp 14261–14263 DOI: 10.1021/ja906198y Supporting Info |
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Size, Shape, and Internal Atomic Ordering of Nanocrystals by Atomic Pair Distribution Functions: A Comparative Study of γ-Fe2O3 Nanosized Spheres and Tetrapods Valeri Petkov, P. Davide Cozzoli, Raffaella Buonsanti, Roberto Cingolani and Yang Ren pp 14264–14266 DOI: 10.1021/ja9067589 Supporting Info |
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Fluorescent Conjugated Polymer Nanoparticles by Polymerization in Miniemulsion Moritz C. Baier, Johannes Huber and Stefan Mecking pp 14267–14273 DOI: 10.1021/ja905077c Supporting Info |
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Microsecond Light-Induced Proton Transfer to Flavin in the Blue Light Sensor Plant Cryptochrome Thomas Langenbacher, Dominik Immeln, Bernhard Dick and Tilman Kottke pp 14274–14280 DOI: 10.1021/ja901628y Supporting Info |
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Synthesis, Stability, and Photochemistry of Pentacene, Hexacene, and Heptacene: A Matrix Isolation Study Rajib Mondal, Christina T pp 14281–14289 DOI: 10.1021/ja901841c Supporting Info |
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First Principles Modeling of Eosin-Loaded ZnO Films: A Step toward the Understanding of Dye-Sensitized Solar Cell Performances Fr pp 14290–14298 DOI: 10.1021/ja902833s Supporting Info |
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Mapping the Optical Properties of CdSe/CdS Heterostructure Nanocrystals: The Effects of Core Size and Shell Thickness Joel van Embden, Jacek Jasieniak and Paul Mulvaney pp 14299–14309 DOI: 10.1021/ja9030209 Supporting Info |
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Decoration of Gold Nanoparticles on Surface-Grown Single-Walled Carbon Nanotubes for Detection of Every Nanotube by Surface-Enhanced Raman Spectroscopy Haibin Chu, Jinyong Wang, Lei Ding, Dongning Yuan, Yan Zhang, Jie Liu and Yan Li pp 14310–14316 DOI: 10.1021/ja9035972 Supporting Info |
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Platinum-Catalyzed Direct Amination of Allylic Alcohols under Mild Conditions: Ligand and Microwave Effects, Substrate Scope, and Mechanistic Study Takashi Ohshima, Yoshiki Miyamoto, Junji Ipposhi, Yasuhito Nakahara, Masaru Utsunomiya and Kazushi Mashima pp 14317–14328 DOI: 10.1021/ja9046075 Supporting Info |
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A Divergent Synthesis of Very Large Polyphenylene Dendrimers with Iridium(III) Cores: Molecular Size Effect on the Performance of Phosphorescent Organic Light-Emitting Diodes Tianshi Qin, Junqiao Ding, Lixiang Wang, Martin Baumgarten, Gang Zhou and Klaus M pp 14329–14336 DOI: 10.1021/ja905118t Supporting Info |
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A New Model for the Presentation of Tumor-Associated Antigens and the Quest for an Anticancer Vaccine: A Solution to the Synthesis Challenge via Ring-Closing Metathesis Insik Jeon, Dongjoo Lee, Isaac J. Krauss and Samuel J. Danishefsky pp 14337–14344 DOI: 10.1021/ja9052625 Supporting Info |
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Crystal Structures of Penicillin-Binding Protein 6 from Escherichia coli Yu Chen, Weilie Zhang, Qicun Shi, Dusan Hesek, Mijoon Lee, Shahriar Mobashery and Brian K. Shoichet pp 14345–14354 DOI: 10.1021/ja903773f |
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Optically Active (aR)- and (aS)-Linear and Vaulted Biaryl Ligands: Deracemization versus Oxidative Dimerization Gang Hu, Daniel Holmes, Brina Fay Gendhar and William D. Wulff pp 14355–14364 DOI: 10.1021/ja903820m Supporting Info |
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Supramolecular Gel Based on a Perylene Diimide Dye: Multiple Stimuli Responsiveness, Robustness, and Photofunction Elisha Krieg, Elijah Shirman, Haim Weissman, Eyal Shimoni, Sharon G. Wolf, Iddo Pinkas and Boris Rybtchinski pp 14365–14373 DOI: 10.1021/ja903938g Supporting Info |
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Unusual Electronic Structure of First Row Transition Metal Complexes Featuring Redox-Active Dipyrromethane Ligands Evan R. King and Theodore A. Betley pp 14374–14380 DOI: 10.1021/ja903997a Supporting Info |
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Structure Sensitivity of Methanol Electrooxidation on Transition Metals Peter Ferrin and Manos Mavrikakis pp 14381–14389 DOI: 10.1021/ja904010u Supporting Info |
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Raman Spectroelectrochemistry of Molecules within Individual Electromagnetic Hot Spots Timur Shegai, Alexander Vaskevich, Israel Rubinstein and Gilad Haran pp 14390–14398 DOI: 10.1021/ja904480r Supporting Info |
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Size-Scaling of Proton Conductivity in Amorphous Aluminosilicate Acid Thin Films Yoshitaka Aoki, Hiroki Habazaki and Toyoki Kunitake pp 14399–14406 DOI: 10.1021/ja904627h |
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One-Pot Room-Temperature Synthesis of Single-Crystalline Gold Nanocorolla in Water Tetsuro Soejima and Nobuo Kimizuka pp 14407–14412 DOI: 10.1021/ja904910m Supporting Info |
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Micelles for Delivery of Nitric Oxide Yun Suk Jo, Andr pp 14413–14418 DOI: 10.1021/ja905123t Supporting Info |
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Dynamic Asymmetric Multicomponent Resolution: Lipase-Mediated Amidation of a Double Dynamic Covalent System Pornrapee Vongvilai and Olof Ramstr pp 14419–14425 DOI: 10.1021/ja9052015 Supporting Info |
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First-Principles Study of Non-heme Fe(II) Halogenase SyrB2 Reactivity Heather J. Kulik, Leah C. Blasiak, Nicola Marzari and Catherine L. Drennan pp 14426–14433 DOI: 10.1021/ja905206k Supporting Info |
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Affinity-Based Screening of Peptides Recognizing Assembly States of Self-Assembling Peptide Nanomaterials Toshiki Sawada, Tsuyoshi Takahashi and Hisakazu Mihara pp 14434–14441 DOI: 10.1021/ja905250u Supporting Info |
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Swallow-Tail Substituted Liquid Crystalline Perylene Bisimides: Synthesis and Thermotropic Properties Andr pp 14442–14453 DOI: 10.1021/ja905260c Supporting Info |
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Thermodynamic Studies and Hydride Transfer Reactions from a Rhodium Complex to BX3 Compounds Michael T. Mock, Robert G. Potter, Donald M. Camaioni, Jun Li, William G. Dougherty, W. Scott Kassel, Brendan Twamley and Daniel L. DuBois pp 14454–14465 DOI: 10.1021/ja905287q Supporting Info |
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Single-Molecule Surface-Enhanced Raman Spectroscopy of Nonresonant Molecules Evan J. Blackie, Eric C. Le Ru and Pablo G. Etchegoin pp 14466–14472 DOI: 10.1021/ja905319w |
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Defining the Mode of Action of Tetramic Acid Antibacterials Derived from Pseudomonas aeruginosa Quorum Sensing Signals Colin A. Lowery, Junguk Park, Christian Gloeckner, Michael M. Meijler, Ryan S. Mueller, Helena I. Boshoff, Ricky L. Ulrich, Clifton E. Barry,, III, Douglas H. Bartlett, Vladimir V. Kravchenko, Gunnar F. Kaufmann and Kim D. Janda pp 14473–14479 DOI: 10.1021/ja9056079 Supporting Info |
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Mimics of the Self-Assembling Chlorosomal Bacteriochlorophylls: Regio- and Stereoselective Synthesis and Stereoanalysis of Acyl(1-hydroxyalkyl)porphyrins Teodor Silviu Balaban, Anil Dnyanoba Bhise, Gerhard Bringmann, Jochen B pp 14480–14492 DOI: 10.1021/ja905628h Supporting Info |
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EPR and ENDOR Characterization of the Reactive Intermediates in the Generation of NO by Cryoreduced Oxy-Nitric Oxide Synthase from Geobacillus stearothermophilus Roman Davydov, Jawahar Sudhamsu, Nicholas S. Lees, Brian R. Crane and Brian M. Hoffman pp 14493–14507 DOI: 10.1021/ja906133h Supporting Info |
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Modeling the Syn Disposition of Nitrogen Donors in Non-Heme Diiron Enzymes. Synthesis, Characterization, and Hydrogen Peroxide Reactivity of Diiron(III) Complexes with the Syn N-Donor Ligand H2BPG2DEV Simone Friedle, Jeremy J. Kodanko, Anna J. Morys, Takahiro Hayashi, Pierre Mo pp 14508–14520 DOI: 10.1021/ja906137y Supporting Info |
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Aza-β3-cyclopeptides: A New Way of Controlling Nitrogen Chirality Cl pp 14521–14525 DOI: 10.1021/ja9058074 Supporting Info |
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Sublimation of GeTe Nanowires and Evidence of Its Size Effect Studied by in Situ TEM Joanne W. L. Yim, Bin Xiang and Junqiao Wu pp 14526–14530 DOI: 10.1021/ja905808d Supporting Info |
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Well-Defined Ir/Pd Complexes with a Triazolyl-diylidene Bridge as Catalysts for Multiple Tandem Reactions Alessandro Zanardi, Jos pp 14531–14537 DOI: 10.1021/ja906028g Supporting Info |
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Enabling Cleaner Fuels: Desulfurization by Adsorption to Microporous Coordination Polymers Katie A. Cychosz, Antek G. Wong-Foy and Adam J. Matzger pp 14538–14543 DOI: 10.1021/ja906034k |
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Unveiling the Chemical and Morphological Features of Sb−SnO2 Nanocrystals by the Combined Use of High-Resolution Transmission Electron Microscopy and ab Initio Surface Energy Calculations Daniel G. Stroppa, Luciano A. Montoro, Armando Beltr pp 14544–14548 DOI: 10.1021/ja905896u Supporting Info |
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Enhancing the Photochemical Stability of N,C-Chelate Boryl Compounds: C−C Bond Formation versus C═C Bond cis,trans-Isomerization Chul Baik, Zachary M. Hudson, Hazem Amarne and Suning Wang pp 14549–14559 DOI: 10.1021/ja906430s Supporting Info |
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Efficient and Rapid Template-Directed Nucleic Acid Copying Using 2′-Amino-2′,3′-dideoxyribonucleoside−5′-Phosphorimidazolide Monomers Jason P. Schrum, Alonso Ricardo, Mathangi Krishnamurthy, J. Craig Blain and Jack W. Szostak pp 14560–14570 DOI: 10.1021/ja906557v Supporting Info |
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Enzymatic Synthesis and Structural Characterization of 13C, 15N-Poly(ADP-ribose) Heather L. Schultheisz, Blair R. Szymczyna and James R. Williamson pp 14571–14578 DOI: 10.1021/ja903155s Supporting Info |
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Development of a Merged Conjugate Addition/Oxidative Coupling Sequence. Application to the Enantioselective Total Synthesis of Metacycloprodigiosin and Prodigiosin R1 Michael D. Clift and Regan J. Thomson pp 14579–14583 DOI: 10.1021/ja906122g Supporting Info |
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Heterogeneously Catalyzed Asymmetric Hydrogenation of C═C Bonds Directed by Surface-Tethered Chiral Modifiers David J. Watson, R.J. Bennie Ram John Jesudason, Simon K. Beaumont, Georgios Kyriakou, Jonathan W. Burton and Richard M. Lambert pp 14584–14589 DOI: 10.1021/ja906356g Supporting Info |
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In Situ and Ex Situ Studies of Platinum Nanocrystals: Growth and Evolution in Solution Soshan Cheong, John Watt, Bridget Ingham, Michael F. Toney and Richard D. Tilley pp 14590–14595 DOI: 10.1021/ja9065688 Supporting Info |
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Optimization of an Unnatural Base Pair toward Natural-Like Replication Young Jun Seo, Gil Tae Hwang, Phillip Ordoukhanian and Floyd E. Romesberg p 14596 DOI: 10.1021/ja907027a |
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Mechanical Catalysis: Methods of Enzymatic, Homogeneous, and Heterogeneous Catalysis David A. Bruce p 14597 DOI: 10.1021/ja9075138 |
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Combinatorial Methods for Chemical and Biological Sensors Marco Bonizzoni and Eric V. Anslyn pp 14597–14598 DOI: 10.1021/ja907230d |
Issue 41
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Protein-Sized Chiral Fe168 Cages with NbO-Type Topology Zhi-Ming Zhang, Shuang Yao, Yang-Guang Li, Rodolphe Cl pp 14600–14601 DOI: 10.1021/ja903776h Supporting Info |
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Enantioselective Synthesis of 2-Methyl-1,2-syn- and 2-Methyl-1,2-anti-3-butenediols via Allene Hydroboration−Aldehyde Allylboration Reaction Sequences Ming Chen, Masaki Handa and William R. Roush pp 14602–14603 DOI: 10.1021/ja904599h Supporting Info |
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Crossed Intermolecular [2+2] Cycloadditions of Acyclic Enones via Visible Light Photocatalysis Juana Du and Tehshik P. Yoon pp 14604–14605 DOI: 10.1021/ja903732v Supporting Info |
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Copolymerization of Vinyl Acetate with Ethylene by Palladium/Alkylphosphine−Sulfonate Catalysts Shingo Ito, Kagehiro Munakata, Akifumi Nakamura and Kyoko Nozaki pp 14606–14607 DOI: 10.1021/ja9050839 Supporting Info |
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Enantioselective Rhodium-Catalyzed Conjugate Alkynylation of 5-Benzylidene Meldrum’s Acids with TMS-acetylene Eric Fillion and Alexander K. Zorzitto pp 14608–14609 DOI: 10.1021/ja905336p Supporting Info |
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Short-Range Coherence of Internal Protein Dynamics Revealed by High-Precision in Silico Study Da-Wei Li, Dan Meng and Rafael Br pp 14610–14611 DOI: 10.1021/ja905340s Supporting Info |
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A Planar Copolymer for High Efficiency Polymer Solar Cells Ruiping Qin, Weiwei Li, Cuihong Li, Chun Du, Clemens Veit, Hans-Frieder Schleiermacher, Mattias Andersson, Zhishan Bo, Zhengping Liu, Olle Ingan pp 14612–14613 DOI: 10.1021/ja9057986 Supporting Info |
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Redox Switch-Off of the Ferromagnetic Coupling in a Mixed-Spin Tricobalt(II) Triple Mesocate Marie-Claire Dul, Emilio Pardo, Rodrigue Lescou pp 14614–14615 DOI: 10.1021/ja9052202 Supporting Info |
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Increasing Hydrogen Storage Capacity Using Tetrahydrofuran Takeshi Sugahara, Joanna C. Haag, Pinnelli S. R. Prasad, Ashleigh A. Warntjes, E. Dendy Sloan, Amadeu K. Sum and Carolyn A. Koh pp 14616–14617 DOI: 10.1021/ja905819z Supporting Info |
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Functionalization of Self-Assembled Hexa-peri-hexabenzocoronene Fibers with Peptides for Bioprobing Meizhen Yin, Jie Shen, Wojciech Pisula, Minghui Liang, Linjie Zhi and Klaus M pp 14618–14619 DOI: 10.1021/ja9058662 Supporting Info |
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PCR with an Expanded Genetic Alphabet Denis A. Malyshev, Young Jun Seo, Phillip Ordoukhanian and Floyd E. Romesberg pp 14620–14621 DOI: 10.1021/ja906186f Supporting Info |
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Programmed Synthesis of Tetraarylthiophenes through Sequential C−H Arylation Shuichi Yanagisawa, Kirika Ueda, Hiromi Sekizawa and Kenichiro Itami pp 14622–14623 DOI: 10.1021/ja906215b Supporting Info |
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An Allosteric Dual-DNAzyme Unimolecular Probe for Colorimetric Detection of Copper(II) Bin-Cheng Yin, Bang-Ce Ye, Weihong Tan, Hui Wang and Cong-Cong Xie pp 14624–14625 DOI: 10.1021/ja9062426 Supporting Info |
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Organocatalytic Asymmetric Vinylogous α-Ketol Rearrangement: Enantioselective Construction of Chiral All-Carbon Quaternary Stereocenters in Spirocyclic Diketones via Semipinacol-Type 1,2-Carbon Migration En Zhang, Chun-An Fan, Yong-Qiang Tu, Fu-Min Zhang and Yan-Lin Song pp 14626–14627 DOI: 10.1021/ja906291n Supporting Info |
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Regioselective Synthesis of 4,6,7-Trisubstituted Benzofurans from Furfural Imines and Nonheteroatom Stabilized Alkynylcarbene Complexes Jos pp 14628–14629 DOI: 10.1021/ja9063712 Supporting Info |
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A Tandem Cascade Cyclization−Electrophilic Aromatic Substitution: Application in the Total Synthesis of (+)-Angelichalcone Joseph J. Topczewski, Michael P. Callahan, Jeffrey D. Neighbors and David F. Wiemer pp 14630–14631 DOI: 10.1021/ja906468v Supporting Info |
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Tuning of Metal−Metal Bonding by Counterion Size in Hypothetical AeTiO2 Compounds Xiao-Dong Wen, Thomas J. Cahill, Roald Hoffmann and Akira Miura pp 14632–14633 DOI: 10.1021/ja9064766 Supporting Info |
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Nanoparticle Size Determination by 1H NMR Spectroscopy M. Victoria Gomez, Javier Guerra, V. Sue Myers, Richard M. Crooks and Aldrik H. Velders pp 14634–14635 DOI: 10.1021/ja9065442 Supporting Info |
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Heterolytic Cleavage of Hydrogen Molecule by Rhodium Thiolate Complexes That Catalyze Chemoselective Hydrogenation of Imines under Ambient Conditions Yoshiyuki Misumi, Hidetake Seino and Yasushi Mizobe pp 14636–14637 DOI: 10.1021/ja905835u Supporting Info |
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Tandem Asymmetric Aza-Darzens/Ring-Opening Reactions: Dual Functionality from the Silane Lewis Acid S. Corey Valdez and James L. Leighton pp 14638–14639 DOI: 10.1021/ja9066354 Supporting Info |
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Current-Driven Ion Fluxes of Polymeric Membrane Ion-Selective Electrode for Potentiometric Biosensing Jiawang Ding and Wei Qin pp 14640–14641 DOI: 10.1021/ja906723h Supporting Info |
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Direct Growth of Semiconducting Single-Walled Carbon Nanotube Array Guo Hong, Bo Zhang, Banghua Peng, Jin Zhang, Won Mook Choi, Jae-Young Choi, Jong Min Kim and Zhongfan Liu pp 14642–14643 DOI: 10.1021/ja9068529 Supporting Info |
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Hard Proof of the NaYF4/NaGdF4 Nanocrystal Core/Shell Structure Keith A. Abel, John-Christopher Boyer and Frank C. J. M. van Veggel pp 14644–14645 DOI: 10.1021/ja906971y Supporting Info |
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Supramolecular Solar Cells: Surface Modification of Nanocrytalline TiO2 with Coordinating Ligands To Immobilize Sensitizers and Dyads via Metal−Ligand Coordination for Enhanced Photocurrent Generation Navaneetha K. Subbaiyan, Channa A. Wijesinghe and Francis D’Souza pp 14646–14647 DOI: 10.1021/ja9067113 Supporting Info |
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An Enzymatic Cyclopentyl[b]indole Formation Involved in Scytonemin Biosynthesis Emily P. Balskus and Christopher T. Walsh pp 14648–14649 DOI: 10.1021/ja906752u Supporting Info |
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Subtype Polymorphisms Among HIV-1 Protease Variants Confer Altered Flap Conformations and Flexibility Jamie L. Kear, Mandy E. Blackburn, Angelo M. Veloro, Ben M. Dunn and Gail E. Fanucci pp 14650–14651 DOI: 10.1021/ja907088a Supporting Info |
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Polyvalent Oligonucleotide Gold Nanoparticle Conjugates as Delivery Vehicles for Platinum(IV) Warheads Shanta Dhar, Weston L. Daniel, David A. Giljohann, Chad A. Mirkin and Stephen J. Lippard pp 14652–14653 DOI: 10.1021/ja9071282 Supporting Info |
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Pd(II)-Catalyzed Hydroxylation of Arenes with 1 atm of O2 or Air Yang-Hui Zhang and Jin-Quan Yu pp 14654–14655 DOI: 10.1021/ja907198n Supporting Info |
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Cross-Coupling of Alkenyl/Aryl Carboxylates with Grignard Reagent via Fe-Catalyzed C−O Bond Activation Bi-Jie Li, Li Xu, Zhen-Hua Wu, Bing-Tao Guan, Chang-Liang Sun, Bi-Qin Wang and Zhang-Jie Shi pp 14656–14657 DOI: 10.1021/ja907281f Supporting Info |
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Preparation of 14C-Labeled Multiwalled Carbon Nanotubes for Biodistribution Investigations Dominique Georgin, Bertrand Czarny, Magali Botquin, Martine Mayne-L’Hermite, Mathieu Pinault, Brigitte Bouchet-Fabre, Marie Carriere, Jean-Luc Poncy, Quang Chau, R pp 14658–14659 DOI: 10.1021/ja906319z Supporting Info |
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Formal Alkyne Aza-Prins Cyclization: Gold(I)-Catalyzed Cycloisomerization of Mixed N,O-Acetals Generated from Homopropargylic Amines to Highly Substituted Piperidines Cheoljae Kim, Hyo Jin Bae, Ji Hyung Lee, Wook Jeong, Haejin Kim, Vasu Sampath and Young Ho Rhee pp 14660–14661 DOI: 10.1021/ja906744r Supporting Info |
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Facile High-Yield Solvothermal Deposition of Inorganic Nanostructures on Zeolite Crystals for Mixed Matrix Membrane Fabrication Tae-Hyun Bae, Junqiang Liu, Jong Suk Lee, William J. Koros, Christopher W. Jones and Sankar Nair pp 14662–14663 DOI: 10.1021/ja907435c Supporting Info |
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Electrochemical Charging of Single Gold Nanorods Carolina Novo, Alison M. Funston, Ann K. Gooding and Paul Mulvaney pp 14664–14666 DOI: 10.1021/ja905216h Supporting Info |
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Gold Nanoparticles Supported on Passivated Silica: Access to an Efficient Aerobic Epoxidation Catalyst and the Intrinsic Oxidation Activity of Gold David Gajan, Kevin Guillois, Pierre Delich pp 14667–14669 DOI: 10.1021/ja903730q Supporting Info |
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Surface-Mediated Visible-Light Photo-oxidation on Pure TiO2(001) Hiroko Ariga, Toshiaki Taniike, Harumo Morikawa, Mizuki Tada, Byoung Koun Min, Kazuya Watanabe, Yoshiyasu Matsumoto, Susumu Ikeda, Koichiro Saiki and Yasuhiro Iwasawa pp 14670–14672 DOI: 10.1021/ja9066805 Supporting Info |
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“Clicking” Polymer Brushes with Thiol-yne Chemistry: Indoors and Out Ryan M. Hensarling, Vanessa A. Doughty, Justin W. Chan and Derek L. Patton pp 14673–14675 DOI: 10.1021/ja9071157 Supporting Info |
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Dip-Pen Lithography of Ferroelectric PbTiO3 Nanodots Jong Yeog Son, Young-Han Shin, Sangwoo Ryu, Hyungjun Kim and Hyun M. Jang pp 14676–14678 DOI: 10.1021/ja906871b Supporting Info |
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Superelectrophilic Intermediates in Nitrogen-Directed Aromatic Borylation Timothy S. De Vries, Aleksandrs Prokofjevs, Jeremy N. Harvey and Edwin Vedejs pp 14679–14687 DOI: 10.1021/ja905369n Supporting Info |
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A Highly Delocalized Triplet Carbene, 5-Methylhexa-1,2,4-triene-1,3-diyl: Matrix IR Identification, Structure, and Reactions Sergey E. Boganov, Valery I. Faustov, Konstantin N. Shavrin, Valentin D. Gvozdev, Vladimir M. Promyslov, Mikhail P. Egorov and Oleg M. Nefedov pp 14688–14698 DOI: 10.1021/ja901508c Supporting Info |
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Molecularly Imprinted Microgels as Enzyme Inhibitors Arnaud Cutivet, Carol Schembri, Jose Kovensky and Karsten Haupt pp 14699–14702 DOI: 10.1021/ja901600e Supporting Info |
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Computational Studies of the Relative Rates for Migratory Insertions of Alkenes into Square-Planar, Methyl, −Amido, and −Hydroxo Complexes of Rhodium Jesse W. Tye and John F. Hartwig pp 14703–14712 DOI: 10.1021/ja901945b Supporting Info |
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Insight into CH4 Formation in Iron-Catalyzed Fischer−Tropsch Synthesis Chun-Fang Huo, Yong-Wang Li, Jianguo Wang and Haijun Jiao pp 14713–14721 DOI: 10.1021/ja9021864 Supporting Info |
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Electrophile Affinity: A Reactivity Measure for Aromatic Substitution Gergana Koleva, Boris Galabov, Judy I. Wu, Henry F. Schaefer III and Paul von R. Schleyer pp 14722–14727 DOI: 10.1021/ja902194y Supporting Info |
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Supramolecular Aggregation of Inorganic Molecules at Au(111) Electrodes under a Strong Ionic Atmosphere Yong-Chun Fu, Yu-Zhuan Su, De-Yin Wu, Jia-Wei Yan, Zhao-Xiong Xie and Bing-Wei Mao pp 14728–14737 DOI: 10.1021/ja902373q Supporting Info |
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Small and Stable Peptidic PEGylated Quantum Dots to Target Polyhistidine-Tagged Proteins with Controlled Stoichiometry Aur pp 14738–14746 DOI: 10.1021/ja902743u Supporting Info |
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Computational and Experimental Analyses Converge to Reveal a Coherent Yet Malleable Aptamer Structure That Controls Chemical Reactivity Tianjiao Wang, Julie A. Hoy, Monica H. Lamm and Marit Nilsen-Hamilton pp 14747–14755 DOI: 10.1021/ja902719q Supporting Info |
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Adsorption/Desorption of Hydrogen on Pt Nanoelectrodes: Evidence of Surface Diffusion and Spillover Dongping Zhan, Jeyavel Velmurugan and Michael V. Mirkin pp 14756–14760 DOI: 10.1021/ja902876v |
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DOTA-M8: An Extremely Rigid, High-Affinity Lanthanide Chelating Tag for PCS NMR Spectroscopy Daniel H pp 14761–14767 DOI: 10.1021/ja903233w Supporting Info |
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Influence of Amorphous Silica Matrices on the Formation, Structure, and Chemistry of Iron and Iron Oxide Nanoparticles Dehipalawage Sunil, Jinquan Dong and Harry D. Gafney pp 14768–14777 DOI: 10.1021/ja9031874 |
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Interaction of ClO Radical with Liquid Water Shiyu Du, Joseph S. Francisco, Gregory K. Schenter and Bruce C. Garrett pp 14778–14785 DOI: 10.1021/ja9033186 Supporting Info |
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Conformational Flexibility of Soluble Cellulose Oligomers: Chain Length and Temperature Dependence Tongye Shen, Paul Langan, Alfred D. French, Glenn P. Johnson and S. Gnanakaran pp 14786–14794 DOI: 10.1021/ja9034158 |
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Facile Synthesis of Polyester Dendrimers from Sequential Click Coupling of Asymmetrical Monomers Xinpeng Ma, Jianbin Tang, Youqing Shen, Maohong Fan, Huadong Tang and Maciej Radosz pp 14795–14803 DOI: 10.1021/ja9037406 Supporting Info |
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Human Insulin-Degrading Enzyme Working Mechanism Orazio Amata, Tiziana Marino, Nino Russo and Marirosa Toscano pp 14804–14811 DOI: 10.1021/ja9037142 Supporting Info |
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Total Synthesis and Biological Evaluation of (+)- and (−)-Bisanthraquinone Antibiotic BE-43472B and Related Compounds K. C. Nicolaou, Jochen Becker, Yee Hwee Lim, Alexandre Lemire, Thomas Neubauer and Ana Montero pp 14812–14826 DOI: 10.1021/ja9073694 Supporting Info |
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Evolving a Polymerase for Hydrophobic Base Analogues David Loakes, Jos pp 14827–14837 DOI: 10.1021/ja9039696 Supporting Info |
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Structural Basis for Catalytic Activation of Thiocyanate Hydrolase Involving Metal-Ligated Cysteine Modification Takatoshi Arakawa, Yoshiaki Kawano, Yoko Katayama, Hiroshi Nakayama, Naoshi Dohmae, Masafumi Yohda and Masafumi Odaka pp 14838–14843 DOI: 10.1021/ja903979s |
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Single Molecule Nanocontainers Made Porous Using a Bacterial Toxin Burak Okumus, Sinan Arslan, Stephanus M. Fengler, Sua Myong and Taekjip Ha pp 14844–14849 DOI: 10.1021/ja9042356 Supporting Info |
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Morphology and Melting Behavior of Ionic Liquids inside Single-Walled Carbon Nanotubes Shimou Chen, Keita Kobayashi, Yasumitsu Miyata, Naoki Imazu, Takeshi Saito, Ryo Kitaura and Hisanori Shinohara pp 14850–14856 DOI: 10.1021/ja904283d Supporting Info |
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Conductance Enhancement in Nanographene−Gold Junctions by Molecular π-Stacking pp 14857–14867 DOI: 10.1021/ja904372d Supporting Info |
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Primary Photoinduced Protein Response in Bacteriorhodopsin and Sensory Rhodopsin II Ruth Gross, Matthias M. N. Wolf, Christian Schumann, Noga Friedman, Mordechai Sheves, Lin Li, Martin Engelhard, Oliver Trentmann, H. Ekkehard Neuhaus and Rolf Diller pp 14868–14878 DOI: 10.1021/ja904218n Supporting Info |
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Direct Observation of Bifunctional Electrocatalysis during CO Oxidation at Ruθ=0.37/Pt{111} Surfaces via Surface Stress Measurements Larry L. Mickelson and Cody Friesen pp 14879–14884 DOI: 10.1021/ja904432c Supporting Info |
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A Combined QM/MM Study on the Reductive Half-Reaction of Xanthine Oxidase: Substrate Orientation and Mechanism Sebastian Metz and Walter Thiel pp 14885–14902 DOI: 10.1021/ja9045394 Supporting Info |
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Addition of Methyl Triflate to a Hafnocene Dinitrogen Complex: Stepwise N2 Methylation and Conversion to a Hafnocene Hydrazonato Compound Donald J. Knobloch, David Benito-Garagorri, Wesley H. Bernskoetter, Ivan Keresztes, Emil Lobkovsky, Hannah Toomey and Paul J. Chirik pp 14903–14912 DOI: 10.1021/ja904436a Supporting Info |
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Deprotection, Tethering, and Activation of a One-Legged Metalloporphyrin on a Chemically Active Metal Surface: NEXAFS, Synchrotron XPS, and STM Study of [SAc]P−Mn(III)Cl on Ag(100) Mark Turner, Owain P. H. Vaughan, Georgios Kyriakou, David J. Watson, Lukas J. Scherer, Anthoula C. Papageorgiou, Jeremy K. M. Sanders and Richard M. Lambert pp 14913–14919 DOI: 10.1021/ja904664e Supporting Info |
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Grafting Oligothiophenes on Surfaces by Diazonium Electroreduction: A Step toward Ultrathin Junction with Well-Defined Metal/Oligomer Interface Verena Stockhausen, Jalal Ghilane, Pascal Martin, Gaelle Tripp pp 14920–14927 DOI: 10.1021/ja9047009 |
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Importance of Charge Independent Effects in Readout of the Trimethyllysine Mark by HP1 Chromodomain Zhenyu Lu, Jonathan Lai and Yingkai Zhang pp 14928–14931 DOI: 10.1021/ja904951t Supporting Info |
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Interplay of Structure, Hydration and Thermal Stability in Formacetal Modified Oligonucleotides: RNA May Tolerate Nonionic Modifications Better than DNA Andrej Kolarovic, Emma Schweizer, Emily Greene, Mark Gironda, Pradeep S. Pallan, Martin Egli and Eriks Rozners pp 14932–14937 DOI: 10.1021/ja904926e Supporting Info |
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K3 Fragment of Amyloidogenic β2-Microglobulin Forms Ion Channels: Implication for Dialysis Related Amyloidosis Mirela Mustata, Ricardo Capone, Hyunbum Jang, Fernando Teran Arce, Srinivasan Ramachandran, Ratnesh Lal and Ruth Nussinov pp 14938–14945 DOI: 10.1021/ja9049299 |
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Dehydrocoupling Reactions of Borane−Secondary and −Primary Amine Adducts Catalyzed by Group-6 Carbonyl Complexes: Formation of Aminoboranes and Borazines Yasuro Kawano, Mikio Uruichi, Mamoru Shimoi, Seitaro Taki, Takayuki Kawaguchi, Taeko Kakizawa and Hiroshi Ogino pp 14946–14957 DOI: 10.1021/ja904918u Supporting Info |
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Redox-Active Metallomacrocycles and Cyclic Metallopolymers: Photocontrolled Ring-Opening Oligomerization and Polymerization of Silicon-Bridged [1]Ferrocenophanes Using Substitutionally-Labile Lewis Bases as Initiators David E. Herbert, Joe B. Gilroy, Wing Yan Chan, Laurent Chabanne, Anne Staubitz, Alan J. Lough and Ian Manners pp 14958–14968 DOI: 10.1021/ja904928c Supporting Info |
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Electron-Transfer Processes in Metal-Free Tetraferrocenylporphyrin. Understanding Internal Interactions To Access Mixed-Valence States Potentially Useful for Quantum Cellular Automata Victor N. Nemykin, Gregory T. Rohde, Christopher D. Barrett, Ryan G. Hadt, Claudia Bizzarri, Pierluca Galloni, Barbara Floris, Israel Nowik, Rolfe H. Herber, Andrea G. Marrani, Robertino Zanoni and Nikolay M. Loim pp 14969–14978 DOI: 10.1021/ja905310h Supporting Info |
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Electrochemical Kinetic Investigations of the Reactions of [FeFe]-Hydrogenases with Carbon Monoxide and Oxygen: Comparing the Importance of Gas Tunnels and Active-Site Electronic/Redox Effects Gabrielle Goldet, Caterina Brandmayr, Sven T. Stripp, Thomas Happe, Christine Cavazza, Juan C. Fontecilla-Camps and Fraser A. Armstrong pp 14979–14989 DOI: 10.1021/ja905388j Supporting Info |
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Managing Highly Coordinative Substrates in Asymmetric Catalysis: A Catalytic Asymmetric Amination with a Lanthanum-Based Ternary Catalyst Tomoyuki Mashiko, Naoya Kumagai and Masakatsu Shibasaki pp 14990–14999 DOI: 10.1021/ja9052653 Supporting Info |
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Micron-Sized Main-Chain Liquid Crystalline Elastomer Actuators with Ultralarge Amplitude Contractions Hong Yang, Axel Buguin, Jean-Marie Taulemesse, Kosuke Kaneko, St pp 15000–15004 DOI: 10.1021/ja905363f Supporting Info |
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Counterion Atmosphere and Hydration Patterns near a Nucleosome Core Particle Christopher K. Materese, Alexey Savelyev and Garegin A. Papoian pp 15005–15013 DOI: 10.1021/ja905376q |
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Patterns of Diacetylene-Containing Peptide Amphiphiles Using Polarization Holography Maaike van den Heuvel, An M. Prenen, Jeroen C. Gielen, Peter C. M. Christianen, Dick J. Broer, Dennis W. P. M. L pp 15014–15017 DOI: 10.1021/ja9054756 Supporting Info |
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Time-Resolved X-ray Diffraction of the Photochromic α-Styrylpyrylium Trifluoromethanesulfonate Crystal Films Reveals Ultrafast Structural Switching J pp 15018–15025 DOI: 10.1021/ja905484u Supporting Info |
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McMurry Chemistry on TiO2(110): Reductive C═C Coupling of Benzaldehyde Driven by Titanium Interstitials Lauren Benz, Jan Haubrich, Ryan G. Quiller, Stephen C. Jensen and Cynthia M. Friend pp 15026–15031 DOI: 10.1021/ja905522c |
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Practical Access to Amines by Platinum-Catalyzed Reduction of Carboxamides with Hydrosilanes: Synergy of Dual Si−H Groups Leads to High Efficiency and Selectivity Shiori Hanada, Emi Tsutsumi, Yukihiro Motoyama and Hideo Nagashima pp 15032–15040 DOI: 10.1021/ja9055307 Supporting Info |
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Abrasion as a Catalyst Deposition Technique for Carbon Nanotube Growth Noe T. Alvarez, Cary L. Pint, Robert H. Hauge and James M. Tour pp 15041–15048 DOI: 10.1021/ja905681a Supporting Info |
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Electric-Field-Induced Charge-Transfer Phase Transition: A Promising Approach Toward Electrically Switchable Devices Tarik Mahfoud, G pp 15049–15054 DOI: 10.1021/ja9055855 Supporting Info |
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Spontaneous Chirality Induction and Enantiomer Separation in Liquid Crystals Composed of Achiral Rod-Shaped 4-Arylbenzoate Esters Hyeon Su Jeong, Shingo Tanaka, Dong Ki Yoon, Suk-Won Choi, Yun Ho Kim, Susumu Kawauchi, Fumito Araoka, Hideo Takezoe and Hee-Tae Jung pp 15055–15060 DOI: 10.1021/ja905785d Supporting Info |
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Total Synthesis and Stereochemical Assignment of (−)-Ushikulide A Barry M. Trost, Brendan M. O’Boyle and Daniel Hund pp 15061–15074 DOI: 10.1021/ja906056v Supporting Info |
Issue 42
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Diverse Chemical Applications of N-Heterocyclic Carbenes William D. Jones pp 15075–15077 DOI: 10.1021/ja908253u |
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Vitamin B12 and Redox Homeostasis: Cob(II)alamin Reacts with Superoxide at Rates Approaching Superoxide Dismutase (SOD) Edward Suarez-Moreira, June Yun, Catherine S. Birch, John H. H. Williams, Andrew McCaddon and Nicola E. Brasch pp 15078–15079 DOI: 10.1021/ja904670x Supporting Info |
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Facile Synthesis of 1,2,4-Triazoles via a Copper-Catalyzed Tandem Addition−Oxidative Cyclization Satoshi Ueda and Hideko Nagasawa pp 15080–15081 DOI: 10.1021/ja905056z Supporting Info |
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Potassium−Lead-Switched G-Quadruplexes: A New Class of DNA Logic Gates Tao Li, Erkang Wang and Shaojun Dong pp 15082–15083 DOI: 10.1021/ja9051075 Supporting Info |
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Disordered Tails of Homeodomains Facilitate DNA Recognition by Providing a Trade-Off between Folding and Specific Binding pp 15084–15085 DOI: 10.1021/ja9052784 Supporting Info |
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1H and 13C Dynamic Nuclear Polarization in Aqueous Solution with a Two-Field (0.35 T/14 T) Shuttle DNP Spectrometer Marcel Reese, Maria-Teresa T pp 15086–15087 DOI: 10.1021/ja905959n Supporting Info |
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Ring-Opening Polymerization of l-Lactide Efficiently Triggered by an Amido-Indole. X-ray Structure of a Complex between l-Lactide and the Hydrogen-Bonding Organocatalyst Sylvain Koeller, Joji Kadota, Alain Deffieux, Fr pp 15088–15089 DOI: 10.1021/ja906119t Supporting Info |
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Ring-Closing Metathesis of Allylsilanes/Electrophilic Desilylation To Prepare exo-Methylidenecycloalkanes. Short Syntheses of Teucladiol and Poitediol Matthew S. Dowling and Christopher D. Vanderwal pp 15090–15091 DOI: 10.1021/ja906241w Supporting Info |
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An Olefination via Ruthenium-Catalyzed Decarbonylative Addition of Aldehydes to Terminal Alkynes Xiangyu Guo, Jun Wang and Chao-Jun Li pp 15092–15093 DOI: 10.1021/ja906265a Supporting Info |
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In-Plane and Out-of-Plane Infrared Difference Spectroscopy Unravels Tilting of Helices and Structural Changes in a Membrane Protein upon Substrate Binding V pp 15094–15095 DOI: 10.1021/ja906324z Supporting Info |
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A Click Chemistry Mediated in Vivo Activity Probe for Dimethylarginine Dimethylaminohydrolase Yun Wang, Shougang Hu and Walter Fast pp 15096–15097 DOI: 10.1021/ja906432e Supporting Info |
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Rechargeable Ni-Li Battery Integrated Aqueous/Nonaqueous System Huiqiao Li, Yonggang Wang, Haitao Na, Haimei Liu and Haoshen Zhou pp 15098–15099 DOI: 10.1021/ja906529g Supporting Info |
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Templating Odd Numbered Magnetic Rings: Oxovanadium Heptagons Sandwiched by β-Cyclodextrins Norihisa Hoshino, Motohiro Nakano, Hiroyuki Nojiri, Wolfgang Wernsdorfer and Hiroki Oshio pp 15100–15101 DOI: 10.1021/ja9066496 Supporting Info |
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Divalent Metal Ion Triggered Activity of a Synthetic Antimicrobial in Cardiolipin Membranes Abhigyan Som, Lihua Yang, Gerard C. L. Wong and Gregory N. Tew pp 15102–15103 DOI: 10.1021/ja9067063 Supporting Info |
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Characterization of the N-Terminal Tail Domain of Histone H3 in Condensed Nucleosome Arrays by Hydrogen Exchange and NMR Hidenori Kato, James Gruschus, Rodolfo Ghirlando, Nico Tjandra and Yawen Bai pp 15104–15105 DOI: 10.1021/ja9070078 Supporting Info |
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Synthesis of ZnO Hexagonal Single-Crystal Slices with Predominant (0001) and (000 Xiaoheng Liu, Mohammad Afzaal, Karthik Ramasamy, Paul O’Brien and Javeed Akhtar pp 15106–15107 DOI: 10.1021/ja906992s Supporting Info |
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Efficient One-Pot Synthesis of 2,3-Dihydropyrimidinthiones via Multicomponent Coupling of Terminal Alkynes, Elemental Sulfur, and Carbodiimides Zitao Wang, Yang Wang, Wen-Xiong Zhang, Zhaomin Hou and Zhenfeng Xi pp 15108–15109 DOI: 10.1021/ja9069419 Supporting Info |
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Lewis Acid-Mediated β-Hydride Abstraction Reactions of Divalent M(C(SiHMe2)3)2THF2 (M = Ca, Yb) KaKing Yan, Brianna M. Upton, Arkady Ellern and Aaron D. Sadow pp 15110–15111 DOI: 10.1021/ja9070865 Supporting Info |
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Regioselective Unsymmetrical Tetraallylation of C60 through Palladium Catalysis Masakazu Nambo, Atsushi Wakamiya, Shigehiro Yamaguchi and Kenichiro Itami pp 15112–15113 DOI: 10.1021/ja9071173 Supporting Info |
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Structure and Reactivity of Alkyne-Chelated Ruthenium Alkylidene Complexes Kung-Pern Wang, Sang Young Yun, Daesung Lee and Donald J. Wink pp 15114–15115 DOI: 10.1021/ja907155r Supporting Info |
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Cs2K(UO)2Si4O12: A Mixed-Valence Uranium(IV,V) Silicate Cheng-Shiuan Lee, Sue-Lein Wang and Kwang-Hwa Lii pp 15116–15117 DOI: 10.1021/ja9071805 Supporting Info |
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Dual-Activation Asymmetric Strecker Reaction of Aldimines and Ketimines Catalyzed by a Tethered Bis(8-quinolinolato) Aluminum Complex Joshua P. Abell and Hisashi Yamamoto pp 15118–15119 DOI: 10.1021/ja907268g Supporting Info |
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Synthesis and Hydrogen Storage Properties of Be12(OH)12(1,3,5-benzenetribenzoate)4 Kenji Sumida, Matthew R. Hill, Satoshi Horike, Anne Dailly and Jeffrey R. Long pp 15120–15121 DOI: 10.1021/ja9072707 Supporting Info |
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Reversible Self-Assembly of Entrapped Fluorescent Gelators in Polymerized Styrene Gel Matrix: Erasable Thermal Imaging via Recreation of Supramolecular Architectures Sampath Srinivasan, Palathingal A. Babu, Sankarapillai Mahesh and Ayyappanpillai Ajayaghosh pp 15122–15123 DOI: 10.1021/ja9072035 Supporting Info |
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Meso-Unsubstituted Iron Corrole in Hemoproteins: Remarkable Differences in Effects on Peroxidase Activities between Myoglobin and Horseradish Peroxidase Takashi Matsuo, Akihiro Hayashi, Masato Abe, Takaaki Matsuda, Yoshio Hisaeda and Takashi Hayashi pp 15124–15125 DOI: 10.1021/ja907428e Supporting Info |
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Remarkably Stable Chalcogen(II) Dications Caleb D. Martin, Christine M. Le and Paul J. Ragogna pp 15126–15127 DOI: 10.1021/ja9073968 Supporting Info |
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Multiresponsive Supramolecular Nanogated Ensembles Rui Liu, Ying Zhang and Pingyun Feng pp 15128–15129 DOI: 10.1021/ja905288m Supporting Info |
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Characterization of Water Wires inside Hydrophobic Tubular Peptide Structures Upadhyayula S. Raghavender, Subrayashastry Aravinda, Narayanaswamy Shamala, Kantharaju, Rajkishor Rai and Padmanabhan Balaram pp 15130–15132 DOI: 10.1021/ja9038906 Supporting Info |
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DFT Study of Hydrogen Storage by Spillover on Graphite with Oxygen Surface Groups George M. Psofogiannakis and George E. Froudakis pp 15133–15135 DOI: 10.1021/ja906159p |
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Controlled-Access Hollow Mechanized Silica Nanocontainers Li Du, Shijun Liao, Hussam A. Khatib, J. Fraser Stoddart and Jeffrey I. Zink pp 15136–15142 DOI: 10.1021/ja904982j Supporting Info |
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Anchoring of Rare-Earth-Based Single-Molecule Magnets on Single-Walled Carbon Nanotubes Svetlana Kyatskaya, Jos pp 15143–15151 DOI: 10.1021/ja906165e Supporting Info |
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Lag Periods During the Self-Assembly of {Mo72Fe30} Macroions: Connection to the Virus Capsid Formation Process Jie Zhang, Dong Li, Guang Liu, Kerney Jebrell Glover and Tianbo Liu pp 15152–15159 DOI: 10.1021/ja903548m Supporting Info |
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6-s-cis Conformation and Polar Binding Pocket of the Retinal Chromophore in the Photoactivated State of Rhodopsin Shivani Ahuja, Markus Eilers, Amiram Hirshfeld, Elsa C. Y. Yan, Martine Ziliox, Thomas P. Sakmar, Mordechai Sheves and Steven O. Smith pp 15160–15169 DOI: 10.1021/ja9034768 |
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Synthesis of a Nitrogen-Stabilized Hexagonal Re3ZnNx Phase Using High Pressures and Temperatures George Serghiou, Christophe L. Guillaume, Andrew Thomson, Jean-Paul Morniroli and Dan J. Frost pp 15170–15175 DOI: 10.1021/ja903976j |
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The Ru−Hbpp Water Oxidation Catalyst Fernando Bozoglian, Sophie Romain, Mehmed Z. Ertem, Tanya K. Todorova, Cristina Sens, Joaquim Mola, Montserrat Rodr pp 15176–15187 DOI: 10.1021/ja9036127 Supporting Info |
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Hydrogen Bonding of β-Turn Structure Is Stabilized in D2O Younhee Cho, Laura B. Sagle, Satoshi Iimura, Yanjie Zhang, Jaibir Kherb, Ashutosh Chilkoti, J. Martin Scholtz and Paul S. Cremer pp 15188–15193 DOI: 10.1021/ja9040785 Supporting Info |
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Stability of Asymmetric Lipid Bilayers Assessed by Molecular Dynamics Simulations Santi Esteban-Mart pp 15194–15202 DOI: 10.1021/ja904450t Supporting Info |
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Rh(II)-Catalyzed Skeletal Reorganization of 1,6- and 1,7-Enynes through Electrophilic Activation of Alkynes Kazusa Ota, Sang Ick Lee, Jhih-Meng Tang, Manabu Takachi, Hiromi Nakai, Tsumoru Morimoto, Hitoshi Sakurai, Ken Kataoka and Naoto Chatani pp 15203–15211 DOI: 10.1021/ja9047637 Supporting Info |
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Activation of the S−H Group in Fe(μ2-SH)Fe Clusters: S−H Bond Strengths and Free Radical Reactivity of the Fe(μ2-SH)Fe Cluster James A. Franz, Suh-Jane Lee, Thomas A. Bowden, Mikhail S. Alnajjar, Aaron M. Appel, Jerome C. Birnbaum, Thomas E. Bitterwolf and Michel Dupuis pp 15212–15224 DOI: 10.1021/ja904602p Supporting Info |
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DNA Interstrand Cross-Link Formation by the 1,4-Dioxobutane Abasic Lesion Lirui Guan and Marc M. Greenberg pp 15225–15231 DOI: 10.1021/ja9061695 Supporting Info |
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Excited States Decay of the A−T DNA: A PCM/TD-DFT Study in Aqueous Solution of the (9-Methyl-adenine)2·(1-methyl-thymine)2 Stacked Tetramer F. Santoro, V. Barone and R. Improta pp 15232–15245 DOI: 10.1021/ja904777h Supporting Info |
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Pulsed Electron−Electron Double-Resonance Determination of Spin-Label Distances and Orientations on the Tetrameric Potassium Ion Channel KcsA Burkhard Endeward, Joel A. Butterwick, Roderick MacKinnon and Thomas F. Prisner pp 15246–15250 DOI: 10.1021/ja904808n |
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Simultaneous Determination of Gene Expression and Enzymatic Activity in Individual Bacterial Cells in Microdroplet Compartments Jung-uk Shim, Luis F. Olguin, Graeme Whyte, Duncan Scott, Ann Babtie, Chris Abell, Wilhelm T. S. Huck and Florian Hollfelder pp 15251–15256 DOI: 10.1021/ja904823z Supporting Info |
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Design, Synthesis, and Testing of Difluoroboron-Derivatized Curcumins as Near-Infrared Probes for in Vivo Detection of Amyloid-β Deposits Chongzhao Ran, Xiaoyin Xu, Scott B. Raymond, Brian J. Ferrara, Krista Neal, Brian J. Bacskai, Zdravka Medarova and Anna Moore pp 15257–15261 DOI: 10.1021/ja9047043 Supporting Info |
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Structural Basis of the Inhibition of Class A β-Lactamases and Penicillin-Binding Proteins by 6-β-Iodopenicillanate Eric Sauvage, Astrid Zervosen, Georges Dive, Raphael Herman, Ana Amoroso, Bernard Joris, Eveline Fonz pp 15262–15269 DOI: 10.1021/ja9051526 Supporting Info |
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Disentangling Eumelanin “Black Chromophore”: Visible Absorption Changes As Signatures of Oxidation State- and Aggregation-Dependent Dynamic Interactions in a Model Water-Soluble 5,6-Dihydroxyindole Polymer Alessandro Pezzella, Alfonso Iadonisi, Silvia Valerio, Lucia Panzella, Alessandra Napolitano, Matteo Adinolfi and Marco d’Ischia pp 15270–15275 DOI: 10.1021/ja905162s Supporting Info |
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Lanthanide-Containing Polymer Microspheres by Multiple-Stage Dispersion Polymerization for Highly Multiplexed Bioassays Ahmed I. Abdelrahman, Sheng Dai, Stuart C. Thickett, Olga Ornatsky, Dmitry Bandura, Vladimir Baranov and Mitchell A. Winnik pp 15276–15283 DOI: 10.1021/ja9052009 Supporting Info |
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An Autoinhibited Coiled-Coil Design Strategy for Split-Protein Protease Sensors Sujan S. Shekhawat, Jason R. Porter, Akshay Sriprasad and Indraneel Ghosh pp 15284–15290 DOI: 10.1021/ja9050857 Supporting Info |
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Impacts of the Location and Number of [Cu(bpy)2]2+ Cross-Links on the Emission Photodynamics of [Ru(bpy)3]2+ with Pendant Oligo(aminoethylglycine) Chains Carl P. Myers, James R. Miller and Mary Elizabeth Williams pp 15291–15300 DOI: 10.1021/ja905493x Supporting Info |
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Highly Enantioselective Organocatalytic Biginelli and Biginelli-Like Condensations: Reversal of the Stereochemistry by Tuning the 3,3′-Disubstituents of Phosphoric Acids Nan Li, Xiao-Hua Chen, Jin Song, Shi-Wei Luo, Wu Fan and Liu-Zhu Gong pp 15301–15310 DOI: 10.1021/ja905320q Supporting Info |
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An Electrochemical Sensor for Single Nucleotide Polymorphism Detection in Serum Based on a Triple-Stem DNA Probe Yi Xiao, Xinhui Lou, Takanori Uzawa, Kory J. I. Plakos, Kevin W. Plaxco and H. Tom Soh pp 15311–15316 DOI: 10.1021/ja905068s Supporting Info |
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Enzymatic Tailoring of Ornithine in the Biosynthesis of the Rhizobium Cyclic Trihydroxamate Siderophore Vicibactin John R. Heemstra, Jr., Christopher T. Walsh and Elizabeth S. Sattely pp 15317–15329 DOI: 10.1021/ja9056008 Supporting Info |
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Homogeneous Deposition of Platinum Nanoparticles on Carbon Black for Proton Exchange Membrane Fuel Cell Baizeng Fang, Nitin K. Chaudhari, Min-Sik Kim, Jung Ho Kim and Jong-Sung Yu pp 15330–15338 DOI: 10.1021/ja905749e Supporting Info |
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Speeding Up 13C Direct Detection Biomolecular NMR Spectroscopy Wolfgang Bermel, Ivano Bertini, Isabella C. Felli and Roberta Pierattelli pp 15339–15345 DOI: 10.1021/ja9058525 Supporting Info |
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FePt Nanoparticles as an Fe Reservoir for Controlled Fe Release and Tumor Inhibition Chenjie Xu, Zhenglong Yuan, Nathan Kohler, Jaemin Kim, Maureen A. Chung and Shouheng Sun pp 15346–15351 DOI: 10.1021/ja905938a Supporting Info |
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Abasic Site-Containing DNAzyme and Aptamer for Label-Free Fluorescent Detection of Pb2+ and Adenosine with High Sensitivity, Selectivity, and Tunable Dynamic Range Yu Xiang, Aijun Tong and Yi Lu pp 15352–15357 DOI: 10.1021/ja905854a Supporting Info |
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Mechanism of Amido-Thiourea Catalyzed Enantioselective Imine Hydrocyanation: Transition State Stabilization via Multiple Non-Covalent Interactions Stephan J. Zuend and Eric N. Jacobsen pp 15358–15374 DOI: 10.1021/ja9058958 Supporting Info |
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Phase Selection and Energetics in Chiral Alkaline Earth Tartrates and Their Racemic and Meso Analogues: Synthetic, Structural, Computational, and Calorimetric Studies Leah N. Appelhans, Monica Kosa, A. V. Radha, Petra Simoncic, Alexandra Navrotsky, Michele Parrinello and Anthony K. Cheetham pp 15375–15386 DOI: 10.1021/ja905690t Supporting Info |
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Toolbox Approach to the Search for Effective Ligands for Catalytic Asymmetric Cr-Mediated Coupling Reactions Haibing Guo, Cheng-Guo Dong, Dae-Shik Kim, Daisuke Urabe, Jiashi Wang, Joseph T. Kim, Xiang Liu, Takeo Sasaki and Yoshito Kishi pp 15387–15393 DOI: 10.1021/ja905843e Supporting Info |
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Efficient Functionalization of Carbon Nanotubes with Porphyrin Dendrons via Click Chemistry Thomas Palacin, Hung Le Khanh, Bruno Jousselme, Pascale Jegou, Arianna Filoramo, Christian Ehli, Dirk M. Guldi and St pp 15394–15402 DOI: 10.1021/ja906020e Supporting Info |
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Energetics of Displacing Water Molecules from Protein Binding Sites: Consequences for Ligand Optimization Julien Michel, Julian Tirado-Rives and William L. Jorgensen pp 15403–15411 DOI: 10.1021/ja906058w Supporting Info |
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Coordination-Mode Control of Bound Nitrile Radical Complex Reactivity: Intercepting End-on Nitrile−Mo(III) Radicals at Low Temperature Meaghan E. Germain, Manuel Temprado, Annie Castonguay, Olga P. Kryatova, Elena V. Rybak-Akimova, John J. Curley, Arjun Mendiratta, Yi-Chou Tsai, Christopher C. Cummins, Rajeev Prabhakar, James E. McDonough and Carl D. Hoff pp 15412–15423 DOI: 10.1021/ja905849a Supporting Info |
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Laboratory Evolution of Robust and Enantioselective Baeyer−Villiger Monooxygenases for Asymmetric Catalysis Manfred T. Reetz and Sheng Wu pp 15424–15432 DOI: 10.1021/ja906212k Supporting Info |
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Aromatic Expanded Isophlorins: Stable 30π Annulene Analogues with Diverse Structural Features J. Sreedhar Reddy and Venkataramanarao G. Anand pp 15433–15439 DOI: 10.1021/ja906290d Supporting Info |
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Monomeric and Oligomeric Amine−Borane σ-Complexes of Rhodium. Intermediates in the Catalytic Dehydrogenation of Amine−Boranes Thomas M. Douglas, Adrian B. Chaplin, Andrew S. Weller, Xinzheng Yang and Michael B. Hall pp 15440–15456 DOI: 10.1021/ja906070r Supporting Info |
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Nucleation Kinetics vs Chemical Kinetics in the Initial Formation of Semiconductor Nanocrystals Renguo Xie, Zheng Li and Xiaogang Peng pp 15457–15466 DOI: 10.1021/ja9063102 Supporting Info |
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Studies on the Mechanism, Selectivity, and Synthetic Utility of Lactone Reduction Using SmI2 and H2O Dixit Parmar, Lorna A. Duffy, Dhandapani V. Sadasivam, Hiroshi Matsubara, Paul A. Bradley, Robert A. Flowers, II and David J. Procter pp 15467–15473 DOI: 10.1021/ja906396u Supporting Info |
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Effects of Terminal Functional Groups on the Stability of the Polyproline II Structure: A Combined Experimental and Theoretical Study Michael Kuemin, Sabine Schweizer, Christian Ochsenfeld and Helma Wennemers pp 15474–15482 DOI: 10.1021/ja906466q Supporting Info |
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Ab Initio Nonadiabatic Molecular Dynamics of Wet-Electrons on the TiO2 Surface Sean A. Fischer, Walter R. Duncan and Oleg V. Prezhdo pp 15483–15491 DOI: 10.1021/ja906599b |
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Synthesis of Highly Enantioenriched 3,4-Dihydroquinolin-2-ones by 6-Exo-trig Radical Cyclizations of Axially Chiral α-Halo-ortho-alkenyl Anilides David B. Guthrie, Steven J. Geib and Dennis P. Curran pp 15492–15500 DOI: 10.1021/ja9066282 Supporting Info |
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Properties and Reactivity Patterns of AsP3: An Experimental and Computational Study of Group 15 Elemental Molecules Brandi M. Cossairt and Christopher C. Cummins pp 15501–15511 DOI: 10.1021/ja906294m Supporting Info |
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Homoleptic Uranium(IV) Alkyl Complexes: Synthesis and Characterization Skye Fortier, Brent C. Melot, Guang Wu and Trevor W. Hayton pp 15512–15521 DOI: 10.1021/ja906516e Supporting Info |
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Detecting Vascular Biosignatures with a Colloidal, Radio-Opaque Polymeric Nanoparticle Dipanjan Pan, Todd A. Williams, Angana Senpan, John S. Allen, Mike J. Scott, Patrick J. Gaffney, Samuel A. Wickline and Gregory M. Lanza pp 15522–15527 DOI: 10.1021/ja906797z Supporting Info |
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Unique Sandwich Stacking of Pyrene-Adenine-Pyrene for Selective and Ratiometric Fluorescent Sensing of ATP at Physiological pH Zhaochao Xu, N. Jiten Singh, Jeesun Lim, Jie Pan, Ha Na Kim, Sungsu Park, Kwang S. Kim and Juyoung Yoon pp 15528–15533 DOI: 10.1021/ja906855a Supporting Info |
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HIV-1 Nucleocapsid Protein Bends Double-Stranded Nucleic Acids Hui Wang, Yu-Shan Yeh and Paul F. Barbara pp 15534–15543 DOI: 10.1021/ja9070046 Supporting Info |
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Surface and Bulk Aspects of Mixed Oxide Catalytic Nanoparticles: Oxidation and Dehydration of CH3OH by Polyoxometallates Lingaiah Nakka, Julie E. Molinari and Israel E. Wachs pp 15544–15554 DOI: 10.1021/ja904957d Supporting Info |
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Hyperfine-Shifted 13C and 15N NMR Signals from Clostridium pasteurianum Rubredoxin: Extensive Assignments and Quantum Chemical Verification I-Jin Lin, Bin Xia, David S. King, Timothy E. Machonkin, William M. Westler and John L. Markley pp 15555–15563 DOI: 10.1021/ja905928x Supporting Info |
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Preparation of the Binary Technetium Bromides: TcBr3 and TcBr4 Frederic Poineau, Efrain E. Rodriguez, Paul M. Forster, Alfred P. Sattelberger, Anthony K. Cheetham and Kenneth R. Czerwinski p 15564 DOI: 10.1021/ja9070656 |
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Dendritic Molecular Switch: Chiral Folding and Helicity Inversion Xuan Jiang, Young-Kwan Lim, Bong June Zhang, Elizabeth A. Opsitnick, Mu-Hyun Baik and Dongwhan Lee p 15564 DOI: 10.1021/ja908024c |
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NMR Characterization of Fourth-Generation PAMAM Dendrimers in the Presence and Absence of Palladium Dendrimer-Encapsulated Nanoparticles M. Victoria Gomez, Javier Guerra, Aldrik H. Velders and Richard M. Crooks p 15564 DOI: 10.1021/ja907940x |
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Gold Chemistry: Applications and Future Directions in the Life Sciences Scott D. Bunge p 15565 DOI: 10.1021/ja907637d |
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Hybrid Methods of Molecular Modeling Darrin York pp 15565–15566 DOI: 10.1021/ja906876n |
Issue 43
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Low-Temperature, Highly Selective, Gas-Phase Oxidation of Benzyl Alcohol over Mesoporous K-Cu-TiO2 with Stable Copper(I) Oxidation State Jie Fan, Yihu Dai, Yunlong Li, Nanfeng Zheng, Junfang Guo, Xiaoqing Yan and Galen D. Stucky pp 15568–15569 DOI: 10.1021/ja9032499 Supporting Info |
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DNA Prism Structures Constructed by Folding of Multiple Rectangular Arms Masayuki Endo, Kumi Hidaka, Takayuki Kato, Keiichi Namba and Hiroshi Sugiyama pp 15570–15571 DOI: 10.1021/ja904252e Supporting Info |
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Formation of Osmium− and Ruthenium−Cyclobutylidene Complexes by Ring Expansion of Alkylidenecyclopropanes Ruth Castro-Rodrigo, Miguel A. Esteruelas, Sara Fuertes, Ana M. L pp 15572–15573 DOI: 10.1021/ja904893j Supporting Info |
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Mechanical Capping of Silica Nanotubes for Encapsulation of Molecules Jaeeun Yu, Xia Bai, Junghun Suh, Sang Bok Lee and Sang Jun Son pp 15574–15575 DOI: 10.1021/ja905485s Supporting Info |
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High-Contrast Visualization of Graphene Oxide on Dye-Sensitized Glass, Quartz, and Silicon by Fluorescence Quenching Emanuele Treossi, Manuela Melucci, Andrea Liscio, Massimo Gazzano, Paolo Samor pp 15576–15577 DOI: 10.1021/ja9055382 Supporting Info |
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Electrogenerated IrOx Nanoparticles as Dissolved Redox Catalysts for Water Oxidation Takaaki Nakagawa, Natalie S. Bjorge and Royce W. Murray pp 15578–15579 DOI: 10.1021/ja9063298 Supporting Info |
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Single-Site, Catalytic Water Oxidation on Oxide Surfaces Zuofeng Chen, Javier J. Concepcion, Jonah W. Jurss and Thomas J. Meyer pp 15580–15581 DOI: 10.1021/ja906391w Supporting Info |
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Reaction of a Redox-Active Ligand Complex of Nickel with Dioxygen Probes Ligand-Radical Character Tony D. Manuel and Jan-Uwe Rohde pp 15582–15583 DOI: 10.1021/ja9065943 Supporting Info |
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Revisiting AI-2 Quorum Sensing Inhibitors: Direct Comparison of Alkyl-DPD Analogues and a Natural Product Fimbrolide Colin A. Lowery, Takumi Abe, Junguk Park, Lisa M. Eubanks, Daisuke Sawada, Gunnar F. Kaufmann and Kim D. Janda pp 15584–15585 DOI: 10.1021/ja9066783 Supporting Info |
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Synthesis of a Low Band Gap Polymer and Its Application in Highly Efficient Polymer Solar Cells Jianhui Hou, Hsiang-Yu Chen, Shaoqing Zhang, Ruby I. Chen, Yang Yang, Yue Wu and Gang Li pp 15586–15587 DOI: 10.1021/ja9064975 Supporting Info |
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Lanthanide Germanate Cluster Organic Frameworks Constructed from {Ln8Ge12} or {Ln11Ge12} Cage Cluster Building Blocks Huan He, Gao-Juan Cao, Shou-Tian Zheng and Guo-Yu Yang pp 15588–15589 DOI: 10.1021/ja906735v Supporting Info |
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RDC Enhanced NMR Spectroscopy in Organic Solvent Media: The Importance for the Experimental Determination of Periodic Hydrogen Bonded Secondary Structures Marelli Udaya Kiran, Ambadi Sudhakar, Jochen Klages, Grit Kummerl pp 15590–15591 DOI: 10.1021/ja906796v Supporting Info |
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Zn-Mediated, Pd-Catalyzed Cross-Couplings in Water at Room Temperature Without Prior Formation of Organozinc Reagents Arkady Krasovskiy, Christophe Duplais and Bruce H. Lipshutz pp 15592–15593 DOI: 10.1021/ja906803t Supporting Info |
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Highly Efficient Reversible Z−E Photoisomerization of a Bridged Azobenzene with Visible Light through Resolved S1(nπ*) Absorption Bands Ron Siewertsen, Hendrikje Neumann, Bengt Buchheim-Stehn, Rainer Herges, Christian N pp 15594–15595 DOI: 10.1021/ja906547d Supporting Info |
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Chemical Labeling Strategy with (R)- and (S)-Trifluoromethylalanine for Solid State 19F NMR Analysis of Peptaibols in Membranes Daniel Maisch, Parvesh Wadhwani, Sergii Afonin, Christoph B pp 15596–15597 DOI: 10.1021/ja9067595 Supporting Info |
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Umpolung Amination: Nickel-Catalyzed Coupling Reactions of N,N-Dialkyl-N-chloroamines with Diorganozinc Reagents Timothy J. Barker and Elizabeth R. Jarvo pp 15598–15599 DOI: 10.1021/ja907038b Supporting Info |
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Compensation Doping in Conjugated Polymers: Engineering Dopable Heterojunctions for Modulating Conductivity in the Solid State G. M. Aminur Rahman, Jun-Hui Zhao, Douglas J. Thomson and Michael S. Freund pp 15600–15601 DOI: 10.1021/ja9070909 Supporting Info |
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High Performance Photodetectors of Individual InSe Single Crystalline Nanowire Jian-Jun Wang, Fei-Fei Cao, Lang Jiang, Yu-Guo Guo, Wen-Ping Hu and Li-Jun Wan pp 15602–15603 DOI: 10.1021/ja9072386 Supporting Info |
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High Rates and Substrate Selectivities in Water by Polyvinylimidazoles as Transaminase Enzyme Mimics with Hydrophobically Bound Pyridoxamine Derivatives as Coenzyme Mimics Rachid Skouta, Sujun Wei and Ronald Breslow pp 15604–15605 DOI: 10.1021/ja9072589 Supporting Info |
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Hydrogenolysis of Unstrained Carbon−Carbon σ Bonds: Stereoselective Entry into Benzylic Tertiary Centers Ashraf Wilsily, Yen Nguyen and Eric Fillion pp 15606–15607 DOI: 10.1021/ja9076815 Supporting Info |
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Phthalides by Rhodium-Catalyzed Ketone Hydroacylation Diem H. T. Phan, Byoungmoo Kim and Vy M. Dong pp 15608–15609 DOI: 10.1021/ja907711a Supporting Info |
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Stabilizing Zr and Ti Cations by Interaction With a Ferrocenyl Fragment Alberto Ramos, Edwin Otten and Douglas W. Stephan pp 15610–15611 DOI: 10.1021/ja9077446 Supporting Info |
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Spectroscopic Characterization of YedY: The Role of Sulfur Coordination in a Mo(V) Sulfite Oxidase Family Enzyme Form Jing Yang, Richard Rothery, Joseph Sempombe, Joel H. Weiner and Martin L. Kirk pp 15612–15614 DOI: 10.1021/ja903087k Supporting Info |
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Evidence for a Boroxinate Based Brønsted Acid Derivative of VAPOL as the Active Catalyst in the Catalytic Asymmetric Aziridination Reaction Gang Hu, Li Huang, Rui H. Huang and William D. Wulff pp 15615–15617 DOI: 10.1021/ja904589k Supporting Info |
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Oxidatively Induced Reductive Elimination from (tBu2bpy)Pd(Me)2: Palladium(IV) Intermediates in a One-Electron Oxidation Reaction Michael P. Lanci, Matthew S. Remy, Werner Kaminsky, James M. Mayer and Melanie S. Sanford pp 15618–15620 DOI: 10.1021/ja905816q Supporting Info |
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Zn−Zn Porphyrin Dimer-Sensitized Solar Cells: Toward 3-D Light Harvesting Attila J. Mozer, Matthew J. Griffith, George Tsekouras, Pawel Wagner, Gordon G. Wallace, Shogo Mori, Kenji Sunahara, Masanori Miyashita, John C. Earles, Keith C. Gordon, Luchao Du, Ryuzi Katoh, Akihiro Furube and David L. Officer pp 15621–15623 DOI: 10.1021/ja9057713 Supporting Info |
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Enantioselective Synthesis of 1,2,3-Trisubstituted Cyclopropanes Using gem-Dizinc Reagents Lucie E. Zimmer and Andr pp 15624–15626 DOI: 10.1021/ja906033g Supporting Info |
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Cleavage of sp3 C−O Bonds via Oxidative Addition of C−H Bonds Jongwook Choi, Yuriy Choliy, Xiawei Zhang, Thomas J. Emge, Karsten Krogh-Jespersen and Alan S. Goldman pp 15627–15629 DOI: 10.1021/ja906930u Supporting Info |
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Probing Interfacial Electron Transfer in Coumarin 343 Sensitized TiO2 Nanoparticles with Femtosecond Stimulated Raman Renee R. Frontiera, Jyotishman Dasgupta and Richard A. Mathies pp 15630–15632 DOI: 10.1021/ja907188b Supporting Info |
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In Situ Generation of Zinc Carbenoids from Diazo Compounds and Zinc Salts: Asymmetric Synthesis of 1,2,3-Substituted Cyclopropanes S pp 15633–15635 DOI: 10.1021/ja9074776 Supporting Info |
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New Syntheses of E7389 C14−C35 and Halichondrin C14−C38 Building Blocks: Double-Inversion Approach Dae-Shik Kim, Cheng-Guo Dong, Joseph T. Kim, Haibing Guo, Jian Huang, Paolo S. Tiseni and Yoshito Kishi pp 15636–15641 DOI: 10.1021/ja9058475 Supporting Info |
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New Syntheses of E7389 C14−C35 and Halichondrin C14−C38 Building Blocks: Reductive Cyclization and Oxy-Michael Cyclization Approaches Cheng-Guo Dong, James A. Henderson, Yosuke Kaburagi, Takeo Sasaki, Dae-Shik Kim, Joseph T. Kim, Daisuke Urabe, Haibing Guo and Yoshito Kishi pp 15642–15646 DOI: 10.1021/ja9058487 Supporting Info |
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Oligoyne Single Molecule Wires Changsheng Wang, Andrei S. Batsanov, Martin R. Bryce, Santiago Mart pp 15647–15654 DOI: 10.1021/ja9061129 Supporting Info |
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Intermolecular Repulsion through Interfacial Attraction: Toward Engineering of Polymorphs Tibor Kudernac, Nadja Sändig, Tatiana Fern pp 15655–15659 DOI: 10.1021/ja901718q Supporting Info |
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Understanding Ground- and Excited-State Properties of Perylene Tetracarboxylic Acid Bisimide Crystals by Means of Quantum Chemical Computations Hong-Mei Zhao, Johannes Pfister, Volker Settels, Manuel Renz, Martin Kaupp, Volker C. Dehm, Frank W pp 15660–15668 DOI: 10.1021/ja902512e Supporting Info |
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Roles of Surface Steps on Pt Nanoparticles in Electro-oxidation of Carbon Monoxide and Methanol Seung Woo Lee, Shuo Chen, Wenchao Sheng, Naoaki Yabuuchi, Yong-Tae Kim, Tadaoki Mitani, Elio Vescovo and Yang Shao-Horn pp 15669–15677 DOI: 10.1021/ja9025648 Supporting Info |
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Theoretical Characterization of the Dynamical Behavior and Transport Properties of α,γ-Peptide Nanotubes in Solution Rebeca García-Fandi pp 15678–15686 DOI: 10.1021/ja903400n Supporting Info |
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Magnetochromatic Microspheres: Rotating Photonic Crystals Jianping Ge, Howon Lee, Le He, Junhoi Kim, Zhenda Lu, Hyoki Kim, James Goebl, Sunghoon Kwon and Yadong Yin pp 15687–15694 DOI: 10.1021/ja903626h Supporting Info |
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Which One Is Preferred: Myers−Saito Cyclization of Ene-Yne-Allene or Garratt−Braverman Cyclization of Conjugated Bisallenic Sulfone? A Theoretical and Experimental Study Amit Basak, Sanket Das, Dibyendu Mallick and Eluvathingal D. Jemmis pp 15695–15704 DOI: 10.1021/ja9023644 Supporting Info |
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Sequestration, Fluorometric Detection, And Mass Spectroscopy Analysis of Lanthanide Ions Using Surface Modified Magnetic Microspheres for Microfluidic Manipulation Ilya A. Shkrob, Michael D. Kaminski, Carol J. Mertz, Paul G. Rickert, Mark S. Derzon and Kamyar Rahimian pp 15705–15710 DOI: 10.1021/ja9035253 Supporting Info |
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Structural and Functional Studies of Aspergillus oryzae Cutinase: Enhanced Thermostability and Hydrolytic Activity of Synthetic Ester and Polyester Degradation Zhiqiang Liu, Yuying Gosser, Peter James Baker, Yaniv Ravee, Ziying Lu, Girum Alemu, Huiguang Li, Glenn L. Butterfoss, Xiang-Peng Kong, Richard Gross and Jin Kim Montclare pp 15711–15716 DOI: 10.1021/ja9046697 Supporting Info |
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Enantioselective Rhodium-Catalyzed [2 + 2 + 2] Cycloadditions of Terminal Alkynes and Alkenyl Isocyanates: Mechanistic Insights Lead to a Unified Model that Rationalizes Product Selectivity Derek M. Dalton, Kevin M. Oberg, Robert T. Yu, Ernest E. Lee, St pp 15717–15728 DOI: 10.1021/ja905065j Supporting Info |
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Structural Examination of the Transient 3-Aminotyrosyl Radical on the PCET Pathway of E. coli Ribonucleotide Reductase by Multifrequency EPR Spectroscopy Mohammad R. Seyedsayamdost, Tomislav Argirevi pp 15729–15738 DOI: 10.1021/ja903879w Supporting Info |
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Oxazine Conjugated Nanoparticle Detects in Vivo Hypochlorous Acid and Peroxynitrite Generation Peter Panizzi, Matthias Nahrendorf, Moritz Wildgruber, Peter Waterman, Jose-Luiz Figueiredo, Elena Aikawa, Jason McCarthy, Ralph Weissleder and Scott A. Hilderbrand pp 15739–15744 DOI: 10.1021/ja903922u Supporting Info |
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Solution Conformation of C-Linked Antifreeze Glycoprotein Analogues and Modulation of Ice Recrystallization Roger Y. Tam, Christopher N. Rowley, Ivan Petrov, Tianyi Zhang, Nicholas A. Afagh, Tom K. Woo and Robert N. Ben pp 15745–15753 DOI: 10.1021/ja904169a Supporting Info |
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Phase Space Prediction of Product Branching Ratios: Canonical Competitive Nonstatistical Model Jingjing Zheng, Ewa Papajak and Donald G. Truhlar pp 15754–15760 DOI: 10.1021/ja904405v Supporting Info |
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Evaluation of Parameters Critical for Observing Nucleic Acids Inside Living Xenopus laevis Oocytes by In-Cell NMR Spectroscopy Robert H pp 15761–15768 DOI: 10.1021/ja9052027 Supporting Info |
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Selective Labeling of Living Cells by a Photo-Triggered Click Reaction Andrei A. Poloukhtine, Ngalle Eric Mbua, Margreet A. Wolfert, Geert-Jan Boons and Vladimir V. Popik pp 15769–15776 DOI: 10.1021/ja9054096 Supporting Info |
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Exciton-Dissociation and Charge-Recombination Processes in Pentacene/C60 Solar Cells: Theoretical Insight into the Impact of Interface Geometry Yuanping Yi, Veaceslav Coropceanu and Jean-Luc Br pp 15777–15783 DOI: 10.1021/ja905975w Supporting Info |
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Synthesis and Biochemical Analysis of Complex Chain-Elongation Intermediates for Interrogation of Molecular Specificity in the Erythromycin and Pikromycin Polyketide Synthases Jonathan D. Mortison, Jeffrey D. Kittendorf and David H. Sherman pp 15784–15793 DOI: 10.1021/ja9060596 Supporting Info |
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Ferromagnetic CoPt3 Nanowires: Structural Evolution from fcc to Ordered L12 Hao Ming Chen, Chia Fen Hsin, Po Yuan Chen, Ru-Shi Liu, Shu-Fen Hu, Chao-Yuan Huang, Jyh-Fu Lee and Ling-Yun Jang pp 15794–15801 DOI: 10.1021/ja906103p Supporting Info |
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Insertion of Molecular Oxygen into a Palladium(II) Methyl Bond: A Radical Chain Mechanism Involving Palladium(III) Intermediates Luc Boisvert, Melanie C. Denney, Susan Kloek Hanson and Karen I. Goldberg pp 15802–15814 DOI: 10.1021/ja9061932 Supporting Info |
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Substituent Effects on the Thermodynamic Stability of Imines Formed from Glycine and Aromatic Aldehydes: Implications for the Catalytic Activity of Pyridoxal-5′-phosphate Juan Crugeiras, Ana Rios, Enrique Riveiros and John P. Richard pp 15815–15824 DOI: 10.1021/ja906230n |
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Are There Stable Ion-Pairs in Room-Temperature Ionic Liquids? Molecular Dynamics Simulations of 1-n-Butyl-3-methylimidazolium Hexafluorophosphate Wei Zhao, Fr pp 15825–15833 DOI: 10.1021/ja906337p Supporting Info |
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Virtual High Throughput Screening Confirmed Experimentally: Porous Coordination Polymer Hydration John J. Low, Annabelle I. Benin, Paulina Jakubczak, Jennifer F. Abrahamian, Syed A. Faheem and Richard R. Willis pp 15834–15842 DOI: 10.1021/ja9061344 Supporting Info |
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Hydrogen Storage Properties of Nanosized MgH2−0.1TiH2 Prepared by Ultrahigh-Energy−High-Pressure Milling Jun Lu, Young Joon Choi, Zhigang Zak Fang, Hong Yong Sohn and Ewa R pp 15843–15852 DOI: 10.1021/ja906340u |
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Deuterium Spin Probes of Backbone Order in Proteins: 2H NMR Relaxation Study of Deuterated Carbon α Sites Devon Sheppard, Da-Wei Li, Rafael Br pp 15853–15865 DOI: 10.1021/ja9063958 Supporting Info |
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Conformational and Configurational Analysis in the Study and Synthesis of Chlorinated Natural Products Christian Nilewski, Roger W. Geisser, Marc-Olivier Ebert and Erick M. Carreira pp 15866–15876 DOI: 10.1021/ja906461h Supporting Info |
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Left- and Right-Handed Alpha-Helical Turns in Homo- and Hetero-Chiral Helical Scaffolds Nicholas E. Shepherd, Huy N. Hoang, Giovanni Abbenante and David P. Fairlie pp 15877–15886 DOI: 10.1021/ja9065283 Supporting Info |
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Dynamic Structural Changes in a Molecular Zeolite-Supported Iridium Catalyst for Ethene Hydrogenation Alper Uzun and Bruce C. Gates pp 15887–15894 DOI: 10.1021/ja906553n Supporting Info |
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Comparison of Isoelectronic 8-HO-G and 8-NH2-G Derivatives in Redox Processes Panagiotis Kaloudis, Mila D’Angelantonio, Maurizio Guerra, Marie Spadafora, Crina Cisma pp 15895–15902 DOI: 10.1021/ja9065464 Supporting Info |
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Multilayer DNA Origami Packed on a Square Lattice Yonggang Ke, Shawn M. Douglas, Minghui Liu, Jaswinder Sharma, Anchi Cheng, Albert Leung, Yan Liu, William M. Shih and Hao Yan pp 15903–15908 DOI: 10.1021/ja906381y Supporting Info |
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Total Syntheses of (±)-Platencin and (−)-Platencin K. C. Nicolaou, G. Scott Tria, David J. Edmonds and Moumita Kar pp 15909–15917 DOI: 10.1021/ja906801g Supporting Info |
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Nanoassembled Capsules as Delivery Vehicles for Large Payloads of High Relaxivity Gd3+ Agents Sally E. Plush, Mark Woods, You-Fu Zhou, Shyam B. Kadali, Michael S. Wong and A. Dean Sherry pp 15918–15923 DOI: 10.1021/ja906981w Supporting Info |
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Active Metal Template Synthesis of [2]Catenanes Stephen M. Goldup, David A. Leigh, Tao Long, Paul R. McGonigal, Mark D. Symes and Jhenyi Wu pp 15924–15929 DOI: 10.1021/ja9070317 Supporting Info |
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Proton Transfer in Guanine−Cytosine Radical Anion Embedded in B-Form DNA Hsing-Yin Chen, Chai-Lin Kao and Sodio C. N. Hsu pp 15930–15938 DOI: 10.1021/ja906899p Supporting Info |
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Simultaneous Nitrogen Doping and Reduction of Graphene Oxide Xiaolin Li, Hailiang Wang, Joshua T. Robinson, Hernan Sanchez, Georgi Diankov and Hongjie Dai pp 15939–15944 DOI: 10.1021/ja907098f Supporting Info |
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Mechanism of N-Fluorobenzenesulfonimide Promoted Diamination and Carboamination Reactions: Divergent Reactivity of a Pd(IV) Species Paul A. Sibbald, Carolyn F. Rosewall, Rodney D. Swartz and Forrest E. Michael pp 15945–15951 DOI: 10.1021/ja906915w Supporting Info |
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Group 4 Metallocene Complexes of Disilenes, Digermenes, and a Silagermene Michaela Zirngast, Michaela Flock, Judith Baumgartner and Christoph Marschner pp 15952–15962 DOI: 10.1021/ja905654r Supporting Info |
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Bioinorganic Photochemistry Peter C. Ford p 15963 DOI: 10.1021/ja908099f |
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Phosphorus Heterocycles I K. Darrell Berlin pp 15963–15964 DOI: 10.1021/ja9078336 |
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Annual Review of Materials Research, Volume 39, 2009 p 15964 DOI: 10.1021/ja9078368 |
Issue 44
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A Photocontrolled Molecular Switch Regulates Paralysis in a Living Organism Usama Al-Atar, Rylan Fernandes, Bob Johnsen, David Baillie and Neil R. Branda pp 15966–15967 DOI: 10.1021/ja903070u Supporting Info |
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Large Protein Complexes with Extreme Rotational Correlation Times Investigated in Solution by Magic-Angle-Spinning NMR Spectroscopy Andi Mainz, Stefan Jehle, Barth J. van Rossum, Hartmut Oschkinat and Bernd Reif pp 15968–15969 DOI: 10.1021/ja904733v Supporting Info |
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Higher Sensitivity through Selective 13C Excitation in Solid-State NMR Spectroscopy Jakob J. Lopez, Christoph Kaiser, Sam Asami and Clemens Glaubitz pp 15970–15971 DOI: 10.1021/ja904963n Supporting Info |
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New Type of Li Ion Conductor with 3D Interconnected Nanopores via Polymerization of a Liquid Organic Electrolyte-Filled Lyotropic Liquid-Crystal Assembly Robert L. Kerr, Seth A. Miller, Richard K. Shoemaker, Brian J. Elliott and Douglas L. Gin pp 15972–15973 DOI: 10.1021/ja905208f Supporting Info |
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Palladium-Catalyzed Direct Carboxylation of Aryl Bromides with Carbon Dioxide Arkaitz Correa and Rub pp 15974–15975 DOI: 10.1021/ja905264a Supporting Info |
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CoS Supersedes Pt as Efficient Electrocatalyst for Triiodide Reduction in Dye-Sensitized Solar Cells Mingkui Wang, Alina M. Anghel, Beno pp 15976–15977 DOI: 10.1021/ja905970y Supporting Info |
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DEER Distance Measurement Between a Spin Label and a Native FAD Semiquinone in Electron Transfer Flavoprotein Michael A. Swanson, Velavan Kathirvelu, Tomas Majtan, Frank E. Frerman, Gareth R. Eaton and Sandra S. Eaton pp 15978–15979 DOI: 10.1021/ja9059816 Supporting Info |
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Hydrophobic Protein−Ligand Interactions Preserved in the Gas Phase Lan Liu, Dhanashri Bagal, Elena N. Kitova, Paul D. Schnier and John S. Klassen pp 15980–15981 DOI: 10.1021/ja9060454 Supporting Info |
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Monitoring of Biological One-Electron Reduction by 19F NMR Using Hypoxia Selective Activation of an 19F-Labeled Indolequinone Derivative Kazuhito Tanabe, Hiroshi Harada, Michiko Narazaki, Kazuo Tanaka, Kenichi Inafuku, Hirokazu Komatsu, Takeo Ito, Hisatsugu Yamada, Yoshiki Chujo, Tetsuya Matsuda, Masahiro Hiraoka and Sei-ichi Nishimoto pp 15982–15983 DOI: 10.1021/ja904953b Supporting Info |
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Tin Nanoparticles Encapsulated in Porous Multichannel Carbon Microtubes: Preparation by Single-Nozzle Electrospinning and Application as Anode Material for High-Performance Li-Based Batteries Yan Yu, Lin Gu, Changbao Zhu, Peter A. van Aken and Joachim Maier pp 15984–15985 DOI: 10.1021/ja906261c Supporting Info |
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Barrierless Free Carrier Formation in an Organic Photovoltaic Material Measured with Ultrafast Vibrational Spectroscopy Ryan D. Pensack and John B. Asbury pp 15986–15987 DOI: 10.1021/ja906293q Supporting Info |
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Synthetic Control of Green Fluorescent Protein Kevin P. Kent, Luke M. Oltrogge and Steven G. Boxer pp 15988–15989 DOI: 10.1021/ja906303f Supporting Info |
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Synthesis of SnS Quantum Dots Ying Xu, Najeh Al-Salim, Chris W. Bumby and Richard D. Tilley pp 15990–15991 DOI: 10.1021/ja906804f Supporting Info |
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A Background Level of Oxygen-Containing Aromatics for Synthetic Control of Carbon Nanotube Structure Don N. Futaba, Jundai Goto, Satoshi Yasuda, Takeo Yamada, Motoo Yumura and Kenji Hata pp 15992–15993 DOI: 10.1021/ja906983r |
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Deconvolution of Complex NMR Spectra in Small Molecules by Multi Frequency Homonuclear Decoupling (MDEC) Ana Paula D. M. Espindola, Ronald Crouch, John R. DeBergh, Joseph M. Ready and John B. MacMillan pp 15994–15995 DOI: 10.1021/ja907110e Supporting Info |
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Direct Alkenylation and Alkylation of Pyridone Derivatives by Ni/AlMe3 Catalysis Yoshiaki Nakao, Hiroaki Idei, Kyalo Stephen Kanyiva and Tamejiro Hiyama pp 15996–15997 DOI: 10.1021/ja907214t Supporting Info |
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Specific Peptide Regulated Synthesis of Ultrasmall Platinum Nanocrystals Yujing Li, Gordon P. Whyburn and Yu Huang pp 15998–15999 DOI: 10.1021/ja907235v Supporting Info |
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Zeolitic Imidazolate Framework Membrane with Molecular Sieving Properties by Microwave-Assisted Solvothermal Synthesis Helge Bux, Fangyi Liang, Yanshuo Li, Janosch Cravillon, Michael Wiebcke and J pp 16000–16001 DOI: 10.1021/ja907359t Supporting Info |
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Calculations Predict a Large Inverse H/D Kinetic Isotope Effect on the Rate of Tunneling in the Ring Opening of Cyclopropylcarbinyl Radical Xue Zhang, Ayan Datta, David A. Hrovat and Weston Thatcher Borden pp 16002–16003 DOI: 10.1021/ja907406q Supporting Info |
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Synthesis of Organic-Soluble Conjugated Polyrotaxanes by Polymerization of Linked Rotaxanes Jun Terao, Susumu Tsuda, Yuji Tanaka, Kento Okoshi, Tetsuaki Fujihara, Yasushi Tsuji and Nobuaki Kambe pp 16004–16005 DOI: 10.1021/ja9074437 Supporting Info |
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Diels−Alder Reactivity of Polycyclic Aromatic Hydrocarbon Bay Regions: Implications for Metal-Free Growth of Single-Chirality Carbon Nanotubes Eric H. Fort, Patrick M. Donovan and Lawrence T. Scott pp 16006–16007 DOI: 10.1021/ja907802g Supporting Info |
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The Abnormal Hydrolysis of 7-Phosphanorbornenium Salts: A Case of Phosphonium−Phosphenium Equivalence Rongqiang Tian, Hui Liu, Zheng Duan and Fran pp 16008–16009 DOI: 10.1021/ja907789y Supporting Info |
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Heating and Cooling Dynamics of Carbon Nanotubes Observed by Temperature-Jump Spectroscopy and Electron Microscopy Omar F. Mohammed, Peter C. Samartzis and Ahmed H. Zewail pp 16010–16011 DOI: 10.1021/ja908079x |
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Heavy Atom Ferromagnets under Pressure: Structural Changes and the Magnetic Response Masaki Mito, Yuki Komorida, Hideki Tsuruda, John S. Tse, Serge Desgreniers, Yauso Ohishi, Alicea A. Leitch, Kristina Cvrkalj, Craig M. Robertson and Richard T. Oakley pp 16012–16013 DOI: 10.1021/ja908238w Supporting Info |
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Proton NMR of 15N-Choline Metabolites Enhanced by Dynamic Nuclear Polarization Riddhiman Sarkar, Arnaud Comment, Paul R. Vasos, Sami Jannin, Rolf Gruetter, Geoffrey Bodenhausen, H pp 16014–16015 DOI: 10.1021/ja9021304 |
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Enantioselective Intramolecular Michael Addition of Nitronates onto Conjugated Esters: Access to Cyclic γ-Amino Acids with up to Three Stereocenters William J. Nodes, David R. Nutt, Ann M. Chippindale and Alexander J. A. Cobb pp 16016–16017 DOI: 10.1021/ja9070915 Supporting Info |
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Stereospecific Synthesis of Conformationally Constrained γ-Amino Acids: New Foldamer Building Blocks That Support Helical Secondary Structure Li Guo, Yonggui Chi, Aaron M. Almeida, Ilia A. Guzei, Brian K. Parker and Samuel H. Gellman pp 16018–16020 DOI: 10.1021/ja907233q Supporting Info |
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Efficient Nucleic Acid Detection by Templated Reductive Quencher Release Raphael M. Franzini and Eric T. Kool pp 16021–16023 DOI: 10.1021/ja904138v Supporting Info |
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DNA-Based Supramolecular Artificial Light Harvesting Complexes Challa V. Kumar and Michael. R. Duff, Jr. pp 16024–16026 DOI: 10.1021/ja904551n Supporting Info |
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Multiroute Synthesis of Porous Anionic Frameworks and Size-Tunable Extraframework Organic Cation-Controlled Gas Sorption Properties Shumei Chen, Jian Zhang, Tao Wu, Pingyun Feng and Xianhui Bu pp 16027–16029 DOI: 10.1021/ja906302t Supporting Info |
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Amplifying Different [2]Catenanes in an Aqueous Donor−Acceptor Dynamic Combinatorial Library Ho Yu Au-Yeung, G. Dan Panto pp 16030–16032 DOI: 10.1021/ja906634h Supporting Info |
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Polyketide Decarboxylative Chain Termination Preceded by O-Sulfonation in Curacin A Biosynthesis Liangcai Gu, Bo Wang, Amol Kulkarni, Jennifer J. Gehret, Kayla R. Lloyd, Lena Gerwick, William H. Gerwick, Peter Wipf, Kristina Håkansson, Janet L. Smith and David H. Sherman pp 16033–16035 DOI: 10.1021/ja9071578 Supporting Info |
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Total Synthesis of Chloropeptin II (Complestatin) and Chloropeptin I Joie Garfunkle, F. Scott Kimball, John D. Trzupek, Shinobu Takizawa, Hiroyuki Shimamura, Masaki Tomishima and Dale L. Boger pp 16036–16038 DOI: 10.1021/ja907193b Supporting Info |
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An N,N′-Diamidocarbene: Studies in C−H Insertion, Reversible Carbonylation, and Transition-Metal Coordination Chemistry Todd W. Hudnall and Christopher W. Bielawski pp 16039–16041 DOI: 10.1021/ja907481w Supporting Info |
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Polymerization of Enantiopure Monomers Using Syndiospecific Catalysts: A New Approach To Sequence Control in Polymer Synthesis John W. Kramer, Daniel S. Treitler, Erin W. Dunn, Pascal M. Castro, Thierry Roisnel, Christophe M. Thomas and Geoffrey W. Coates pp 16042–16044 DOI: 10.1021/ja9075327 Supporting Info |
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Concise Syntheses of (−)-Galanthamine and (±)-Codeine via Intramolecular Alkylation of a Phenol Derivative Philip Magnus, Neeraj Sane, Benjamin P. Fauber and Vince Lynch pp 16045–16047 DOI: 10.1021/ja9085534 Supporting Info |
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Columnar Structure in Bulk Heterojunction in Solution-Processable Three-Layered p-i-n Organic Photovoltaic Devices Using Tetrabenzoporphyrin Precursor and Silylmethyl[60]fullerene Yutaka Matsuo, Yoshiharu Sato, Takaaki Niinomi, Iwao Soga, Hideyuki Tanaka and Eiichi Nakamura pp 16048–16050 DOI: 10.1021/ja9048702 Supporting Info |
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Water Oxidation at a Tetraruthenate Core Stabilized by Polyoxometalate Ligands: Experimental and Computational Evidence To Trace the Competent Intermediates Andrea Sartorel, Pere Mir pp 16051–16053 DOI: 10.1021/ja905067u Supporting Info |
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ESI-MS, DFT, and Synthetic Studies on the H2-Mediated Coupling of Acetylene: Insertion of C═X Bonds into Rhodacyclopentadienes and Brønsted Acid Cocatalyzed Hydrogenolysis of Organorhodium Intermediates Vanessa M. Williams, Jong Rock Kong, Byoung Joon Ko, Yogita Mantri, Jennifer S. Brodbelt, Mu-Hyun Baik and Michael J. Krische pp 16054–16062 DOI: 10.1021/ja906225n Supporting Info |
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Molecular Alloys, Linking Organometallics with Intermetallic Hume−Rothery Phases: The Highly Coordinated Transition Metal Compounds [M(ZnR)n] (n ≥ 8) Containing Organo−Zinc Ligands Thomas Cadenbach, Timo Bollermann, Christian Gemel, Mustafa Tombul, Israel Fernandez, Moritz von Hopffgarten, Gernot Frenking and Roland A. Fischer pp 16063–16077 DOI: 10.1021/ja904061w Supporting Info |
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Zeolitic Polyoxometalate-Based Metal−Organic Frameworks (Z-POMOFs): Computational Evaluation of Hypothetical Polymorphs and the Successful Targeted Synthesis of the Redox-Active Z-POMOF1 L. Marleny Rodriguez-Albelo, A. Rabdel Ruiz-Salvador, Alvaro Sampieri, Dewi W. Lewis, Ariel G pp 16078–16087 DOI: 10.1021/ja905009e Supporting Info |
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Comprehensive Investigation of the Energetics of Pyrimidine Nucleoside Formation in a Model Prebiotic Reaction Yinghong Sheng, Heather D. Bean, Irena Mamajanov, Nicholas V. Hud and Jerzy Leszczynski pp 16088–16095 DOI: 10.1021/ja900807m Supporting Info |
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Structural Perturbations Induced by the α-Anomer of the Aflatoxin B1 Formamidopyrimidine Adduct in Duplex and Single-Strand DNA Kyle L. Brown, Markus W. Voehler, Shane M. Magee, Constance M. Harris, Thomas M. Harris and Michael P. Stone pp 16096–16107 DOI: 10.1021/ja902052v Supporting Info |
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Deciphering Low Energy Deactivation Channels in Adenine Irene Conti, Marco Garavelli and Giorgio Orlandi pp 16108–16118 DOI: 10.1021/ja902311y Supporting Info |
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Gramicidin Pores Report the Activity of Membrane-Active Enzymes Sheereen Majd, Erik C. Yusko, Alexander D. MacBriar, Jerry Yang and Michael Mayer pp 16119–16126 DOI: 10.1021/ja904072s Supporting Info |
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Single-Ion Reorganization Free Energy of Aqueous Ru(bpy)32+/3+ and Ru(H2O)62+/3+ from Photoemission Spectroscopy and Density Functional Molecular Dynamics Simulation Robert Seidel, Manfred Faubel, Bernd Winter and Jochen Blumberger pp 16127–16137 DOI: 10.1021/ja9047834 Supporting Info |
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Anion-Complexation-Induced Stabilization of Charge Separation Francis D’Souza, Navaneetha K. Subbaiyan, Yongshu Xie, Jonathan P. Hill, Katsuhiko Ariga, Kei Ohkubo and Shunichi Fukuzumi pp 16138–16146 DOI: 10.1021/ja9048306 Supporting Info |
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Synthesis of Highly Antibacterial Nanocrystalline Trivalent Silver Polydiguanide Sukdeb Pal, Eun Jeong Yoon, Yu Kyung Tak, Eung Chil Choi and Joon Myong Song pp 16147–16155 DOI: 10.1021/ja9051125 |
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Mechanism and Plasticity of Isochorismate Pyruvate Lyase: A Computational Study Sergio Mart pp 16156–16161 DOI: 10.1021/ja905271g Supporting Info |
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Steric and Solvation Effects in Ionic SN2 Reactions Xin Chen, Colleen K. Regan, Stephen L. Craig, Elizabeth H. Krenske, K. N. Houk, William L. Jorgensen and John I. Brauman pp 16162–16170 DOI: 10.1021/ja9053459 Supporting Info |
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Electrical Wiring of Live, Metabolically Enhanced Bacillus subtilis Cells with Flexible Osmium-Redox Polymers Vasile Coman, Tobias Gustavsson, Arnonas Finkelsteinas, Claes von Wachenfeldt, Cecilia H pp 16171–16176 DOI: 10.1021/ja905442a Supporting Info |
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Solution−Liquid−Solid Growth of Ternary Cu−In−Se Semiconductor Nanowires from Multiple- and Single-Source Precursors Alfred J. Wooten, Donald J. Werder, Darrick J. Williams, Joanna L. Casson and Jennifer A. Hollingsworth pp 16177–16188 DOI: 10.1021/ja905730n Supporting Info |
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Oxygen Exchange in the Selective Oxidation of 2-Butanol on Oxygen Precovered Au(111) Ting Yan, Jinlong Gong and C. Buddie Mullins pp 16189–16194 DOI: 10.1021/ja9062986 Supporting Info |
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Modified Thermodynamics in Ionic Liquids for Controlled Electrocrystallization of Nanocubes, Nanowires, and Crystalline Thin Films of Silver−Tetracyanoquinodimethane Chuan Zhao, Douglas R. MacFarlane and Alan M. Bond pp 16195–16205 DOI: 10.1021/ja9063519 |
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Visible Light Generation of Iodine Atoms and I−I Bonds: Sensitized I− Oxidation and I3− Photodissociation James M. Gardner, Maria Abrahamsson, Byron H. Farnum and Gerald J. Meyer pp 16206–16214 DOI: 10.1021/ja905021c |
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Control of Electrochemical and Ferryloxy Formation Kinetics of Cyt P450s in Polyion Films by Heme Iron Spin State and Secondary Structure Sadagopan Krishnan, Amila Abeykoon, John B Schenkman and James F Rusling pp 16215–16224 DOI: 10.1021/ja9065317 Supporting Info |
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Hydroperoxylation by Hydroxyethylphosphonate Dioxygenase John T. Whitteck, Robert M. Cicchillo and Wilfred A. van der Donk pp 16225–16232 DOI: 10.1021/ja906238r Supporting Info |
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Triple-Bond Reactivity of an AsP Complex Intermediate: Synthesis Stemming from Molecular Arsenic, As4 Heather A. Spinney, Nicholas A. Piro and Christopher C. Cummins pp 16233–16243 DOI: 10.1021/ja906550h Supporting Info |
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Various Valence States of Square-Coordinated Mn in A-Site-Ordered Perovskites Youwen Long, Takashi Saito, Masaichiro Mizumaki, Akane Agui and Yuichi Shimakawa pp 16244–16247 DOI: 10.1021/ja906668c |
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Molecular Basis for the Electric Field Modulation of Cytochrome c Structure and Function Pablo M. De Biase, Dami pp 16248–16256 DOI: 10.1021/ja906726n Supporting Info |
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Selective Characterization of Microsecond Motions in Proteins by NMR Relaxation D. Flemming Hansen, Haniqiao Feng, Zheng Zhou, Yawen Bai and Lewis E. Kay pp 16257–16265 DOI: 10.1021/ja906842s Supporting Info |
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Electrospray Ionization Mass Spectrometry of Intrinsically Cationized Nanoparticles, [Au144/146(SC11H22N(CH2CH3)3+)x(S(CH2)5CH3)y]x+ Christina A. Fields-Zinna, Rajesh Sardar, Christopher A. Beasley and Royce W. Murray pp 16266–16271 DOI: 10.1021/ja906976w Supporting Info |
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Reaction of Hydrogen or Ammonia with Unsaturated Germanium or Tin Molecules under Ambient Conditions: Oxidative Addition versus Arene Elimination Yang Peng, Jing-Dong Guo, Bobby D. Ellis, Zhongliang Zhu, James C. Fettinger, Shigeru Nagase and Philip P. Power pp 16272–16282 DOI: 10.1021/ja9068408 Supporting Info |
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Turn-On Fluorescence Detection of Cyanide in Water: Activation of Latent Fluorophores through Remote Hydrogen Bonds That Mimic Peptide β-Turn Motif Junyong Jo and Dongwhan Lee pp 16283–16291 DOI: 10.1021/ja907056m Supporting Info |
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A Reliable Quantum-Chemical Protocol for the Characterization of Organic Mixed-Valence Compounds Manuel Renz, Kolja Theilacker, Christoph Lambert and Martin Kaupp pp 16292–16302 DOI: 10.1021/ja9070859 Supporting Info |
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The Tellurophosphate K4P8Te4: Phase-Change Properties, Exfoliation, Photoluminescence in Solution and Nanospheres In Chung, Jung-Hwan Song, Myung Gil Kim, Christos D. Malliakas, Angela L. Karst, Arthur J. Freeman, David P. Weliky and Mercouri G. Kanatzidis pp 16303–16312 DOI: 10.1021/ja907273g Supporting Info |
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Biomimetic Synthesis of Lispro Insulin via a Chemically Synthesized “Mini-Proinsulin” Prepared by Oxime-Forming Ligation Youhei Sohma and Stephen B. H. Kent pp 16313–16318 DOI: 10.1021/ja9052398 Supporting Info |
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Ferrocenylhydridoborates: Synthesis, Structural Characterization, and Application to the Preparation of Ferrocenylborane Polymers Matthias Scheibitz, Haiyan Li, Jan Schnorr, Alejandro S pp 16319–16329 DOI: 10.1021/ja906575s Supporting Info |
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Springer Handbook of Enzymes, Supplement, Volume S4: Class 2 Transferases, EC 2.7.11.17−2.8, 2nd ed. p 16330 DOI: 10.1021/ja907877n |
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Polymer Data Handbook, 2nd ed. p 16330 DOI: 10.1021/ja907879q |
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Self-Organization of Molecular Systems: From Molecules and Clusters to Nanotubes and Proteins p 16330 DOI: 10.1021/ja907977w |
Issue 45
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Accurate Random Coil Chemical Shifts from an Analysis of Loop Regions in Native States of Proteins Alfonso De Simone, Andrea Cavalli, Shang-Te Danny Hsu, Wim Vranken and Michele Vendruscolo pp 16332–16333 DOI: 10.1021/ja904937a Supporting Info |
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MgF3− and α-Galactose 1-Phosphate in the Active Site of β-Phosphoglucomutase Form a Transition State Analogue of Phosphoryl Transfer Nicola J. Baxter, Andrea M. Hounslow, Matthew W. Bowler, Nicholas H. Williams, G. Michael Blackburn and Jonathan P. Waltho pp 16334–16335 DOI: 10.1021/ja905972m Supporting Info |
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Tandem Application of Virtual Screening and NMR Experiments in the Discovery of Brand New DNA Quadruplex Groove Binders Sandro Cosconati, Luciana Marinelli, Roberta Trotta, Ada Virno, Luciano Mayol, Ettore Novellino, Arthur J. Olson and Antonio Randazzo pp 16336–16337 DOI: 10.1021/ja9063662 Supporting Info |
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Nanorings of Self-Assembled Fullerene C70 as Templating Nanoreactors K. Swaminathan Iyer, Martin Saunders, Thomas Becker, Cameron W. Evans and Colin L. Raston pp 16338–16339 DOI: 10.1021/ja9065046 Supporting Info |
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Selective Inhibitors of Bacterial Phosphopantothenoylcysteine Synthetase James D. Patrone, Jiangwei Yao, Nicole E. Scott and Garry D. Dotson pp 16340–16341 DOI: 10.1021/ja906537f Supporting Info |
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Anionic Surfactant with Hydrophobic and Hydrophilic Chains for Nanoparticle Dispersion and Shape Memory Polymer Nanocomposites Motoyuki Iijima, Murino Kobayakawa, Miwa Yamazaki, Yasuhiro Ohta and Hidehiro Kamiya pp 16342–16343 DOI: 10.1021/ja906655r Supporting Info |
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One-Dimensional Assembly of Silica Nanospheres Mediated by Block Copolymer in Liquid Phase Masashi Fukao, Ayae Sugawara, Atsushi Shimojima, Wei Fan, Manickam Adhimoolam Arunagirinathan, Michael Tsapatsis and Tatsuya Okubo pp 16344–16345 DOI: 10.1021/ja907013u Supporting Info |
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A Convenient Catalyst for Aqueous and Protein Suzuki−Miyaura Cross-Coupling Justin M. Chalker, Charlotte S. C. Wood and Benjamin G. Davis pp 16346–16347 DOI: 10.1021/ja907150m Supporting Info |
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Degradation of Carbon-Supported Pt Bimetallic Nanoparticles by Surface Segregation Karl J. J. Mayrhofer, Katrin Hartl, Viktorija Juhart and Matthias Arenz pp 16348–16349 DOI: 10.1021/ja9074216 Supporting Info |
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Growth of Tetrahexahedral Gold Nanocrystals with High-Index Facets Tian Ming, Wei Feng, Qin Tang, Feng Wang, Lingdong Sun, Jianfang Wang and Chunhua Yan pp 16350–16351 DOI: 10.1021/ja907549n Supporting Info |
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Platinum(II)-Catalyzed Intermolecular [3 + 2] Cycloaddition of Propadienyl Silyl Ethers and Alkenyl Ethers Hiroyuki Kusama, Masaru Ebisawa, Hideaki Funami and Nobuharu Iwasawa pp 16352–16353 DOI: 10.1021/ja907633b Supporting Info |
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Palladium-Catalyzed Intramolecular Aminofluorination of Unactivated Alkenes Tao Wu, Guoyin Yin and Guosheng Liu pp 16354–16355 DOI: 10.1021/ja9076588 Supporting Info |
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Isolating Surface-Enhanced Raman Scattering Hot Spots Using Multiphoton Lithography Eric D. Diebold, Paul Peng and Eric Mazur pp 16356–16357 DOI: 10.1021/ja9073936 |
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The Functional Significance of Lipid Diversity: Orientation of Cholesterol in Bilayers Is Determined by Lipid Species Norbert Ku pp 16358–16359 DOI: 10.1021/ja907659u |
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Chiral Amplification with a Stereodynamic Triaryl Probe: Assignment of the Absolute Configuration and Enantiomeric Excess of Amino Alcohols Marwan W. Ghosn and Christian Wolf pp 16360–16361 DOI: 10.1021/ja907741v Supporting Info |
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Inhibiting Lateral Domain Formation in Lipid Bilayers: Simulations of Alternative Steroid Headgroup Chemistries Jason D. Perlmutter and Jonathan N. Sachs pp 16362–16363 DOI: 10.1021/ja9079258 Supporting Info |
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Highly Luminescent Self-Organized Sub-2-nm EuOF Nanowires Ya-Ping Du, Ya-Wen Zhang, Zheng-Guang Yan, Ling-Dong Sun and Chun-Hua Yan pp 16364–16365 DOI: 10.1021/ja9080088 Supporting Info |
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Direct Evidence for the Interfacial Oxidation of CO with Hydroxyls Catalyzed by Pt/Oxide Nanocatalysts Lingshun Xu, Yunsheng Ma, Yulin Zhang, Zhiquan Jiang and Weixin Huang pp 16366–16367 DOI: 10.1021/ja908081s Supporting Info |
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Evidence of Significant Covalent Bonding in Au(CN)2− Xue-Bin Wang, Yi-Lei Wang, Jie Yang, Xiao-Peng Xing, Jun Li and Lai-Sheng Wang pp 16368–16370 DOI: 10.1021/ja908106e Supporting Info |
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Lysine-60 in Copper Chaperone Atox1 Plays an Essential Role in Adduct Formation with a Target Wilson Disease Domain Faiza Hussain, Agustina Rodriguez-Granillo and Pernilla Wittung-Stafshede pp 16371–16373 DOI: 10.1021/ja9058266 Supporting Info |
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Self-Assembly of 1-D n-Type Nanostructures Based on Naphthalene Diimide-Appended Dipeptides Hui Shao, Tuan Nguyen, Natalie C. Romano, David A. Modarelli and Jon R. Parquette pp 16374–16376 DOI: 10.1021/ja906377q Supporting Info |
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Exploiting Substrate Stress To Modify Nanoscale SAM Patterns Chetana Singh, Alicia M. Jackson, Francesco Stellacci and Sharon C. Glotzer pp 16377–16379 DOI: 10.1021/ja9063876 |
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A Nonmetal Catalyst for Molecular Hydrogen Activation with Comparable Catalytic Hydrogenation Capability to Noble Metal Catalyst Baojun Li and Zheng Xu pp 16380–16382 DOI: 10.1021/ja9061097 Supporting Info |
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Experimental Evidence for the All-Up Reactive Conformation of Chiral Rhodium(II) Carboxylate Catalysts: Enantioselective Synthesis of cis-Cyclopropane α-Amino Acids Vincent N. G. Lindsay, Wei Lin and Andr pp 16383–16385 DOI: 10.1021/ja9044955 Supporting Info |
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Comparison of Structural Behavior of Nanocrystals in Randomly Packed Films and Long-Range Ordered Superlattices by Time-Resolved Small Angle X-ray Scattering Byeongdu Lee, Paul Podsiadlo, Sara Rupich, Dmitri V. Talapin, Tijana Rajh and Elena V. Shevchenko pp 16386–16388 DOI: 10.1021/ja906632b Supporting Info |
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Complex Hydrides with (BH4)− and (NH2)− Anions as New Lithium Fast-Ion Conductors Motoaki Matsuo, Arndt Remhof, Pascal Martelli, Riccarda Caputo, Matthias Ernst, Yohei Miura, Toyoto Sato, Hiroyuki Oguchi, Hideki Maekawa, Hitoshi Takamura, Andreas Borgschulte, Andreas Z pp 16389–16391 DOI: 10.1021/ja907249p Supporting Info |
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An Antibody-Recruiting Small Molecule That Targets HIV gp120 Christopher G. Parker, Robert A. Domaoal, Karen S. Anderson and David A. Spiegel pp 16392–16394 DOI: 10.1021/ja9057647 Supporting Info |
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Self-Assembly and Traveling Wave Ion Mobility Mass Spectrometry Analysis of Hexacadmium Macrocycles Yi-Tsu Chan, Xiaopeng Li, Monica Soler, Jin-Liang Wang, Chrys Wesdemiotis and George R. Newkome pp 16395–16397 DOI: 10.1021/ja907262c Supporting Info |
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Stimuli-Responsive Reversible Assembly of 2D and 3D Metallosupramolecular Architectures Paul J. Lusby, Peter M pp 16398–16400 DOI: 10.1021/ja907297z Supporting Info |
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Oligocarbonate Molecular Transporters: Oligomerization-Based Syntheses and Cell-Penetrating Studies Christina B. Cooley, Brian M. Trantow, Fredrik Nederberg, Matthew K. Kiesewetter, James L. Hedrick, Robert M. Waymouth and Paul A. Wender pp 16401–16403 DOI: 10.1021/ja907363k Supporting Info |
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Amphoteric Amino Aldehydes Reroute the Aza-Michael Reaction Ryan Hili and Andrei K. Yudin pp 16404–16406 DOI: 10.1021/ja9072194 Supporting Info |
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The Significance of Degenerate Processes to Enantioselective Olefin Metathesis Reactions Promoted by Stereogenic-at-Mo Complexes Simon J. Meek, Steven J. Malcolmson, Bo Li, Richard R. Schrock and Amir H. Hoveyda pp 16407–16409 DOI: 10.1021/ja907805f Supporting Info |
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Characterization of the SgcF Epoxide Hydrolase Supporting an (R)-Vicinal Diol Intermediate for Enediyne Antitumor Antibiotic C-1027 Biosynthesis Shuangjun Lin, Geoffrey P. Horsman, Yihua Chen, Wenli Li and Ben Shen pp 16410–16417 DOI: 10.1021/ja901242s Supporting Info |
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Breaking Mechanism of Single Molecular Junctions Formed by Octanedithiol Molecules and Au Electrodes Yuanhua Qi, Jingyu Qin, Guoli Zhang and Tao Zhang pp 16418–16422 DOI: 10.1021/ja902573e Supporting Info |
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Shape Control of CdSe Nanocrystals with Zinc Blende Structure Liping Liu, Zhongbin Zhuang, Ting Xie, Yang-Gang Wang, Jun Li, Qing Peng and Yadong Li pp 16423–16429 DOI: 10.1021/ja903633d Supporting Info |
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Yeast Display Evolution of a Kinetically Efficient 13-Amino Acid Substrate for Lipoic Acid Ligase Sujiet Puthenveetil, Daniel S. Liu, Katharine A. White, Samuel Thompson and Alice Y. Ting pp 16430–16438 DOI: 10.1021/ja904596f Supporting Info |
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Engineering an Inward Proton Transport from a Bacterial Sensor Rhodopsin Akira Kawanabe, Yuji Furutani, Kwang-Hwan Jung and Hideki Kandori pp 16439–16444 DOI: 10.1021/ja904855g |
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“Hairy” Poly(3-hexylthiophene) Particles Prepared via Surface-Initiated Kumada Catalyst-Transfer Polycondensation Volodymyr Senkovskyy, Roman Tkachov, Tetyana Beryozkina, Hartmut Komber, Ulrich Oertel, Marta Horecha, Vera Bocharova, Manfred Stamm, Suren A. Gevorgyan, Frederik C. Krebs and Anton Kiriy pp 16445–16453 DOI: 10.1021/ja904885w Supporting Info |
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Phage Wrapping with Cationic Polymers Eliminates Nonspecific Binding between M13 Phage and High pI Target Proteins Jorge A. Lamboy, Jessica A. Arter, Kristeene A. Knopp, Denise Der, Cathie M. Overstreet, Edmund F. Palermo, Hiromitsu Urakami, Ting-Bin Yu, Ozgul Tezgel, Gregory N. Tew, Zhibin Guan, Kenichi Kuroda and Gregory A. Weiss pp 16454–16460 DOI: 10.1021/ja9050873 Supporting Info |
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Formation of PbS Nanowire Pine Trees Driven by Screw Dislocations Y. K. Albert Lau, Davin J. Chernak, Matthew J. Bierman and Song Jin pp 16461–16471 DOI: 10.1021/ja906499a Supporting Info |
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Carboxyl-Catalyzed Prototropic Rearrangements in Histidine Peptide Radicals upon Electron Transfer: Effects of Peptide Sequence and Conformation Franti pp 16472–16487 DOI: 10.1021/ja9050229 Supporting Info |
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Isotope-Exchange Dynamics in Isostructural Decametalates with Profound Differences in Reactivity Eric M. Villa, C. Andr pp 16488–16492 DOI: 10.1021/ja905166c Supporting Info |
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Hydrogen Storage in High Surface Area Carbons: Experimental Demonstration of the Effects of Nitrogen Doping Yongde Xia, Gavin S. Walker, David M. Grant and Robert Mokaya pp 16493–16499 DOI: 10.1021/ja9054838 Supporting Info |
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Unprecedented Glycosidase Activity at a Lectin Carbohydrate-Binding Site Exemplified by the Cyanobacterial Lectin MVL Syed Shahzad-ul-Hussan, Mengli Cai and Carole A. Bewley pp 16500–16508 DOI: 10.1021/ja905929c Supporting Info |
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Molecular Insights into the Self-Aggregation of Aromatic Molecules in the Synthesis of Nanoporous Aluminophosphates: A Multilevel Approach Luis G pp 16509–16524 DOI: 10.1021/ja906105x Supporting Info |
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C−H Bond Functionalization via Hydride Transfer: Direct Coupling of Unactivated Alkynes and sp3 C−H Bonds Catalyzed by Platinum Tetraiodide Paul A. Vadola and Dalibor Sames pp 16525–16528 DOI: 10.1021/ja906480w Supporting Info |
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Facile and Scalable Route for Highly Efficient Enrichment of Semiconducting Single-Walled Carbon Nanotubes Hanxun Qiu, Yutaka Maeda and Takeshi Akasaka pp 16529–16533 DOI: 10.1021/ja906932p Supporting Info |
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Assignment of Ile, Leu, and Val Methyl Correlations in Supra-Molecular Systems: An Application to Aspartate Transcarbamoylase Algirdas Velyvis, Howard K. Schachman and Lewis E. Kay pp 16534–16543 DOI: 10.1021/ja906978r Supporting Info |
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From 2-Fold Completive to Integrative Self-Sorting: A Five-Component Supramolecular Trapezoid Kingsuk Mahata and Michael Schmittel pp 16544–16554 DOI: 10.1021/ja907185k Supporting Info |
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New Strategies for the Design of Folded Peptoids Revealed by a Survey of Noncovalent Interactions in Model Systems Benjamin C. Gorske, Joseph R. Stringer, Brent L. Bastian, Sarah A. Fowler and Helen E. Blackwell pp 16555–16567 DOI: 10.1021/ja907184g Supporting Info |
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Thermally Switchable One- and Two-Dimensional Arrays of Single-Walled Carbon Nanotubes in a Polymeric System Changwoo Doe, Hyung-Sik Jang, Tae-Hwan Kim, Steven R. Kline and Sung-Min Choi pp 16568–16572 DOI: 10.1021/ja9073479 Supporting Info |
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Mechanistic Studies on Ni(dppe)Cl2-Catalyzed Chain-Growth Polymerizations: Evidence for Rate-Determining Reductive Elimination Erica L. Lanni and Anne J. McNeil pp 16573–16579 DOI: 10.1021/ja904197q Supporting Info |
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Framework Stabilization of Ge-Rich Zeolites via Postsynthesis Alumination Feifei Gao, Maguy Jaber, Krassimir Bozhilov, Aurelie Vicente, Christian Fernandez and Valentin Valtchev pp 16580–16586 DOI: 10.1021/ja904458y Supporting Info |
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Understanding the Torquoselectivity in 8π-Electrocyclic Cascade Reactions: Synthesis of Fenestradienes versus Cyclooctatrienes Catherine Hulot, Shadi Amiri, Ga p 16587 DOI: 10.1021/ja908012j |
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Controlled/Living Radical Polymerization: Progress in ATRP p 16588 DOI: 10.1021/ja908613x |
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Controlled/Living Radical Polymerization: Progress in RAFT, DT, NMP & OMRP p 16588 DOI: 10.1021/ja9086159 |
Issue 46
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Advancing the Frontiers in Nanocatalysis, Biointerfaces, and Renewable Energy Conversion by Innovations of Surface Techniques Gabor A. Somorjai, Heinz Frei and Jeong Y. Park pp 16589–16605 DOI: 10.1021/ja9061954 |
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Molecular Dynamics Simulations of a Membrane Protein−Micelle Complex in Vacuo Rosmarie Friemann, Daniel S. D. Larsson, Yaofeng Wang and David van der Spoel pp 16606–16607 DOI: 10.1021/ja902962y Supporting Info |
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Characterization of Protein Aggregation via Intrinsic Fluorescence Lifetime Kristian H. Schlick, Candace K. Lange, Gregory D. Gillispie and Mary J. Cloninger pp 16608–16609 DOI: 10.1021/ja904073p Supporting Info |
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Photoactive Yellow Protein-Based Protein Labeling System with Turn-On Fluorescence Intensity Yuichiro Hori, Hideki Ueno, Shin Mizukami and Kazuya Kikuchi pp 16610–16611 DOI: 10.1021/ja904800k Supporting Info |
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Coupling Variation Induced Ultrasensitive Label-Free Biosensing by Using Single Mode Coupled Microcavity Laser Hao Li, Lei Shang, Xin Tu, Liying Liu and Lei Xu pp 16612–16613 DOI: 10.1021/ja9055728 Supporting Info |
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Enzyme Responsive Nanocontainers with Cyclodextrin Gatekeepers and Synergistic Effects in Release of Guests Chiyoung Park, Hyehyeon Kim, Saehee Kim and Chulhee Kim pp 16614–16615 DOI: 10.1021/ja9061085 Supporting Info |
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Poly(diketopyrrolopyrrole−terthiophene) for Ambipolar Logic and Photovoltaics Johan C. Bijleveld, Arjan P. Zoombelt, Simon G. J. Mathijssen, Martijn M. Wienk, Mathieu Turbiez, Dago M. de Leeuw and Ren pp 16616–16617 DOI: 10.1021/ja907506r Supporting Info |
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Stereoelectronic Effects in Vinyl Sulfoxides Roland Ulsh pp 16618–16619 DOI: 10.1021/ja904354g Supporting Info |
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Enantioselective Base-Free Phase-Transfer Reaction in Water-Rich Solvent Rongjun He, Seiji Shirakawa and Keiji Maruoka pp 16620–16621 DOI: 10.1021/ja906821y Supporting Info |
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Umpolung of a Hydrogen Atom of Water by Using a Hexacoordinated Phosphate and Its Application to Deuteride Reduction Reactions of Carbonyl Compounds Hideaki Miyake, Naokazu Kano and Takayuki Kawashima pp 16622–16623 DOI: 10.1021/ja906875d Supporting Info |
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Palladium-Catalyzed Silylene-1,3-Diene [4 + 1] Cycloaddition with Use of (Aminosilyl)boronic Esters as Synthetic Equivalents of Silylene Toshimichi Ohmura, Kohei Masuda, Ichiro Takase and Michinori Suginome pp 16624–16625 DOI: 10.1021/ja907170p Supporting Info |
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Formation of N-Alkylpyrroles via Intermolecular Redox Amination Nirmal K. Pahadi, Miranda Paley, Ranjan Jana, Shelli R. Waetzig and Jon A. Tunge pp 16626–16627 DOI: 10.1021/ja907357g Supporting Info |
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Lewis Acid Catalyzed Inverse-Electron-Demand Diels−Alder Reaction of Tropones Pingfan Li and Hisashi Yamamoto pp 16628–16629 DOI: 10.1021/ja908127f Supporting Info |
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Highly Z-Selective Metathesis Homocoupling of Terminal Olefins Annie J. Jiang, Yu Zhao, Richard R. Schrock and Amir H. Hoveyda pp 16630–16631 DOI: 10.1021/ja908098t Supporting Info |
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Total Synthesis of (−)-Nakadomarin A Pavol Jakubec, Dane M. Cockfield and Darren J. Dixon pp 16632–16633 DOI: 10.1021/ja908399s Supporting Info |
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Intensely Luminescent Gold(I)−Silver(I) Cluster with Hypercoordinated Carbon Jian-Hua Jia and Quan-Ming Wang pp 16634–16635 DOI: 10.1021/ja906695h Supporting Info |
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Low Temperature CO Oxidation over Supported Ultrathin MgO Films Anders Hellman, Simon Klacar and Henrik Gr pp 16636–16637 DOI: 10.1021/ja906865f Supporting Info |
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A New Porous Reaction Layer for Developing Addressable Molecular Libraries Libo Hu, Jennifer L. Bartels, Jeremy W. Bartels, Karl Maurer and Kevin D. Moeller pp 16638–16639 DOI: 10.1021/ja907000m Supporting Info |
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Thermal Isomerization of Cannabinoid Analogues Angie Garcia, Dan Borchardt, Chia-En A. Chang and Michael J. Marsella pp 16640–16641 DOI: 10.1021/ja907062v Supporting Info |
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Asymmetric Histidine-Catalyzed Cross-Aldol Reactions of Enolizable Aldehydes: Access to Defined Configured Quaternary Stereogenic Centers Morris Markert, Ulf Scheffler and Rainer Mahrwald pp 16642–16643 DOI: 10.1021/ja907054y Supporting Info |
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Successful Bifunctional Photoswitching and Electronic Communication of Two Platinum(II) Acetylide Bridged Dithienylethenes Matthew N. Roberts, Carl-Johan Carling, Jeffrey K. Nagle, Neil R. Branda and Michael O. Wolf pp 16644–16645 DOI: 10.1021/ja907434x Supporting Info |
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Russian-Doll-Type Metal Carbide Endofullerene: Synthesis, Isolation, and Characterization of Sc4C2@C80 Tai-Shan Wang, Ning Chen, Jun-Feng Xiang, Bao Li, Jing-Yi Wu, Wei Xu, Li Jiang, Kai Tan, Chun-Ying Shu, Xin Lu and Chun-Ru Wang pp 16646–16647 DOI: 10.1021/ja9077842 Supporting Info |
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Uranyl−Peroxide Interactions Favor Nanocluster Self-Assembly Ginger E. Sigmon, Jie Ling, Daniel K. Unruh, Laura Moore-Shay, Matthew Ward, Brittany Weaver and Peter C. Burns pp 16648–16649 DOI: 10.1021/ja907837u Supporting Info |
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Nanopore Extrusion-Induced Transition from Spherical to Cylindrical Block Copolymer Micelles Qianjin Chen, Hong Zhao, Tian Ming, Jianfang Wang and Chi Wu pp 16650–16651 DOI: 10.1021/ja907898u Supporting Info |
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Ultrafast Spectroscopy of Arylchlorodiazirines: Hammett Correlations of Excited State Lifetimes Yunlong Zhang, Lei Wang, Robert A. Moss and Matthew S. Platz pp 16652–16653 DOI: 10.1021/ja907915z Supporting Info |
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Different Modes of Inhibitor Binding to Prolyl Hydroxylase by Combined Use of X-ray Crystallography and NMR Spectroscopy of Paramagnetic Complexes Leszek Poppe, Christopher M. Tegley, Vivian Li, Jeffrey Lewis, James Zondlo, Evelyn Yang, Robert JM Kurzeja and Rashid Syed pp 16654–16655 DOI: 10.1021/ja907933p Supporting Info |
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Revelation of the Difference between Arylzinc Reagents Prepared from Aryl Grignard and Aryllithium Reagents Respectively: Kinetic and Structural Features Liqun Jin, Chao Liu, Jing Liu, Fang Hu, Yu Lan, Andrei S. Batsanov, Judith A. K. Howard, Todd B. Marder and Aiwen Lei pp 16656–16657 DOI: 10.1021/ja908198d Supporting Info |
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Amine Catalyzed Solvent C−H Bond Activation as Deactivation Route for Cationic Decamethylzirconocene Olefin Polymerization Catalysts Itzel Guerrero Rios, Elena Novarino, Siebe van der Veer, Bart Hessen and Marco W. Bouwkamp pp 16658–16659 DOI: 10.1021/ja908330v Supporting Info |
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Small Molecule-Based Binding Environments: Combinatorial Construction of Microarrays for Multiplexed Affinity Screening Rachel L. Weller Roska, Tenzing Gawa Surshar Lama, Jay P. Hennes and Robert E. Carlson pp 16660–16662 DOI: 10.1021/ja9046944 Supporting Info |
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Small Molecule Modulators of Copper-Induced Aβ Aggregation Sarmad S. Hindo, Allana M. Mancino, Joseph J. Braymer, Yihong Liu, Subramanian Vivekanandan, Ayyalusamy Ramamoorthy and Mi Hee Lim pp 16663–16665 DOI: 10.1021/ja907045h Supporting Info |
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Nonpolymeric Thermosensitive Supramolecules Jos pp 16666–16668 DOI: 10.1021/ja9070927 Supporting Info |
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Total Synthesis of the 2,6-Sialylated Immunoglobulin G Glycopeptide Fragment in Homogeneous Form Ping Wang, Jianglong Zhu, Yu Yuan and Samuel J. Danishefsky pp 16669–16671 DOI: 10.1021/ja907136d Supporting Info |
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High Yield, Large Scale Synthesis of Thiolate-Protected Ag7 Clusters Zhikun Wu, Eric Lanni, Wenqian Chen, Mark E. Bier, Danith Ly and Rongchao Jin pp 16672–16674 DOI: 10.1021/ja907627f Supporting Info |
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Modulating Metal−Organic Frameworks To Breathe: A Postsynthetic Covalent Modification Approach Zhenqiang Wang and Seth M. Cohen pp 16675–16677 DOI: 10.1021/ja907742z Supporting Info |
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Dramatic Improvement in Catalyst Loadings and Molar Ratios of Coupling Partners for Ni/Cr-Mediated Coupling Reactions: Heterobimetallic Catalysts Xiang Liu, James A. Henderson, Takeo Sasaki and Yoshito Kishi pp 16678–16680 DOI: 10.1021/ja9079308 Supporting Info |
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High-Triplet-Energy Dendrons: Enhancing the Luminescence of Deep Blue Phosphorescent Iridium(III) Complexes Shih-Chun Lo, Ruth E. Harding, Christopher P. Shipley, Stuart G. Stevenson, Paul L. Burn and Ifor D. W. Samuel pp 16681–16688 DOI: 10.1021/ja903157e Supporting Info |
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Preferential Interactions of Guanidinum Ions with Aromatic Groups over Aliphatic Groups Philip E. Mason, Christopher E. Dempsey, George W. Neilson, Steve R. Kline and John W. Brady pp 16689–16696 DOI: 10.1021/ja903478s |
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Functional Roles of a Structural Element Involving Na+-π Interactions in the Catalytic Site of T1 Lipase Revealed by Molecular Dynamics Simulations Yohsuke Hagiwara, Hiroyoshi Matsumura and Masaru Tateno pp 16697–16705 DOI: 10.1021/ja903451b Supporting Info |
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Coupling of Triamines with Diisocyanates on Au(111) Leads to the Formation of Polyurea Networks Sean Jensen, Herbert Fr pp 16706–16713 DOI: 10.1021/ja9043032 |
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Fundamental Link between Folding States and Functional States of Proteins Hans Robert Kalbitzer, Michael Spoerner, Petra Ganser, Constantin Hozsa and Werner Kremer pp 16714–16719 DOI: 10.1021/ja904314q Supporting Info |
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Pd-Catalyzed N-Arylation of Secondary Acyclic Amides: Catalyst Development, Scope, and Computational Study Jacqueline D. Hicks, Alan M. Hyde, Alberto Martinez Cuezva and Stephen L. Buchwald pp 16720–16734 DOI: 10.1021/ja9044357 Supporting Info |
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Complex Rare-Earth Aluminum Hydrides: Mechanochemical Preparation, Crystal Structure and Potential for Hydrogen Storage Claudia Weidenthaler, Andr pp 16735–16743 DOI: 10.1021/ja9042565 |
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Cooperation between a Coenzyme A-Independent Stand-Alone Initiation Module and an Iterative Type I Polyketide Synthase during Synthesis of Mycobacterial Phenolic Glycolipids Weiguo He, Clifford E. Soll, Sivagami Sundaram Chavadi, Guangtao Zhang, J. David Warren and Luis E. N. Quadri pp 16744–16750 DOI: 10.1021/ja904792q Supporting Info |
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Femtosecond Fluorescence Spectra of Tryptophan in Human γ-Crystallin Mutants: Site-Dependent Ultrafast Quenching Jianhua Xu, Jiejin Chen, Dmitri Toptygin, Olga Tcherkasskaya, Patrik Callis, Jonathan King, Ludwig Brand and Jay R. Knutson pp 16751–16757 DOI: 10.1021/ja904857t |
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Thermodynamic and Structural Effects of Conformational Constraints in Protein−Ligand Interactions. Entropic Paradoxy Associated with Ligand Preorganization John E. DeLorbe, John H. Clements, Martin G. Teresk, Aaron P. Benfield, Hilary R. Plake, Laura E. Millspaugh and Stephen F. Martin pp 16758–16770 DOI: 10.1021/ja904698q Supporting Info |
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Laser Photolysis of Dye-Sensitized Nanocapsules Occurs via a Photothermal Pathway Kimberly A. Dendramis and Daniel T. Chiu pp 16771–16778 DOI: 10.1021/ja904976r |
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Nylon-3 Copolymers that Generate Cell-Adhesive Surfaces Identified by Library Screening Myung-Ryul Lee, Shannon S. Stahl, Samuel H. Gellman and Kristyn S. Masters pp 16779–16789 DOI: 10.1021/ja9050636 Supporting Info |
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Dynamics of Photochemical Electron Injection and Efficiency of Electron Transport in DNA Pierre Daublain, Arun K. Thazhathveetil, Qiang Wang, Anton Trifonov, Torsten Fiebig and Frederick D. Lewis pp 16790–16797 DOI: 10.1021/ja905140n Supporting Info |
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A Preliminary Survey of the Peptoid Folding Landscape Glenn L. Butterfoss, P. Douglas Renfrew, Brian Kuhlman, Kent Kirshenbaum and Richard Bonneau pp 16798–16807 DOI: 10.1021/ja905267k Supporting Info |
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Chemical Properties of Oxidized Silicon Carbide Surfaces upon Etching in Hydrofluoric Acid Sarit Dhar, Oliver Seitz, Mathew D. Halls, Sungho Choi, Yves J. Chabal and Leonard C. Feldman pp 16808–16813 DOI: 10.1021/ja9053465 Supporting Info |
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Photoconversion of the Fluorescent Protein EosFP: A Hybrid Potential Simulation Study Reveals Intersystem Crossings Micka pp 16814–16823 DOI: 10.1021/ja905380y Supporting Info |
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Giardia Telomeric Sequence d(TAGGG)4 Forms Two Intramolecular G-Quadruplexes in K+ Solution: Effect of Loop Length and Sequence on the Folding Topology Lanying Hu, Kah Wai Lim, Serge Bouaziz and Anh Tu pp 16824–16831 DOI: 10.1021/ja905611c Supporting Info |
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Room-Temperature Synthesis of Soluble Carbon Nanotubes by the Sonication of Graphene Oxide Nanosheets Shuai Wang, Lena Ai ling Tang, Qiaoliang Bao, Ming Lin, Suzi Deng, Bee Min Goh and Kian Ping Loh pp 16832–16837 DOI: 10.1021/ja905968v |
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Large Magnetization-Induced Second Harmonic Generation in an Enantiopure Chiral Magnet Cyrille Train, Tomohiro Nuida, Ruxandra Gheorghe, Michel Gruselle and Shin-ichi Ohkoshi pp 16838–16843 DOI: 10.1021/ja9061568 Supporting Info |
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Supramolecular Ordering in Oligothiophene−Fullerene Monolayers Jennifer M. MacLeod, Oleksandr Ivasenko, Chaoying Fu, Tyler Taerum, Federico Rosei and Dmitrii F. Perepichka pp 16844–16850 DOI: 10.1021/ja906206g Supporting Info |
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Synthesis of PbS Nanorods and Other Ionic Nanocrystals of Complex Morphology by Sequential Cation Exchange Reactions Joseph M. Luther, Haimei Zheng, Bryce Sadtler and A. Paul Alivisatos pp 16851–16857 DOI: 10.1021/ja906503w Supporting Info |
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Superbasicity of a Bis-guanidino Compound with a Flexible Linker: A Theoretical and Experimental Study Martyn P. Coles, Pedro J. Arag pp 16858–16868 DOI: 10.1021/ja906618g Supporting Info |
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Near-IR Femtosecond Transient Absorption Spectroscopy of Ultrafast Polaron and Triplet Exciton Formation in Polythiophene Films with Different Regioregularities Jiamo Guo, Hideo Ohkita, Hiroaki Benten and Shinzaburo Ito pp 16869–16880 DOI: 10.1021/ja906621a Supporting Info |
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Facilitation of RNA Enzyme Activity in the Molecular Crowding Media of Cosolutes Shu-ichi Nakano, Hisae Tateishi Karimata, Yuichi Kitagawa and Naoki Sugimoto pp 16881–16888 DOI: 10.1021/ja9066628 Supporting Info |
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Anion−Macrodipole Interactions: Self-Assembling Oligourea/Amide Macrocycles as Anion Transporters that Respond to Membrane Polarization Andreas Hennig, Lucile Fischer, Gilles Guichard and Stefan Matile pp 16889–16895 DOI: 10.1021/ja9067518 Supporting Info |
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Dynamic Molecular Propeller: Supramolecular Chirality Sensing by Enhanced Chiroptical Response through the Transmission of Point Chirality to Mobile Helicity Ryo Katoono, Hidetoshi Kawai, Kenshu Fujiwara and Takanori Suzuki pp 16896–16904 DOI: 10.1021/ja906810b Supporting Info |
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Total Synthesis of Platensimycin and Related Natural Products K. C. Nicolaou, Ang Li, David J. Edmonds, G. Scott Tria and Shelby P. Ellery pp 16905–16918 DOI: 10.1021/ja9068003 Supporting Info |
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Lipid Membrane Adhesion and Fusion Driven by Designed, Minimally Multivalent Hydrogen-Bonding Lipids Mingming Ma, Yun Gong and Dennis Bong pp 16919–16926 DOI: 10.1021/ja9072657 Supporting Info |
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Wavelength-Selective Photoactivatable Protecting Groups for Thiols Nico Kotzur, Beno pp 16927–16931 DOI: 10.1021/ja907287n Supporting Info |
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Tomographic Energy Dispersive Diffraction Imaging To Study the Genesis of Ni Nanoparticles in 3D within γ-Al2O3 Catalyst Bodies Leticia Espinosa-Alonso, Matthew G. O’Brien, Simon D. M. Jacques, Andrew M. Beale, Krijn P. de Jong, Paul Barnes and Bert M. Weckhuysen pp 16932–16938 DOI: 10.1021/ja907329j Supporting Info |
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Excited-State Dynamics of Cytosine Tautomers Kyriaki Kosma, Christian Schr pp 16939–16943 DOI: 10.1021/ja907355a |
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Structural Phase Transitions and Superconductivity in Fe1+δSe0.57Te0.43 at Ambient and Elevated Pressures Nathalie C. Gresty, Yasuhiro Takabayashi, Alexey Y. Ganin, Martin T. McDonald, John B. Claridge, Duong Giap, Yoshikazu Mizuguchi, Yoshihiko Takano, Tomoko Kagayama, Yasuo Ohishi, Masaki Takata, Matthew J. Rosseinsky, Serena Margadonna and Kosmas Prassides pp 16944–16952 DOI: 10.1021/ja907345x Supporting Info |
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Family of Multifunctional Layered-Lanthanum Crystalline Nanowires with Hierarchical Pores: Hydrothermal Synthesis and Applications Peng-peng Wang, Bo Bai, Shi Hu, Jing Zhuang and Xun Wang pp 16953–16960 DOI: 10.1021/ja907043b Supporting Info |
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A Single-Component Molecular Metal Based on a Thiazole Dithiolate Gold Complex Nadine Tenn, Nathalie Bellec, Olivier Jeannin, Lidia Piekara-Sady, Pascale Auban-Senzier, Jorge pp 16961–16967 DOI: 10.1021/ja907426s Supporting Info |
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Toward a Unified Representation of Protein Structural Dynamics in Solution Phineus R. L. Markwick, Guillaume Bouvignies, Loic Salmon, J. Andrew McCammon, Michael Nilges and Martin Blackledge pp 16968–16975 DOI: 10.1021/ja907476w Supporting Info |
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Metal Ion Facilitated Dissociation of Heme from b-Type Heme Proteins Marcia R. Mauk, Federico I. Rosell and A. Grant Mauk pp 16976–16983 DOI: 10.1021/ja907484j |
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Single-Centered Hydrogen-Bonded Enhanced Acidity (SHEA) Acids: A New Class of Brønsted Acids Zhixin Tian, Alireza Fattahi, Lev Lis and Steven R. Kass pp 16984–16988 DOI: 10.1021/ja9075106 Supporting Info |
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Catalysis via Homolytic Substitutions with C−O and Ti−O Bonds: Oxidative Additions and Reductive Eliminations in Single Electron Steps Andreas Gans pp 16989–16999 DOI: 10.1021/ja907817y Supporting Info |
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Phosphinopnictonium Cations: High Yield and General Preparative Procedures for New Interpnictogen Frameworks Exploiting As→P and Sb→P Coordinate Bonds Eamonn Conrad, Neil Burford, Robert McDonald and Michael J. Ferguson pp 17000–17008 DOI: 10.1021/ja907613c Supporting Info |
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High Yield of Liquid Range Olefins Obtained by Converting i-Propanol over Zeolite H-ZSM-5 Uffe V. Mentzel, Saravanamurugan Shunmugavel, Sarah L. Hruby, Claus H. Christensen and Martin S. Holm pp 17009–17013 DOI: 10.1021/ja907692t |
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Selective Lithiation and Phosphane-Functionalization of [(η7-C7H7)Ti(η5-C5H5)] (Troticene) and Its Use for the Preparation of Early-Late Heterobimetallic Complexes Swagat K. Mohapatra, Susanne B pp 17014–17023 DOI: 10.1021/ja9080056 Supporting Info |
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Evolution of Efficient Strategies for Enone−Alkyne and Enal−Alkyne Reductive Couplings Wei Li, Ananda Herath and John Montgomery pp 17024–17029 DOI: 10.1021/ja9083607 Supporting Info |
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Open-Cage Fullerene-like Graphitic Carbons as Catalysts for Oxidative Dehydrogenation of Isobutane Chengdu Liang, Hong Xie, Viviane Schwartz, Jane Howe, Sheng Dai and Steven H. Overbury p 17030 DOI: 10.1021/ja9083557 |
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Bioinorganic Chemistry: Cellular Systems and Synthetic Models p 17031 DOI: 10.1021/ja908171p |
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Ionic Liquids in Chemical Analysis Dominic Rochefort p 17031 DOI: 10.1021/ja9087693 |
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Inorganic Rings and Polymers of the p-Block Elements: From Fundamentals to Applications Christopher W. Allen pp 17031–17032 DOI: 10.1021/ja908614c |
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Compendium of Organic Synthetic Methods, Volume 12 p 17032 DOI: 10.1021/ja909175c |
Issue 47
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Electrical Double Layer Catalyzed Wet-Etching of Silicon Dioxide Haitao Liu, Michael L. Steigerwald and Colin Nuckolls pp 17034–17035 DOI: 10.1021/ja903333s Supporting Info |
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One-Step Synthesis of Au@Pd Core−Shell Nanooctahedron Young Wook Lee, Minjung Kim, Zee Hwan Kim and Sang Woo Han pp 17036–17037 DOI: 10.1021/ja905603p Supporting Info |
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Deactivation Pathways of an Isolated Green Fluorescent Protein Model Chromophore Studied by Electronic Action Spectroscopy Matthew W. Forbes and Rebecca A. Jockusch pp 17038–17039 DOI: 10.1021/ja9066404 Supporting Info |
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Temperature and Concentration Control over Interpenetration in a Metal−Organic Material JianJun Zhang, Lukasz Wojtas, Randy W. Larsen, Mohamed Eddaoudi and Michael J. Zaworotko pp 17040–17041 DOI: 10.1021/ja906911q Supporting Info |
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Synthesis and Surface Modification of Highly Monodispersed, Spherical Gold Nanoparticles of 50−200 nm Steven D. Perrault and Warren C. W. Chan pp 17042–17043 DOI: 10.1021/ja907069u Supporting Info |
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Low-Temperature Addition of Organolithiums to Functionalized Vinylsilanes under Formation of Secondary α-Lithiated Alkylsilanes Christian Unkelbach and Carsten Strohmann pp 17044–17045 DOI: 10.1021/ja9076167 Supporting Info |
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Reaction of Br2 with Adsorbed CO on Pt, Studied by the Surface Interrogation Mode of Scanning Electrochemical Microscopy Qian Wang, Joaqu pp 17046–17047 DOI: 10.1021/ja907626t Supporting Info |
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Using Cocrystals To Systematically Modulate Aqueous Solubility and Melting Behavior of an Anticancer Drug Christer B. Aaker pp 17048–17049 DOI: 10.1021/ja907674c Supporting Info |
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Bimetallic Palladium Catalysis: Direct Observation of Pd(III)−Pd(III) Intermediates David C. Powers, Matthias A. L. Geibel, Johannes E. M. N. Klein and Tobias Ritter pp 17050–17051 DOI: 10.1021/ja906935c Supporting Info |
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An Aromatic Glaser−Hay Reaction Hien-Quang Do and Olafs Daugulis pp 17052–17053 DOI: 10.1021/ja907479j Supporting Info |
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Double-Nucleus Enhanced Recoupling for Efficient 13C MAS NMR Correlation Spectroscopy of Perdeuterated Proteins pp 17054–17055 DOI: 10.1021/ja907493p Supporting Info |
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High-Performance Zeolite NaA Membranes on Polymer−Zeolite Composite Hollow Fiber Supports Qinqin Ge, Zhengbao Wang and Yushan Yan pp 17056–17057 DOI: 10.1021/ja9082057 Supporting Info |
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Luminescent Bow-Tie-Shaped Decaaryl[60]fullerene Mesogens Chang-Zhi Li, Yutaka Matsuo and Eiichi Nakamura pp 17058–17059 DOI: 10.1021/ja907908m Supporting Info |
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Merging Nucleophilic and Hydrogen Bonding Catalysis: An Anion Binding Approach to the Kinetic Resolution of Amines Chandra Kanta De, Eric G. Klauber and Daniel Seidel pp 17060–17061 DOI: 10.1021/ja9079435 Supporting Info |
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Homoleptic Gadolinium Guanidinate: A Single Source Precursor for Metal−Organic Chemical Vapor Deposition of Gadolinium Nitride Thin Films Andrian P. Milanov, Tobias B. Thiede, Anjana Devi and Roland A. Fischer pp 17062–17063 DOI: 10.1021/ja907952g Supporting Info |
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Time-Resolved Dehydration-Induced Structural Changes in an Intact Bovine Cortical Bone Revealed by Solid-State NMR Spectroscopy Peizhi Zhu, Jiadi Xu, Nadder Sahar, Michael D. Morris, David H. Kohn and Ayyalusamy Ramamoorthy pp 17064–17065 DOI: 10.1021/ja9081028 Supporting Info |
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Total Synthesis of Vinigrol Thomas J. Maimone, Jun Shi, Shinji Ashida and Phil S. Baran pp 17066–17067 DOI: 10.1021/ja908194b Supporting Info |
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Differential Sensing Using Proteins: Exploiting the Cross-Reactivity of Serum Albumin To Pattern Individual Terpenes and Terpenes in Perfume Michelle M. Adams and Eric V. Anslyn pp 17068–17069 DOI: 10.1021/ja908319m Supporting Info |
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Suppression of Proton Mobility by Hydrophobic Hydration Mischa Bonn, Huib J. Bakker, Gianluca Rago, Frederick Pouzy, Joanna R. Siekierzycka, Albert M. Brouwer and Daniel Bonn pp 17070–17071 DOI: 10.1021/ja9083094 Supporting Info |
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Evidence To Support the Hypothesis That Promoting Vibrations Enhance the Rate of an Enzyme Catalyzed H-Tunneling Reaction Christopher R Pudney, Sam Hay, Colin Levy, Jiayun Pang, Michael J Sutcliffe, David Leys and Nigel S. Scrutton pp 17072–17073 DOI: 10.1021/ja908469m Supporting Info |
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Palladium-Catalyzed Enantioselective Addition of Two Distinct Nucleophiles across Alkenes Capable of Quinone Methide Formation Katrina H. Jensen, Tejas P. Pathak, Yang Zhang and Matthew S. Sigman pp 17074–17075 DOI: 10.1021/ja909030c Supporting Info |
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Wavelength Control of Diastereodifferentiating Patern Kazuyuki Matsumura, Tadashi Mori and Yoshihisa Inoue pp 17076–17077 DOI: 10.1021/ja907156j Supporting Info |
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A Single Genomic Copy of an Engineered Methionyl-tRNA Synthetase Enables Robust Incorporation of Azidonorleucine into Recombinant Proteins in E. coli Diya M. Abdeljabbar, Thomas J. Klein, Siyan Zhang and A. James Link pp 17078–17079 DOI: 10.1021/ja907969m Supporting Info |
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Synthesis of Imogolite Fibers from Decimolar Concentration at Low Temperature and Ambient Pressure: A Promising Route for Inexpensive Nanotubes Cl pp 17080–17081 DOI: 10.1021/ja9076952 Supporting Info |
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Construction of Contiguous Tetrasubstituted Chiral Carbon Stereocenters via Direct Catalytic Asymmetric Aldol Reaction of α-Isothiocyanato Esters with Ketones Tatsuhiko Yoshino, Hiroyuki Morimoto, Gang Lu, Shigeki Matsunaga and Masakatsu Shibasaki pp 17082–17083 DOI: 10.1021/ja908571w Supporting Info |
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Mn3+ in Trigonal Bipyramidal Coordination: A New Blue Chromophore Andrew E. Smith, Hiroshi Mizoguchi, Kris Delaney, Nicola A. Spaldin, Arthur W. Sleight and M. A. Subramanian pp 17084–17086 DOI: 10.1021/ja9080666 Supporting Info |
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Evaluating Transition-Metal-Catalyzed Transformations for the Synthesis of Laulimalide Barry M. Trost, Dominique Amans, W. Michael Seganish and Cheol K. Chung pp 17087–17089 DOI: 10.1021/ja907924j Supporting Info |
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Chemical Control over Immune Recognition: A Class of Antibody-Recruiting Small Molecules That Target Prostate Cancer Ryan P. Murelli, Andrew X. Zhang, Julien Michel, William L. Jorgensen and David A. Spiegel pp 17090–17092 DOI: 10.1021/ja906844e Supporting Info |
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Buckyballs Meet Viral Nanoparticles: Candidates for Biomedicine Nicole F. Steinmetz, Vu Hong, Erik D. Spoerke, Ping Lu, Kurt Breitenkamp, M. G. Finn and Marianne Manchester pp 17093–17095 DOI: 10.1021/ja902293w Supporting Info |
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A Glycophorin A-Like Framework for the Dimerization of Photosynthetic Core Complexes Jen Hsin, Christophe Chipot and Klaus Schulten pp 17096–17098 DOI: 10.1021/ja905903n Supporting Info |
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Photochemical Reactivity of Graphene Haitao Liu, Sunmin Ryu, Zheyuan Chen, Michael L. Steigerwald, Colin Nuckolls and Louis E. Brus pp 17099–17101 DOI: 10.1021/ja9043906 Supporting Info |
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An Essential Epitope of Anti-MUC1 Monoclonal Antibody KL-6 Revealed by Focused Glycopeptide Library Naoki Ohyabu, Hiroshi Hinou, Takahiko Matsushita, Ryukou Izumi, Hiroki Shimizu, Keiko Kawamoto, Yoshito Numata, Hiroko Togame, Hiroshi Takemoto, Hirosato Kondo and Shin-Ichiro Nishimura pp 17102–17109 DOI: 10.1021/ja903361f Supporting Info |
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Product Protection, the Key to Developing High Performance Methane Selective Oxidation Catalysts Mårten Ahlquist, Robert J. Nielsen, Roy A. Periana and William A. Goddard III pp 17110–17115 DOI: 10.1021/ja903930e Supporting Info |
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Iron-Porphyrin NO Complexes with Covalently Attached N-Donor Ligands: Formation of a Stable Six-Coordinate Species in Solution Timothy C. Berto, V. K. K. Praneeth, Lauren E. Goodrich and Nicolai Lehnert pp 17116–17126 DOI: 10.1021/ja904368n Supporting Info |
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Mechanistic Insights into Hydride-Transfer and Electron-Transfer Reactions by a Manganese(IV)−Oxo Porphyrin Complex Shunichi Fukuzumi, Naofumi Fujioka, Hiroaki Kotani, Kei Ohkubo, Yong-Min Lee and Wonwoo Nam pp 17127–17134 DOI: 10.1021/ja9045235 Supporting Info |
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Unusual Bonding in Trisilaallene and Related Heavy Allenes Mitsuo Kira, Takeaki Iwamoto, Shintaro Ishida, Hidenori Masuda, Takashi Abe and Chizuko Kabuto pp 17135–17144 DOI: 10.1021/ja904525a Supporting Info |
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Multiplexed Imaging of Therapeutic Cells with Multispectrally Encoded Magnetofluorescent Nanocomposite Emulsions Yong Taik Lim, Young-Woock Noh, Jee-Hyun Cho, Jung Hyun Han, Bang Sil Choi, Jina Kwon, Kwan Soo Hong, Anisha Gokarna, Yong-Hoon Cho and Bong Hyun Chung pp 17145–17154 DOI: 10.1021/ja904472z Supporting Info |
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Alternating Pattern of Stereochemistry in the Nonactin Macrocycle Is Required for Antibacterial Activity and Efficient Ion Binding Brian R. Kusche, Adrienne E. Smith, Michele A. McGuirl and Nigel D. Priestley pp 17155–17165 DOI: 10.1021/ja9050235 Supporting Info |
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Active Sites in Graphene and the Mechanism of CO2 Formation in Carbon Oxidation Ljubisa R. Radovic pp 17166–17175 DOI: 10.1021/ja904731q Supporting Info |
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Fragment 101−108 of Myelin Oligodendrocyte Glycoprotein: A Possible Lead Compound for Multiple Sclerosis Carlo Guardiani, Simone Marsili, Piero Procacci and Roberto Livi pp 17176–17184 DOI: 10.1021/ja905154j Supporting Info |
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Energy Transfer, Unfolding, and Fragmentation Dynamics in Collisions of N-Protonated Octaglycine with an H-SAM Surface George L. Barnes and William L. Hase pp 17185–17193 DOI: 10.1021/ja904925p |
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Mechanistic Investigations of Horseradish Peroxidase-Catalyzed Degradation of Single-Walled Carbon Nanotubes Brett L. Allen, Gregg P. Kotchey, Yanan Chen, Naveena V. K. Yanamala, Judith Klein-Seetharaman, Valerian E. Kagan and Alexander Star pp 17194–17205 DOI: 10.1021/ja9083623 Supporting Info |
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Insights into the (Superoxo)Fe(III)Fe(III) Intermediate and Reaction Mechanism of myo-Inositol Oxygenase: DFT and ONIOM(DFT:MM) Study Hajime Hirao and Keiji Morokuma pp 17206–17214 DOI: 10.1021/ja905296w Supporting Info |
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Exact Distances and Internal Dynamics of Perdeuterated Ubiquitin from NOE Buildups Beat V pp 17215–17225 DOI: 10.1021/ja905366h Supporting Info |
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Reversed Enantioselectivity of Diisopropyl Fluorophosphatase against Organophosphorus Nerve Agents by Rational Design Marco Melzer, Julian C.-H. Chen, Anne Heidenreich, J pp 17226–17232 DOI: 10.1021/ja905444g Supporting Info |
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Creating Protein Affinity Reagents by Combining Peptide Ligands on Synthetic DNA Scaffolds Berea A. R. Williams, Chris W. Diehnelt, Paul Belcher, Matthew Greving, Neal W. Woodbury, Stephen A. Johnston and John C. Chaput pp 17233–17241 DOI: 10.1021/ja9051735 Supporting Info |
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A Stereoselective Approach to Nucleosides and 4′-Thioanalogues from Acyclic Precursors Daniel Chapdelaine, Benoit Cardinal-David, Michel Pr pp 17242–17245 DOI: 10.1021/ja905452f Supporting Info |
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Continuous Wave Photolysis Magnetic Field Effect Investigations with Free and Protein-Bound Alkylcobalamins Alex R. Jones, Jonathan R. Woodward and Nigel S. Scrutton pp 17246–17253 DOI: 10.1021/ja9059238 Supporting Info |
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Molecular Weights of Cyclic and Hollow Clusters Measured by DOSY NMR Spectroscopy S pp 17254–17259 DOI: 10.1021/ja9052619 |
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17α-Estradiol·1/2 H2O: Super-Structural Ordering, Electronic Properties, Chemical Bonding, and Biological Activity in Comparison with Other Estrogens Elizabeth A. Zhurova, Vladimir V. Zhurov, Deepak Chopra, Adam I. Stash and A. Alan Pinkerton pp 17260–17269 DOI: 10.1021/ja906057z Supporting Info |
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A Nanostructure Made of a Bacterial Noncoding RNA Bastien Cayrol, Claude Nogues, Alexandre Dawid, Irit Sagi, Pascal Silberzan and Herv pp 17270–17276 DOI: 10.1021/ja906076e Supporting Info |
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Infrared Spectroscopy of Ionophore-Model Systems: Hydrated Alkali Metal Ion 18-Crown-6 Ether Complexes Jason D. Rodriguez, Timothy D. Vaden and James M. Lisy pp 17277–17285 DOI: 10.1021/ja906185t Supporting Info |
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Chemoselective Catalytic Hydrogenation of Acrolein on Ag(111): Effect of Molecular Orientation on Reaction Selectivity Katrin Brandt, May E. Chiu, David J. Watson, Mintcho S. Tikhov and Richard M. Lambert pp 17286–17290 DOI: 10.1021/ja9063469 |
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Characterizing Dynamic Protein−Protein Interactions Using Differentially Scaled Paramagnetic Relaxation Enhancement Dongmei Yu, Alexander N. Volkov and Chun Tang pp 17291–17297 DOI: 10.1021/ja906673c Supporting Info |
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Oxygen Reduction on Well-Defined Core−Shell Nanocatalysts: Particle Size, Facet, and Pt Shell Thickness Effects Jia X. Wang, Hiromi Inada, Lijun Wu, Yimei Zhu, YongMan Choi, Ping Liu, Wei-Ping Zhou and Radoslav R. Adzic pp 17298–17302 DOI: 10.1021/ja9067645 Supporting Info |
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Control of DNA Strand Displacement Kinetics Using Toehold Exchange David Yu Zhang and Erik Winfree pp 17303–17314 DOI: 10.1021/ja906987s Supporting Info |
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Nanowire Crystals of a Rigid Rod Conjugated Polymer Huanli Dong, Shidong Jiang, Lang Jiang, Yaling Liu, Hongxiang Li, Wenping Hu, Erjing Wang, Shouke Yan, Zhongming Wei, Wei Xu and Xiong Gong pp 17315–17320 DOI: 10.1021/ja907015p Supporting Info |
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Conjugated Polymers with Large Effective Stokes Shift: Benzobisdioxole-Based Poly(phenylene ethynylene)s Tanmoy Dutta, Kathy B. Woody, Sean R. Parkin, Mark D. Watson and Johannes Gierschner pp 17321–17327 DOI: 10.1021/ja9068134 Supporting Info |
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Nanoparticle-Mediated IgE−Receptor Aggregation and Signaling in RBL Mast Cells Yu-Fen Huang, Haipeng Liu, Xiangling Xiong, Yan Chen and Weihong Tan pp 17328–17334 DOI: 10.1021/ja907125t Supporting Info |
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Hybrid Helices: Motifs for Secondary Structure Scaffolds in Foldamers Gangavaram V. M. Sharma, Nagula Chandramouli, Madavi Choudhary, Pendem Nagendar, Kallaganti V. S. Ramakrishna, Ajit C. Kunwar, Peter Schramm and Hans-J pp 17335–17344 DOI: 10.1021/ja907074u Supporting Info |
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Redesign of High-Affinity Nonspecific Nucleases with Altered Sequence Preference Yi-Ting Wang, Jon D. Wright, Lyudmila G. Doudeva, Hua-Ci Jhang, Carmay Lim and Hanna S. Yuan pp 17345–17353 DOI: 10.1021/ja907160r Supporting Info |
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Dots versus Antidots: Computational Exploration of Structure, Magnetism, and Half-Metallicity in Boron−Nitride Nanostructures Aijun Du, Ying Chen, Zhonghua Zhu, Rose Amal, Gao Qing (Max) Lu and Sean C. Smith pp 17354–17359 DOI: 10.1021/ja9071942 Supporting Info |
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Structural, Physicochemical, and Reactivity Properties of an All-Inorganic, Highly Active Tetraruthenium Homogeneous Catalyst for Water Oxidation Yurii V. Geletii, Claire Besson, Yu Hou, Qiushi Yin, Djamaladdin G. Musaev, David Qui pp 17360–17370 DOI: 10.1021/ja907277b Supporting Info |
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Channel Structures from Self-Assembled Hexameric Macrocycles in Laterally Grafted Bent Rod Molecules Ho-Joong Kim, Young-Hwan Jeong, Eunji Lee and Myongsoo Lee pp 17371–17375 DOI: 10.1021/ja907457h Supporting Info |
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Precision Polyethylene: Changes in Morphology as a Function of Alkyl Branch Size Giovanni Rojas, Bora Inci, Yuying Wei and Kenneth B. Wagener pp 17376–17386 DOI: 10.1021/ja907521p Supporting Info |
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Iron-Catalyzed Tandem Oxidative Coupling and Annulation: An Efficient Approach to Construct Polysubstituted Benzofurans Xingwei Guo, Rong Yu, Haijun Li and Zhiping Li pp 17387–17393 DOI: 10.1021/ja907568j Supporting Info |
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Modular Synthesis of Heparan Sulfate Oligosaccharides for Structure−Activity Relationship Studies Sailaja Arungundram, Kanar Al-Mafraji, Jinkeng Asong, Franklin E. Leach, III, I. Jonathan Amster, Andre Venot, Jeremy E. Turnbull and Geert-Jan Boons pp 17394–17405 DOI: 10.1021/ja907358k Supporting Info |
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Au Growth on Semiconductor Nanorods: Photoinduced versus Thermal Growth Mechanisms Gabi Menagen, Janet E. Macdonald, Yossi Shemesh, Inna Popov and Uri Banin pp 17406–17411 DOI: 10.1021/ja9077733 Supporting Info |
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Self-Assembly and Structure of Directly Imaged Inorganic-Anion Monolayers on a Gold Nanoparticle Yifeng Wang, Alevtina Neyman, Elizabeth Arkhangelsky, Vitaly Gitis, Louisa Meshi and Ira A. Weinstock pp 17412–17422 DOI: 10.1021/ja907815d Supporting Info |
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Orthogonal Cu- and Pd-Based Catalyst Systems for the O- and N-Arylation of Aminophenols Debabrata Maiti and Stephen L. Buchwald pp 17423–17429 DOI: 10.1021/ja9081815 Supporting Info |
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Mechanism of Glycan Receptor Recognition and Specificity Switch for Avian, Swine, and Human Adapted Influenza Virus Hemagglutinins: A Molecular Dynamics Perspective E. Irene Newhouse, Dong Xu, Phineus R. L. Markwick, Rommie E. Amaro, Hsing C. Pao, Kevin J. Wu, Maqsudul Alam, J. Andrew McCammon and Wilfred W. Li pp 17430–17442 DOI: 10.1021/ja904052q Supporting Info |
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Locked Chromophore Analogs Reveal That Photoactive Yellow Protein Regulates Biofilm Formation in the Deep Sea Bacterium Idiomarina loihiensis Michael A. van der Horst, T. Page Stalcup, Sandip Kaledhonkar, Masato Kumauchi, Miwa Hara, Aihua Xie, Klaas J. Hellingwerf and Wouter D. Hoff pp 17443–17451 DOI: 10.1021/ja9057103 Supporting Info |
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Rational Design of d-PeT Phenylethynylated-Carbazole Monoboronic Acid Fluorescent Sensors for the Selective Detection of α-Hydroxyl Carboxylic Acids and Monosaccharides Xin Zhang, Lina Chi, Shaomin Ji, Yubo Wu, Peng Song, Keli Han, Huimin Guo, Tony D. James and Jianzhang Zhao pp 17452–17463 DOI: 10.1021/ja9060646 Supporting Info |
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Controlling the Specificity of Modularly Assembled Small Molecules for RNA via Ligand Module Spacing: Targeting the RNAs That Cause Myotonic Muscular Dystrophy Melissa M. Lee, Jessica L. Childs-Disney, Alexei Pushechnikov, Jonathan M. French, Krzysztof Sobczak, Charles A. Thornton and Matthew D. Disney pp 17464–17472 DOI: 10.1021/ja906877y Supporting Info |
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Synthesis of Heteroleptic Uranium (μ−η6:η6-C6H6)2− Sandwich Complexes via Facile Displacement of (η5-C5Me5)1− by Ligands of Lower Hapticity and Their Conversion to Heteroleptic Bis(imido) Compounds William J. Evans, Christopher A. Traina and Joseph W. Ziller pp 17473–17481 DOI: 10.1021/ja9075259 Supporting Info |
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Structural Properties of Pore-Forming Oligomers of α-Synuclein Hai-Young Kim, Min-Kyu Cho, Ashutosh Kumar, Elke Maier, Carsten Siebenhaar, Stefan Becker, Claudio O. Fernandez, Hilal A. Lashuel, Roland Benz, Adam Lange and Markus Zweckstetter pp 17482–17489 DOI: 10.1021/ja9077599 Supporting Info |
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Co-adsorption and Separation of CO2−CH4 Mixtures in the Highly Flexible MIL-53(Cr) MOF Lomig Hamon, Philip L. Llewellyn, Thomas Devic, Aziz Ghoufi, Guillaume Clet, Vincent Guillerm, Gerhard D. Pirngruber, Guillaume Maurin, Christian Serre, Gordon Driver, Wouter van Beek, Elsa Jolima pp 17490–17499 DOI: 10.1021/ja907556q Supporting Info |
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Predicting the Structure of Supramolecular Dendrimers via the Analysis of Libraries of AB3 and Constitutional Isomeric AB2 Biphenylpropyl Ether Self-Assembling Dendrons Brad M. Rosen, Daniela A. Wilson, Christopher J. Wilson, Mihai Peterca, Betty C. Won, Chenghong Huang, Linda R. Lipski, Xiangbing Zeng, Goran Ungar, Paul A. Heiney and Virgil Percec pp 17500–17521 DOI: 10.1021/ja907882n Supporting Info |
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Electronic Effects on the Surface Potential at the Vapor−Liquid Interface of Water Shawn M. Kathmann, I-Feng William Kuo and Christopher J. Mundy p 17522 DOI: 10.1021/ja908142d |
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Microwave Assisted Proteomics Nicholas E. Leadbeater p 17523 DOI: 10.1021/ja9091352 |
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Three-Dimensional Free-Radical Polymerization: Cross-Linked and Hyper-Branched Polymers Lon Jay Mathias pp 17523–17524 DOI: 10.1021/ja9088428 |
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Surface Charging and Points of Zero Charge p 17524 DOI: 10.1021/ja909328w |
Issue 48
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Edaxadiene: A New Bioactive Diterpene from Mycobacterium tuberculosis Francis M. Mann, Meimei Xu, Xiaoming Chen, D. Bruce Fulton, David G. Russell and Reuben J. Peters pp 17526–17527 DOI: 10.1021/ja9019287 Supporting Info |
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Evidence of Diketopiperazine and Oxazolone Structures for HA b2+ Ion Brittany R. Perkins, Julia Chamot-Rooke, Sung Hwan Yoon, Ashley C. Gucinski, pp 17528–17529 DOI: 10.1021/ja9054542 Supporting Info |
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Enantioselective Catalysis of the Aza-Cope Rearrangement by a Chiral Supramolecular Assembly Casey J. Brown, Robert G. Bergman and Kenneth N. Raymond pp 17530–17531 DOI: 10.1021/ja906386w Supporting Info |
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Reduction of Pentavalent Uranyl to U(IV) Facilitated by Oxo Functionalization David D. Schnaars, Guang Wu and Trevor W. Hayton pp 17532–17533 DOI: 10.1021/ja906880d Supporting Info |
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CH Stretching Excitation Steers the F Atom to the CD Bond in the F + CHD3 Reaction G pp 17534–17535 DOI: 10.1021/ja906886z Supporting Info |
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Identification of Cell-Active Lysine Specific Demethylase 1-Selective Inhibitors Rie Ueda, Takayoshi Suzuki, Koshiki Mino, Hiroki Tsumoto, Hidehiko Nakagawa, Makoto Hasegawa, Ryuzo Sasaki, Tamio Mizukami and Naoki Miyata pp 17536–17537 DOI: 10.1021/ja907055q Supporting Info |
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Apparent Transverse Relaxation Rates in Systems with Scalar-Coupled Protons Bikash Baishya, Takuya F. Segawa and Geoffrey Bodenhausen pp 17538–17539 DOI: 10.1021/ja907391z Supporting Info |
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Haq+ Structures in Proton Wires inside Nanotubes Evgenii S. Stoyanov, Irina V. Stoyanova, Fook S. Tham and Christopher A. Reed pp 17540–17541 DOI: 10.1021/ja907708g Supporting Info |
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Selective Imaging of Damaged Bone Structure (Microcracks) Using a Targeting Supramolecular Eu(III) Complex As a Lanthanide Luminescent Contrast Agent Brian McMahon, Peter Mauer, Colin P. McCoy, T. Clive Lee and Thorfinnur Gunnlaugsson pp 17542–17543 DOI: 10.1021/ja908006r Supporting Info |
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Measuring the Charge State of Point Defects on MgO/Ag(001) T. K pp 17544–17545 DOI: 10.1021/ja908049n Supporting Info |
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Pressure-Induced Amorphization and Porosity Modification in a Metal−Organic Framework Karena W. Chapman, Gregory J. Halder and Peter J. Chupas pp 17546–17547 DOI: 10.1021/ja908415z Supporting Info |
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A Convergent Stereoselective Synthesis of Quinolizidines and Indolizidines: Chemoselective Coupling of 2-Hydroxymethyl-Substituted Allylic Silanes with Imines Dexi Yang and Glenn C. Micalizio pp 17548–17549 DOI: 10.1021/ja908504z Supporting Info |
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Crystallization Controlled by the Geometry of a Surface Amanda J. Page and Richard P. Sear pp 17550–17551 DOI: 10.1021/ja9085512 Supporting Info |
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Highly Stereoselective Proton/Hydride Exchange: Assistance of Hydrogen Bonding for the Heterolytic Splitting of H2 Anja Friedrich, Markus Drees, J pp 17552–17553 DOI: 10.1021/ja908644n Supporting Info |
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Electrochemical Analysis of Single-Walled Carbon Nanotubes Functionalized with Pyrene-Pendant Transition Metal Complexes Eden W. McQueen and Jonas I. Goldsmith pp 17554–17556 DOI: 10.1021/ja907294q Supporting Info |
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Deuterium Isotope Effect on Excited-State Dynamics in an Alternating GC Oligonucleotide Kimberly de La Harpe, Carlos E. Crespo-Hern pp 17557–17559 DOI: 10.1021/ja9076364 Supporting Info |
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Direct Synthesis of Cubic ZrMo2O8 Followed by Ultrafast In Situ Powder Diffraction Jennifer E. Readman, Sarah E. Lister, Lars Peters, Jon Wright and John S. O. Evans pp 17560–17562 DOI: 10.1021/ja907648z Supporting Info |
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Generation of Thiocillin Variants by Prepeptide Gene Replacement and in Vivo Processing by Bacillus cereus Michael G. Acker, Albert A. Bowers and Christopher T. Walsh pp 17563–17565 DOI: 10.1021/ja908777t Supporting Info |
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Synthesis, Characterization, and Hierarchical Organization of Tungsten Oxide Nanorods: Spreading Driven by Marangoni Flow Aswani Yella, Muhammad Nawaz Tahir, Stefan Meuer, Rudolf Zentel, R pp 17566–17575 DOI: 10.1021/ja9007479 Supporting Info |
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Ternary Protein Complex of Ferredoxin, Ferredoxin:Thioredoxin Reductase, and Thioredoxin Studied by Paramagnetic NMR Spectroscopy Xingfu Xu, Peter Sch pp 17576–17582 DOI: 10.1021/ja904205k Supporting Info |
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2D Networks of Rhombic-Shaped Fused Dehydrobenzo[12]annulenes: Structural Variations under Concentration Control Kazukuni Tahara, Satoshi Okuhata, Jinne Adisoejoso, Shengbin Lei, Takumi Fujita, Steven De Feyter and Yoshito Tobe pp 17583–17590 DOI: 10.1021/ja904481j Supporting Info |
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Hyperpolarized [2-13C]-Fructose: A Hemiketal DNP Substrate for In Vivo Metabolic Imaging Kayvan R. Keshari, David M. Wilson, Albert P. Chen, Robert Bok, Peder E. Z. Larson, Simon Hu, Mark Van Criekinge, Jeffrey M. Macdonald, Daniel B. Vigneron and John Kurhanewicz pp 17591–17596 DOI: 10.1021/ja9049355 Supporting Info |
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Surface-Segregated Monolayers: A New Type of Ordered Monolayer for Surface Modification of Organic Semiconductors Qingshuo Wei, Keisuke Tajima, Yujin Tong, Shen Ye and Kazuhito Hashimoto pp 17597–17604 DOI: 10.1021/ja9057053 Supporting Info |
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FRET Enabled Real Time Detection of RNA-Small Molecule Binding Yun Xie, Andrew V. Dix and Yitzhak Tor pp 17605–17614 DOI: 10.1021/ja905767g Supporting Info |
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Plasmonic Split-Ring Resonators as Dichroic Nanophotonic DNA Biosensors Alasdair W. Clark, Andrew Glidle, David R. S. Cumming and Jonathan M. Cooper pp 17615–17619 DOI: 10.1021/ja905910q Supporting Info |
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Macrocycles with Switchable exo/endo Metal Binding Sites Lei-lei Tian, Chun Wang, Sandipan Dawn, Mark D. Smith, Jeanette A. Krause and Linda S. Shimizu pp 17620–17629 DOI: 10.1021/ja906474z Supporting Info |
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Sc3N@(C80-Ih(7))(CF3)14 and Sc3N@(C80-Ih(7))(CF3)16. Endohedral Metallofullerene Derivatives with Exohedral Addends on Four and Eight Triple-Hexagon Junctions. Does the Sc3N Cluster Control the Addition Pattern or Vice Versa? Natalia B. Shustova, Yu-Sheng Chen, Mary A. Mackey, Curtis E. Coumbe, J. Paige Phillips, Steven Stevenson, Alexey A. Popov, Olga V. Boltalina and Steven H. Strauss pp 17630–17637 DOI: 10.1021/ja9069216 Supporting Info |
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De Novo Design of Saccharide−Peptide Hydrogels as Synthetic Scaffolds for Tailored Cell Responses Sophia W. Liao, Ting-Bin Yu and Zhibin Guan pp 17638–17646 DOI: 10.1021/ja907097t Supporting Info |
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Principles of Ligand Binding within a Completely Buried Cavity in HIF2α PAS-B Jason Key, Thomas H. Scheuermann, Peter C. Anderson, Valerie Daggett and Kevin H. Gardner pp 17647–17654 DOI: 10.1021/ja9073062 Supporting Info |
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Spin-Selective Charge Transport Pathways through p-Oligophenylene-Linked Donor−Bridge−Acceptor Molecules Amy M. Scott, Tomoaki Miura, Annie Butler Ricks, Zachary E. X. Dance, Emilie M. Giacobbe, Michael T. Colvin and Michael R. Wasielewski pp 17655–17666 DOI: 10.1021/ja907625k Supporting Info |
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The i-Motif in the bcl-2 P1 Promoter Forms an Unexpectedly Stable Structure with a Unique 8:5:7 Loop Folding Pattern Samantha Kendrick, Yoshitsugu Akiyama, Sidney M. Hecht and Laurence H. Hurley pp 17667–17676 DOI: 10.1021/ja9076292 |
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Biochemical Analysis of the Biosynthetic Pathway of an Anticancer Tetracycline SF2575 Lauren B. Pickens, Woncheol Kim, Peng Wang, Hui Zhou, Kenji Watanabe, Shuichi Gomi and Yi Tang pp 17677–17689 DOI: 10.1021/ja907852c Supporting Info |
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Gigantic Enhancement in Sensitivity Using Schottky Contacted Nanowire Nanosensor Te-Yu Wei, Ping-Hung Yeh, Shih-Yuan Lu and Zhong Lin Wang pp 17690–17695 DOI: 10.1021/ja907585c Supporting Info |
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Analyzing the Molecular Weight Distribution in Supramolecular Polymers Stephan A. Schmid, Robert Abbel, Albertus P. H. Schenning, E. W. Meijer, Rint P. Sijbesma and Laura M. Herz pp 17696–17704 DOI: 10.1021/ja9080452 Supporting Info |
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β-Directing Effect of Electron-Withdrawing Groups at O-3, O-4, and O-6 Positions and α-Directing Effect by Remote Participation of 3-O-Acyl and 6-O-Acetyl Groups of Donors in Mannopyranosylations Ju Yuel Baek, Bo-Young Lee, Myung Gi Jo and Kwan Soo Kim pp 17705–17713 DOI: 10.1021/ja907252u Supporting Info |
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Total Syntheses of Isodomoic Acids G and H: An Exercise in Tetrasubstituted Alkene Synthesis Yike Ni, Refaie M. Kassab, Maxim V. Chevliakov and John Montgomery pp 17714–17718 DOI: 10.1021/ja907931u Supporting Info |
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CaFe4As3: A Metallic Iron Arsenide with Anisotropic Magnetic and Charge-Transport Properties Iliya Todorov, Duck Young Chung, Christos D. Malliakas, Quing’an Li, Thomas Bakas, Alexios Douvalis, Giancarlo Trimarchi, Kenneth Gray, John F. Mitchell, Arthur J. Freeman and Mercouri G. Kanatzidis p 17719 DOI: 10.1021/ja907195h |
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Vibrationally Mediated Photodissociation Ricardo B. Metz p 17720 DOI: 10.1021/ja9093296 |
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Macromolecules, Volume 4: Applications of Polymers p 17720 DOI: 10.1021/ja909401b |
Issue 49
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“Bicontinuous Cubic” Liquid Crystalline Materials from Discotic Molecules: A Special Effect of Paraffinic Side Chains with Ionic Liquid Pendants Md. Akhtarul Alam, Jin Motoyanagi, Yohei Yamamoto, Takanori Fukushima, Jungeun Kim, Kenichi Kato, Masaki Takata, Akinori Saeki, Shu Seki, Seiichi Tagawa and Takuzo Aida pp 17722–17723 DOI: 10.1021/ja905373d Supporting Info |
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Poly(Pyridinium Phenylene)s: Water-Soluble N-Type Polymers Daisuke Izuhara and Timothy M. Swager pp 17724–17725 DOI: 10.1021/ja906513u Supporting Info |
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Direct Synthesis of CdSe Nanoparticles in Poly(3-hexylthiophene) Smita Dayal, Nikos Kopidakis, Dana C. Olson, David S. Ginley and Garry Rumbles pp 17726–17727 DOI: 10.1021/ja9067673 |
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Theoretical Predictions of Size-Dependent Carrier Mobility and Polarity in Graphene Meng-Qiu Long, Ling Tang, Dong Wang, Linjun Wang and Zhigang Shuai pp 17728–17729 DOI: 10.1021/ja907528a Supporting Info |
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Cationic siRNAs Provide Carrier-Free Gene Silencing in Animal Cells Marc Nothisen, Mitsuharu Kotera, Emilie Voirin, Jean-Serge Remy and Jean-Paul Behr pp 17730–17731 DOI: 10.1021/ja908017e Supporting Info |
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An Enhanced Hydrogen Adsorption Enthalpy for Fluoride Intercalated Graphite Compounds Hansong Cheng, Xianwei Sha, Liang Chen, Alan C. Cooper, Maw-Lin Foo, Garret C. Lau, Wade H. Bailey III and Guido P. Pez pp 17732–17733 DOI: 10.1021/ja907232y Supporting Info |
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IspG Converts an Epoxide Substrate Analogue to (E)-4-Hydroxy-3-methylbut-2-enyl Diphosphate: Implications for IspG Catalysis in Isoprenoid Biosynthesis Rodney L. Nyland II, Youli Xiao, Pinghua Liu and Caren L. Freel Meyers pp 17734–17735 DOI: 10.1021/ja907470n Supporting Info |
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Indium Tin Oxide Nanoparticles with Compositionally Tunable Surface Plasmon Resonance Frequencies in the Near-IR Region Masayuki Kanehara, Hayato Koike, Taizo Yoshinaga and Toshiharu Teranishi pp 17736–17737 DOI: 10.1021/ja9064415 Supporting Info |
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Excellent Photocatalysis of HF-Treated Silicon Nanowires Mingwang Shao, Liang Cheng, Xiaohong Zhang, Dorthy Duo Duo Ma and Shuit-tong Lee pp 17738–17739 DOI: 10.1021/ja908085c Supporting Info |
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Spectroscopic STM Studies of Single Gold(III) Porphyrin Molecules Stefan M pp 17740–17741 DOI: 10.1021/ja908157j Supporting Info |
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Efficient Recognition of an Unpaired Lesion by a DNA Repair Glycosylase Derek M. Lyons and Patrick J. O’Brien pp 17742–17743 DOI: 10.1021/ja908378y Supporting Info |
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Band Gap Engineering of Quaternary-Alloyed ZnCdSSe Quantum Dots via a Facile Phosphine-Free Colloidal Method Zhengtao Deng, Hao Yan and Yan Liu pp 17744–17745 DOI: 10.1021/ja908408m Supporting Info |
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Intramolecular Schmidt Reaction Involving Primary Azidoalcohols under Nonacidic Conditions: Synthesis of Indolizidine (−)-167B Ajoy Kapat, Erich Nyfeler, Guy T. Giuffredi and Philippe Renaud pp 17746–17747 DOI: 10.1021/ja908933s Supporting Info |
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Suzuki−Miyaura Coupling of Aryl Carbamates, Carbonates, and Sulfamates Kyle W. Quasdorf, Michelle Riener, Krastina V. Petrova and Neil K. Garg pp 17748–17749 DOI: 10.1021/ja906477r Supporting Info |
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N,N-Diethyl O-Carbamate: Directed Metalation Group and Orthogonal Suzuki−Miyaura Cross-Coupling Partner Aurora Antoft-Finch, Tom Blackburn and Victor Snieckus pp 17750–17752 DOI: 10.1021/ja907700e Supporting Info |
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Zeolite-like Metal−Organic Frameworks (ZMOFs) Based on the Directed Assembly of Finite Metal−Organic Cubes (MOCs) Mohamed H. Alkordi, Jacilynn A. Brant, Lukasz Wojtas, Victor Ch. Kravtsov, Amy J. Cairns and Mohamed Eddaoudi pp 17753–17755 DOI: 10.1021/ja905557z Supporting Info |
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Widening the View on Dispersant−Pigment Interactions in Colloidal Dispersions with Saturation Transfer Difference NMR Spectroscopy Agnieszka Szczygiel, Leo Timmermans, Bernd Fritzinger and Jos pp 17756–17758 DOI: 10.1021/ja905637y Supporting Info |
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Urea Destabilizes RNA by Forming Stacking Interactions and Multiple Hydrogen Bonds with Nucleic Acid Bases U. Deva Priyakumar, Changbong Hyeon, D. Thirumalai and Alexander D. MacKerell, Jr. pp 17759–17761 DOI: 10.1021/ja905795v Supporting Info |
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Rational Design of Highly Effective Asymmetric Diels−Alder Catalysts Bearing 4,4′-Sulfonamidomethyl Groups Akira Sakakura, Rei Kondo, Yuki Matsumura, Matsujiro Akakura and Kazuaki Ishihara pp 17762–17764 DOI: 10.1021/ja906098b Supporting Info |
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Probing the Relevance of Lectin Clustering for the Reliable Evaluation of Multivalent Carbohydrate Recognition Eva Maria Munoz, Juan Correa, Eduardo Fernandez-Megia and Ricardo Riguera pp 17765–17767 DOI: 10.1021/ja9074826 Supporting Info |
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Reversible Transformation of Helical Coils and Straight Rods in Cylindrical Assembly of Elliptical Macrocycles Jung-Keun Kim, Eunji Lee, Min-Cheol Kim, Eunji Sim and Myongsoo Lee pp 17768–17770 DOI: 10.1021/ja907462h Supporting Info |
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Controlled Encapsulation of Multiple Proteins in Virus Capsids Inge J. Minten, Linda J. A. Hendriks, Roeland J. M. Nolte and Jeroen J. L. M. Cornelissen pp 17771–17773 DOI: 10.1021/ja907843s Supporting Info |
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Spectrally Tunable Leakage-Free Gold Nanocontainers Yongdong Jin and Xiaohu Gao pp 17774–17776 DOI: 10.1021/ja9076765 Supporting Info |
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Structural and Functional Characterization of the Integral Membrane Protein VDAC-1 in Lipid Bilayer Nanodiscs Thomas Raschle, Sebastian Hiller, Tsyr-Yan Yu, Amanda J. Rice, Thomas Walz and Gerhard Wagner pp 17777–17779 DOI: 10.1021/ja907918r Supporting Info |
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Preferential Encapsulation and Stability of La3N Cluster in 80 Atom Cages: Experimental Synthesis and Computational Investigation of La3N@C79N Steven Stevenson, Yan Ling, Curtis E. Coumbe, Mary A. Mackey, Bridget S. Confait, J. Paige Phillips, Harry C. Dorn and Yong Zhang pp 17780–17782 DOI: 10.1021/ja908370t Supporting Info |
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Why Is Copper(I) Complex More Competent Than Dirhodium(II) Complex in Catalytic Asymmetric O−H Insertion Reactions? A Computational Study of the Metal Carbenoid O−H Insertion into Water Yong Liang, Haolai Zhou and Zhi-Xiang Yu pp 17783–17785 DOI: 10.1021/ja9086566 Supporting Info |
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Size Effects in the Li4+xTi5O12 Spinel W. J. H. Borghols, M. Wagemaker, U. Lafont, E. M. Kelder and F. M. Mulder pp 17786–17792 DOI: 10.1021/ja902423e |
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Electronic Structure of (6−4) DNA Photoproduct Repair Involving a Non-Oxetane Pathway Tatiana Domratcheva and Ilme Schlichting pp 17793–17799 DOI: 10.1021/ja904550d Supporting Info |
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Mimicking the Protein Access Channel to a Metal Center: Effect of a Funnel Complex on Dissociative versus Associative Copper Redox Chemistry Nicolas Le Poul, B pp 17800–17807 DOI: 10.1021/ja9055905 Supporting Info |
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Molecular Motion of Surface-Immobilized Double-Decker Phthalocyanine Complexes Koji Miyake, Megumi Fukuta, Masumi Asakawa, Yukari Hori, Taichi Ikeda and Toshimi Shimizu pp 17808–17813 DOI: 10.1021/ja904629d Supporting Info |
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Molecular Rectification in Metal−SAM−Metal Oxide−Metal Junctions Christian A. Nijhuis, William F. Reus and George M. Whitesides pp 17814–17827 DOI: 10.1021/ja9048898 Supporting Info |
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Role of Self-Organization, Nanostructuring, and Lattice Strain on Phonon Transport in NaPb18-xSnxBiTe20 Thermoelectric Materials Jiaqing He, Aurelie Gueguen, Joseph R. Sootsman, Jin-cheng Zheng, Lijun Wu, Yimei Zhu, Mercouri G. Kanatzidis and Vinayak P. Dravid pp 17828–17835 DOI: 10.1021/ja905448b |
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Remarkable Product Diversity in the “Self-Organized” Reaction of Deprotonated Acetonitrile with Chlorophosphines Kirsten Spannhoff, Nadine Kuhl, Gerald Kehr, Roland Fr pp 17836–17842 DOI: 10.1021/ja905676a Supporting Info |
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Structures of β-Amyloid Peptide 1−40, 1−42, and 1−55—the 672−726 Fragment of APP—in a Membrane Environment with Implications for Interactions with γ-Secretase Naoyuki Miyashita, John E. Straub and D. Thirumalai pp 17843–17852 DOI: 10.1021/ja905457d |
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Amphiphillic Organic Crystals J. J. Segura, A. Verdaguer, M. Cobi pp 17853–17859 DOI: 10.1021/ja905961h Supporting Info |
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Energetics of Allosteric Negative Coupling in the Zinc Sensor S. aureus CzrA Nicholas E. Grossoehme and David P. Giedroc pp 17860–17870 DOI: 10.1021/ja906131b Supporting Info |
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Au Nanocrystal-Directed Growth of Au−Cu2O Core−Shell Heterostructures with Precise Morphological Control Chun-Hong Kuo, Tzu-En Hua and Michael H. Huang pp 17871–17878 DOI: 10.1021/ja9065333 Supporting Info |
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Synthesis of Chiroptical Molecular Switches by Pd-Catalyzed Domino Reactions Lutz F. Tietze, Alexander D pp 17879–17884 DOI: 10.1021/ja906260x Supporting Info |
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An Efficient Photocatalyst Structure: TiO2(B) Nanofibers with a Shell of Anatase Nanocrystals Dongjiang Yang, Hongwei Liu, Zhanfeng Zheng, Yong Yuan, Jin-cai Zhao, Eric R. Waclawik, Xuebin Ke and Huaiyong Zhu pp 17885–17893 DOI: 10.1021/ja906774k |
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Tuning of Refractive Indices and Optical Band Gaps in Oxidized Silicon Quantum Dot Solids Jin-Kyu Choi, Seunghyun Jang, Honglae Sohn and Hyun-Dam Jeong pp 17894–17900 DOI: 10.1021/ja9065656 |
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Precise Characterization of the Conformation Fluctuations of Freely Diffusing DNA: Beyond Rouse and Zimm Kevin McHale and Hideo Mabuchi pp 17901–17907 DOI: 10.1021/ja906979j Supporting Info |
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Quantitative Description of Backbone Conformational Sampling of Unfolded Proteins at Amino Acid Resolution from NMR Residual Dipolar Couplings Gabrielle Nodet, Lo pp 17908–17918 DOI: 10.1021/ja9069024 Supporting Info |
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Electronic and Magnetic Properties of Partially Open Carbon Nanotubes Bing Huang, Young-Woo Son, Gunn Kim, Wenhui Duan and Jisoon Ihm pp 17919–17925 DOI: 10.1021/ja907212g Supporting Info |
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Imaging Hindered Rotations of Alkoxy Species on TiO2(110) Zhenrong Zhang, Roger Rousseau, Jinlong Gong, Bruce D. Kay and Zdenek Dohn pp 17926–17932 DOI: 10.1021/ja907431s Supporting Info |
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Fluoro Derivatives of Retinal Illuminate the Decisive Role of the C12-H Element in Photoisomerization and Rhodopsin Activation Petra H. M. Bovee-Geurts, Isabelle Fern pp 17933–17942 DOI: 10.1021/ja907577p |
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New Synthetic Procedures to Catena-Phosphorus Cations: Preparation and Dissociation of the First cyclo-Phosphino-halophosphonium Salts Jan J. Weigand, Neil Burford, Reagan J. Davidson, T. Stanley Cameron and Patrick Seelheim pp 17943–17953 DOI: 10.1021/ja907693f Supporting Info |
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Selective Cross-Linking of Interacting Proteins Using Self-Labeling Tags Arnaud Gautier, Eiji Nakata, Gra pp 17954–17962 DOI: 10.1021/ja907818q Supporting Info |
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Chemoenzymatic Synthesis and Lectin Array Characterization of a Class of N-Glycan Clusters Wei Huang, Denong Wang, Masao Yamada and Lai-Xi Wang pp 17963–17971 DOI: 10.1021/ja9078539 Supporting Info |
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NMR Structure in a Membrane Environment Reveals Putative Amyloidogenic Regions of the SEVI Precursor Peptide PAP248−286 Ravi P. R. Nanga, Jeffrey R. Brender, Subramanian Vivekanandan, Nataliya Popovych and Ayyalusamy Ramamoorthy pp 17972–17979 DOI: 10.1021/ja908170s Supporting Info |
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Amidine Dications as Superelectrophiles Michael J. Corr, Mark D. Roydhouse, Kirsty F. Gibson, Sheng-ze Zhou, Alan R. Kennedy and John A. Murphy pp 17980–17985 DOI: 10.1021/ja908191k Supporting Info |
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Early Stage Reversed Crystal Growth of Zeolite A and Its Phase Transformation to Sodalite Heather Greer, Paul S. Wheatley, Sharon E. Ashbrook, Russell E. Morris and Wuzong Zhou pp 17986–17992 DOI: 10.1021/ja907475z Supporting Info |
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O6-(Benzotriazol-1-yl)inosine Derivatives: Easily Synthesized, Reactive Nucleosides Suyeal Bae and Mahesh K. Lakshman p 17993 DOI: 10.1021/ja909083p Supporting Info |
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Inclusion Polymers Brian D. Wagner p 17994 DOI: 10.1021/ja909542g |
Issue 50
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Organocatalysis in Organic Synthesis Louis S. Hegedus pp 17995–17997 DOI: 10.1021/ja908581u |
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New Light on Molecular and Materials Complexity: 4D Electron Imaging Dmitry Shorokhov and Ahmed H. Zewail pp 17998–18015 DOI: 10.1021/ja907432p |
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SEMPRE: Spectral Editing Mediated by Paramagnetic Relaxation Enhancement Ruth Kellner, Christian Mangels, Kristian Schweimer, Stefan J. Prasch, Philipp R. Weiglmeier, Paul R pp 18016–18017 DOI: 10.1021/ja905412z Supporting Info |
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Optically Active Calixarenes Conduced by Methylene Substitution Vijay Gopalsamuthiram, Alexander V. Predeus, Rui H. Huang and William D. Wulff pp 18018–18019 DOI: 10.1021/ja905990u Supporting Info |
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A Turn-On Fluorescent Sensor for Detecting Nickel in Living Cells Sheel C. Dodani, Qiwen He and Christopher J. Chang pp 18020–18021 DOI: 10.1021/ja906500m Supporting Info |
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Catalyzed Catalysis Using Carbophilic Lewis Acidic Gold and Lewis Basic Palladium: Synthesis of Substituted Butenolides and Isocoumarins Yili Shi, Katrina E. Roth, Stephen D. Ramgren and Suzanne A. Blum pp 18022–18023 DOI: 10.1021/ja9068497 Supporting Info |
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Isolated Monomeric and Dimeric Mixed Diorganocuprates Based on the Size-Controllable Bulky “Rind” Ligands Mikinao Ito, Daisuke Hashizume, Takeo Fukunaga, Tsukasa Matsuo and Kohei Tamao pp 18024–18025 DOI: 10.1021/ja9071964 Supporting Info |
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A Bimetallic Ru2Pt Complex Containing a Trigonal-Planar μ3-Carbido Ligand: Formation, Structure, and Reactivity Relevant to the Fischer−Tropsch Process Shin Takemoto, Hidenobu Morita, Kenji Karitani, Hideki Fujiwara and Hiroyuki Matsuzaka pp 18026–18027 DOI: 10.1021/ja907387w Supporting Info |
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N-Heterocyclic Carbene-Catalyzed Enantioselective Mannich Reactions with α-Aryloxyacetaldehydes Yasufumi Kawanaka, Eric M. Phillips and Karl A. Scheidt pp 18028–18029 DOI: 10.1021/ja9094044 Supporting Info |
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Block-Copolymer-Nanowires with Nanosized Domain Segregation and High Charge Mobilities as Stacked p/n Heterojunction Arrays for Repeatable Photocurrent Switching Richard Charvet, Somobrata Acharya, Jonathan P. Hill, Misaho Akada, Meiyong Liao, Shu Seki, Yoshihito Honsho, Akinori Saeki and Katsuhiko Ariga pp 18030–18031 DOI: 10.1021/ja907414z Supporting Info |
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Complete Conversion of Hydrous Hydrazine to Hydrogen at Room Temperature for Chemical Hydrogen Storage Sanjay Kumar Singh and Qiang Xu pp 18032–18033 DOI: 10.1021/ja908037t Supporting Info |
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Rhodium-Catalyzed Enantioselective Cyclopropanation of Olefins with N-Sulfonyl 1,2,3-Triazoles Stepan Chuprakov, Sen Wai Kwok, Li Zhang, Lukas Lercher and Valery V. Fokin pp 18034–18035 DOI: 10.1021/ja908075u Supporting Info |
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Direct Observation of a Photoinduced Nonstabilized Nitrile Imine Structure in the Solid State Shao-Liang Zheng, Yizhong Wang, Zhipeng Yu, Qing Lin and Philip Coppens pp 18036–18037 DOI: 10.1021/ja9094523 Supporting Info |
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Duck-Billed Platypus Venom Peptides Induce Ca2+ Influx in Neuroblastoma Cells Masaki Kita, David StC. Black, Osamu Ohno, Kaoru Yamada, Hideo Kigoshi and Daisuke Uemura pp 18038–18039 DOI: 10.1021/ja908148z Supporting Info |
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Transient 2D IR Spectroscopy of Charge Injection in Dye-Sensitized Nanocrystalline Thin Films Wei Xiong, Jennifer E. Laaser, Peerasak Paoprasert, Ryan A. Franking, Robert J. Hamers, Padma Gopalan and Martin T. Zanni pp 18040–18041 DOI: 10.1021/ja908479r Supporting Info |
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Palladium-Catalyzed Hydroalkylation of Styrenes with Organozinc Reagents To Form Carbon−Carbon sp3−sp3 Bonds under Oxidative Conditions Kaveri Balan Urkalan and Matthew S. Sigman pp 18042–18043 DOI: 10.1021/ja908545b Supporting Info |
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Unnatural Amino Acid Substitution as a Probe of the Allosteric Coupling Pathway in a Mycobacterial Cu(I) Sensor Zhen Ma, Darin M. Cowart, Brian P. Ward, Randy J. Arnold, Richard D. DiMarchi, Limei Zhang, Graham N. George, Robert A. Scott and David P. Giedroc pp 18044–18045 DOI: 10.1021/ja908372b Supporting Info |
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Insulated Molecular Wire with Highly Conductive π-Conjugated Polymer Core Jun Terao, Yuji Tanaka, Susumu Tsuda, Nobuaki Kambe, Masateru Taniguchi, Tomoji Kawai, Akinori Saeki and Shu Seki pp 18046–18047 DOI: 10.1021/ja908783f Supporting Info |
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DNA Aptamers as Analyte-Responsive Cation Transporters in Fluorogenic Vesicles: Signal Amplification by Supramolecular Polymerization Toshihide Takeuchi and Stefan Matile pp 18048–18049 DOI: 10.1021/ja908909m Supporting Info |
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Investigating the Weak to Evaluate the Strong: An Experimental Determination of the Electron Binding Energy of Carborane Anions and the Gas phase Acidity of Carborane Acids Matthew M. Meyer, Xue-Bin Wang, Christopher A. Reed, Lai-Sheng Wang and Steven R. Kass pp 18050–18051 DOI: 10.1021/ja908964h Supporting Info |
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Design of More Powerful Iron-TAML Peroxidase Enzyme Mimics W. Chadwick Ellis, Camly T. Tran, Matthew A. Denardo, Andreas Fischer, Alexander D. Ryabov and Terrence J. Collins pp 18052–18053 DOI: 10.1021/ja9086837 Supporting Info |
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Identification of Single-Base Mismatches in Duplex DNA by EPR Spectroscopy Pavol Cekan and Snorri Th. Sigurdsson pp 18054–18056 DOI: 10.1021/ja905623k Supporting Info |
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Synthesis of Dialkyl Ethers from Organotrifluoroborates and Acetals T. Andrew Mitchell and Jeffrey W. Bode pp 18057–18059 DOI: 10.1021/ja906514s Supporting Info |
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Modulating Unimolecular Charge Transfer by Exciting Bridge Vibrations Zhiwei Lin, Candace M. Lawrence, Dequan Xiao, Victor V. Kireev, Spiros S. Skourtis, Jonathan L. Sessler, David N. Beratan and Igor V. Rubtsov pp 18060–18062 DOI: 10.1021/ja907041t Supporting Info |
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Structural Basis of X-ray-Induced Transient Photobleaching in a Photoactivatable Green Fluorescent Protein Virgile Adam, Philippe Carpentier, Sebastien Violot, Micka pp 18063–18065 DOI: 10.1021/ja907296v Supporting Info |
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Biosynthetic Studies of Aziridine Formation in Azicemicins Yasushi Ogasawara and Hung-wen Liu pp 18066–18068 DOI: 10.1021/ja907307h Supporting Info |
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Near-Infrared Luminescent Lanthanide MOF Barcodes Kiley A. White, Demetra A. Chengelis, Kristy A. Gogick, Jack Stehman, Nathaniel L. Rosi and St pp 18069–18071 DOI: 10.1021/ja907885m Supporting Info |
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Cyclic Poly(α-peptoid)s and Their Block Copolymers from N-Heterocyclic Carbene-Mediated Ring-Opening Polymerizations of N-Substituted N-Carboxylanhydrides Li Guo and Donghui Zhang pp 18072–18074 DOI: 10.1021/ja907380d Supporting Info |
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Hyperbranched Polymers by Thiol−Yne Chemistry: From Small Molecules to Functional Polymers Dominik Konkolewicz, Angus Gray-Weale and S pp 18075–18077 DOI: 10.1021/ja908206a Supporting Info |
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Direct Inhibition of Hypoxia-Inducible Transcription Factor Complex with Designed Dimeric Epidithiodiketopiperazine Katherine M. Block, Hui Wang, Lajos Z. Szabó, Nathan W. Polaske, Laura K. Henchey, Ramin Dubey, Swati Kushal, Csaba F. László, Joshua Makhoul, Zuohe Song, Emmanuelle J. Meuillet and Bogdan Z. Olenyuk pp 18078–18088 DOI: 10.1021/ja807601b Supporting Info |
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Formation of Well-Oriented Microtubules with Preferential Polarity in a Confined Space under a Temperature Gradient Akira Kakugo, Yoshiki Tamura, Kazuhiro Shikinaka, Momoko Yoshida, Ryuzo Kawamura, Hidemitsu Furukawa, Yoshihito Osada and Jian Ping Gong pp 18089–18095 DOI: 10.1021/ja901538n Supporting Info |
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Nafion Structural Phenomena at Platinum and Carbon Interfaces David L. Wood, III, Jerzy Chlistunoff, Jaroslaw Majewski and Rodney L. Borup pp 18096–18104 DOI: 10.1021/ja9033928 Supporting Info |
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Nitric Oxide Oxidatively Nitrosylates Ni(I) and Cu(I) C-Organonitroso Adducts Stefan Wiese, Pooja Kapoor, Kamille D. Williams and Timothy H. Warren pp 18105–18111 DOI: 10.1021/ja903550n Supporting Info |
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Exceptional Ion-Exchange Selectivity in a Flexible Open Framework Lanthanum(III)tetrakisphosphonate Monika Plabst, Lynne B. McCusker and Thomas Bein pp 18112–18118 DOI: 10.1021/ja904636y Supporting Info |
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The Distal Pocket Histidine Residue in Horse Heart Myoglobin Directs the O-Binding Mode of Nitrite to the Heme Iron Jun Yi, Julie Heinecke, Hui Tan, Peter C. Ford and George B. Richter-Addo pp 18119–18128 DOI: 10.1021/ja904726q |
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Enthalpic Nature of the CH/π Interaction Involved in the Recognition of Carbohydrates by Aromatic Compounds, Confirmed by a Novel Interplay of NMR, Calorimetry, and Theoretical Calculations Karla Ram pp 18129–18138 DOI: 10.1021/ja903950t Supporting Info |
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Thermodynamic Analysis of mRNA Cap Binding by the Human Initiation Factor eIF4E via Free Energy Perturbations Cristiano R. W. Guimar pp 18139–18146 DOI: 10.1021/ja9064359 Supporting Info |
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Common Folding Mechanism of a β-Hairpin Peptide via Non-native Turn Formation Revealed by Unbiased Molecular Dynamics Simulations Lipi Thukral, Jeremy C. Smith and Isabella Daidone pp 18147–18152 DOI: 10.1021/ja9064365 |
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Functionalization and Dissolution of Nitric Acid Treated Single-Walled Carbon Nanotubes Kimberly A. Worsley, Irina Kalinina, Elena Bekyarova and Robert C. Haddon pp 18153–18158 DOI: 10.1021/ja906267g Supporting Info |
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Copper−Metal Deposition on Self Assembled Monolayer for Making Top Contacts in Molecular Electronic Devices Oliver Seitz, Min Dai, F. S. Aguirre-Tostado, Robert M. Wallace and Yves J. Chabal pp 18159–18167 DOI: 10.1021/ja907003w Supporting Info |
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Complete Mapping of the Stereochemical Course of Retentive Deprotonation/Alkylation of 1H-Benzo[e][1,4]diazepin-2(3H)-ones Danny C. Hsu, Polo C.-H. Lam, Carla Slebodnick and Paul R. Carlier pp 18168–18176 DOI: 10.1021/ja907507j Supporting Info |
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Luminescent Ethynyl−Pyrene Liquid Crystals and Gels for Optoelectronic Devices St pp 18177–18185 DOI: 10.1021/ja908061q Supporting Info |
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Proteases That Can Distinguish among Different Post-translational Forms of Tyrosine Engineered Using Multicolor Flow Cytometry Navin Varadarajan, Mark Pogson, George Georgiou and Brent L. Iverson pp 18186–18190 DOI: 10.1021/ja907803k Supporting Info |
Issue 51
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Photoswitching Mechanism of Cyanine Dyes Graham T. Dempsey, Mark Bates, Walter E. Kowtoniuk, David R. Liu, Roger Y. Tsien and Xiaowei Zhuang pp 18192–18193 DOI: 10.1021/ja904588g Supporting Info |
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Structural Insights from 15N Relaxation Data for an Anisotropic Collagen Peptide Jianxi Xiao and Jean Baum pp 18194–18195 DOI: 10.1021/ja9056823 Supporting Info |
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Seeded Growth of CdS Nanoparticles within a Conducting Metallopolymer Matrix Michelle L. Mej pp 18196–18197 DOI: 10.1021/ja906773g Supporting Info |
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Screening of Metal−Organic Frameworks for Carbon Dioxide Capture from Flue Gas Using a Combined Experimental and Modeling Approach A. pp 18198–18199 DOI: 10.1021/ja9057234 Supporting Info |
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Direct Atomic-Scale Observation of Redox-Induced Cation Dynamics in an Oxide-Supported Monolayer Catalyst: WOx/α-Fe2O3(0001) Zhenxing Feng, Chang-Yong Kim, Jeffrey W. Elam, Qing Ma, Zhan Zhang and Michael J. Bedzyk pp 18200–18201 DOI: 10.1021/ja906816y Supporting Info |
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Identifying Modulators of Protein−Protein Interactions Using Photonic Crystal Biosensors James T. Heeres, Seok-Ho Kim, Benjamin J. Leslie, Erich A. Lidstone, Brian T. Cunningham and Paul J. Hergenrother pp 18202–18203 DOI: 10.1021/ja907066r Supporting Info |
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Spatially Selective Optical Tuning of Quantum Dot Thin Film Luminescence Jixin Chen, Yang-Hsiang Chan, Tinglu Yang, Stacey E. Wark, Dong Hee Son and James D. Batteas pp 18204–18205 DOI: 10.1021/ja906837s Supporting Info |
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Direct Observation of an Enamine Intermediate in Amine Catalysis Xueyong Zhu, Fujie Tanaka, Richard A. Lerner, Carlos F. Barbas III and Ian A. Wilson pp 18206–18207 DOI: 10.1021/ja907271a Supporting Info |
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Analysis of an Anomalous Mutant of MutM DNA Glycosylase Leads to New Insights into the Catalytic Mechanism Kwangho Nam, Gregory L. Verdine and Martin Karplus pp 18208–18209 DOI: 10.1021/ja907544b Supporting Info |
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Asymmetric Hollow Nanorod Formation through a Partial Galvanic Replacement Reaction Daeha Seo and Hyunjoon Song pp 18210–18211 DOI: 10.1021/ja907640h Supporting Info |
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Formation of Nanosized Organic Molecular Crystals on Engineered Surfaces Kitae Kim, In sung Lee, Andrea Centrone, T. Alan Hatton and Allan S. Myerson pp 18212–18213 DOI: 10.1021/ja908055y Supporting Info |
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Slow Internal Protein Dynamics from Water 1H Magnetic Relaxation Dispersion Erik P. Sunde and Bertil Halle pp 18214–18215 DOI: 10.1021/ja908144y Supporting Info |
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Magic Numbers of Gold Clusters Stabilized by PVP Hironori Tsunoyama and Tatsuya Tsukuda pp 18216–18217 DOI: 10.1021/ja908188f Supporting Info |
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Self-Aggregation of a Polyalanine Octamer Promoted by Its C-Terminal Tyrosine and Probed by a Strongly Enhanced Vibrational Circular Dichroism Signal Thomas J. Measey, Kathryn B. Smith, Sean M. Decatur, Liming Zhao, Guoliang Yang and Reinhard Schweitzer-Stenner pp 18218–18219 DOI: 10.1021/ja908324m Supporting Info |
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Improved Injection in n-Type Organic Transistors with Conjugated Polyelectrolytes Jung Hwa Seo, Andrea Gutacker, Bright Walker, Shinuk Cho, Andres Garcia, Renqiang Yang, Thuc-Quyen Nguyen, Alan J. Heeger and Guillermo C. Bazan pp 18220–18221 DOI: 10.1021/ja908441c Supporting Info |
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Amino Acid Based Metal−Organic Nanofibers Inhar Imaz, Marta Rubio-Martínez, Wojciech J. Saletra, David B. Amabilino and Daniel Maspoch pp 18222–18223 DOI: 10.1021/ja908721t Supporting Info |
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X-ray Structure of a CT Complex Relevant to Diels−Alder Reactivity of Anthracenes Guillaume Berionni, Pierre-Alexandre Bertelle, J pp 18224–18225 DOI: 10.1021/ja908747j Supporting Info |
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Site−Site Interactions Enhances Intramolecular Electron Transfer in Streptomyces coelicolor laccase Ole Farver, Armand W. J. W. Tepper, Scot Wherland, Gerard W. Canters and Israel Pecht pp 18226–18227 DOI: 10.1021/ja908793d Supporting Info |
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Noncovalent Cell Surface Engineering with Cationic Graft Copolymers John T. Wilson, Venkata R. Krishnamurthy, Wanxing Cui, Zheng Qu and Elliot L. Chaikof pp 18228–18229 DOI: 10.1021/ja908887v Supporting Info |
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Studying a Cell Division Amidase Using Defined Peptidoglycan Substrates Tania J. Lupoli, Tohru Taniguchi, Tsung-Shing Wang, Deborah L. Perlstein, Suzanne Walker and Daniel E. Kahne pp 18230–18231 DOI: 10.1021/ja908916z Supporting Info |
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Electropolymerization of an N-Heterocyclic Carbene−Gold(I) Complex Adam B. Powell, Christopher W. Bielawski and Alan H. Cowley pp 18232–18233 DOI: 10.1021/ja908969q Supporting Info |
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Vicinal Diboronates in High Enantiomeric Purity through Tandem Site-Selective NHC−Cu-Catalyzed Boron−Copper Additions to Terminal Alkynes Yunmi Lee, Hwanjong Jang and Amir H. Hoveyda pp 18234–18235 DOI: 10.1021/ja9089928 Supporting Info |
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Direct Probing of a Polymer Electrolyte/Luminescent Conjugated Polymer Mixed Ionic/Electronic Conductor Yufeng Hu and Jun Gao pp 18236–18237 DOI: 10.1021/ja908962b Supporting Info |
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An Energetic Comparison of Different Models for the Oxygen Evolving Complex of Photosystem II Per E. M. Siegbahn pp 18238–18239 DOI: 10.1021/ja908712a Supporting Info |
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Catalytic Enantioselective Hydrophosphonylation of Ketimines Using Cinchona Alkaloids Shuichi Nakamura, Masashi Hayashi, Yuichi Hiramatsu, Norio Shibata, Yasuhiro Funahashi and Takeshi Toru pp 18240–18241 DOI: 10.1021/ja908940e Supporting Info |
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Tubular Stacking of Water-Soluble Toroids Triggered by Guest Encapsulation Eunji Lee, Jung-Keun Kim and Myongsoo Lee pp 18242–18243 DOI: 10.1021/ja909279b Supporting Info |
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Direct Catalytic Asymmetric Aldol Reactions of Thioamides: Toward a Stereocontrolled Synthesis of 1,3-Polyols Mitsutaka Iwata, Ryo Yazaki, Yuta Suzuki, Naoya Kumagai and Masakatsu Shibasaki pp 18244–18245 DOI: 10.1021/ja909758e Supporting Info |
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Broadening the Scope of Group 4 Hydroamination Catalysis Using a Tethered Ureate Ligand David C. Leitch, Philippa R. Payne, Christine R. Dunbar and Laurel L. Schafer pp 18246–18247 DOI: 10.1021/ja906955b Supporting Info |
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Phosphate Monoester Hydrolysis in Cyclohexane Randy B. Stockbridge and Richard Wolfenden pp 18248–18249 DOI: 10.1021/ja907967y Supporting Info |
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Kinetic Resolution of 2,3-Dihydro-2-substituted 4-Quinolones by Palladium-Catalyzed Asymmetric Allylic Alkylation Bai-Lin Lei, Chang-Hua Ding, Xiao-Fei Yang, Xiao-Long Wan and Xue-Long Hou pp 18250–18251 DOI: 10.1021/ja9082717 Supporting Info |
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Cobalt-Catalyzed Regioselective Synthesis of Pyrrolidinone Derivatives by Reductive Coupling of Nitriles and Acrylamides Ying-Chieh Wong, Kanniyappan Parthasarathy and Chien-Hong Cheng pp 18252–18253 DOI: 10.1021/ja9088296 Supporting Info |
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Ultrasensitive Detection of Interfacial Water Diffusion on Lipid Vesicle Surfaces at Molecular Length Scales Ravinath Kausik and Songi Han pp 18254–18256 DOI: 10.1021/ja9060849 |
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Acid-Induced Surface Functionalization of Polyoxometalate by Enclosure in a Polyhedral Silver−Alkynyl Cage Guang-Gang Gao, Ping-Shing Cheng and Thomas C. W. Mak pp 18257–18259 DOI: 10.1021/ja907900b Supporting Info |
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Magnetolithographic Patterning of Inner Walls of a Tube: A New Dimension in Microfluidics and Sequential Microreactors Amos Bardea, Aviad Baram, Anand Kumar Tatikonda and Ron Naaman pp 18260–18262 DOI: 10.1021/ja908675c Supporting Info |
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SylC Catalyzes Ureido-Bond Formation During Biosynthesis of the Proteasome Inhibitor Syringolin A Heidi J. Imker, Christopher T. Walsh and William M. Wuest pp 18263–18265 DOI: 10.1021/ja909170u Supporting Info |
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Scandium-Catalyzed Regio- and Stereospecific Methylalumination of Silyloxy/Alkoxy-Substituted Alkynes and Alkenes Masanori Takimoto, Saori Usami and Zhaomin Hou pp 18266–18268 DOI: 10.1021/ja909126k Supporting Info |
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A pH Activated Configurational Rotary Switch: Controlling the E/Z Isomerization in Hydrazones Shainaz M. Landge and Ivan Aprahamian pp 18269–18271 DOI: 10.1021/ja909149z Supporting Info |
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Effect of Peptide Fragment Size on the Propensity of Cyclization in Collision-Induced Dissociation: Oligoglycine b2−b8 Xian Chen, Long Yu, Jeffrey D. Steill, Jos Oomens and Nick C. Polfer pp 18272–18282 DOI: 10.1021/ja9030837 Supporting Info |
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Human Islet Amyloid Polypeptide Monomers Form Ordered β-hairpins: A Possible Direct Amyloidogenic Precursor Nicholas F. Dupuis, Chun Wu, Joan-Emma Shea and Michael T. Bowers pp 18283–18292 DOI: 10.1021/ja903814q Supporting Info |
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Electrostatically Self-Assembled Polyoxometalates on Molecular-Dye-Functionalized Diamond Yu Lin Zhong, Wibowo Ng, Jia-Xiang Yang and Kian Ping Loh pp 18293–18298 DOI: 10.1021/ja908131t Supporting Info |
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First Observation of Phase Transformation of All Four Fe2O3 Phases (γ → ε → β → α-Phase) Shunsuke Sakurai, Asuka Namai, Kazuhito Hashimoto and Shin-ichi Ohkoshi pp 18299–18303 DOI: 10.1021/ja9046069 Supporting Info |
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Ferromagnetic Nanoscale Electron Correlation Promoted by Organic Spin-Dependent Delocalization Martin L. Kirk, David A. Shultz, Robert D. Schmidt, Diana Habel-Rodriguez, Hyoyoung Lee and Junghyun Lee pp 18304–18313 DOI: 10.1021/ja904648r Supporting Info |
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Determination of the Free Energy Landscape of α-Synuclein Using Spin Label Nuclear Magnetic Resonance Measurements Jane R. Allison, Peter Varnai, Christopher M. Dobson and Michele Vendruscolo pp 18314–18326 DOI: 10.1021/ja904716h Supporting Info |
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A Cascade Biodegradable Polymer Based on Alternating Cyclization and Elimination Reactions Matthew A. DeWit and Elizabeth R. Gillies pp 18327–18334 DOI: 10.1021/ja905343x Supporting Info |
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Residue-Specific Information about the Dynamics of Antimicrobial Peptides from 1H−15N and 2H Solid-State NMR Spectroscopy Kresten Bertelsen, Berit Paaske, Lea Thøgersen, Emad Tajkhorshid, Birgit Schiøtt, Troels Skrydstrup, Niels Chr. Nielsen and Thomas Vosegaard pp 18335–18342 DOI: 10.1021/ja908604u |
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Palladium-Catalyzed Decarboxylative Asymmetric Allylic Alkylation of Enol Carbonates Barry M. Trost, Jiayi Xu and Thomas Schmidt pp 18343–18357 DOI: 10.1021/ja9053948 Supporting Info |
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Elucidating the Bimodal Acid−Base Behavior of the Water−Silica Interface from First Principles Kevin Leung, Ida M. B. Nielsen and Louise J. Criscenti pp 18358–18365 DOI: 10.1021/ja906190t Supporting Info |
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Reactions of Ruthenium Cp Phosphine Complex with 4,4-Disubstituted-1,6-Enynes: Effect of Methyl Substituents in the Olefinic Fraction Chia-Pei Chung, Chien-Chih Chen, Ying-Chih Lin, Yi-Hong Liu and Yu Wang pp 18366–18375 DOI: 10.1021/ja906745j Supporting Info |
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Uracil and Thymine Reactivity in the Gas Phase: The SN2 Reaction and Implications for Electron Delocalization in Leaving Groups Anna Zhachkina and Jeehiun K. Lee pp 18376–18385 DOI: 10.1021/ja906814d Supporting Info |
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Laterally Azo-Bridged H-Shaped Ferroelectric Dimesogens for Second-Order Nonlinear Optics: Ferroelectricity and Second Harmonic Generation Yongqiang Zhang, Josu Martinez-Perdiguero, Ute Baumeister, Christopher Walker, Jesus Etxebarria, Marko Prehm, Josu Ortega, Carsten Tschierske, Michael J. O’Callaghan, Adam Harant and Mark Handschy pp 18386–18392 DOI: 10.1021/ja9069166 Supporting Info |
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Direct Perfluorination of K2B12H12 in Acetonitrile Occurs at the Gas Bubble−Solution Interface and Is Inhibited by HF. Experimental and DFT Study of Inhibition by Protic Acids and Soft, Polarizable Anions Dmitry V. Peryshkov, Alexey A. Popov and Steven H. Strauss pp 18393–18403 DOI: 10.1021/ja9069437 Supporting Info |
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Mechanism of Calcite Co-Orientation in the Sea Urchin Tooth Christopher E. Killian, Rebecca A. Metzler, Y. U. T. Gong, Ian C. Olson, Joanna Aizenberg, Yael Politi, Fred H. Wilt, Andreas Scholl, Anthony Young, Andrew Doran, Martin Kunz, Nobumichi Tamura, Susan N. Coppersmith and P. U. P. A. Gilbert pp 18404–18409 DOI: 10.1021/ja907063z Supporting Info |
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Nanoscale 3D Tracking with Conjugated Polymer Nanoparticles Jiangbo Yu, Changfeng Wu, Sushant P. Sahu, Lawrence P. Fernando, Craig Szymanski and Jason McNeill pp 18410–18414 DOI: 10.1021/ja907228q Supporting Info |
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Loop and Backbone Modifications of Peptide Nucleic Acid Improve G-Quadruplex Binding Selectivity Sabrina Lusvarghi, Connor T. Murphy, Subhadeep Roy, Farial A. Tanious, Iulia Sacui, W. David Wilson, Danith H. Ly and Bruce A. Armitage pp 18415–18424 DOI: 10.1021/ja907250j Supporting Info |
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Metal- and Hydrogen-Bonding Competition during Water Adsorption on Pd(111) and Ru(0001) Mous Tatarkhanov, D. Frank Ogletree, Franck Rose, Toshiyuki Mitsui, Evgeny Fomin, Sabine Maier, Mark Rose, Jorge I. Cerd pp 18425–18434 DOI: 10.1021/ja907468m |
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Highly Birefringent Cyanoaurate Coordination Polymers: The Effect of Polarizable C−X Bonds (X = Cl, Br) Michael J. Katz and Daniel B. Leznoff pp 18435–18444 DOI: 10.1021/ja907519c Supporting Info |
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Pressure-Induced Insertion of Liquid Alcohols into Graphite Oxide Structure Alexandr V. Talyzin, Bertil Sundqvist, Tam pp 18445–18449 DOI: 10.1021/ja907492s Supporting Info |
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NMR Characterization of Membrane Protein−Detergent Micelle Solutions by Use of Microcoil Equipment Pawel Stanczak, Reto Horst, Pedro Serrano and Kurt W pp 18450–18456 DOI: 10.1021/ja907842u |
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Visible Light-Driven H2 Production by Hydrogenases Attached to Dye-Sensitized TiO2 Nanoparticles Erwin Reisner, Daniel J. Powell, Christine Cavazza, Juan C. Fontecilla-Camps and Fraser A. Armstrong pp 18457–18466 DOI: 10.1021/ja907923r Supporting Info |
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Chemoenzymatic Synthesis of GD3 Oligosaccharides and Other Disialyl Glycans Containing Natural and Non-natural Sialic Acids Hai Yu, Jiansong Cheng, Li Ding, Zahra Khedri, Yi Chen, Sharlene Chin, Kam Lau, Vinod Kumar Tiwari and Xi Chen pp 18467–18477 DOI: 10.1021/ja907750r Supporting Info |
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High-Throughput Screening To Identify Inhibitors Which Stabilize Inactive Kinase Conformations in p38α Jeffrey R. Simard, Christian Gr pp 18478–18488 DOI: 10.1021/ja907795q Supporting Info |
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The Ni(II)-Binding Properties of the Metallochaperone SlyD Harini Kaluarachchi, Duncan E. K. Sutherland, Alex Young, Ingrid J. Pickering, Martin J. Stillman and Deborah B. Zamble pp 18489–18500 DOI: 10.1021/ja9081765 Supporting Info |
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The Biochemical Basis for Stereochemical Control in Polyketide Biosynthesis Chiara R. Valenzano, Rachel J. Lawson, Alice Y. Chen, Chaitan Khosla and David E. Cane pp 18501–18511 DOI: 10.1021/ja908296m Supporting Info |
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Rattling in the Cage: Ions as Probes of Sub-picosecond Water Network Dynamics Diedrich A. Schmidt, pp 18512–18517 DOI: 10.1021/ja9083545 Supporting Info |
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Chemical Double Mutant Cycles for the Quantification of Cooperativity in H-Bonded Complexes Amaya Camara-Campos, Daniele Musumeci, Christopher A. Hunter and Simon Turega pp 18518–18524 DOI: 10.1021/ja9083495 Supporting Info |
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Efficient Synthesis of Narrowly Dispersed Brush Copolymers and Study of Their Assemblies: The Importance of Side Chain Arrangement Yan Xia, Bradley D. Olsen, Julia A. Kornfield and Robert H. Grubbs pp 18525–18532 DOI: 10.1021/ja908379q Supporting Info |
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Block Copolymers with a Twist Rong-Ming Ho, Yeo-Wan Chiang, Chun-Ku Chen, Hsin-Wei Wang, Hirokazu Hasegawa, Satoshi Akasaka, Edwin L. Thomas, Christian Burger and Benjamin S. Hsiao pp 18533–18542 DOI: 10.1021/ja9083804 Supporting Info |
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A General Strategy for Preparation of Pt 3d-Transition Metal (Co, Fe, Ni) Nanocubes Jun Zhang and Jiye Fang pp 18543–18547 DOI: 10.1021/ja908245r Supporting Info |
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Site-Specific Functionalization of Anisotropic Nanoparticles: From Colloidal Atoms to Colloidal Molecules Fan Li, Won Cheol Yoo, Molly B. Beernink and Andreas Stein pp 18548–18555 DOI: 10.1021/ja908364k Supporting Info |
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Hydrogen Exchange Rate of Tyrosine Hydroxyl Groups in Proteins As Studied by the Deuterium Isotope Effect on Cζ Chemical Shifts Mitsuhiro Takeda, JunGoo Jee, Akira Mei Ono, Tsutomu Terauchi and Masatsune Kainosho pp 18556–18562 DOI: 10.1021/ja907911y Supporting Info |
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Enzyme-Modulated DNA Translocation through a Nanopore Ajay S. Panwar and M. Muthukumar pp 18563–18570 DOI: 10.1021/ja904047q Supporting Info |
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Large Magnetization-Induced Second Harmonic Generation in an Enantiopure Chiral Magnet Cyrille Train, Tomohiro Nuida, Ruxandra Gheorghe, Michel Gruselle and Shin-ichi Ohkoshi p 18571 DOI: 10.1021/ja910113v |
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Targets in Heterocyclic Systems: Chemistry and Properties, Volume 12 (2008) p 18572 DOI: 10.1021/ja909790b |
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Name Reactions: A Collection of Detailed Mechanisms and Synthetic Applications, 4th ed. p 18572 DOI: 10.1021/ja9097912 |
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Encyclopedia of Chromatography, 3rd ed., Vols. I−III p 18572 DOI: 10.1021/ja9099467 |